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MAPO-18 Catalysts for the Methanol to Olefins Process: Influence of Catalyst Acidity in a High-Pressure Syngas (CO and H 2 ) Environment
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1002/adma.201902181openalex-snapshot
Recent Progress in Methanol‐to‐Olefins (MTO) Catalysts
inferredcites →https://doi.org/10.1002/ange.201511678openalex-snapshot
Formation Mechanism of the First Carbon–Carbon Bond and the First Olefin in the Methanol Conversion into Hydrocarbons
inferredcites →https://doi.org/10.1002/ange.201601208openalex-snapshot
Direct and Highly Selective Conversion of Synthesis Gas into Lower Olefins: Design of a Bifunctional Catalyst Combining Methanol Synthesis and Carbon–Carbon Coupling
inferredcites →https://doi.org/10.1002/ange.201803279openalex-snapshot
Bridging the Gap between the Direct and Hydrocarbon Pool Mechanisms of the Methanol‐to‐Hydrocarbons Process
inferredcites →https://doi.org/10.1002/ange.201807814openalex-snapshot
Coupling of Methanol and Carbon Monoxide over H‐ZSM‐5 to Form Aromatics
inferredcites →https://doi.org/10.1002/anie.201103657openalex-snapshot
Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity
inferredcites →https://doi.org/10.1002/anie.201511678openalex-snapshot
Formation Mechanism of the First Carbon–Carbon Bond and the First Olefin in the Methanol Conversion into Hydrocarbons
inferredcites →https://doi.org/10.1002/anie.201601208openalex-snapshot
Direct and Highly Selective Conversion of Synthesis Gas into Lower Olefins: Design of a Bifunctional Catalyst Combining Methanol Synthesis and Carbon–Carbon Coupling
inferredcites →https://doi.org/10.1002/anie.201803279openalex-snapshot
Bridging the Gap between the Direct and Hydrocarbon Pool Mechanisms of the Methanol‐to‐Hydrocarbons Process
inferredcites →https://doi.org/10.1002/anie.201807814openalex-snapshot
Coupling of Methanol and Carbon Monoxide over H‐ZSM‐5 to Form Aromatics
inferredcites →https://doi.org/10.1002/anie.202007609openalex-snapshot
Impact of Zeolite Framework Composition and Flexibility on Methanol‐To‐Olefins Selectivity: Confinement or Diffusion?
inferredcites →https://doi.org/10.1002/chem.201002624openalex-snapshot
Coke Formation during the Methanol‐to‐Olefin Conversion: In Situ Microspectroscopy on Individual H‐ZSM‐5 Crystals with Different Brønsted Acidity
inferredcites →https://doi.org/10.1002/cphc.201701024openalex-snapshot
A Systematic Study of Isomorphically Substituted H‐MAlPO‐5 Materials for the Methanol‐to‐Hydrocarbons Reaction
inferredcites →https://doi.org/10.1007/s10562-018-2330-7openalex-snapshot
Theoretical Insights into the Effect of the Framework on the Initiation Mechanism of the MTO Process
inferredcites →https://doi.org/10.1016/0304-5102(93)e0206-vopenalex-snapshot
Cracking of n-hexane and n-butane over SAPO5, MgAPO5 and CoAPO5
inferredcites →https://doi.org/10.1016/0926-860x(96)00118-4openalex-snapshot
Synthesis, characterization and catalytic testing of SAPO-18, MgAPO-18, and ZnAPO-18 in the MTO reaction
inferredcites →https://doi.org/10.1016/j.jcat.2006.09.020openalex-snapshot
Site requirements and elementary steps in dimethyl ether carbonylation catalyzed by acidic zeolites
inferredcites →https://doi.org/10.1016/j.jcat.2009.03.009openalex-snapshot
Product shape selectivity dominates the Methanol-to-Olefins (MTO) reaction over H-SAPO-34 catalysts
inferredcites →https://doi.org/10.1016/j.jcat.2013.09.005openalex-snapshot
Towards full one-pass conversion of carbon dioxide to methanol and methanol-derived products
