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Dehydration of Methanol to Dimethyl Ether over Heteropoly Acid Catalysts: The Relationship between Reaction Rate and Catalyst Acid Strength

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Handbook of Heterogeneous Catalysis
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Understanding the Failure of Direct CC Coupling in the Zeolite‐Catalyzed Methanol‐to‐Olefin Process
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The Proton in Chemistry
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Characterization of sorbed intermediates and implications for the mechanism of chain growth in the conversion of methanol and ethanol to hydrocarbons over 12-tungstophosphoric acid using infrared photoacoustic spectroscopy
inferredcites →https://doi.org/10.1016/0022-2860(92)85083-sopenalex-snapshot
CRC Handbook of Chemistry and Physics
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Silica-included heteropoly compounds as solid acid catalysts
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Modification of acid properties and catalytic properties of AlPO4 by hydrothermal pretreatment for methanol dehydration to dimethyl ether
inferredcites →https://doi.org/10.1016/j.cattod.2011.04.049openalex-snapshot
CO2-based methanol and DME – Efficient technologies for industrial scale production
inferredcites →https://doi.org/10.1016/j.cej.2012.04.016openalex-snapshot
Dimethyl ether, diethyl ether & ethylene from alcohols over tungstophosphoric acid based mesoporous catalysts
inferredcites →https://doi.org/10.1016/j.fuproc.2009.04.018openalex-snapshot
Relationship between surface acidity and activity of solid-acid catalysts in vapour phase dehydration of methanol
inferredcites →https://doi.org/10.1016/j.jcat.2004.03.001openalex-snapshot
A calorimetric study of the acidity of bulk and silica-supported heteropoly acid H3PW12O40
inferredcites →https://doi.org/10.1016/j.jcat.2010.09.014openalex-snapshot
Solid acid catalysts based on H3PW12O40 heteropoly acid: Acid and catalytic properties at a gas–solid interface
inferredcites →https://doi.org/10.1016/j.jcat.2010.11.017openalex-snapshot
Catalytic consequences of acid strength in the conversion of methanol to dimethyl ether
inferredcites →https://doi.org/10.1016/j.jcat.2012.06.021openalex-snapshot
Compensation effect in isopropanol dehydration over heteropoly acid catalysts at a gas–solid interface
inferredcites →https://doi.org/10.1016/j.jcat.2014.01.007openalex-snapshot
Acid strength and solvation in catalysis by MFI zeolites and effects of the identity, concentration and location of framework heteroatoms
inferredcites →https://doi.org/10.1016/j.jcat.2014.01.016openalex-snapshot
TiO2-supported heteropoly acids for low-temperature synthesis of dimethyl ether from methanol
inferredcites →https://doi.org/10.1016/j.jcat.2014.09.003openalex-snapshot
Dehydration of ethanol over heteropoly acid catalysts in the gas phase
inferredcites →https://doi.org/10.1016/j.jiec.2009.09.037openalex-snapshot
Dehydration of methanol over Nordstrandite based catalysts for dimethyl ether synthesis
inferredcites →https://doi.org/10.1016/j.jngse.2012.05.012openalex-snapshot
Introduction and advancement of a new clean global fuel: The status of DME developments in China and beyond
inferredcites →https://doi.org/10.1016/j.tca.2004.12.023openalex-snapshot
Surface acidity and the dehydration of methanol to dimethyl ether
inferredcites →https://doi.org/10.1016/s0166-9834(00)81258-0openalex-snapshot
Catalysis by heteropoly compounds x. Synthesis of lower olefins by conversion of dimethyl ether over 12-tungstophosphates
inferredcites →https://doi.org/10.1016/s0360-0564(08)60041-3openalex-snapshot
Catalytic Chemistry of Heteropoly Compounds
inferredcites →https://doi.org/10.1016/s0360-0564(08)60390-9openalex-snapshot
Interpretation of Measurements in Experimental Catalysis
inferredcites →https://doi.org/10.1021/cr0103569openalex-snapshot
Water-Tolerant Solid Acid Catalysts
inferredcites →https://doi.org/10.1021/cr960400yopenalex-snapshot
Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions
inferredcites →https://doi.org/10.1021/cr960401qopenalex-snapshot
Heterogeneous Catalysis
inferredcites →https://doi.org/10.1021/cs300722wopenalex-snapshot
Methanol to Dimethyl Ether over ZSM-22: A Periodic Density Functional Theory Study
inferredcites →https://doi.org/10.1021/ja803114ropenalex-snapshot
Mechanistic Consequences of Composition in Acid Catalysis by Polyoxometalate Keggin Clusters
inferredcites →https://doi.org/10.1021/ja9729037openalex-snapshot
