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“Cut and Sew” Transformations via Transition-Metal-Catalyzed Carbon–Carbon Bond Activation

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Palladium‐Catalyzed Diastereo‐ and Enantioselective Synthesis of Substituted Cyclopentanes through a Dynamic Kinetic Asymmetric Formal [3+2]‐Cycloaddition of Vinyl Cyclopropanes and Alkylidene Azlactones
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[3+2] Cycloaddition Reaction of Cyclopropyl Ketones with Alkynes Catalyzed by Nickel/Dimethylaluminum Chloride
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Rhodium‐Catalyzed Regioselective Carboacylation of Olefins: A CC Bond Activation Approach for Accessing Fused‐Ring Systems
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Divergent Syntheses of Fused β‐Naphthol and Indene Scaffolds by Rhodium‐Catalyzed Direct and Decarbonylative Alkyne–Benzocyclobutenone Couplings
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Highly Enantioselective Rhodium(I)‐Catalyzed Activation of Enantiotopic Cyclobutanone CC Bonds
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Coupling of Sterically Hindered Trisubstituted Olefins and Benzocyclobutenones by CC Activation: Total Synthesis and Structural Revision of Cycloinumakiol
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Highly Enantioselective Rhodium(I)‐Catalyzed Carbonyl Carboacylations Initiated by CC Bond Activation
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Nickel‐Catalyzed Chemo‐, Regio‐ and Diastereoselective Bond Formation through Proximal CC Cleavage of Benzocyclobutenones
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Synthesis of Bridged Cyclopentane Derivatives by Catalytic Decarbonylative Cycloaddition of Cyclobutanones and Olefins
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Synthesis of Aromatic Compounds by Catalytic CC Bond Activation of Biphenylene or Angular [3]Phenylene
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Ruthenium‐ and Rhodium‐Catalyzed Strain‐Driven Cleavage and Reconstruction of the C–C Bond
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Mechanistic Studies of Transition Metal-Mediated C–C Bond Activation
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Catalytic C–CN Bond Activation
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Transition Metal-Catalyzed C–C Bond Activation of Four-Membered Cyclic Ketones
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Cleavage of Carbon—Carbon Single Bonds by Transition Metals
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C-C Bond Activation
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Structure and reactivity of cyclopropenones and triafulvenes
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Synthesis, characterization, and C–H/C–C cleavage reactions of two rhodium–trispyrazolylborate dihydrides
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Arylcyanation of alkynes catalyzed by nickel
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Cyanoesterification of norbornenes catalyzed by palladium: facile synthetic methodology to introduce cyano and ester functionalities via direct carbon–carbon bond cleavage of cyanoformates
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Alkynylcyanation of alkynes and dienes catalyzed by nickel
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Formal syntheses of (±)-Asterisca-3(15),6-diene and (±)-Pentalenene using Rh(I)-catalyzed [(5+2)+1] cycloaddition
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Synthesis of 3,3-disubstituted oxindoles through Pd-catalyzed intramolecular cyanoamidation
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Recent developments in the synthesis and reactivity of methylene- and alkylidenecyclopropane derivatives
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Directed carbonylative (3+1+2) cycloadditions of amino-substituted cyclopropanes and alkynes: reaction development and increased efficiencies using a cationic rhodium system
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Ring-opening, cycloaddition and rearrangement reactions of nitrogen-substituted cyclopropane derivatives
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Nickel-catalyzed [4+3] cycloaddition of ethyl cyclopropylideneacetate and 1,3-dienes
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Rhodium-catalyzed rapid synthesis of substituted phenols from cyclobutenones and alkynes or alkenes via C–C bond cleavage
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Nickel-catalyzed [3+2+2] cycloaddition of ethyl cyclopropylideneacetate and diynes. Synthesis of 7,6- and 7,5-fused bicyclic compounds
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An expeditious and high-yield formal synthesis of hirsutene using Rh(I)-catalyzed [(5+2)+1] cycloaddition
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Ni-catalyzed [3+2+2] cycloaddition of ethyl cyclopropylideneacetate and 1,3-diynes. Application to the three-component cycloaddition
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Nickel catalyzed [3+2] cycloaddition reaction of bis(methylenecyclopropane) with cyclic and acyclic dienophiles
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Directed cleavage of sp2sp carbon—carbon bonds
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Cyclobutenediones as precursors to quinones and cyclopentenones
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The development of an organotransition metal synthesis of quinones
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The first metal-catalyzed intramolecular [5+2] cycloadditions of vinylcyclopropanes and alkenes: Scope, stereochemistry, and asymmetric catalysis
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Intramolecular cycloadditions of methylenecyclopropanes: A novel chelation effect
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Palladium-catalyzed [3 + 2] cycloaddition reaction of vinylcyclopropanes with α,β-unsaturated esters or ketones
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Palladium-catalyzed [3+2] cycloaddition of alkylidenecyclopropanes with imines
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Palladium-catalyzed [3 + 2] cycloaddition reaction using 2-(sulfonylmethyl)- or 2-(cyanomethyl)allyl carbonate
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Regiospecific intramolecular [2π+2σ] cycloadditions of methylene cyclopropanes
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Transition metal-catalyzed asymmetric cycloaddition reactions of a chiral (β-sulfinyl)vinylcyclopropane derivative: asymmetric synthesis of a cyclopentane derivative using a chiral sulfinyl functionality as the chiral source
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Cleavage of the carbon–carbon bond in biphenylene using transition metals
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Rhodium-Catalyzed [5 + 2 + 1] Cycloaddition of Ene–Vinylcyclopropanes and CO: Reaction Design, Development, Application in Natural Product Synthesis, and Inspiration for Developing New Reactions for Synthesis of Eight-Membered Carbocycles
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Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals
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Formal Synthesis of Gracilamine Using Rh(I)-Catalyzed [3 + 2 + 1] Cycloaddition of 1-Yne–Vinylcyclopropanes and CO
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Asymmetric [3 + 2] Cycloaddition of Vinylcyclopropanes and α,β-Unsaturated Aldehydes by Synergistic Palladium and Organocatalysis
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Theoretical Study of Nickel-Catalyzed Proximal C–C Cleavage in Benzocyclobutenones with Insertion of 1,3-Diene: Origin of Selectivity and Role of Ligand
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Efficient Benzimidazolidinone Synthesis via Rhodium-Catalyzed Double-Decarbonylative C–C Activation/Cycloaddition between Isatins and Isocyanates
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Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery
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Heterocycles from Alkylidenecyclopropanes
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The Application of Cyclobutane Derivatives in Organic Synthesis
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Cyclobutarenes and Related Compounds
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Transition Metal Chemistry of Cyclopropenes and Cyclopropanes
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[5 + 2] Cycloaddition Reactions in Organic and Natural Product Synthesis
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Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds
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Progress in the Synthesis and Transformations of Alkylidenecyclopropanes and Alkylidenecyclobutanes
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Chemistry of cyclopropenones
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Nickel(0)-catalyzed synthesis of substituted phenols from cyclobutenones and alkynes
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Ruthenium-Catalyzed Reconstructive Synthesis of Cyclopentenones by Unusual Coupling of Cyclobutenediones with Alkenes Involving Carbon−Carbon Bond Cleavage
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Stereochemical Control in Metal-Catalyzed [3 + 2] Cycloadditions of Methylenecyclopropanes
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Insertion of (.eta.5-indeny)cobalt(I) into cyclobutenones: the first synthesis of phenols from isolated vinylketene complexes
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Regiospecific total synthesis of (.+-.)-nanaomycin A using phthaloylcobalt complexes
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Convergent, high-yield, regioselective synthesis of substituted benzoquinones from maleoylcobalt complexes and alkynes
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The C−C Bond Activation and Skeletal Rearrangement of Cycloalkanone Imine by Rh(I) Catalysts
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Palladium-mediated cycloaddition approach to cyclopentanoids. Introduction and initial studies
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Palladium-mediated cycloaddition approach to cyclopentanoids. Mechanistic studies
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Nickel(0)-catalyzed reaction of methylenecyclopropanes with olefins. A novel [.sigma.2 + .pi.2] cycloaddition
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Nickel-catalyzed reactions involving strained .sigma. bonds. IV. Nickel(0)-catalyzed reaction of methylenecyclopropane with olefins. Orientation and stereochemistry
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Catalyzed Intramolecular Olefin Insertion into a Carbon−Carbon Single Bond
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Nickel-Catalyzed Arylcyanation of Alkynes
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Nickel-Catalyzed Intermolecular [3 + 2 + 2] Cocyclization of Ethyl Cyclopropylideneacetate and Alkynes
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Asymmetric Catalysis of the [5 + 2] Cycloaddition Reaction of Vinylcyclopropanes and π-Systems
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Dimerization of Cyclopropyl Ketones and Crossed Reactions of Cyclopropyl Ketones with Enones as an Entry to Five-Membered Rings
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Formation of Nickeladihydropyran by Oxidative Addition of Cyclopropyl Ketone. Key Intermediate in Nickel-Catalyzed Cycloaddition
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Allylcyanation of Alkynes: Regio- and Stereoselective Access to Functionalized Di- or Trisubstituted Acrylonitriles
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Cyanoesterification of 1,2-Dienes: Synthesis and Transformations of Highly Functionalized α-Cyanomethylacrylate Esters
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Cyclopentadienone Synthesis by Rhodium(I)-Catalyzed [3 + 2] Cycloaddition Reactions of Cyclopropenones and Alkynes
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A Dramatic Effect of Lewis-Acid Catalysts on Nickel-Catalyzed Carbocyanation of Alkynes
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A Computationally Designed Rh(I)-Catalyzed Two-Component [5+2+1] Cycloaddition of Ene-vinylcyclopropanes and CO for the Synthesis of Cyclooctenones
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Heteroatom-Directed Alkylcyanation of Alkynes
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Nickel/Lewis Acid-Catalyzed Cyanoesterification and Cyanocarbamoylation of Alkynes
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Density Functional Theory Study of the Mechanisms and Stereochemistry of the Rh(I)-Catalyzed Intramolecular [3+2] Cycloadditions of 1-Ene- and 1-Yne-Vinylcyclopropanes
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Rhodium-Catalyzed Acylation with Quinolinyl Ketones: Carbon−Carbon Single Bond Activation as the Turnover-Limiting Step of Catalysis
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Rh(I)-Catalyzed Formal [5 + 1]/[2 + 2 + 1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds
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Asymmetric Rh(I)-Catalyzed Intramolecular [3 + 2] Cycloaddition of 1-Yne-vinylcyclopropanes for Bicyclo[3.3.0] Compounds with a Chiral Quaternary Carbon Stereocenter and Density Functional Theory Study of the Origins of Enantioselectivity
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Rate-Limiting Step of the Rh-Catalyzed Carboacylation of Alkenes: C–C Bond Activation or Migratory Insertion?
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Palladium-Catalyzed Diastereo- and Enantioselective Formal [3 + 2]-Cycloadditions of Substituted Vinylcyclopropanes
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Highly Enantioselective Rh-Catalyzed Carboacylation of Olefins: Efficient Syntheses of Chiral Poly-Fused Rings
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Directing Group Enhanced Carbonylative Ring Expansions of Amino-Substituted Cyclopropanes: Rhodium-Catalyzed Multicomponent Synthesis of N-Heterobicyclic Enones
inferredcites →https://doi.org/10.1021/ja511335vopenalex-snapshot
Reversible C–C Bond Activation Enables Stereocontrol in Rh-Catalyzed Carbonylative Cycloadditions of Aminocyclopropanes
inferredcites →https://doi.org/10.1021/ja512306aopenalex-snapshot
Rh-Catalyzed Decarbonylative Coupling with Alkynes via C–C Activation of Isatins
inferredcites →https://doi.org/10.1021/ja8008715openalex-snapshot
Rh(I)-Catalyzed Intramolecular [3 + 2] Cycloaddition of trans-Vinylcyclopropane-enes
inferredcites →https://doi.org/10.1021/ja805088ropenalex-snapshot
Intramolecular Arylcyanation of Alkenes Catalyzed by Nickel/AlMe2Cl
inferredcites →https://doi.org/10.1021/ja805094jopenalex-snapshot
Asymmetric Intramolecular Arylcyanation of Unactivated Olefins via C−CN Bond Activation
inferredcites →https://doi.org/10.1021/ja8066308openalex-snapshot
Catalytic Carbon−Carbon σ Bond Activation: An Intramolecular Carbo-Acylation Reaction with Acylquinolines
inferredcites →https://doi.org/10.1021/ja9010282openalex-snapshot
Cyanoesterification of 1,2-Dienes Catalyzed by Nickel
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Nickel-Catalyzed Carbocyanation of Alkynes with Allyl Cyanides
inferredcites →https://doi.org/10.1021/ja9604525openalex-snapshot
Breaking of the C−C Bond of Cyclobutanones by Rhodium(I) and Its Extension to Catalytic Synthetic Reactions
inferredcites →https://doi.org/10.1021/ja9611809openalex-snapshot
Transition Metal Catalyzed Stereospecific Intramolecular [3 + 2] Cycloadditions of Methylenecyclopropanes with Alkynes
inferredcites →https://doi.org/10.1021/ja962148hopenalex-snapshot
Palladium-Catalyzed Intramolecular [3 + 2] Cycloadditions of Methylenecyclopropanes With Alkenes: Diastereomeric Methylenecyclopropanes Exhibit Complementary Facial Selectivity
inferredcites →https://doi.org/10.1021/ja9638061openalex-snapshot
Why Are Methylenecyclopropane and 1-Methylcylopropene More “Strained” than Methylcyclopropane?