inferredcites →https://doi.org/10.1016/j.jcat.2013.09.011openalex-snapshot
Acid strength controlled reaction pathways for the catalytic cracking of 1-butene to propene over ZSM-5
inferredcites →https://doi.org/10.1016/j.jcat.2015.03.013openalex-snapshot
Morphology-induced shape selectivity in zeolite catalysis
inferredcites →https://doi.org/10.1016/j.jcat.2017.05.008openalex-snapshot
Effect of framework topology of SAPO catalysts on selectivity and deactivation profile in the methanol-to-olefins reaction
inferredcites →https://doi.org/10.1016/j.jcat.2017.10.014openalex-snapshot
The critical role of methanol pressure in controlling its transfer dehydrogenation and the corresponding effect on propylene-to-ethylene ratio during methanol-to-hydrocarbons catalysis on H-ZSM-5
inferredcites →https://doi.org/10.1016/j.jcat.2020.03.020openalex-snapshot
A temporal analysis of products (TAP) study of C2-C4 alkene reactions with a well-defined pool of methylating species on ZSM-22 zeolite
inferredcites →https://doi.org/10.1016/j.jcat.2021.11.002openalex-snapshot
Acidity effect on benzene methylation kinetics over substituted H-MeAlPO-5 catalysts
inferredcites →https://doi.org/10.1016/j.micromeso.2007.09.026openalex-snapshot
The study of methanol-to-olefin over proton type aluminosilicate CHA zeolites
inferredcites →https://doi.org/10.1016/s0022-4596(03)00275-5openalex-snapshot
Modeling the framework stability and catalytic activity of pure and transition metal-doped zeotypes
inferredcites →https://doi.org/10.1016/s0144-2449(05)80167-8openalex-snapshot
The structure determination and rietveld refinement of the aluminophosphate AIPO4-18
inferredcites →https://doi.org/10.1016/s1387-1811(98)00319-9openalex-snapshot
Methanol-to-hydrocarbons: catalytic materials and their behavior
inferredcites →https://doi.org/10.1016/s1387-1811(98)00325-4openalex-snapshot
The characteristics of SAPO-34 which influence the conversion of methanol to light olefins
inferredcites →https://doi.org/10.1016/s1387-1811(98)00330-8openalex-snapshot
Structural and chemical influences on the MTO reaction: a comparison of chabazite and SAPO-34 as MTO catalysts
inferredcites →https://doi.org/10.1016/s1387-1811(98)00331-xopenalex-snapshot
The effect of crystal size of SAPO-34 on the selectivity and deactivation of the MTO reaction
inferredcites →https://doi.org/10.1021/acscatal.0c04011openalex-snapshot
Methanol-to-Olefins Catalysis on HSSZ-13 and HSAPO-34 and Its Relationship to Acid Strength
inferredcites →https://doi.org/10.1021/acscatal.5b00007openalex-snapshot
Methanol to Olefins (MTO): From Fundamentals to Commercialization
inferredcites →https://doi.org/10.1021/acscatal.5b02139openalex-snapshot
Insight into the Effect of Water on the Methanol-to-Olefins Conversion in H-SAPO-34 from Molecular Simulations and in Situ Microspectroscopy
inferredcites →https://doi.org/10.1021/acscatal.6b03677openalex-snapshot
Insights into the Activity and Deactivation of the Methanol-to-Olefins Process over Different Small-Pore Zeolites As Studied with Operando UV–vis Spectroscopy
inferredcites →https://doi.org/10.1021/acscatal.7b01643openalex-snapshot
Hydrogen Transfer versus Methylation: On the Genesis of Aromatics Formation in the Methanol-To-Hydrocarbons Reaction over H-ZSM-5
inferredcites →https://doi.org/10.1021/acscatal.7b03114openalex-snapshot
Unraveling the Mechanism of the Initiation Reaction of the Methanol to Olefins Process Using ab Initio and DFT Calculations
