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Toward Advanced High-Performance Insensitive FOX-7-like Energetic Materials via Positional Isomerization

https://doi.org/10.1021/acsami.2c15643
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Multiwfn: A multifunctional wavefunction analyzer
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CL‐20 performance exceeds that of HMX and its sensitivity is moderate
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5‐Amino‐3,4‐dinitropyrazole as a Promising Energetic Material
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A Review of Illuminating Pyrotechnics
inferredcites →https://doi.org/10.1016/j.cej.2020.124027openalex-snapshot
A simple and efficient method to synthesize high-nitrogen compounds: Incorporation of tetrazole derivatives with N5 chains
inferredcites →https://doi.org/10.1016/j.cej.2020.128148openalex-snapshot
1,2,3-Triazole with linear and branched catenated nitrogen chains – The role of regiochemistry in energetic materials
inferredcites →https://doi.org/10.1016/j.cej.2021.128990openalex-snapshot
Bilateral modification of FOX-7 towards an enhanced energetic compound with promising performances
inferredcites →https://doi.org/10.1016/j.cej.2021.132399openalex-snapshot
LiN5: A novel pentazolate salt with high nitrogen content
inferredcites →https://doi.org/10.1016/j.cej.2022.136539openalex-snapshot
Unraveling the direct effect of hydrogen bonding on density and thermostability of energetic materials through isomerism
inferredcites →https://doi.org/10.1016/j.cej.2022.136596openalex-snapshot
Assembling high nitrogen isomeric energetic molecules via a lithium-mediated concerted [2 + 3] reaction of two diazo compounds
inferredcites →https://doi.org/10.1016/j.eng.2020.01.013openalex-snapshot
Construction of an Unusual Two-Dimensional Layered Structure for Fused-Ring Energetic Materials with High Energy and Good Stability
inferredcites →https://doi.org/10.1016/j.enmf.2022.03.002openalex-snapshot
An unusual reaction of 1,1-diamino-2-nitro-2-(1H-triazol-5-yl)ethene and hydrazine: The synthesis of a dihydrotetrazine bridged energetic compound
inferredcites →https://doi.org/10.1016/j.mencom.2018.03.007openalex-snapshot
1-Amino-1-hydroxyamino-2,2-dinitroethene: novel insights in chemistry of FOX-7
inferredcites →https://doi.org/10.1016/s0040-4020(98)00711-xopenalex-snapshot
Synthesis of Polyazapolycyclic Caged Polynitramines
inferredcites →https://doi.org/10.1021/acsami.0c08526openalex-snapshot
Derivatives of 3,6-Bis(3-aminofurazan-4-ylamino)-1,2,4,5-tetrazine: Excellent Energetic Properties with Lower Sensitivities
inferredcites →https://doi.org/10.1021/ja01150a099openalex-snapshot
Cyclic and Linear Nitramines Formed by Nitrolysis of Hexamine1
inferredcites →https://doi.org/10.1021/jacs.0c01640openalex-snapshot
Enforced Planar FOX-7-like Molecules: A Strategy for Thermally Stable and Insensitive π-Conjugated Energetic Materials
inferredcites →https://doi.org/10.1021/jacs.1c05292openalex-snapshot
One Step Closer to an Ideal Insensitive Energetic Molecule: 3,5-Diamino-6-hydroxy-2-oxide-4-nitropyrimidone and its Derivatives
inferredcites →https://doi.org/10.1021/jacs.2c00995openalex-snapshot
Synthesis and Characterization of Binary, Highly Endothermic, and Extremely Sensitive 2,2′-Azobis(5-azidotetrazole)
inferredcites →https://doi.org/10.1021/jacs.6b03819openalex-snapshot
Energetic Salts Based on 3,5-Bis(dinitromethyl)-1,2,4-triazole Monoanion and Dianion: Controllable Preparation, Characterization, and High Performance
inferredcites →https://doi.org/10.1021/jacs.7b05158openalex-snapshot
Pushing the Limits of Oxygen Balance in 1,3,4-Oxadiazoles