inferredcites →https://doi.org/10.1021/ja971949xopenalex-snapshot
Rhodium(I)-Catalyzed Successive Double Cleavage of Carbon−Carbon Bonds of Strained Spiro Cyclobutanones
inferredcites →https://doi.org/10.1021/ja973368dopenalex-snapshot
Mechanistic Investigation of Catalytic Carbon−Carbon Bond Activation and Formation by Platinum and Palladium Phosphine Complexes
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New Domino Sequences Involving Successive Cleavage of Carbon−Carbon and Carbon−Oxygen Bonds: Discrete Product Selection Dictated by Catalyst Ligands
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Catalytic Carbon−Carbon Bond Activation of Unstrained Ketone by Soluble Transition-Metal Complex
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Computational Study of Rh-Catalyzed Carboacylation of Olefins: Ligand-Promoted Rhodacycle Isomerization Enables Regioselective C–C Bond Functionalization of Benzocyclobutenones
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(4+1) vs (4+2): Catalytic Intramolecular Coupling between Cyclobutanones and Trisubstituted Allenes via C–C Activation
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Enantioselective Rh-Catalyzed Carboacylation of C═N Bonds via C–C Activation of Benzocyclobutenones
inferredcites →https://doi.org/10.1021/jacs.6b08608openalex-snapshot
New Initiation Modes for Directed Carbonylative C–C Bond Activation: Rhodium-Catalyzed (3 + 1 + 2) Cycloadditions of Aminomethylcyclopropanes
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Palladium-catalyzed decarbonylation of acyl cyanides
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Vinylcyclopropane Derivatives in Transition-Metal-Catalyzed Cycloadditions for the Synthesis of Carbocyclic Compounds
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Formal Synthesis of (±)-Galanthamine and (±)-Lycoramine Using Rh(I)-Catalyzed [(3 + 2) + 1] Cycloaddition of 1-Ene–Vinylcyclopropane and CO
inferredcites →https://doi.org/10.1021/jo7014714openalex-snapshot
Nickel-Catalyzed Intermolecular [3 + 2 + 2] Cocyclization of Ethyl Cyclopropylideneacetate and Alkynes. Synthesis of Seven-Membered Carbocycles
inferredcites →https://doi.org/10.1021/jo900189gopenalex-snapshot
Synthesis of Vinylcycloheptadienes by the Nickel-Catalyzed Three-Component [3 + 2 + 2] Cocyclization. Application to the Synthesis of Polycyclic Compounds
inferredcites →https://doi.org/10.1021/ol050749kopenalex-snapshot
Palladium-Catalyzed Cyanoesterification of Norbornenes with Cyanoformates via the NC−Pd−COOR (R = Me and Et) Intermediate
inferredcites →https://doi.org/10.1021/ol060733+openalex-snapshot
Palladium-Catalyzed Intramolecular Cyanoamidation of Alkynyl and Alkenyl Cyanoformamides
inferredcites →https://doi.org/10.1021/ol071376lopenalex-snapshot
[3+2] Cycloaddition Reactions of Cyclopropyl Imines with Enones
inferredcites →https://doi.org/10.1021/ol100237hopenalex-snapshot
Reaction of α-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddition?
inferredcites →https://doi.org/10.1021/ol100625eopenalex-snapshot
Rh(I)-Catalyzed [(3 + 2) + 1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson−Khand Reaction and Total Synthesis of (±)-α-Agarofuran
inferredcites →https://doi.org/10.1021/ol101091ropenalex-snapshot
Rh(I)-Catalyzed Carbonylative Carbocyclization of Tethered Ene− and Yne−cyclopropenes
inferredcites →https://doi.org/10.1021/ol1028628openalex-snapshot
Ni-Catalyzed Intramolecular Cycloaddition of Methylenecyclopropanes to Alkynes
inferredcites →https://doi.org/10.1021/ol200274hopenalex-snapshot
Palladium-Catalyzed C−CN Activation for Intramolecular Cyanoesterification of Alkynes
inferredcites →https://doi.org/10.1021/ol2017615openalex-snapshot
A Palladium-Catalyzed Vinylcyclopropane (3 + 2) Cycloaddition Approach to the Melodinus Alkaloids
inferredcites →https://doi.org/10.1021/ol502288xopenalex-snapshot
Nickel-Catalyzed Intramolecular [3 + 2 + 2] Cycloadditions of Alkylidenecyclopropanes. A Straightforward Entry to Fused 6,7,5-Tricyclic Systems
inferredcites →https://doi.org/10.1021/ol801168jopenalex-snapshot
Enantioselective Synthesis of 3,3-Disubstituted Oxindoles through Pd-Catalyzed Cyanoamidation
inferredcites →https://doi.org/10.1021/om00037a047openalex-snapshot
Reaction of cyclobutenones with low-valent metal reagents to form .eta.4- and .eta.2-vinylketene complexes. Reaction of .eta.4-vinylketene complexes with alkynes to form phenols
inferredcites →https://doi.org/10.1021/om00121a003openalex-snapshot
Organic chemistry of subvalent transition complexes. 9. Oxidative addition of nickel(0) complexes to carbon-carbon bonds in biphenylene: formation of nickelole and 1,2-dinickelecin intermediates
inferredcites →https://doi.org/10.1021/om00158a009openalex-snapshot
Synthesis of metallacyclopentenones by insertion of rhodium into cyclobutenones
inferredcites →https://doi.org/10.1021/om010111mopenalex-snapshot
Formation of Phenylene Oligomers Using Platinum−Phosphine Complexes
inferredcites →https://doi.org/10.1021/om0107946openalex-snapshot
Rhodium-Catalyzed Activation and Functionalization of the C−C Bond of Biphenylene
inferredcites →https://doi.org/10.1021/om0110989openalex-snapshot
Catalytic C−C Bond Activation in Biphenylene and Cyclotrimerization of Alkynes: Increased Reactivity of P,N- versus P,P-Substituted Nickel Complexes
inferredcites →https://doi.org/10.1021/om0604223openalex-snapshot
Nickel(0) Complexes of N-Alkyl-Substituted N-Heterocyclic Carbenes and Their Use in the Catalytic Carbon−Carbon Bond Activation of Biphenylene
inferredcites →https://doi.org/10.1021/om300896zopenalex-snapshot
Palladium-Catalyzed Asymmetric Formal [3+2] Cycloaddition of Vinyl Cyclopropanes and β,γ-Unsaturated α-Keto Esters: An Effective Route to Highly Functionalized Cyclopentanes
inferredcites →https://doi.org/10.1021/om4011627openalex-snapshot
