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Organoseleno-Catalyzed Synthesis of α,β-Unsaturated α′-Alkoxy Ketones from Allenes Enabled by Se···O Interactions

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Organoselenium‐Catalyzed Regioselective C−H Pyridination of 1,3‐Dienes and Alkenes
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Applications of Selenonium Cations as Lewis Acids in Organocatalytic Reactions
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Probing the Formation of a Seleninic Acid in Living Cells by the Fluorescence Switching of a Glutathione Peroxidase Mimetic
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The Importance of 1,5‐Oxygen⋅⋅⋅Chalcogen Interactions in Enantioselective Isochalcogenourea Catalysis
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Straightforward Synthesis of ( R )‐(−)‐Kjellmanianone
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Controlled Rearrangement of Lactam‐Tethered Allenols with Brominating Reagents: A Combined Experimental and Theoretical Study on α‐ versus β‐Keto Lactam Formation
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Carbonyl Activation by Selenium‐ and Tellurium‐Based Chalcogen Bonding in a Michael Addition Reaction
inferredcites →https://doi.org/10.1002/chem.202000166openalex-snapshot
Gold Redox Catalysis with a Selenium Cation as a Mild Oxidant
inferredcites →https://doi.org/10.1002/ejoc.200400898openalex-snapshot
The RuO4‐Catalyzed Ketohydroxylation, Part II:A Regio‐, Chemo‐ and Stereoselectivity Study
inferredcites →https://doi.org/10.1002/ejoc.200900913openalex-snapshot
Highly Selective Synthesis of [( Z )‐3‐Chloro‐2‐(phenylselanyl)‐1‐alkenyl]phosphonates and 2‐Ethoxy‐4‐(phenylselanyl)‐2,5‐dihydro‐1,2‐oxaphosphole 2‐Oxides by Electrophilic Reaction of 1,2‐Alkadienylphosphonates with PhSeCl
inferredcites →https://doi.org/10.1016/j.tet.2006.02.053openalex-snapshot
Studies on electrophilic addition reaction of 2,3-allenoates with PhSeCl
inferredcites →https://doi.org/10.1016/j.tet.2009.04.023openalex-snapshot
Studies on highly regio- and stereoselective selenohydroxylation reaction of 1,2-allenyl phosphine oxides with PhSeCl
inferredcites →https://doi.org/10.1016/j.tet.2019.05.054openalex-snapshot
Organoselenium-catalyzed enantioselective syn-dichlorination of unbiased alkenes
inferredcites →https://doi.org/10.1016/s0040-4039(99)00953-3openalex-snapshot
Nucleophilic alkenoylation of aldehydes with metalated α-aminonitriles: regioselective synthesis of α-hydroxyenones
inferredcites →https://doi.org/10.1021/acscatal.7b01216openalex-snapshot
Oxidative Alkene Functionalizations via Selenium-π-Acid Catalysis
inferredcites →https://doi.org/10.1021/acscatal.7b03829openalex-snapshot
Organoselenium-Catalyzed Oxidative Allylic Fluorination with Electrophilic N–F Reagent
inferredcites →https://doi.org/10.1021/acscatal.8b01595openalex-snapshot
Selenium-π-Acid Catalyzed Oxidative Functionalization of Alkynes: Facile Access to Ynones and Multisubstituted Oxazoles
inferredcites →https://doi.org/10.1021/ja025906eopenalex-snapshot
A Chiral Acrylate Equivalent for Metal-Free Diels−Alder Reactions: endo-2-Acryloylisoborneol
inferredcites →https://doi.org/10.1021/ja100936wopenalex-snapshot
Revealing Noncovalent Interactions
inferredcites →https://doi.org/10.1021/ja9700515openalex-snapshot
Stereocontrolled Synthesis of a Nonracemic Vitamin B12 A−B-Semicorrin
inferredcites →https://doi.org/10.1021/jacs.6b01462openalex-snapshot
A Chiral Electrophilic Selenium Catalyst for Highly Enantioselective Oxidative Cyclization
inferredcites →https://doi.org/10.1021/jacs.9b03806openalex-snapshot
Chalcogen–Chalcogen Bonding Catalysis Enables Assembly of Discrete Molecules
