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Vanadium-Catalyzed Stereo- and Regioselective Hydroboration of Alkynes to Vinyl Boronates

https://doi.org/10.1021/acscatal.2c01318

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Redox Non‐innocent Ligands

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Multiple Spin‐State Scenarios in Organometallic Reactivity

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Synthesis of Organoboronic Acids, Organoboronates, and Related Compounds

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Overview of Regioselective and Stereoselective Catalytic Hydroboration of Alkynes

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Z‐Selective Semihydrogenation of Alkynes Catalyzed by a Cationic Vanadium Bisimido Complex

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A trans ‐Selective Hydroboration of Internal Alkynes

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Radical trans ‐Hydroboration of Alkynes with N‐Heterocyclic Carbene Boranes

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Alkenyl Boronates: Synthesis and Applications

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Systematics and Future Projections Concerning Redox‐Noninnocent Amide/Imine Ligands

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Cooperative & Redox Non‐Innocent Ligands in Directing Organometallic Reactivity (Eur. J. Inorg. Chem. 3/2012)

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Two‐State Reactivity: Personal Recounting of its Conception and Future Prospects

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Catalytic hydrogenation of olefins with the VCl4−Mg−H2 system in tetrahydrofuran

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Spin Crossover Reactivity

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Advances in the Design and Application of Redox-Active and Reactive Pincer Ligands for Substrate Activation and Homogeneous Catalysis

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Vanadium complexes: Recent progress in oxidation catalysis

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The Suzuki-Miyaura reaction after the Nobel prize

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(CAAC)CuX-catalyzed hydroboration of terminal alkynes with pinacolborane directed by the X-ligand

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Recent developments in alkyne borylations

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Rhodium-catalyzed asymmetric 1,4-addition of 2-alkenyl-1,3,2-benzodioxaboroles to α,β-unsaturated ketones

inferredcites →https://doi.org/10.1016/s0957-4166(99)00417-6openalex-snapshot

Rhodium-catalyzed asymmetric 1,4-addition of arylboron reagents to α,β-unsaturated esters

inferredcites →https://doi.org/10.1021/acs.chemrev.8b00245openalex-snapshot

Catalytic Applications of Vanadium: A Mechanistic Perspective

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Hydroboration of Alkynes Catalyzed by Pyrrolide-Based PNP Pincer–Iron Complexes

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Metal–Ligand Bifunctional Catalysis: The “Accepted” Mechanism, the Issue of Concertedness, and the Function of the Ligand in Catalytic Cycles Involving Hydrogen Atoms

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Highly Chemoselective Hydroboration of Alkynes and Nitriles Catalyzed by Group 4 Metal Amidophosphine–Borane Complexes

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Two-State Reactivity as a New Concept in Organometallic Chemistry

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Boronic Acids and Esters in the Petasis-Borono Mannich Multicomponent Reaction

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Design of Vanadium Complex Catalysts for Precise Olefin Polymerization

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Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

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“Turning Over” Definitions in Catalytic Cycles

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Preface: Forum on Redox-Active Ligands

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Rhodium- or Iridium-Catalyzed trans -Hydroboration of Terminal Alkynes, Giving ( Z )-1-Alkenylboron Compounds

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Ruthenium Catalyzed Hydroboration of Terminal Alkynes to Z -Vinylboronates

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Catalytic Dehydrogenative Borylation of Terminal Alkynes by a SiNN Pincer Complex of Iridium

inferredcites →https://doi.org/10.1021/ja907982wopenalex-snapshot

Copper-Promoted Coupling of Vinyl Boronates and Alcohols: A Mild Synthesis of Allyl Vinyl Ethers

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Cobalt Catalyzed Z -Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity

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Site-Selective and Stereoselective trans -Hydroboration of 1,3-Enynes Catalyzed by 1,4-Azaborine-Based Phosphine–Pd Complex

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Stable, Yet Highly Reactive Nonclassical Iron(II) Polyhydride Pincer Complexes: Z -Selective Dimerization and Hydroboration of Terminal Alkynes

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Redox-Noninnocent Ligand-Supported Vanadium Catalysts for the Chemoselective Reduction of C═X (X = O, N) Functionalities

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Alkoxydienes via Copper-Promoted Couplings: Utilizing an Alkyne Effect