inferredcites →https://doi.org/10.1021/jacs.9b06961openalex-snapshot
Impact of Stereo- and Regiochemistry on Energetic Materials
inferredcites →https://doi.org/10.1021/jacs.9b11326openalex-snapshot
Bis(3-nitro-1-(trinitromethyl)-1 H -1,2,4-triazol-5-yl)methanone: An Applicable and Very Dense Green Oxidizer
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A promising high-energy-density material
inferredcites →https://doi.org/10.1038/s41467-018-04897-zopenalex-snapshot
Accelerating the discovery of insensitive high-energy-density materials by a materials genome approach
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Hirshfeld surface analysis
inferredcites →https://doi.org/10.1039/c8ta09176eopenalex-snapshot
Desensitization of the dinitromethyl group: molecular/crystalline factors that affect the sensitivities of energetic materials
inferredcites →https://doi.org/10.1039/d0nj05152gopenalex-snapshot
Very thermostable energetic materials based on a fused-triazole: 3,6-diamino-1 H -[1,2,4]triazolo[4,3- b ][1,2,4]triazole
inferredcites →https://doi.org/10.1039/d0ta03008bopenalex-snapshot
Embellishing bis-1,2,4-triazole with four nitroamino groups: advanced high-energy-density materials with remarkable performance and good stability
inferredcites →https://doi.org/10.1039/d0ta03010dopenalex-snapshot
A promising hydrogen peroxide adduct of ammonium cyclopentazolate as a green propellant component
inferredcites →https://doi.org/10.1126/sciadv.abn3176openalex-snapshot
Full-nitro-nitroamino cooperative action: Climbing the energy peak of benzenes with enhanced chemical stability

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4782910openalex-extracted
One-Dimensional Copper-Based Energetic Coordination Polymers Applied to Heat-Resistant Primary Explosive
inferred← citeshttps://doi.org/10.1002/ejoc.70664openalex-snapshot
Functionalization of FOX‐7 Toward an Energetic Oxidizer With Enhanced Stability
inferred← citeshttps://doi.org/10.1002/prep.70129openalex-snapshot
Synthesis and Properties of [1,2,4]Triazolo[4,3‐b][1,2,4,5]Tetrazine and Their Salts: High‐nitrogen Materials for Solid Propellants
inferred← citeshttps://doi.org/10.1002/smtd.70683openalex-snapshot
In Situ Emulsion Crystallization Combined With Deep Potential Molecular Dynamics: Desensitization of Energetic Perovskite DAP‐4
inferred← citeshttps://doi.org/10.1016/j.cej.2023.141654openalex-snapshot
An advanced zwitterionic compound based on dinitropyrazole and 1,3,4-oxadiazole: Combining the high detonation performances and low sensitivities
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Exchanging of NH2/NHNH2/NHOH groups: An effective strategy for balancing the energy and safety of fused-ring energetic materials
inferred← citeshttps://doi.org/10.1016/j.chemphys.2024.112234openalex-snapshot
Pressure-induce structural changes of 1,1-diamino-2-nitro-2-(1-amino-1H-tetrazol-5-yl) ethene: An insensitive FOX-7-like energetic materials
inferred← citeshttps://doi.org/10.1016/j.combustflame.2024.113507openalex-snapshot
A positional isomer of LLM-116: N—NO2 moiety enhancing the laser ignition combustion performance of nitrogen-rich energetic materials
inferred← citeshttps://doi.org/10.1016/j.enmf.2024.02.004openalex-snapshot
Packing coefficient determining the packing density difference of CHON-containing isomers
inferred← citeshttps://doi.org/10.1016/j.enmf.2024.11.003openalex-snapshot
Vicinal combination of N—NH2 and C—NO2 benefitting for low sensitivity and high energy azole molecules: A strategy developed from isomerization
inferred← citeshttps://doi.org/10.1016/j.enmf.2024.12.001openalex-snapshot
Advancing thermal stability through positional pyrazole isomerization: Synthesis and characterization of 2’-(1H-pyrazol-4-yl)-1H,2’H-5,5’-bistetrazole and its energetic derivatives