Asymmetric Rhodium(I)-Catalyzed C–C Activations with Zwitterionic Bis-phospholane Ligands
inferredcites →https://doi.org/10.1021/om961059aopenalex-snapshot
C−C Activation in Biphenylene. Synthesis, Structure, and Reactivity of (C5Me5)2M2(2,2‘-biphenyl) (M = Rh, Co)
inferredcites →https://doi.org/10.1021/om9805281openalex-snapshot
Catalytic Hydrogenolysis of Biphenylene with Platinum, Palladium, and Nickel Phosphine Complexes
inferredcites →https://doi.org/10.1021/om990387iopenalex-snapshot
Catalytic Carbon−Carbon Bond Activation and Functionalization by Nickel Complexes
inferredcites →https://doi.org/10.1038/364676a0openalex-snapshot
The fall of the C-C bond
inferredcites →https://doi.org/10.1038/370540a0openalex-snapshot
Selective activation of carbon–carbon bonds next to a carbonyl group
inferredcites →https://doi.org/10.1038/nchem.1989openalex-snapshot
Cooperative activation of cyclobutanones and olefins leads to bridged ring systems by a catalytic [4 + 2] coupling
inferredcites →https://doi.org/10.1039/b308864mopenalex-snapshot
Transition metal-catalyzed carbon–carbon bond activation
inferredcites →https://doi.org/10.1039/b702940nopenalex-snapshot
Catalytic reactions involving the cleavage of carbon–cyano and carbon–carbon triple bonds
inferredcites →https://doi.org/10.1039/b907290jopenalex-snapshot
Nickel/AlMe2Cl-catalysed carbocyanation of alkynes using arylacetonitriles
inferredcites →https://doi.org/10.1039/b922417copenalex-snapshot
Rh(i)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes
inferredcites →https://doi.org/10.1039/c0cc02566fopenalex-snapshot
Metal-catalysed cleavage of carbon–carbon bonds
inferredcites →https://doi.org/10.1039/c1cc11005eopenalex-snapshot
Enantioselective total synthesis of (+)-asteriscanolide via Rh(i)-catalyzed [(5+2)+1] reaction
inferredcites →https://doi.org/10.1039/c39880000948openalex-snapshot
Observations on the intramolecular palladium(0) catalysed [3 + 2] cycloaddition of diphenylmethylenecyclopropanes
inferredcites →https://doi.org/10.1039/c39930001877openalex-snapshot
Redox-active organometallic Ir complexes containing biphenyl-2,2′-diyl
inferredcites →https://doi.org/10.1039/c3ra45178jopenalex-snapshot
Transformations of X (C, O, N)–CN bonds: cases of selective X (C, O, N)–C activation
inferredcites →https://doi.org/10.1039/c4cc04068fopenalex-snapshot
Palladium catalyzed intramolecular acylcyanation of alkenes using α-iminonitriles
inferredcites →https://doi.org/10.1039/c4qo00053fopenalex-snapshot
Direct activation of relatively unstrained carbon–carbon bonds in homogeneous systems
inferredcites →https://doi.org/10.1039/c4ra08675aopenalex-snapshot
Recent advances in transition-metal-catalyzed C–CN bond activations
inferredcites →https://doi.org/10.1039/c5ob00868aopenalex-snapshot
Heterocycles from methylenecyclopropanes
inferredcites →https://doi.org/10.1039/c6cc04359copenalex-snapshot
Synthesis and applications of rhodacyclopentanones derived from C–C bond activation
inferredcites →https://doi.org/10.1039/c6dt00341aopenalex-snapshot
The molecular mechanism of palladium-catalysed cyanoesterification of methyl cyanoformate onto norbornene
inferredcites →https://doi.org/10.1039/c6ob00734aopenalex-snapshot
Rhodium( i )-catalysed intermolecular alkyne insertion into (2-pyridylmethylene)cyclobutenes
inferredcites →https://doi.org/10.1055/s-0030-1259536openalex-snapshot
β-Carbon Elimination from Cyclobutanols: A Clean Access to Alkylrhodium Intermediates Bearing a Quaternary Stereogenic Center
inferredcites →https://doi.org/10.1055/s-0032-1316850openalex-snapshot
Recent Advances in the Synthesis and Application of Benzocyclobutenones and Related Compounds
inferredcites →https://doi.org/10.1055/s-0034-1378371openalex-snapshot
Regio- and Diastereoselective Nickel-Catalyzed Cycloaddition of Activated Cyclopropanes with Allenes
inferredcites →https://doi.org/10.1055/s-0035-1560442openalex-snapshot
Transition-Metal-Catalyzed C–C and C–X Bond-Forming Reactions Using Cyclopropanols
inferredcites →https://doi.org/10.1055/s-0035-1561343openalex-snapshot
Synthesis of Phenanthridines via a Rhodium-Catalyzed C–C Bond Cleavage Reaction of Biphenylene with Nitriles
inferredcites →https://doi.org/10.1055/s-2008-1032112openalex-snapshot
Iridium-Catalyzed Enantioselective Formal [4+2] Cycloaddition of Biphenylene and Alkynes for the Construction of Axial Chirality
inferredcites →https://doi.org/10.1080/01614940.2014.920178openalex-snapshot
Transition Metals Catalyzed Element-Cyano Bonds Activations
inferredcites →https://doi.org/10.1139/v95-153openalex-snapshot
1994 Merck Frosst Award Lecture New strategies for the stereoselective synthesis of natural and unnatural products via organometallic reagents and catalysts
inferredcites →https://doi.org/10.1246/bcsj.20100023openalex-snapshot
Nickel/Lewis Acid-Catalyzed Carbocyanation of Alkynes Using Acetonitrile and Substituted Acetonitriles
inferredcites →https://doi.org/10.1246/bcsj.20120081openalex-snapshot
Nickel/Lewis Acid-Catalyzed Carbocyanation of Unsaturated Compounds
inferredcites →https://doi.org/10.1246/cl.1976.11openalex-snapshot
REACTIONS OF DIPHENYLCYCLOPROPENONE WITH N-SULFINYLAMINES IN THE PRESENCE OF NICKEL TETRACARBONYL
inferredcites →https://doi.org/10.1246/cl.1999.705openalex-snapshot
Rhodium Catalyzed Transformation of 4-Pentynyl Cyclopropanes to Bicyclo[4.3.0]nonenones via Cleavage of Cyclopropane Ring
inferredcites →https://doi.org/10.1246/cl.2005.1462openalex-snapshot
Ruthenium-catalyzed Reconstructive Synthesis of Functional Organic Molecules via Cleavage of Carbon–Carbon Bonds
inferredcites →https://doi.org/10.1351/pac200274010025openalex-snapshot
Toward the ideal synthesis. New transition metal-catalyzed reactions inspired by novel medicinal leads
inferredcites →https://doi.org/10.1351/pac200880051097openalex-snapshot