inferredcites →https://doi.org/10.1021/jacs.9b11261openalex-snapshot
Catalytic, Enantioselective syn- Diamination of Alkenes
inferredcites →https://doi.org/10.1021/jacs.9b12610openalex-snapshot
Dual Chalcogen–Chalcogen Bonding Catalysis
inferredcites →https://doi.org/10.1021/jo00258a003openalex-snapshot
Fluoride ion-catalyzed reduction of aldehydes and ketones with hydrosilanes. Synthetic and mechanistic aspects and an application to the threo-directed reduction of .alpha.-substituted alkanones
inferredcites →https://doi.org/10.1021/jo048822sopenalex-snapshot
The RuO4-Catalyzed Ketohydroxylation. Part 1. Development, Scope, and Limitation
inferredcites →https://doi.org/10.1021/jo061680copenalex-snapshot
Electrophilic Interaction of 2,3-Allenoates with PhSeCl. An Unexpected Highly Stereoselective Synthesis of 3-Phenylseleno-4-oxo-2(E)-alkenoates
inferredcites →https://doi.org/10.1021/jo0618573openalex-snapshot
Two-Directional Elaboration of Hydroxyacetone under Thermodynamically Controlled Conditions: Allylation or 2-Propynylation and Aldol Reaction
inferredcites →https://doi.org/10.1021/jo202495zopenalex-snapshot
Ring Enlargement versus Selenoetherification on the Reaction of Allenyl Oxindoles with Selenenylating Reagents
inferredcites →https://doi.org/10.1021/jo301239popenalex-snapshot
Stereoselective Synthesis of Monofluoroalkyl α,β-Unsaturated Ketones From Allenyl Carbinol Esters Mediated by Gold and Selectfluor
inferredcites →https://doi.org/10.1021/jo972253popenalex-snapshot
A Novel Photoinduced Thioselenation of Allenes by Use of a Disulfide−Diselenide Binary System
inferredcites →https://doi.org/10.1021/np049883oopenalex-snapshot
Cucurbitane Triterpenoids from Leucopaxillus gentianeus
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Chromenes from the Brown Alga Sargassum siliquastrum
inferredcites →https://doi.org/10.1021/np970338fopenalex-snapshot
New Phomopsolides from a Penicillium sp.
inferredcites →https://doi.org/10.1021/ol0362663openalex-snapshot
Alkenes as Ketol Surrogates−A New Approach toward Enantiopure Acyloins
inferredcites →https://doi.org/10.1021/ol0621102openalex-snapshot
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inferredcites →https://doi.org/10.1021/ol200198zopenalex-snapshot
Highly Stereoselective Facile Synthesis of 2-Acetoxy-1,3(E)-alkadienes via a Rh(I)-Catalyzed Isomerization of 2,3-Allenyl Carboxylates
inferredcites →https://doi.org/10.1038/nchem.2141openalex-snapshot
Catalytic, stereospecific syn-dichlorination of alkenes
inferredcites →https://doi.org/10.1039/b508069jopenalex-snapshot
Efficient two-step synthesis of 3-halo-3-enals or 2-halo-2-alkenyl ketones from propargylic bromides via a unique cationic 1,2-aryl or proton shift in electrophilic addition reaction of 2,3-allenols with X+
inferredcites →https://doi.org/10.1039/c2cs35046gopenalex-snapshot
α-Hydroxy ketones as useful templates in asymmetric reactions
inferredcites →https://doi.org/10.1039/c4cc05414hopenalex-snapshot
Enantioselective iodolactonization of allenoic acids
inferredcites →https://doi.org/10.1039/c9qo00561gopenalex-snapshot
Oxidative selenofunctionalization of allenes: convenient access to 2-(phenylselanyl)-but-2-enals and 4-oxo-3-(phenylselanyl)pent-2-enoates
inferredcites →https://doi.org/10.1039/c9qo00620fopenalex-snapshot
Recent progress in selenium-catalyzed organic reactions
inferredcites →https://doi.org/10.1039/c9sc05335bopenalex-snapshot
Selenophosphoramide-catalyzed diamination and oxyamination of alkenes
inferredcites →https://doi.org/10.1039/d0cc01079kopenalex-snapshot
An organoselenium-catalyzed N 1 - and N 2 -selective aza-Wacker reaction of alkenes with benzotriazoles