Acidity Differences between Inorganic Solids Induced by Their Framework Structure. A Combined Quantum Mechanics/Molecular Mechanics ab Initio Study on Zeolites
inferredcites →https://doi.org/10.1021/je00049a015openalex-snapshot
Thermodynamic equilibrium constants for the methanol-dimethyl ether-water system
inferredcites →https://doi.org/10.1021/jp962006+openalex-snapshot
Theoretical Study of the Mechanism of Surface Methoxy and Dimethyl Ether Formation from Methanol Catalyzed by Zeolitic Protons
inferredcites →https://doi.org/10.1021/jp982345yopenalex-snapshot
Acidity of Keggin-Type Heteropolycompounds Evaluated by Catalytic Probe Reactions, Sorption Microcalorimetry, and Density Functional Quantum Chemical Calculations
inferredcites →https://doi.org/10.1023/a:1019127919907openalex-snapshot
Acidity characterization by microcalorimetry and relationship with reactivity
inferredcites →https://doi.org/10.1023/b:catl.0000029524.94392.9fopenalex-snapshot
Surface Properties and Catalytic Activity of TiO2–ZrO2 Mixed Oxides in Dehydration of Methanol to Dimethyl Ether
inferredcites →https://doi.org/10.1039/jm9940400125openalex-snapshot
Microcalorimetric study of the acidity of tungstic heteropolyanions
inferredcites →https://doi.org/10.3906/kim-0809-31openalex-snapshot
Methanol dehydration reaction to produce clean diesel alternative dimethylether over mesoporous aluminosilicate-based catalysts
inferredcites →https://doi.org/10.5012/bkcs.2004.25.2.185openalex-snapshot
Dehydration of Methanol to Dimethyl Ether over ZSM-5 Zeolite

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Methanol Dehydration to Dimethyl Ether Over Kfi Zeolites. Effect of Template and Crystallization Time on Catalyst Properties And Activity
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Hydrogenation of CO 2 to Chemicals with Green Hydrogen
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Effiziente Synthese von Dimethylether aus Methanol in einem Membranreaktor mit bifunktioneller Membran
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Ethanol as a Binder to Fabricate a Highly‐Efficient Capsule‐Structured CuO−ZnO−Al2O3@HZSM‐5 Catalyst for Direct Production of Dimethyl Ether from Syngas
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Isophthalic acid production catalyzed by Co(II) together with phosphotungstic acid loaded on carbon modified with tartaric acid
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Adsorption and Decomposition of DMMP on Size‐Selected (WO 3 ) 3 Clusters
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Solvent‐Free Efficient Hydrogenation of Levulinic Acid over Silicotungstic Acid Promoting the Activity of CuNiAl Catalysts: A Synergistic Effect
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Promotional Effect of B2O3, WO3 and ZrO2 on the Structural, Textural and Catalytic Properties of FePO4 Catalyst Towards the Selective Dehydration of Methanol into Dimethyl Ether
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Stability of Zeolite HZSM-5 in Liquid Phase Dehydration of Methanol to Dimethyl Ether
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The Catalytic Performance of Ultrasonically Prepared AlPO4 Nanocatalysts for the Selective Production of Dimethyl Ether from Methanol
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Zirconia Incorporated Aluminum Phosphate Molecular Sieves as Efficient Microporous Nano Catalysts for the Selective Dehydration of Methanol into Dimethyl Ether
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Structure–Activity Relationships in Tungsten Oxide Superacid Catalysts: Insights from Isopropanol Conversion and Reaction Mechanisms
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Catalysts for Clean Energy: A Review on Current Progress for the Catalyzed Recycling of CO2 into Dimethyl Ether
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Power-to-DME: a cornerstone towards a sustainable energy system
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Biomass, biorefinery, and biofuels
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Economics and Applications of Dimethyl Ether from Dehydration of Methanol
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Methanol dehydration to dimethyl ether over KFI zeolites. Effect of template concentration and crystallization time on catalyst properties and activity
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TiO2 promoted alcohol dehydrations on the Wells-Dawson type heteropolyacids
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Heteropolyacid supported on Zr-Beta zeolite as an active catalyst for one-pot transformation of furfural to γ-valerolactone