inferredcites →https://doi.org/10.1021/acscatal.8b03465openalex-snapshot
Understanding the Enhanced Lifetime of SAPO-34 in a Direct Syngas-to-Hydrocarbons Process
inferredcites →https://doi.org/10.1021/acscatal.8b03924openalex-snapshot
Significant Advances in C1 Catalysis: Highly Efficient Catalysts and Catalytic Reactions
inferredcites →https://doi.org/10.1021/acscatal.8b04402openalex-snapshot
Achieving a Superlong Lifetime in the Zeolite-Catalyzed MTO Reaction under High Pressure: Synergistic Effect of Hydrogen and Water
inferredcites →https://doi.org/10.1021/acscatal.9b00641openalex-snapshot
Role of Acetaldehyde in the Roadmap from Initial Carbon–Carbon Bonds to Hydrocarbons during Methanol Conversion
inferredcites →https://doi.org/10.1021/acscatal.9b00746openalex-snapshot
Cage-Defining Ring: A Molecular Sieve Structural Indicator for Light Olefin Product Distribution from the Methanol-to-Olefins Reaction
inferredcites →https://doi.org/10.1021/acscatal.9b00969openalex-snapshot
Mechanistic Basis for Effects of High-Pressure H2 Cofeeds on Methanol-to-Hydrocarbons Catalysis over Zeolites
inferredcites →https://doi.org/10.1021/acscatal.9b04529openalex-snapshot
Contrasting Arene, Alkene, Diene, and Formaldehyde Hydrogenation in H-ZSM-5, H-SSZ-13, and H-SAPO-34 Frameworks during MTO
inferredcites →https://doi.org/10.1021/ar200138nopenalex-snapshot
The Roles of Entropy and Enthalpy in Stabilizing Ion-Pairs at Transition States in Zeolite Acid Catalysis
inferredcites →https://doi.org/10.1021/cs3006583openalex-snapshot
Mechanism of the Catalytic Conversion of Methanol to Hydrocarbons
inferredcites →https://doi.org/10.1021/cs501967ropenalex-snapshot
Acid Strength Controlled Reaction Pathways for the Catalytic Cracking of 1-Pentene to Propene over ZSM-5
inferredcites →https://doi.org/10.1021/j100101a040openalex-snapshot
Bronsted, Lewis, and Redox Centers on CoAPO-18 Catalysts. 1. Vibrational Modes of Adsorbed Water
inferredcites →https://doi.org/10.1021/ja065810aopenalex-snapshot
Conversion of Methanol into Hydrocarbons over Zeolite H-ZSM-5: Ethene Formation Is Mechanistically Separated from the Formation of Higher Alkenes
inferredcites →https://doi.org/10.1021/jacs.6b09605openalex-snapshot
Hydrogen Transfer Pathways during Zeolite Catalyzed Methanol Conversion to Hydrocarbons
inferredcites →https://doi.org/10.1021/jacs.9b00585openalex-snapshot
Identification of the Reaction Sequence of the MTO Initiation Mechanism Using Ab Initio-Based Kinetics
inferredcites →https://doi.org/10.1021/jp027285hopenalex-snapshot
Computational Study of the Structural and Electronic Properties of Dopant Ions in Microporous AlPOs. 1. Acid Catalytic Activity of Divalent Metal Ions
inferredcites →https://doi.org/10.1021/jp066479kopenalex-snapshot
Density Functional for Spectroscopy: No Long-Range Self-Interaction Error, Good Performance for Rydberg and Charge-Transfer States, and Better Performance on Average than B3LYP for Ground States
inferredcites →https://doi.org/10.1021/jp970701ropenalex-snapshot
Interaction of Acetonitrile with Cobalt-Containing Aluminophosphates: An X-ray Absorption Investigation
inferredcites →https://doi.org/10.1023/a:1020514911456openalex-snapshot
A Simple, Inexpensive, and Reliable Method for Measuring Brønsted-Acid Site Densities in Solid Acids
inferredcites →https://doi.org/10.1038/s41467-019-13638-9openalex-snapshot
CO2 hydrogenation to high-value products via heterogeneous catalysis
inferredcites →https://doi.org/10.1038/s41467-020-17355-6openalex-snapshot
