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Dual-Site-Mediated Hydrogenation Catalysis on Pd/NiO: Selective Biomass Transformation and Maintenance of Catalytic Activity at Low Pd Loading

https://doi.org/10.1021/acscatal.0c00414
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/anie.200604274openalex-snapshot
Liquid‐Phase Catalytic Processing of Biomass‐Derived Oxygenated Hydrocarbons to Fuels and Chemicals
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Au on Nanosized NiO: A Cooperative Effect between Au and Nanosized NiO in the Base‐Free Alcohol Oxidation
inferredcites →https://doi.org/10.1002/cctc.201200100openalex-snapshot
How to Control the Selectivity of Palladium‐based Catalysts in Hydrogenation Reactions: The Role of Subsurface Chemistry
inferredcites →https://doi.org/10.1002/cctc.201200218openalex-snapshot
Total Hydrogenation of Furfural over a Silica‐Supported Nickel Catalyst Prepared by the Reduction of a Nickel Nitrate Precursor
inferredcites →https://doi.org/10.1002/qua.24521openalex-snapshot
Hubbard-corrected DFT energy functionals: The LDA+U description of correlated systems
inferredcites →https://doi.org/10.1007/s10562-011-0581-7openalex-snapshot
Hydrodeoxygenation of Furfural Over Supported Metal Catalysts: A Comparative Study of Cu, Pd and Ni
inferredcites →https://doi.org/10.1007/s11144-012-0530-5openalex-snapshot
Pd-containing catalysts promoted by NiO designed for the reduction of NO with CO at stoichiometric NO/CO ratio
inferredcites →https://doi.org/10.1016/0021-9517(74)90081-5openalex-snapshot
Infrared spectra of carbon monoxide adsorbed on supported palladium and palladium-silver alloys
inferredcites →https://doi.org/10.1016/j.jcat.2010.10.005openalex-snapshot
Kinetics and mechanism of hydrogenation of furfural on Cu/SiO2 catalysts
inferredcites →https://doi.org/10.1016/j.jcat.2011.02.006openalex-snapshot
Conversion of furfural and 2-methylpentanal on Pd/SiO2 and Pd–Cu/SiO2 catalysts
inferredcites →https://doi.org/10.1016/j.jtice.2017.02.012openalex-snapshot
Tuning/exploiting Strong Metal-Support Interaction (SMSI) in Heterogeneous Catalysis
inferredcites →https://doi.org/10.1016/j.rser.2014.07.003openalex-snapshot
Production, properties and catalytic hydrogenation of furfural to fuel additives and value-added chemicals
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A DFT+U description of oxygen vacancies at the TiO2 rutile (110) surface
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Effects of van der Waals density functional corrections on trends in furfural adsorption and hydrogenation on close-packed transition metal surfaces
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Characterization of oxide surfaces and zeolites by carbon monoxide as an IR probe molecule
inferredcites →https://doi.org/10.1021/acscatal.5b00754openalex-snapshot
Tailoring Gold Nanoparticle Characteristics and the Impact on Aqueous-Phase Oxidation of Glycerol
inferredcites →https://doi.org/10.1021/acscatal.6b01838openalex-snapshot
Furfural: A Promising Platform Compound for Sustainable Production of C 4 and C 5 Chemicals
inferredcites →https://doi.org/10.1021/acscatal.6b03190openalex-snapshot
Tandem Site- and Size-Controlled Pd Nanoparticles for the Directed Hydrogenation of Furfural
inferredcites →https://doi.org/10.1021/acscatal.7b01095openalex-snapshot
Support Induced Control of Surface Composition in Cu–Ni/TiO2 Catalysts Enables High Yield Co-Conversion of HMF and Furfural to Methylated Furans
inferredcites →https://doi.org/10.1021/acscatal.9b00238openalex-snapshot
A Control over Hydrogenation Selectivity of Furfural via Tuning Exposed Facet of Ni Catalysts
inferredcites →https://doi.org/10.1021/ar500029yopenalex-snapshot
Controlling the Surface Environment of Heterogeneous Catalysts Using Self-Assembled Monolayers
inferredcites →https://doi.org/10.1021/cr068360dopenalex-snapshot
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
inferredcites →https://doi.org/10.1021/cr4002269openalex-snapshot
Conversion of Biomass into Chemicals over Metal Catalysts
inferredcites →https://doi.org/10.1021/cs300395aopenalex-snapshot
DFT Study of Furfural Conversion to Furan, Furfuryl Alcohol, and 2-Methylfuran on Pd(111)
inferredcites →https://doi.org/10.1021/cs400616popenalex-snapshot
Catalytic Reduction of Biomass-Derived Furanic Compounds with Hydrogen
inferredcites →https://doi.org/10.1021/cs500598yopenalex-snapshot
Effects of Thiol Modifiers on the Kinetics of Furfural Hydrogenation over Pd Catalysts
inferredcites →https://doi.org/10.1021/cs5015145openalex-snapshot