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Heteropoly-12-tungstophosphoric acid H3[PW12O40] over natural bentonite as a heterogeneous catalyst for the synthesis of 3,4-dihydropyrimidin-2-(1H)-ones
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Solid acid catalysts comprising heteropoly acids supported on SiO2, TiO2 and ZrO2: A microcalorimetric investigation of catalyst acidity and new insight into the mechanism of alcohol dehydration over HPA
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Efficient methanol dehydration to DME and light hydrocarbons by submicrometric ZrO2-ZSM-5 fibrillar catalysts with a shell-like structure
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Operando Raman to Enhance the Methanol-to-DME Conversion Over Non-Thermally-Pretreated Keggin Heteropolyacids
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Cation Effects on the Brønsted Acidity of Solid Tungstosilicic Acid Clusters
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Ethanol Dehydration over Silica-Supported H3PW12O40 and the Role of Water
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Deoxygenation of Ethers and Esters over Bifunctional Pt–Heteropoly Acid Catalyst in the Gas Phase
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Acid–Base Reactivity of Perovskite Catalysts Probed via Conversion of 2-Propanol over Titanates and Zirconates
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Boron Nitride: A Support for Highly Active Heteropolyacids in the Methanol-to-DME Reaction
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Kinetics and Mechanism of Methanol Conversion over Anatase Titania Nanoshapes
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Isomerization of Cyclohexane over Bifunctional Pt-, Au-, and PtAu-Heteropoly Acid Catalysts
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Diethyl Ether Conversion to Ethene and Ethanol Catalyzed by Heteropoly Acids
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From CO2 to DME: Enhancement through Heteropoly Acids from a Catalyst Screening and Stability Study
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Molecular Tuning of Reactivity of Zeolite Protons in HZSM-5
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Methylations with methanol via bioinspired catalytic C–O bond cleavage
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Effects of support and reaction pressure for the synthesis of dimethyl ether over heteropolyacid catalysts
inferred← citeshttps://doi.org/10.1038/s42004-023-01080-4openalex-snapshot
Economically viable co-production of methanol and sulfuric acid via direct methane oxidation
inferred← citeshttps://doi.org/10.1039/9781837675166-00018openalex-snapshot
Synthetic Methods for Dialkyl Ethers
inferred← citeshttps://doi.org/10.1039/c6cp02459aopenalex-snapshot
Correlation between the acid–base properties of the La 2 O 3 catalyst and its methane reactivity
inferred← citeshttps://doi.org/10.1039/c6cy02264bopenalex-snapshot
Elucidating and exploiting the chemistry of Keggin heteropolyacids in the methanol-to-DME conversion: enabling the bulk reaction thanks to operando Raman
inferred← citeshttps://doi.org/10.1039/c6gc01523aopenalex-snapshot
Catalytic and mechanistic insights into the production of ethyl levulinate from biorenewable feedstocks
inferred← citeshttps://doi.org/10.1039/c6ra02266aopenalex-snapshot
Heteropoly acid catalysts for the synthesis of fragrance compounds from bio-renewables: acetylation of nopol and terpenic alcohols
inferred← citeshttps://doi.org/10.1039/d0gc01092hopenalex-snapshot
Catalytic reduction of CO 2 into fuels and fine chemicals
inferred← citeshttps://doi.org/10.1039/d0gc01692fopenalex-snapshot
One-pot hydrodeoxygenation (HDO) of lignin monomers to C9 hydrocarbons co-catalysed by Ru/C and Nb 2 O 5
inferred← citeshttps://doi.org/10.1039/d1re00468aopenalex-snapshot
Effect of H-ZSM-5 zeolite content on the intrinsic kinetics of methanol dehydration to dimethyl ether over H-ZSM-5/Al 2 O 3 molded catalyst
inferred← citeshttps://doi.org/10.1039/d2sc06010hopenalex-snapshot
Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties
inferred← citeshttps://doi.org/10.1039/d4cy00020jopenalex-snapshot
Designing bifunctional catalysts for the one-pot conversion of CO 2 to sustainable marine transportation fuels
inferred← citeshttps://doi.org/10.1039/d4ra07964gopenalex-snapshot
Study of supported heteropolyacid catalysts for one-step DME synthesis from CO 2 and H 2
inferred← citeshttps://doi.org/10.1039/d5cy00747jopenalex-snapshot
Heteropoly acid catalysts for limonene oxide isomerization: the correlation of catalyst acid strength to activity and selectivity