Nickel-catalyzed carbocyanation of alkynes
inferredcites →https://doi.org/10.6023/cjoc201212033openalex-snapshot
Recent Progress in the Research of Transition-Metal-Catalyzed C—CN Bond Cleavage

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/047084289x.rn00699.pub2openalex-snapshot
Chloro(1,5‐Cyclooctadiene)Rhodium(I) Dimer
inferred← citeshttps://doi.org/10.1002/9780470842898.rn00699openalex-snapshot
Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
inferred← citeshttps://doi.org/10.1002/9783527346028.ch8openalex-snapshot
Theoretical Study of Rh ‐Catalysis
inferred← citeshttps://doi.org/10.1002/9783527804801.ch6openalex-snapshot
Double Functionalization of Alkynes by Addition of Carbon–Element Bonds
inferred← citeshttps://doi.org/10.1002/9783527811908.ch10openalex-snapshot
Rhodium( I )‐Catalyzed Cycloadditions Involving Vinylcyclopropanes and Their Derivatives
inferred← citeshttps://doi.org/10.1002/adsc.201800536openalex-snapshot
Copper‐Catalyzed Domino C−C Bond Cleavage of 2,3‐Unsubstituted Indoles/Indolines and Oxindoles via Oxidation and Directed Insertion of 2‐Aminopyridines: Direct Access to Quinazolinediones
inferred← citeshttps://doi.org/10.1002/adsc.201801475openalex-snapshot
Transition Metal‐Free Difunctionalization of C−C Bond with Sodium Sulfinates and Water Leading to (E)‐1‐Phenyl‐4‐sulfonylbut‐1‐enes
inferred← citeshttps://doi.org/10.1002/adsc.201900799openalex-snapshot
Palladium‐Catalyzed Cross‐Coupling of Furfuryl Alcohols with Arylboronic Acids via Aromatization‐Driven Carbon−Carbon Bond Cleavage to Synthesize 5‐Arylfurfuryl Alcohols and 2,5‐Diaryl Furans
inferred← citeshttps://doi.org/10.1002/adsc.202001430openalex-snapshot
Rh(III)‐Catalyzed Csp2−Csp3 Bond Cleavage/Carbonylethylation of α‐Indolyl Alcohols
inferred← citeshttps://doi.org/10.1002/adsc.202100293openalex-snapshot
Palladium‐Catalyzed Alkene Thioacylation: A C−S Bond Activation Approach for Accessing Indanone Derivatives
inferred← citeshttps://doi.org/10.1002/adsc.202200256openalex-snapshot
Electrosynthesis of ortho‐Amino Aryl Ketones by Aerobic Electrooxidative Cleavage of the C(2)=C(3)/C(2)−N Bonds of N‐Boc Indoles
inferred← citeshttps://doi.org/10.1002/adsc.202301040openalex-snapshot
Cobalt‐Catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes
inferred← citeshttps://doi.org/10.1002/adsc.70361openalex-snapshot
Ru(II)‐Catalyzed CH Bond Activation and Alkyne Annulation Reactions
inferred← citeshttps://doi.org/10.1002/adsc.9589openalex-snapshot
Pd‐Catalyzed Regio‐ and Stereoselective Ring‐Opening Hydrosulfonylation of Methylenecyclopropanes for Branched Allylic Sulfones
inferred← citeshttps://doi.org/10.1002/advs.201902020openalex-snapshot
Visible Light–Driven Cascade Carbon–Carbon Bond Scission for Organic Transformations and Plastics Recycling
inferred← citeshttps://doi.org/10.1002/advs.202401243openalex-snapshot
High‐Valent Copper Catalysis Enables Regioselective Fluoroarylation of Gem ‐Difluorinated Cyclopropanes
inferred← citeshttps://doi.org/10.1002/advs.202407931openalex-snapshot
Ring Transformation of Cyclopropenes to Benzo‐Fused Five‐Membered Oxa‐ and Aza‐Heterocycles via a Formal [4+1] Cyclization
inferred← citeshttps://doi.org/10.1002/ajoc.201800294openalex-snapshot
RhI‐Catalyzed Intramolecular [3+2] Cycloaddition of 1‐Allene‐vinylcyclopropanes
inferred← citeshttps://doi.org/10.1002/ajoc.202100571openalex-snapshot
A Formal [3+3+1] Reaction of Enyne‐Methylenecyclopropanes through Au(I)‐Catalyzed Enyne Cycloisomerization and Rh(I)‐Catalyzed [6+1] Reaction of Vinylspiropentanes and CO
inferred← citeshttps://doi.org/10.1002/ajoc.202400459openalex-snapshot
Solid‐State Melt Rearrangement of Azidofluorenes for the Synthesis of Phenanthridine Derivatives
inferred← citeshttps://doi.org/10.1002/ange.201704068openalex-snapshot
γ‐Functionalizations of Amines through Visible‐Light‐Mediated, Redox‐Neutral C−C Bond Cleavage
inferred← citeshttps://doi.org/10.1002/ange.201709916openalex-snapshot
Ruthenium(0)‐katalysierte Cycloaddition von 1,2‐Diolen, Ketolen oder Dionen durch Alkohol‐vermittelte Wasserstoffübertragung
inferred← citeshttps://doi.org/10.1002/ange.201711394openalex-snapshot
Intramolecular Acetyl Transfer to Olefins by Catalytic C−C Bond Activation of Unstrained Ketones
inferred← citeshttps://doi.org/10.1002/ange.201712487openalex-snapshot
Fused‐Ring Formation by an Intramolecular “Cut‐and‐Sew” Reaction between Cyclobutanones and Alkynes
inferred← citeshttps://doi.org/10.1002/ange.201713096openalex-snapshot
Rhodium(I)‐Catalyzed Cycloisomerization of Homopropargylallene‐Alkynes through C(sp3)−C(sp) Bond Activation
inferred← citeshttps://doi.org/10.1002/ange.201713179openalex-snapshot
Rhodium(I)‐Catalyzed Carboacylation/Aromatization Cascade Initiated by Regioselective C−C Activation of Benzocyclobutenones
inferred← citeshttps://doi.org/10.1002/ange.201801612openalex-snapshot
Cascade Claisen Rearrangement: Rapid Synthesis of Polysubstituted Salicylaldehydes and Total Syntheses of Hemigossypol and Gossypol
inferred← citeshttps://doi.org/10.1002/ange.201803156openalex-snapshot
Intermolecular σ‐Bond Cross‐Exchange Reaction between Cyclopropenones and (Benzo)silacyclobutanes: Straightforward Access towards Sila(benzo)cycloheptenones
inferred← citeshttps://doi.org/10.1002/ange.201807542openalex-snapshot
Cobalt‐Catalyzed Reductive Dimethylcyclopropanation of 1,3‐Dienes
inferred← citeshttps://doi.org/10.1002/ange.201811460openalex-snapshot
Carbonylative C−C Bond Activation of Electron‐Poor Cyclopropanes: Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides
inferred← citeshttps://doi.org/10.1002/ange.201906990openalex-snapshot
Synthesis of Polyethylene with In‐Chain α,β‐Unsaturated Ketone and Isolated Ketone Units: Pd‐Catalyzed Ring‐Opening Copolymerization of Cyclopropenone with Ethylene