inferredcites →https://doi.org/10.1055/s-0037-1609938openalex-snapshot
Aerobic Allylation of Alcohols with Non-Activated Alkenes Enabled by Light-Driven Selenium-π-Acid Catalysis
inferredcites →https://doi.org/10.1055/s-0039-1690109openalex-snapshot
Scalable Synthesis of a Chiral Selenium π-Acid Catalyst and Its Use in Enantioselective Iminolactonization of β,γ-Unsaturated Amides
inferredcites →https://doi.org/10.1351/pac200779020261openalex-snapshot
Control of regio- and stereoselectivity in electrophilic addition reactions of allenes
inferredcites →https://doi.org/10.3390/catal9020153openalex-snapshot
Rational Design of Chiral Selenium-π-Acid Catalysts
inferredcites →https://doi.org/10.3390/molecules22050835openalex-snapshot
Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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A Theoretical Study on Organoselenium-Catalyzed Exo-Selective Oxidative Ring-Closing Reaction Promoted by 3 Different N-F Oxidants: Active Catalytic Species Screening, Reaction Mechanism, Origin of Exo-/Endo- and (E)-/(Z)- Selectivities, and the Influence of Different Reagents on Reaction Yields
inferred← citeshttps://doi.org/10.1007/s11144-025-02949-2openalex-snapshot
A theoretical study of organoselenium-catalyzed oxidative ring-closing reaction: structure/selectivity/yield relationships
inferred← citeshttps://doi.org/10.1016/j.mcat.2024.114442openalex-snapshot
Both N-F oxidant and NaF determined reaction yield in the organoselenium-catalyzed oxidative ring-closing reaction of unsaturated alcohol: A theoretical study
inferred← citeshttps://doi.org/10.1021/acs.chemrev.0c00986openalex-snapshot
Deciphering the Chameleonic Chemistry of Allenols: Breaking the Taboo of a Onetime Esoteric Functionality
inferred← citeshttps://doi.org/10.1021/acs.joc.1c00167openalex-snapshot
Meyer–Schuster-Type Rearrangement of Propargylic Alcohols into α-Selenoenals and -enones with Diselenides
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02681openalex-snapshot
The Synthesis of α-Keto Acetals from Terminal Alkynes and Alcohols via Synergistic Interaction of Organoselenium Catalysis and Electrochemical Oxidation
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c01983openalex-snapshot
Electrochemical Organoselenium-Catalyzed Intermolecular Hydroazolylation of Alkenes with Low Catalyst Loadings
inferred← citeshttps://doi.org/10.1021/acscatal.4c01327openalex-snapshot
Intermolecular Aza-Wacker Coupling of Alkenes with Azoles by Photo-Aerobic Selenium-π-Acid Multicatalysis
inferred← citeshttps://doi.org/10.1039/d2cc01901aopenalex-snapshot
Electrochemical selenium–π–acid promoted hydration of alkynyl phosphonates
inferred← citeshttps://doi.org/10.1039/d3ob01116jopenalex-snapshot
Electrochemical selenium-catalyzed para -amination of N -aryloxyamides: access to polysubstituted aminophenols
inferred← citeshttps://doi.org/10.1055/a-2169-3807openalex-snapshot
Recent Advances in Electrochemically Mediated Reactions of Diselenides
inferred← citeshttps://doi.org/10.1246/cl.210065openalex-snapshot
Selenium-catalyzed Functionalization of Alkynes
inferred← citeshttps://doi.org/10.2139/ssrn.4968864openalex-snapshot
How Did Hypervalent Iodide Oxidant Species Influence Reaction Yield of Organoselenium-Catalzyed Oxidative Ring-Closing Reaction of (E)-4-Phenylbut-3-Enoic Acid? A Theoretical Study
inferred← citeshttps://doi.org/10.3390/molecules28186614openalex-snapshot
Recent Advances in the Use of Diorganyl Diselenides as Versatile Catalysts
inferred← citeshttps://doi.org/10.6023/cjoc202508009openalex-snapshot
Research Progress in Electrophilic Selenium-Catalyzed Rearrangement Reactions
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