inferred← citeshttps://doi.org/10.1039/d5re00481kopenalex-snapshot
The promotional effect of gallium loading on the bifunctional Cu–Ga/γ-Al 2 O 3 catalyst for CO 2 hydrogenation to methanol and dimethyl ether at atmospheric pressure
inferred← citeshttps://doi.org/10.1080/17518253.2024.2360477openalex-snapshot
Obtaining glycerol alkyl ethers via Williamson synthesis in heterogeneous media using amberlyst-A26 TM − OH form and KOH/Al 2 O 3 as basic solid reagents
inferred← citeshttps://doi.org/10.1098/rsos.180740openalex-snapshot
Synthesis of cyclic ethers by cyclodehydration of 1, n -diols using heteropoly acids as catalysts
inferred← citeshttps://doi.org/10.1098/rsos.230524openalex-snapshot
Temperature-dependent synthesis of dimethyl ether (DME) from methanol over beta zeolite: a novel approach to a sustainable fuel
inferred← citeshttps://doi.org/10.1126/sciadv.abg0396openalex-snapshot
Hydrogen-bond donor and acceptor cooperative catalysis strategy for cyclic dehydration of diols to access O-heterocycles
inferred← citeshttps://doi.org/10.1134/s2070050419010045openalex-snapshot
Development of Heterogeneous Catalysts for Dehydration of Methanol to Dimethyl Ether: A Review
inferred← citeshttps://doi.org/10.1155/2023/6629794openalex-snapshot
ZSM-5/γ-Al2O3 Catalysts for Methanol Dehydration: Tuning Pore Structure by Carbon Nanotubes as a Pore-Forming Agent
inferred← citeshttps://doi.org/10.1201/9781003336587-5openalex-snapshot
CO2 hydrogenation into dimethyl ether
inferred← citeshttps://doi.org/10.1246/cl.170185openalex-snapshot
Single-step Simple Solvothermal Synthetic Approach to Ultrafine MgO Nanocrystals Using High-temperature and High-pressure Acetonitrile
inferred← citeshttps://doi.org/10.18412/1816-0387-2018-4-6-30openalex-snapshot
Development of Heterogeneous Catalysts for Dehydration of Methanol to Dimethyl Ether: a Review
inferred← citeshttps://doi.org/10.21203/rs.3.rs-8307998/v1openalex-snapshot
Unraveling the Propene Selectivity in Isopropanol Conversion on Graphene-Enhanced WO3 Superacids: An Integrated Experimental and DFT Study
inferred← citeshttps://doi.org/10.2174/1570178618666211006145422openalex-snapshot
An Efficient Bifunctional Ionic Liquid [BIL] as Solvent and Catalyst System for O-Alkylation of Phenols Under Solvent-Free Conditions: An Environmental Benign Approach
inferred← citeshttps://doi.org/10.3390/catal10060655openalex-snapshot
Trends and Outlook of Computational Chemistry and Microkinetic Modeling for Catalytic Synthesis of Methanol and DME
inferred← citeshttps://doi.org/10.3390/catal10091071openalex-snapshot
Direct Synthesis of Dimethyl Ether from Syngas on Bifunctional Hybrid Catalysts Based on Supported H3PW12O40 and Cu-ZnO(Al): Effect of Heteropolyacid Loading on Hybrid Structure and Catalytic Activity
inferred← citeshttps://doi.org/10.3390/catal10111282openalex-snapshot
Silica-Related Catalysts for CO2 Transformation into Methanol and Dimethyl Ether
inferred← citeshttps://doi.org/10.3390/catal11040411openalex-snapshot
Direct Synthesis of Dimethyl Ether from CO2: Recent Advances in Bifunctional/Hybrid Catalytic Systems
inferred← citeshttps://doi.org/10.3390/catal13020408openalex-snapshot
Direct Synthesis of Dimethyl Ether from CO2 Hydrogenation over Core-Shell Nanotube Bi-Functional Catalyst
inferred← citeshttps://doi.org/10.3390/catal14010051openalex-snapshot
Dehydration of Isopropanol over Silica-Supported Heteropoly Acids
inferred← citeshttps://doi.org/10.3390/catal14070435openalex-snapshot
Effect of TiO2 on Acidity and Dispersion of H3PW12O40 in Bifunctional Cu-ZnO(Al)-H3PW12O40/TiO2 Catalysts for Direct Dimethyl Ether Synthesis
inferred← citeshttps://doi.org/10.3390/catal9040320openalex-snapshot
Heteropolyacid Salt Catalysts for Methanol Conversion to Hydrocarbons and Dimethyl Ether: Effect of Reaction Temperature
inferred← citeshttps://doi.org/10.3390/en15155420openalex-snapshot
A Review on Deactivation and Regeneration of Catalysts for Dimethyl Ether Synthesis
inferred← citeshttps://doi.org/10.3390/ma12132204openalex-snapshot
Methanol Dehydration to Dimethyl Ether on Zr-Loaded P-Containing Mesoporous Activated Carbon Catalysts
inferred← citeshttps://doi.org/10.3390/ma15020596openalex-snapshot
A Kinetic Model Considering Catalyst Deactivation for Methanol-to-Dimethyl Ether on a Biomass-Derived Zr/P-Carbon Catalyst
inferred← citeshttps://doi.org/10.3390/molecules23010031openalex-snapshot
CO2 Recycling to Dimethyl Ether: State-of-the-Art and Perspectives
inferred← citeshttps://doi.org/10.4028/www.scientific.net/msf.1029.147openalex-snapshot
Synthesis Dimethyl Ether from Methanol Using Red Mud Catalyst
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