inferred← citeshttps://doi.org/10.1002/ange.201910276openalex-snapshot
Modular Access to Eight‐Membered N‐Heterocycles by Directed Carbonylative C−C Bond Activation of Aminocyclopropanes
inferred← citeshttps://doi.org/10.1002/ange.201910767openalex-snapshot
Enantioselektive Desymmetrisierung von Cyclobutanonen: Eine Schnellstraße zu molekularer Komplexität
inferred← citeshttps://doi.org/10.1002/ange.201913130openalex-snapshot
Nickel(0)‐Catalyzed Enantioselective [3+2] Annulation of Cyclopropenones and α,β‐Unsaturated Ketones/Imines
inferred← citeshttps://doi.org/10.1002/ange.201913373openalex-snapshot
Hypervalent‐Iodine‐Mediated Carbon–Carbon Bond Cleavage and Dearomatization of 9H‐Fluoren‐9‐ols
inferred← citeshttps://doi.org/10.1002/ange.201915657openalex-snapshot
Übergangsmetallvermittelte Spaltung von C‐C‐Einfachbindungen
inferred← citeshttps://doi.org/10.1002/ange.201915821openalex-snapshot
Asymmetric Total Syntheses of Di‐ and Sesquiterpenoids by Catalytic C−C Activation of Cyclopentanones
inferred← citeshttps://doi.org/10.1002/ange.202001142openalex-snapshot
Chiral Aluminum Complex Controls Enantioselective Nickel‐Catalyzed Synthesis of Indenes: C−CN Bond Activation
inferred← citeshttps://doi.org/10.1002/ange.202005882openalex-snapshot
Pd‐Senphos Catalyzed trans‐Selective Cyanoboration of 1,3‐Enynes
inferred← citeshttps://doi.org/10.1002/ange.202007371openalex-snapshot
[C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights
inferred← citeshttps://doi.org/10.1002/ange.202008886openalex-snapshot
Selective Alkynylallylation of the C−C σ Bond of Cyclopropenes
inferred← citeshttps://doi.org/10.1002/ange.202012720openalex-snapshot
Photocatalytic Aerobic Oxidative Ring Expansion of Cyclic Ketones to Macrolactones by Cerium and Cyanoanthracene Catalysis
inferred← citeshttps://doi.org/10.1002/ange.202014308openalex-snapshot
3‐(Methoxycarbonyl)Cyclobutenone as a Reactive Dienophile in Enantioselective Diels–Alder Reactions Catalyzed by Chiral Oxazaborolidinium Ions
inferred← citeshttps://doi.org/10.1002/ange.202015202openalex-snapshot
Highly Enantioselective Cobalt‐Catalyzed (3+2) Cycloadditions of Alkynylidenecyclopropanes
inferred← citeshttps://doi.org/10.1002/ange.202106007openalex-snapshot
Intermolecular [5+2] Annulation between 1‐Indanones and Internal Alkynes by Rhodium‐Catalyzed C–C Activation
inferred← citeshttps://doi.org/10.1002/ange.202108258openalex-snapshot
Mild Intermolecular Synthesis of a Cyclopropane‐Containing Tricyclic Skeleton: Unusual Reactivity of Isobenzopyryliums
inferred← citeshttps://doi.org/10.1002/ange.202108589openalex-snapshot
Ring Expansion Fluorination of Unactivated Cyclopropanes Mediated by a New Monofluoroiodane(III) Reagent
inferred← citeshttps://doi.org/10.1002/ange.202112695openalex-snapshot
Dynamische kinetische Sensibilisierung von β‐Dicarbonyl‐verbindungen – Zugang zu mittelgroßen Ringen durch eine De‐Mayo‐artige Ringerweiterung
inferred← citeshttps://doi.org/10.1002/ange.202200052openalex-snapshot
Palladium‐Catalyzed Stagewise Strain‐Release‐Driven C−C Activation of Bicyclo[1.1.1]pentanyl Alcohols
inferred← citeshttps://doi.org/10.1002/ange.202202703openalex-snapshot
Rhodium‐Catalyzed (4+1) Cycloaddition between Benzocyclobutenones and Styrene‐Type Alkenes
inferred← citeshttps://doi.org/10.1002/ange.202205007openalex-snapshot
An endo‐Directing‐Group Strategy Unlocks Enantioselective (3+1+2) Carbonylative Cycloadditions of Aminocyclopropanes
inferred← citeshttps://doi.org/10.1002/ange.202211080openalex-snapshot
Directing Group‐Free Formal Suzuki–Miyaura Coupling of Simple Ketones Enabled by Activation of Unstrained C−C Bonds
inferred← citeshttps://doi.org/10.1002/ange.202214633openalex-snapshot
Trifluoromethylation of Carbonyl and Unactivated Olefin Derivatives by C(sp3)−C Bond Cleavage
inferred← citeshttps://doi.org/10.1002/ange.202303727openalex-snapshot
Palladium‐Catalyzed Enantio‐ and Regioselective Ring‐Opening Hydrophosphinylation of Methylenecyclopropanes
inferred← citeshttps://doi.org/10.1002/ange.202307129openalex-snapshot
Rhodium‐Catalyzed Regio‐ and Diastereoselective [3+2] Cycloaddition of gem‐Difluorinated Cyclopropanes with Internal Olefins
inferred← citeshttps://doi.org/10.1002/ange.202309681openalex-snapshot
Catalytic Asymmetric Ring‐Opening Reactions of Unstrained Heterocycles Using Cobalt Vinylidenes
inferred← citeshttps://doi.org/10.1002/ange.202314701openalex-snapshot
Intermolecular Carbophosphination of Alkynes with Phosphole Oxides via Ni−Al Bimetal‐Catalyzed C−P Bond Activation
inferred← citeshttps://doi.org/10.1002/ange.202317433openalex-snapshot
Diastereo‐ and Enantioselective Synthesis of Tetracyclic Cycloheptanols through (4+3) Annulation via C−C/C−H Activation Cascade
inferred← citeshttps://doi.org/10.1002/ange.202405838openalex-snapshot
Type I [4σ+4π] versus [4σ+4π−1] Cycloaddition To Access Medium‐Sized Carbocycles and Discovery of a Liver X Receptor β‐Selective Ligand
inferred← citeshttps://doi.org/10.1002/ange.202413723openalex-snapshot
Strain‐Release‐Driven Electrochemical Skeletal Rearrangement of Non‐Biased Alkyl Cyclopropanes/Butanes
inferred← citeshttps://doi.org/10.1002/ange.202500148openalex-snapshot
Ring Expansion via Palladium‐Catalyzed Aryne Insertion into C−C Bonds of Benzocyclobutenones
inferred← citeshttps://doi.org/10.1002/ange.202509640openalex-snapshot
Enantioselective Synthesis of ε‐Lactams via Rh(I)‐Catalyzed C─C Bond Activation
inferred← citeshttps://doi.org/10.1002/ange.202512579openalex-snapshot
Sequential Heterolytic Carbon‐Halide and Carbon–Carbon Bond Activation in Unactivated Piperidines
inferred← citeshttps://doi.org/10.1002/ange.202520490openalex-snapshot
Ring Expansion of Oximes via Photochemical Aza‐di‐π‐methane Rearrangement
inferred← citeshttps://doi.org/10.1002/ange.3386705openalex-snapshot