inferred← citeshttps://doi.org/10.1016/j.enmf.2025.03.001openalex-snapshot
Understanding how molecular skeletal isomerism affects the stability of energetic fused-ring molecules: A comparative study of ICM-103 and NAPTO
inferred← citeshttps://doi.org/10.1016/j.enmf.2025.03.003openalex-snapshot
Polynitro 1,2,3-triazole energetic materials with excellent properties through the combination of hydrogen-rich cation and N-amino group
inferred← citeshttps://doi.org/10.1016/j.enmf.2025.03.007openalex-snapshot
The effects of isomer ligands on characteristics of novel structural energetic coordination compounds
inferred← citeshttps://doi.org/10.1016/j.fpc.2022.11.004openalex-snapshot
Synthesis, characterization and properties of halogen-substituted 1,1-diamino-2-nitro-2-(1-amino-1H-tetrazol-5-yl) ethene derivatives as energetic materials
inferred← citeshttps://doi.org/10.1016/j.fpc.2025.12.001openalex-snapshot
Impact of explosophoric group isomerism on fine-tuning of energetic compounds: Isomeric N2O2CH3 groups as a key structural motif
inferred← citeshttps://doi.org/10.1016/j.fpc.2026.07.003openalex-snapshot
An influence of intra- and intermolecular hydrogen bonding on crystal structure stability and density: Dance of amino and nitro groups around the pyrazole ring
inferred← citeshttps://doi.org/10.1016/j.fsisyn.2026.100700openalex-snapshot
Detection and characterization of explosives and explosives residues: a review 2022-2025
inferred← citeshttps://doi.org/10.1016/j.inoche.2025.115864openalex-snapshot
Design and synthesis of a RAHBs-stabilized N-amino energetic coordination compound for enhanced detonation and laser initiation
inferred← citeshttps://doi.org/10.1016/j.molstruc.2024.139539openalex-snapshot
One-dimensional copper-based energetic coordination polymers applied to heat-resistant primary explosive based on 4-hydroxy-3,5-dinitropyrazole
inferred← citeshttps://doi.org/10.1016/j.mtcomm.2024.109759openalex-snapshot
Density functional theory (DFT) study on the structures and energy properties of high energy density materials based on polynitroazofurazan derivatives
inferred← citeshttps://doi.org/10.1016/j.proci.2026.106241openalex-snapshot
Ab initio and SVUV-PIMS study of FOX-7 pyrolysis in the gas-phase: Mechanism development and kinetic analysis
inferred← citeshttps://doi.org/10.1021/acs.cgd.2c01268openalex-snapshot
Bicyclic High-Energy and Low-Sensitivity Regioisomeric Energetic Compounds Based on Polynitrobenzene and Pyrazoles
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c02755openalex-snapshot
Regulating the Coordination Environment by Using Isomeric Ligands: Enhancing the Energy and Sensitivity of Energetic Coordination Compounds
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c04842openalex-snapshot
Balancing the Energy and Sensitivity of Primary Explosives: Using Isomers to Prepare Energetic Coordination Compounds
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Controlling the Energetic Properties of N -Methylene-C-Linked 4-Hydroxy-3,5-dinitropyrazole- and Tetrazole-Based Compounds via a Selective Mono- and Dicationic Salt Formation Strategy
inferred← citeshttps://doi.org/10.1021/acs.joc.4c01771openalex-snapshot
Polynitro-1,2,4-triazole Energetic Materials with N-Amino Functionalization
inferred← citeshttps://doi.org/10.1021/acs.joc.4c02287openalex-snapshot
Adjusting the Coordination Configuration by Changing Electrostatic Potential: Introducing N/O/S Heteroatoms Based on the Electronic Effect
inferred← citeshttps://doi.org/10.1021/acs.jpcc.3c04039openalex-snapshot
From Concept to Synthesis: Developing Heat-Resistant High Explosives through Automated High-Throughput Virtual Screening