Imaging spatiotemporal evolution of molecules and active sites in zeolite catalyst during methanol-to-olefins reaction
inferredcites →https://doi.org/10.1038/s41557-018-0081-0openalex-snapshot
Structure–performance descriptors and the role of Lewis acidity in the methanol-to-propylene process
inferredcites →https://doi.org/10.1038/s41563-020-0800-yopenalex-snapshot
Insight into the effects of confined hydrocarbon species on the lifetime of methanol conversion catalysts
inferredcites →https://doi.org/10.1038/s41929-018-0078-5openalex-snapshot
Recent trends and fundamental insights in the methanol-to-hydrocarbons process
inferredcites →https://doi.org/10.1038/s41929-018-0104-7openalex-snapshot
Synthesis of reaction‐adapted zeolites as methanol-to-olefins catalysts with mimics of reaction intermediates as organic structure‐directing agents
inferredcites →https://doi.org/10.1038/s41929-018-0125-2openalex-snapshot
Lifetime improvement in methanol-to-olefins catalysis over chabazite materials by high-pressure H2 co-feeds
inferredcites →https://doi.org/10.1039/c39940000603openalex-snapshot
MAPO-18 (M ? Mg, Zn, Co): a new family of catalysts for the conversion of methanol to light olefins
inferredcites →https://doi.org/10.1039/c4cy00551aopenalex-snapshot
Elucidating the olefin formation mechanism in the methanol to olefin reaction over AlPO-18 and SAPO-18
inferredcites →https://doi.org/10.1039/c4cy01692kopenalex-snapshot
Transition-state scaling relations in zeolite catalysis: influence of framework topology and acid-site reactivity
inferredcites →https://doi.org/10.1039/c5cs00304kopenalex-snapshot
The formation and degradation of active species during methanol conversion over protonated zeotype catalysts
inferredcites →https://doi.org/10.1039/c5cy02298copenalex-snapshot
Improving the catalytic performance of SAPO-18 for the methanol-to-olefins (MTO) reaction by controlling the Si distribution and crystal size
inferredcites →https://doi.org/10.1039/c7cc09239copenalex-snapshot
Increasing the selectivity to ethylene in the MTO reaction by enhancing diffusion limitation in the shell layer of SAPO-34 catalyst
inferredcites →https://doi.org/10.1039/c8cs00502hopenalex-snapshot
New horizon in C1 chemistry: breaking the selectivity limitation in transformation of syngas and hydrogenation of CO 2 into hydrocarbon chemicals and fuels
inferredcites →https://doi.org/10.1039/ft9949003455openalex-snapshot
IR spectroscopic study of CD3CN adsorbed on ALPO-18 molecular sieve and the solid acid catalysts SAPO-18 and MeAPO-18
inferredcites →https://doi.org/10.1063/1.2370993openalex-snapshot
A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions
inferredcites →https://doi.org/10.1126/science.aaf1835openalex-snapshot
Selective conversion of syngas to light olefins
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
inferred← citeshttps://doi.org/10.1002/asia.202401387openalex-snapshot
Nano‐alloy Catalysts for Methanol Synthesis from CO2 Hydrogenation
inferred← citeshttps://doi.org/10.1002/chem.202204040openalex-snapshot
Co 2+ to Al 3+ Substitution Induced Dual‐Site Synergistic Catalysis to Friedel‐Crafts Alkylation Reactions
inferred← citeshttps://doi.org/10.1002/slct.202403823openalex-snapshot
Tuning CO2 Hydrogenation to Light Olefin Selectivity via Cu/Zn/Zr Supported on Modified SAPO‐34
inferred← citeshttps://doi.org/10.1007/s11144-022-02295-7openalex-snapshot
Grinding synthesis of SAPO-18 zeolite by a single/dual-template route: which is the best catalyst of methanol-to-olefins reaction?