Mechanism Reevaluation and Reaction Development in Rhodium‐Catalyzed Cycloaddition of gem ‐Difluorinated Cyclopropanes
inferred← citeshttps://doi.org/10.1002/ange.6371423openalex-snapshot
Transition Metal‐Free Heteroarene Insertion Into C─C Bonds of Benzocyclobutenones
inferred← citeshttps://doi.org/10.1002/anie.201704068openalex-snapshot
γ‐Functionalizations of Amines through Visible‐Light‐Mediated, Redox‐Neutral C−C Bond Cleavage
inferred← citeshttps://doi.org/10.1002/anie.201709916openalex-snapshot
Ruthenium(0)‐Catalyzed Cycloaddition of 1,2‐Diols, Ketols, or Diones via Alcohol‐Mediated Hydrogen Transfer
inferred← citeshttps://doi.org/10.1002/anie.201711394openalex-snapshot
Intramolecular Acetyl Transfer to Olefins by Catalytic C−C Bond Activation of Unstrained Ketones
inferred← citeshttps://doi.org/10.1002/anie.201712487openalex-snapshot
Fused‐Ring Formation by an Intramolecular “Cut‐and‐Sew” Reaction between Cyclobutanones and Alkynes
inferred← citeshttps://doi.org/10.1002/anie.201713096openalex-snapshot
Rhodium(I)‐Catalyzed Cycloisomerization of Homopropargylallene‐Alkynes through C(sp3)−C(sp) Bond Activation
inferred← citeshttps://doi.org/10.1002/anie.201713179openalex-snapshot
Rhodium(I)‐Catalyzed Carboacylation/Aromatization Cascade Initiated by Regioselective C−C Activation of Benzocyclobutenones
inferred← citeshttps://doi.org/10.1002/anie.201801612openalex-snapshot
Cascade Claisen Rearrangement: Rapid Synthesis of Polysubstituted Salicylaldehydes and Total Syntheses of Hemigossypol and Gossypol
inferred← citeshttps://doi.org/10.1002/anie.201803156openalex-snapshot
Intermolecular σ‐Bond Cross‐Exchange Reaction between Cyclopropenones and (Benzo)silacyclobutanes: Straightforward Access towards Sila(benzo)cycloheptenones
inferred← citeshttps://doi.org/10.1002/anie.201807542openalex-snapshot
Cobalt‐Catalyzed Reductive Dimethylcyclopropanation of 1,3‐Dienes
inferred← citeshttps://doi.org/10.1002/anie.201811460openalex-snapshot
Carbonylative C−C Bond Activation of Electron‐Poor Cyclopropanes: Rhodium‐Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides
inferred← citeshttps://doi.org/10.1002/anie.201906990openalex-snapshot
Synthesis of Polyethylene with In‐Chain α,β‐Unsaturated Ketone and Isolated Ketone Units: Pd‐Catalyzed Ring‐Opening Copolymerization of Cyclopropenone with Ethylene
inferred← citeshttps://doi.org/10.1002/anie.201910276openalex-snapshot
Modular Access to Eight‐Membered N‐Heterocycles by Directed Carbonylative C−C Bond Activation of Aminocyclopropanes
inferred← citeshttps://doi.org/10.1002/anie.201910767openalex-snapshot
Enantioselective Desymmetrization of Cyclobutanones: A Speedway to Molecular Complexity
inferred← citeshttps://doi.org/10.1002/anie.201913130openalex-snapshot
Nickel(0)‐Catalyzed Enantioselective [3+2] Annulation of Cyclopropenones and α,β‐Unsaturated Ketones/Imines
inferred← citeshttps://doi.org/10.1002/anie.201913373openalex-snapshot
Hypervalent‐Iodine‐Mediated Carbon–Carbon Bond Cleavage and Dearomatization of 9H‐Fluoren‐9‐ols
inferred← citeshttps://doi.org/10.1002/anie.201915657openalex-snapshot
Transition Metal‐Mediated C−C Single Bond Cleavage: Making the Cut in Total Synthesis
inferred← citeshttps://doi.org/10.1002/anie.201915821openalex-snapshot
Asymmetric Total Syntheses of Di‐ and Sesquiterpenoids by Catalytic C−C Activation of Cyclopentanones
inferred← citeshttps://doi.org/10.1002/anie.202001142openalex-snapshot
Chiral Aluminum Complex Controls Enantioselective Nickel‐Catalyzed Synthesis of Indenes: C−CN Bond Activation
inferred← citeshttps://doi.org/10.1002/anie.202005882openalex-snapshot
Pd‐Senphos Catalyzed trans ‐Selective Cyanoboration of 1,3‐Enynes
inferred← citeshttps://doi.org/10.1002/anie.202007371openalex-snapshot
[C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights
inferred← citeshttps://doi.org/10.1002/anie.202008886openalex-snapshot
Selective Alkynylallylation of the C−C σ Bond of Cyclopropenes
inferred← citeshttps://doi.org/10.1002/anie.202012720openalex-snapshot
Photocatalytic Aerobic Oxidative Ring Expansion of Cyclic Ketones to Macrolactones by Cerium and Cyanoanthracene Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202014308openalex-snapshot
3‐(Methoxycarbonyl)Cyclobutenone as a Reactive Dienophile in Enantioselective Diels–Alder Reactions Catalyzed by Chiral Oxazaborolidinium Ions
inferred← citeshttps://doi.org/10.1002/anie.202015202openalex-snapshot
Highly Enantioselective Cobalt‐Catalyzed (3+2) Cycloadditions of Alkynylidenecyclopropanes
inferred← citeshttps://doi.org/10.1002/anie.202106007openalex-snapshot
Intermolecular [5+2] Annulation between 1‐Indanones and Internal Alkynes by Rhodium‐Catalyzed C–C Activation
inferred← citeshttps://doi.org/10.1002/anie.202108258openalex-snapshot
Mild Intermolecular Synthesis of a Cyclopropane‐Containing Tricyclic Skeleton: Unusual Reactivity of Isobenzopyryliums
inferred← citeshttps://doi.org/10.1002/anie.202108589openalex-snapshot
Ring Expansion Fluorination of Unactivated Cyclopropanes Mediated by a New Monofluoroiodane(III) Reagent
inferred← citeshttps://doi.org/10.1002/anie.202112695openalex-snapshot
Dynamic Kinetic Sensitization of β‐Dicarbonyl Compounds—Access to Medium‐Sized Rings by De Mayo‐Type Ring Expansion
inferred← citeshttps://doi.org/10.1002/anie.202200052openalex-snapshot
Palladium‐Catalyzed Stagewise Strain‐Release‐Driven C−C Activation of Bicyclo[1.1.1]pentanyl Alcohols
inferred← citeshttps://doi.org/10.1002/anie.202202703openalex-snapshot
Rhodium‐Catalyzed (4+1) Cycloaddition between Benzocyclobutenones and Styrene‐Type Alkenes
inferred← citeshttps://doi.org/10.1002/anie.202205007openalex-snapshot
An endo‐Directing‐Group Strategy Unlocks Enantioselective (3+1+2) Carbonylative Cycloadditions of Aminocyclopropanes
inferred← citeshttps://doi.org/10.1002/anie.202211080openalex-snapshot