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A Dihydrazone as a Remarkably Nitrogen-Rich Thermostable and Insensitive Energetic Material
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Single Step Synthesis of gem -Dinitro Methyl-1,2,4-triazole and Its Hydroxylamine Salt: An Alternative to the FOX-7 and Other Benchmark Explosives
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c01870openalex-snapshot
Understanding the Stability of Highly Nitrated Sensitive Pyrazole Isomers
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c03691openalex-snapshot
Synthesis of 4-Amino-5-nitro-7H-pyrazolo[3,4-d][1,2,3]triazine-2-oxide and Its Heat-Resistant Derivatives
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Reactivity Investigation of Bis-Tetrazole Isomers Prepared through Dimroth Rearrangement
inferred← citeshttps://doi.org/10.1021/acsami.4c10299openalex-snapshot
Solvent Vapor/Gas-Induced Guest Transport and Exchange of a Nonporous Organic Crystal to Construct Smart Host–Guest Energetic Materials
inferred← citeshttps://doi.org/10.1021/acsami.4c16858openalex-snapshot
Skeletal Editing of Energetic Materials: Acid-Catalyzed One-Step Synthesis of Bridged Triazoles as High-Energy-Density Materials via the Nef Reaction
inferred← citeshttps://doi.org/10.1021/acsami.6c14655openalex-snapshot
Two-Step Access to High-Energy Materials via Intrinsic Fuel–Oxidizer Design
inferred← citeshttps://doi.org/10.1039/d3ce01234dopenalex-snapshot
A desirable coplanar energetic pentazolate salt driven by hydrogen bonds
inferred← citeshttps://doi.org/10.1039/d3cp02121aopenalex-snapshot
Thermal stability of azole-rich energetic compounds: their structure, density, enthalpy of formation and energetic properties
inferred← citeshttps://doi.org/10.1039/d3dt01416aopenalex-snapshot
Triazole-induced planarization of a twisted tetrazole-based molecule towards energetic materials with improved thermostability and insensitivity
inferred← citeshttps://doi.org/10.1039/d3dt04237eopenalex-snapshot
Obtaining superior high-density fused-ring energetic materials via the introduction of carbonyl, o -NH 2 –NO 2 and nitroamino groups
inferred← citeshttps://doi.org/10.1039/d3nj02968aopenalex-snapshot
Touching the density limits of energetic materials by molecular design
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Energetic bi-diazole ‘transformers’ toward high-energy thermostable energetic compounds
inferred← citeshttps://doi.org/10.1039/d4nj01262copenalex-snapshot
Computational insight into the reactivity of FOX-7 and its bridge-ring energetic derivatives from Diels–Alder reactions
inferred← citeshttps://doi.org/10.1039/d4qm01120aopenalex-snapshot
Skeletal editing of pyrimidines: new approaches to diverse high energy density materials
inferred← citeshttps://doi.org/10.1039/d5cc01332aopenalex-snapshot
Revisiting the sensitive nature of H-FOX: interplay of nitro and hydrazine functionalities to construct an insensitive energetic material
inferred← citeshttps://doi.org/10.1039/d5dt00730eopenalex-snapshot
Exploring new frontiers: alliance of pyrazole and thiadiazole in energetic materials
inferred← citeshttps://doi.org/10.1039/d6ce00547kopenalex-snapshot
Effect of positional isomerism on the properties of highly nitrated triazoles: a comparative study based on 5-nitro-3-trinitromethyl-1 H -1,2,4-triazole (NTNF) and its isomer
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Extreme oxygen-rich functionalization of pyrazine via bis(trinitromethyl) substitution
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Isomerism in energetic materials: where structure defines performance
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