Coverage-Induced Conformational Effects on Activity and Selectivity: Hydrogenation and Decarbonylation of Furfural on Pd(111)
inferredcites →https://doi.org/10.1021/ja302070kopenalex-snapshot
A New Type of Strong Metal–Support Interaction and the Production of H2 through the Transformation of Water on Pt/CeO2(111) and Pt/CeOx/TiO2(110) Catalysts
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Furfuraldehyde Hydrogenation on Titanium Oxide-Supported Platinum Nanoparticles Studied by Sum Frequency Generation Vibrational Spectroscopy: Acid–Base Catalysis Explains the Molecular Origin of Strong Metal–Support Interactions
inferredcites →https://doi.org/10.1023/a:1019090520407openalex-snapshot
Furfural hydrogenation over carbon‐supported copper
inferredcites →https://doi.org/10.1038/ncomms3448openalex-snapshot
Directing reaction pathways by catalyst active-site selection using self-assembled monolayers
inferredcites →https://doi.org/10.1038/s41929-018-0213-3openalex-snapshot
Structural selectivity of supported Pd nanoparticles for catalytic NH3 oxidation resolved using combined operando spectroscopy
inferredcites →https://doi.org/10.1039/b823504jopenalex-snapshot
Preparation, structure, and stability of Pt and Pd monolayer modified Pd and Pt electrocatalysts
inferredcites →https://doi.org/10.1039/c2cy20235bopenalex-snapshot
Advances in conversion of hemicellulosic biomass to furfural and upgrading to biofuels
inferredcites →https://doi.org/10.1039/c4cy00184bopenalex-snapshot
Conversion of furfuryl alcohol into 2-methylfuran at room temperature using Pd/TiO 2 catalyst
inferredcites →https://doi.org/10.1039/c6ra13374fopenalex-snapshot
Low temperature hydrogenation of α-angelica lactone on silica supported Pd–NiO catalysts with synergistic effect
inferredcites →https://doi.org/10.1039/c7fd00039aopenalex-snapshot
Selective production of mono-aromatics from lignocellulose over Pd/C catalyst: the influence of acid co-catalysts
inferredcites →https://doi.org/10.1039/c8cy02536copenalex-snapshot
Hierarchically constructed NiO with improved performance for catalytic transfer hydrogenation of biomass-derived aldehydes
inferredcites →https://doi.org/10.1039/c9cp05476fopenalex-snapshot
A DFT and KMC based study on the mechanism of the water gas shift reaction on the Pd(100) surface
inferredcites →https://doi.org/10.1063/1.2101487openalex-snapshot
The application of infrared spectroscopy to probe the surface morphology of alumina-supported palladium catalysts
inferredcites →https://doi.org/10.1063/1.3382344openalex-snapshot
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
inferredcites →https://doi.org/10.1103/physrevb.46.16067openalex-snapshot
Adsorbate-substrate and adsorbate-adsorbate interactions of Na and K adlayers on Al(111)
inferredcites →https://doi.org/10.1103/physrevb.47.4873openalex-snapshot
Temperature dependence of the PdK-edge extended x-ray-absorption fine structure of PdCx (x∼0.13)
inferredcites →https://doi.org/10.1103/physrevb.47.558openalex-snapshot
Ab initio molecular dynamics for liquid metals
inferredcites →https://doi.org/10.1103/physrevb.48.666openalex-snapshot
Erratum: Temperature dependence of the Pd K -edge extended x-ray-absorption fine structure of PdCx ( x∼0.13 )
inferredcites →https://doi.org/10.1103/physrevb.49.14251openalex-snapshot
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
inferredcites →https://doi.org/10.1103/physrevb.50.17953openalex-snapshot
Projector augmented-wave method
inferredcites →https://doi.org/10.1103/physrevb.51.4014openalex-snapshot
Periodic boundary conditions in ab initio calculations
inferredcites →https://doi.org/10.1103/physrevb.54.11169openalex-snapshot
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
inferredcites →https://doi.org/10.1103/physrevlett.77.3865openalex-snapshot
Generalized Gradient Approximation Made Simple
inferredcites →https://doi.org/10.1107/s0909049500016964openalex-snapshot
IFEFFIT : interactive XAFS analysis and FEFF fitting
inferredcites →https://doi.org/10.1107/s0909049505012719openalex-snapshot
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
inferredcites →https://doi.org/10.1116/1.579146openalex-snapshot
Infrared study of CO on NiO(100)
inferredcites →https://doi.org/10.1126/science.211.4487.1121openalex-snapshot
Strong Interactions in Supported-Metal Catalysts
inferredcites →https://doi.org/10.3390/app8071159openalex-snapshot
Understanding Heteroatom-Mediated Metal–Support Interactions in Functionalized Carbons: A Perspective Review

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Nanoscale Intimacy in Hierarchical Catalytic Structures for Mediating Furfural Hydroconversion Over Pd/Co3o4/Sio2