inferred← citeshttps://doi.org/10.1007/s11426-024-2078-4openalex-snapshot
Recent progress in the deactivation mechanism of zeolite catalysts in methanol to olefins
inferred← citeshttps://doi.org/10.1016/j.apcata.2024.119799openalex-snapshot
One-pot CO2-to-olefins via methanol over In2O3-ZrO2/SAPO-34 catalysts mixtures with different spatial arrangements
inferred← citeshttps://doi.org/10.1016/j.apcata.2024.119982openalex-snapshot
Recent progress for boosting CO2 hydrogenation to light olefins
inferred← citeshttps://doi.org/10.1016/j.apcata.2025.120313openalex-snapshot
ZnO supported on zinc spinel structures enabling the direct conversion of CO2 to olefins when combined with acidic CHA catalysts
inferred← citeshttps://doi.org/10.1016/j.cej.2022.140867openalex-snapshot
The effects of CO co-feed on the catalytic performance of Methanol-to-Hydrocarbons conversion on HZSM-5
inferred← citeshttps://doi.org/10.1016/j.cej.2023.141401openalex-snapshot
Improved catalytic activity and stability of Cu/ZnO catalyst by boron oxide modification for low-temperature methanol synthesis
inferred← citeshttps://doi.org/10.1016/j.cej.2024.149045openalex-snapshot
Improving the propylene selectivity in the methanol-to-olefins reaction over CIT-17, a SAT-type molecular sieve
inferred← citeshttps://doi.org/10.1016/j.cej.2024.155783openalex-snapshot
Cu nanoparticles immobilized in mesopores generated in zeolite for high-performing CO2 hydrogenation to methanol
inferred← citeshttps://doi.org/10.1016/j.cej.2025.161114openalex-snapshot
Role of the external surface Brønsted acid of ZSM-5 in the suppressed side reaction of olefin hydrogenation during syngas conversion
inferred← citeshttps://doi.org/10.1016/j.checat.2022.05.012openalex-snapshot
Recent progress on MTO reaction mechanisms and regulation of acid site distribution in the zeolite framework
inferred← citeshttps://doi.org/10.1016/j.cjsc.2024.100412openalex-snapshot
A minireview to ketene chemistry in zeolite catalysis
inferred← citeshttps://doi.org/10.1016/j.fuel.2023.128298openalex-snapshot
Effect of water and methanol concentration in the feed on the deactivation of In2O3-ZrO2/SAPO-34 catalyst in the conversion of CO2/CO to olefins by hydrogenation
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Tailoring the acidity of ZSM-5 via surface passivation: Catalytic assessment on dimethyl ether to olefins (DTO) process
inferred← citeshttps://doi.org/10.1016/j.jcat.2022.07.035openalex-snapshot
Methanol-to-olefins catalysis on window-cage type zeolites/zeotypes with syngas co-feeds: Understanding syngas-to-olefins chemistry
inferred← citeshttps://doi.org/10.1016/j.jcat.2023.03.022openalex-snapshot
Metrics of performance relevant in methanol-to-hydrocarbons catalysis
inferred← citeshttps://doi.org/10.1016/j.jcat.2024.115911openalex-snapshot
Molecularly modified aluminum phosphates as support materials for Ru nanoparticles in selective hydrogenation
inferred← citeshttps://doi.org/10.1016/j.jcat.2024.115927openalex-snapshot
Role of coupling and zeolite acidity in the methanol-mediated CO2 conversion to olefins over ZnZrOx-AEI zeolite tandem catalysis
inferred← citeshttps://doi.org/10.1016/j.jcat.2025.116570openalex-snapshot
Recent advances of CO2 hydrogenation to C2+ hydrocarbons via methanol intermediate route
inferred← citeshttps://doi.org/10.1016/j.jechem.2026.08.092openalex-snapshot
Methanol bridges H2 storage/release with CO2-to-hydrocarbon chemicals
inferred← citeshttps://doi.org/10.1016/j.joei.2026.102473openalex-snapshot
Modulation of iron carbide phases and product distribution in Fischer-Tropsch to olefins via physical mixing of K-FeCx with zeolites
inferred← citeshttps://doi.org/10.1016/j.mcat.2023.113181openalex-snapshot
Combining hierarchization and Mg2+ ions insertion in ZSM-5: acidity-modulation effect on MTO reaction
inferred← citeshttps://doi.org/10.1016/j.micromeso.2024.113400openalex-snapshot
MAPO-5 molecular sieves from alkylimidazolium bromide ionic liquids
inferred← citeshttps://doi.org/10.1016/j.progpolymsci.2026.102087openalex-snapshot
Advanced polymer design and synthesis for high-performance membranes in water electrolysis