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Oxidative Addition of a Dinuclear and Divalent Vanadium Hydride to an Olefin C−H Bond, Leading to Catalytic Hydrogenation

inferredcites →https://doi.org/10.1038/s41570-018-0049-zopenalex-snapshot

The role of the metal-bound N–H functionality in Noyori-type molecular catalysts

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Spin forbidden chemical reactions of transition metal compounds. New ideas and new computational challenges

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Redox-active ligands in catalysis

inferredcites →https://doi.org/10.1039/c3cs60197hopenalex-snapshot

Selection of boron reagents for Suzuki–Miyaura coupling

inferredcites →https://doi.org/10.1039/c4cc90480jopenalex-snapshot

Non-innocent ligands

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Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN)

inferredcites →https://doi.org/10.1039/c7cc01671aopenalex-snapshot

Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling

inferredcites →https://doi.org/10.1055/s-2005-861874openalex-snapshot

Addition of Metalloid Hydrides to Alkynes: Hydrometallation with Boron, Silicon, and Tin

inferredcites →https://doi.org/10.1070/rc2005v074n06abeh000977openalex-snapshot

Metal complexes with non-innocent ligands

inferredcites →https://doi.org/10.1080/02603590903423942openalex-snapshot

THE ELUCIDATION OF MECHANISMS IN HOMOGENEOUS CATALYSIS

inferredcites →https://doi.org/10.1126/science.1183281openalex-snapshot

Radical Ligands Confer Nobility on Base-Metal Catalysts

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Advanced inorganic chemistry

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Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Hydroboration Of Acid Anhydrides Catalyzed by Organoaluminum

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Vanadium (Iv)–Salphen Complex Catalyzed H2o2 Oxidation of Methionines – an Experimental and Computational Analysis

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Sterically Engineered Mo─V Cluster Catalyst for Switchable Z / E ‐Selective Alkyne Hydrophosphorylation

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Sterically Engineered Mo─V Cluster Catalyst for Switchable Z / E ‐Selective Alkyne Hydrophosphorylation

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An Operationally Simple, Regioselective, Platinum‐Catalyzed Hydroboration of Unactivated Alkynes

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Hydroboration of C–C π-Bonds

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Hydrometallation of C C and C C Bonds. Group-3

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Defect-engineering improves the activity of Metal-Organic frameworks for catalyzing hydroboration of Alkynes: A combination of experimental investigation and Density functional theory calculations

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Paramagnetic Transition Metal Hydride Complexes

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Cobalt-Catalyzed Borylative Reduction of Azobenzenes to Hydrazobenzenes via a Diborylated-Hydrazine Intermediate

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Visible-Light-Mediated Radical trans-Hydroboration of Alkynes with NHC Borane

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Rhodium-Promoted anti-Hydroboration of Terminal Alkynes via Combined Stoichiometric Reactions

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Sustainable Catalysis for Borylation: Earth-Abundant Homogeneous Catalysts and Their Mechanisms

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Mechanistic Study on Copper- and Silver-Catalyzed Hydroboration of Internal Alkynes: A DFT Study

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Atomically precise copper clusters with dual sites for highly chemoselective and efficient hydroboration

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Giant N-heterocyclic carbene-containing macrocycles for cobalt-catalysed hydroboration of alkynes

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Visible-light-driven PhSSPh-catalysed regioselective hydroborylation of α,β-unsaturated carbonyl compounds with NHC-boranes

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A simple synthesis of surfactant-free polycrystalline CuO nanoparticles supported on carbon nanofibers for regioselective hydroboration of alkynes

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An ionic Fe-based metal–organic-framework with 4′-pyridyl-2,2′:6′,2′′-terpyridine for catalytic hydroboration of alkynes

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Vanadium-catalysed regioselective hydroboration of epoxides for synthesis of secondary alcohols

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Homoleptic octahedral Co II complexes as precatalysts for regioselective hydroboration of alkenes with high turnover frequencies

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Tandem manganese catalysis for the chemo-, regio-, and stereoselective hydroboration of terminal alkynes: in situ precatalyst activation as a key to enhanced chemoselectivity

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Metallated dihydropyridinates: prospects in hydride transfer and (electro)catalysis

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Catalytic synthesis of organometalloidal compounds with alkenyl and alkynyl substituents

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Alumina-Promoted Copper-Catalyzed Hydroboration of Alkynes

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