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i-Pr2NMgCl·LiCl Enables the Synthesis of Ketones by Direct Addition of Grignard Reagents to Carboxylate Anions

https://doi.org/10.1021/acs.orglett.9b02899

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BuMgNiPr2: A New Base for Stoichiometric, Position-Selective Deprotonation of Cyclopropane Carboxamides and Other Weak CH Acids This work was supported in part by Eastman Chemical. We are grateful to Z. Hantosi and C.-H. Lee for trial experiments, to I. Steele for the X-ray analyses, and to…

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