inferred← citeshttps://doi.org/10.1016/j.psep.2026.109383openalex-snapshot
Catalytic valorization of CO2: Dry reforming of methane, CO2-assisted alkane oxidative dehydrogenation, and CO2 hydrogenation toward a circular carbon economy
inferred← citeshttps://doi.org/10.1016/j.rser.2026.116911openalex-snapshot
Integrated and intensified bioprocesses for bioethanol production and catalytic conversion toward renewable biojet fuel
inferred← citeshttps://doi.org/10.1016/s1872-2067(26)65118-2openalex-snapshot
Dynamic evolution and stability of ketenes in MAPO-18 (M = Si or Mg): Molecular insights into the reaction mechanism for CO2-to-hydrocarbons
inferred← citeshttps://doi.org/10.1021/acs.accounts.3c00734openalex-snapshot
Selectivity Control by Relay Catalysis in CO and CO 2 Hydrogenation to Multicarbon Compounds
inferred← citeshttps://doi.org/10.1021/acs.chemmater.3c01632openalex-snapshot
Zn Redistribution and Volatility in ZnZrO x Catalysts for CO 2 Hydrogenation
inferred← citeshttps://doi.org/10.1021/acs.chemrev.3c00058openalex-snapshot
The Oxygenate-Mediated Conversion of CO x to Hydrocarbons─On the Role of Zeolites in Tandem Catalysis
inferred← citeshttps://doi.org/10.1021/acs.chemrev.6c00026openalex-snapshot
Relay Catalysis in Selective Transformations of C 1 into C 2+ Molecules
inferred← citeshttps://doi.org/10.1021/acs.energyfuels.3c03172openalex-snapshot
Modulating the Formation of Coke to Improve the Production of Light Olefins from CO2 Hydrogenation over In2O3 and SSZ-13 Catalysts
inferred← citeshttps://doi.org/10.1021/acs.iecr.3c04512openalex-snapshot
Improved Catalytic Performance on Post-Treated Zeolites SAPO-18 for 1-Butene Cracking
inferred← citeshttps://doi.org/10.1021/acs.iecr.6c00076openalex-snapshot
Controlled Construction of Hierarchical ZSM-5 Zeolite with Highly Dispersed Surface-Metals for Catalytic Cracking of n -Pentane to Light Olefins
inferred← citeshttps://doi.org/10.1021/acs.jpcc.4c00082openalex-snapshot
Machine Learning Prediction of Transition-State Energies in Small-Pore Zeolites Combining Acidity and Topology Descriptors
inferred← citeshttps://doi.org/10.1021/acs.jpcc.4c03408openalex-snapshot
Methanol-Mediated Hydrogen Transfer Reactions at Surface Lewis Acid Sites of H-SSZ-13
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From Lewis Acid to Lewis Base by La 3+ -to-Y 3+ Substitution in α-YB 5 O 9 : Local Structure Modification Induced Lewis Basicity
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Impact of Nonzeolite-Catalyzed Formation of Formaldehyde on the Methanol-to-Hydrocarbons Conversion
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The SURFCAT Summer School 2022: The Science of Sustainable Fuels and Chemicals
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Transitioning from Methanol to Olefins (MTO) toward a Tandem CO2 Hydrogenation Process: On the Role and Fate of Heteroatoms (Mg, Si) in MAPO-18 Zeotypes
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Catalyst sites and active species in the early stages of MTO conversion over cobalt AlPO-18 followed by IR spectroscopy
inferred← citeshttps://doi.org/10.1039/d6cy00470aopenalex-snapshot
Methanol-to-hydrocarbon process using ZSM-5 obtained from natural mordenite from Spain
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Copper-doped ZnO-ZrO 2 solid solution catalysts for promoting methanol synthesis from CO 2 hydrogenation
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Physical Mixing of K-FeCX with Zeolites for Modulation of Iron Carbide Phases and Product Distribution during Fischer-Tropsch to Olefins
inferred← citeshttps://doi.org/10.2139/ssrn.5967042openalex-snapshot
Methanol-to-hydrocarbon process using ZSM-5 obtained from natural mordenite from Spain
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Recent Developments in Catalysts for Methanol-to-Olefins (MTO) Reactions: Challenges and Opportunities
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Role of intimacy in bifunctional catalysts for the production of light olefins : application to the Ox-Zeo process
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