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Catalytic Activity of Ti‐based MXenes for the Hydrogenation of Furfural
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Controlling the Production of Acid Catalyzed Products of Furfural Hydrogenation by Pd/TiO 2
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Capping Agent, Solvent, and Nanoparticle Interactions: Driving Selectivity for Biomass Transformations
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Realizing Influence of Supports in Aqueous‐Phase Hydrogenation of Furfural over Nickel Catalysts
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Hydrogen Spillover‐Enhanced Heterogeneously Catalyzed Hydrodeoxygenation for Biomass Upgrading
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Supporting Nano Catalysts for the Selective Hydrogenation of Biomass‐derived Compounds
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Defective N‐Doped Carbon Nanospheres Anchored Pd for Selective Hydrodeoxygenation of Bio‐Models under Mild Conditions
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Selective Hydrogenation of Furfural: Pure Silica Supported Metal Catalysts
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Comparative study on the reaction mechanism of 5-hydroxymethyl furfural on Pd(111) and Cu(111)
inferred← citeshttps://doi.org/10.1007/s10934-022-01269-3openalex-snapshot
Pd@silicate-1 synthesized by steam-assisted-crystallization strategy for high-efficient catalytic hydrogenation of furfural
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Supported Pd–B alloy mesoporous nanospheres as efficient catalysts for nitrobenzene hydrogenation
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inferred← citeshttps://doi.org/10.1016/j.apcata.2025.120612openalex-snapshot
Specific insights on the synergistic role of metal and acid sites of low loading Pd(PVA)/zeolite catalysts for furfural hydrogenation
inferred← citeshttps://doi.org/10.1016/j.apcatb.2021.120120openalex-snapshot
RuO2–Ru/Hβ zeolite catalyst for high-yield direct conversion of xylose to tetrahydrofurfuryl alcohol
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Construction of Pd nanoparticles/two-dimensional Co-MOF nanosheets heterojunction for enhanced electrocatalytic hydrodechlorination
inferred← citeshttps://doi.org/10.1016/j.apcatb.2023.123191openalex-snapshot
Synergy between Ni3Sn2 alloy and Lewis acidic ReOx enables selectivity control of furfural hydrogenation to cyclopentanone
inferred← citeshttps://doi.org/10.1016/j.apcatb.2023.123501openalex-snapshot
Highly-dispersed surface NiO species and exposed Ni (200) facets facilitating activation of furan ring for high-efficiency total hydrogenation of furfural
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High-selectivity demethoxylation of lignin alkylmethoxyphenols enhanced by hydrogen spillover on Ag/Fe-CoOx nanocatalyst
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Effects of alloying palladium with gold in furfural hydrogenation:An in situ ATR-IR spectroscopy and density functional theory study
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Two-dimensional MXenes as catalytic “flying carpets” to transport biomass valorization towards new horizons: The case of furfural catalytic transfer hydrogenation over noble-metal free niobium-based carbides
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Electrocatalytic furfural oxidation to furoic acid: mechanistic insights, advanced catalysts design and characterization, and future perspectives
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Recent advances in 2-methylfuran production via catalytic transfer hydrogenation of biomass-derived furfural
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Ba2+ doping into Ni/Al2O3 nanofibers promotes CO2 methanation via alkaline modulation
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Current advances in furfural reduction to furfuryl alcohol via thermal- and electrocatalysis
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Synergy of metallic Cu and Cu3N species as dual active sites for enhanced hydrogenation catalysis
inferred← citeshttps://doi.org/10.1016/j.cej.2026.180408openalex-snapshot
Engineering MoOₓ-based catalysts and reaction conditions to balance deoxygenation and hydrogenation in glycerol conversion for stable propylene production
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Synergistic interaction of Co0 species with surface oxygen vacancies in CoCu Al catalysts for the liquid-phase hydrogenation of furfural to 2-methylfuran
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Binary CuO/TiO2 nanocomposites as high-performance catalysts for tandem hydrogenation of nitroaromatics
inferred← citeshttps://doi.org/10.1016/j.fuel.2021.123074openalex-snapshot
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Low-Palladium-Content Iron(III) Nanocatalyst Supported on Zeolite-NaY for C–Cl Bond Activation
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Size Sensitivity of Supported Palladium Species on Layered Double Hydroxides for the Electro-oxidation Dehydrogenation of Hydrazine: From Nanoparticles to Nanoclusters and Single Atoms
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Oxygen Vacancy-Reinforced Water-Assisted Proton Hopping for Enhanced Catalytic Hydrogenation
inferred← citeshttps://doi.org/10.1021/acscatal.3c01217openalex-snapshot
Surface Synergetic Effects of Ni–ReOx for Promoting the Mild Hydrogenation of Furfural to Tetrahydrofurfuryl Alcohol
inferred← citeshttps://doi.org/10.1021/acscatal.6c04274openalex-snapshot
Local Hydrogen Field Engineering in Ni-Based Catalysts for Low-Temperature Aromatic Hydrogenation
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Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3
inferred← citeshttps://doi.org/10.1039/d0cp04139dopenalex-snapshot
Recent progress in use and observation of surface hydrogen migration over metal oxides
inferred← citeshttps://doi.org/10.1039/d0cp05752eopenalex-snapshot
Theoretical prediction by DFT and experimental observation of heterocation-doping effects on hydrogen adsorption and migration over the CeO 2 (111) surface
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Consecutive methane activation mediated by single metal boride cluster anions NbB 4 −
inferred← citeshttps://doi.org/10.1039/d1nr04962copenalex-snapshot
Dual-site electrocatalytic nitrate reduction to ammonia on oxygen vacancy-enriched and Pd-decorated MnO 2 nanosheets
inferred← citeshttps://doi.org/10.1039/d2cy01599dopenalex-snapshot
Facile synthesis of a high-efficiency NiFe bimetallic catalyst without pre-reduction for the selective hydrogenation reaction of furfural
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Wood-inspired high-efficiency bioreactors with hierarchical porous structures for continuous flow reactions
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Synthesis of Quasi-MOFs featuring special hub-and-spoke channels and surface NiO species for enhanced total hydrogenation of furfural
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Bicomponent CuO/NiCo 2 O 4 nanocomposites for the dehydrogenation of ammonia borane and the tandem hydrogenation of halogenated nitroaromatics
inferred← citeshttps://doi.org/10.1039/d4cy01190bopenalex-snapshot
Reduction behavior of PdO–NiO/SiO 2 : how Pd location affects cinnamaldehyde hydrogenation
inferred← citeshttps://doi.org/10.1039/d4ey00044gopenalex-snapshot
Structural selectivity of supported Pd nanoparticles: selective ethanol ammoxidation to acetonitrile
inferred← citeshttps://doi.org/10.1039/d4sc07375dopenalex-snapshot
Effects of oxygen vacancies on hydrogenation efficiency by spillover in catalysts
inferred← citeshttps://doi.org/10.1039/d6nj01286hopenalex-snapshot
Boosting cyclopentanone selective production via tuning the electron effect between Pt and NiO in MCM-41 catalysts from furfural hydrogenation rearrangement
inferred← citeshttps://doi.org/10.1039/d6nr01841fopenalex-snapshot
Efficient transfer hydrogenation of furfural via F doping in mesoporous ZrO 2
inferred← citeshttps://doi.org/10.1088/2053-1591/adc170openalex-snapshot
One-step depolymerization of calcium lignosulfonate to produce phenolics with the action of solid base oxides
inferred← citeshttps://doi.org/10.1098/rsos.211516openalex-snapshot
A comparative study on the stability of the furfural molecule on the low index Ni, Pd and Pt surfaces
inferred← citeshttps://doi.org/10.3389/fchem.2022.966270openalex-snapshot
A novel and highly efficient Zr-containing catalyst supported by biomass-derived sodium carboxymethyl cellulose for hydrogenation of furfural
inferred← citeshttps://doi.org/10.3390/catal14020119openalex-snapshot
Hydrogen Production from Hydrous Hydrazine Decomposition Using Ir Catalysts: Effect of the Preparation Method and the Support
inferred← citeshttps://doi.org/10.3390/catal14110781openalex-snapshot
Depolymerization of Lignosulfonate Catalyzed by Different Solid Base Oxides to Prepare Phenolic Compounds
inferred← citeshttps://doi.org/10.3390/catal15020193openalex-snapshot
Theoretical Insight into the Mechanism and Descriptor for Hydrogen Spillover on the Pt/CeO2(111) Surface with Different Pt Coverages
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