Directing Group‐Free Formal Suzuki–Miyaura Coupling of Simple Ketones Enabled by Activation of Unstrained C−C Bonds
inferred← citeshttps://doi.org/10.1002/anie.202214633openalex-snapshot
Trifluoromethylation of Carbonyl and Unactivated Olefin Derivatives by C( sp 3 )−C Bond Cleavage
inferred← citeshttps://doi.org/10.1002/anie.202303727openalex-snapshot
Palladium‐Catalyzed Enantio‐ and Regioselective Ring‐Opening Hydrophosphinylation of Methylenecyclopropanes
inferred← citeshttps://doi.org/10.1002/anie.202307129openalex-snapshot
Rhodium‐Catalyzed Regio‐ and Diastereoselective [3+2] Cycloaddition of gem ‐Difluorinated Cyclopropanes with Internal Olefins
inferred← citeshttps://doi.org/10.1002/anie.202309681openalex-snapshot
Catalytic Asymmetric Ring‐Opening Reactions of Unstrained Heterocycles Using Cobalt Vinylidenes
inferred← citeshttps://doi.org/10.1002/anie.202314701openalex-snapshot
Intermolecular Carbophosphination of Alkynes with Phosphole Oxides via Ni−Al Bimetal‐Catalyzed C−P Bond Activation
inferred← citeshttps://doi.org/10.1002/anie.202317433openalex-snapshot
Diastereo‐ and Enantioselective Synthesis of Tetracyclic Cycloheptanols through (4+3) Annulation via C−C/C−H Activation Cascade
inferred← citeshttps://doi.org/10.1002/anie.202405838openalex-snapshot
Type I [4σ+4π] versus [4σ+4π−1] Cycloaddition To Access Medium‐Sized Carbocycles and Discovery of a Liver X Receptor β‐Selective Ligand
inferred← citeshttps://doi.org/10.1002/anie.202413723openalex-snapshot
Strain‐Release‐Driven Electrochemical Skeletal Rearrangement of Non‐Biased Alkyl Cyclopropanes/Butanes
inferred← citeshttps://doi.org/10.1002/anie.202500148openalex-snapshot
Ring Expansion via Palladium‐Catalyzed Aryne Insertion into C−C Bonds of Benzocyclobutenones
inferred← citeshttps://doi.org/10.1002/anie.202509640openalex-snapshot
Enantioselective Synthesis of ε‐Lactams via Rh(I)‐Catalyzed C─C Bond Activation
inferred← citeshttps://doi.org/10.1002/anie.202512579openalex-snapshot
Sequential Heterolytic Carbon‐Halide and Carbon–Carbon Bond Activation in Unactivated Piperidines
inferred← citeshttps://doi.org/10.1002/anie.202520490openalex-snapshot
Ring Expansion of Oximes via Photochemical Aza‐di‐π‐methane Rearrangement
inferred← citeshttps://doi.org/10.1002/anie.3386705openalex-snapshot
Mechanism Reevaluation and Reaction Development in Rhodium‐Catalyzed Cycloaddition of gem ‐Difluorinated Cyclopropanes
inferred← citeshttps://doi.org/10.1002/anie.6371423openalex-snapshot
Transition Metal‐Free Heteroarene Insertion Into C─C Bonds of Benzocyclobutenones
inferred← citeshttps://doi.org/10.1002/asia.201700239openalex-snapshot
Exchanging Alkyl Groups through Unstrained C−C Bond Cleavage in the Presence of a Copper Catalyst
inferred← citeshttps://doi.org/10.1002/asia.201900443openalex-snapshot
Transition‐Metal‐Mediated Cleavage of C−C Bonds in Aromatic Rings
inferred← citeshttps://doi.org/10.1002/asia.201901067openalex-snapshot
Exploiting Strained Rings in Chelation Guided C−H Functionalization: Integration of C−H Activation with Ring Cleavage
inferred← citeshttps://doi.org/10.1002/asia.202401768openalex-snapshot
Palladium‐Catalyzed Cross‐Coupling of Ynones with Aryl Bromides Enabled by C(O)‐C(sp) Bond Activation
inferred← citeshttps://doi.org/10.1002/cctc.201800237openalex-snapshot
Computational Insights into the Gold‐Catalyzed Ring‐Opening of Methylenecyclopropanes and Vinylcyclopropanes with Sulfonamides
inferred← citeshttps://doi.org/10.1002/cctc.201902069openalex-snapshot
Theoretical Study of Rhodium‐Catalyzed C−C Activation of Cyclobutanones: Origin of Ligand‐Controlled Product Selectivity
inferred← citeshttps://doi.org/10.1002/ceur.202500005openalex-snapshot
Palladium‐Catalyzed [3+2] Cycloadditions of Alkylidenecyclopropanes to Imines: A Direct Approach to Pyrrolidine Scaffolds
inferred← citeshttps://doi.org/10.1002/chem.201701191openalex-snapshot
Manganese(I)‐Catalyzed Dispersion‐Enabled C−H/C−C Activation
inferred← citeshttps://doi.org/10.1002/chem.201702316openalex-snapshot
Mechanism and Origins of the Chemo‐ and Regioselectivities in Nickel‐Catalyzed Intermolecular Cycloadditions of Benzocyclobutenones with 1,3‐Dienes
inferred← citeshttps://doi.org/10.1002/chem.201801239openalex-snapshot
Rhodium(I)‐Catalyzed Ring‐Closing Reaction of Allene–Alkene–Alkynes: One‐Step Construction of Tricyclo[6.4.0.02,6] and Bicyclo[6.3.0] Skeletons from Linear Carbon Chains
inferred← citeshttps://doi.org/10.1002/chem.201804044openalex-snapshot
Regioselective Activation of a Sterically More Hindered C−C Bond of Biphenylenes Using an Alkene as Both a Directing Group and a Reaction Moiety
inferred← citeshttps://doi.org/10.1002/chem.201804170openalex-snapshot
RhI‐Catalyzed Carbonylative [3+1] Construction of Cyclobutenones via C−C σ‐Bond Activation of Cyclopropenes
inferred← citeshttps://doi.org/10.1002/chem.202004923openalex-snapshot
Recent Advances in Enantioselective Desymmetrizations of Prochiral Oxetanes
inferred← citeshttps://doi.org/10.1002/chem.202100390openalex-snapshot
Synthesis of Spirocycles via Ni‐Catalyzed Intramolecular Coupling of Thioesters and Olefins
inferred← citeshttps://doi.org/10.1002/chem.202100426openalex-snapshot
Co‐Catalyzed Asymmetric Intramolecular [3+2] Cycloaddition of Yne‐Alkylidenecyclopropanes and its Reaction Mechanism
inferred← citeshttps://doi.org/10.1002/chem.202500595openalex-snapshot
Skeletal Rearrangements of Amides via Breaking Inert Bonds
inferred← citeshttps://doi.org/10.1002/chem.202503515openalex-snapshot
Pd‐Catalyzed C─C Bond Borylation of Biphenylenes Leading to Tri‐ Ortho ‐Substituted Biaryls
inferred← citeshttps://doi.org/10.1002/cjoc.201900384openalex-snapshot
Cu‐Catalyzed Selective Oxy‐Cyanoalkylation of Allylamines with Cycloketone Oxime Esters and CO2
inferred← citeshttps://doi.org/10.1002/cjoc.202100879openalex-snapshot
Dancing on Ropes ‐ Enantioselective Functionalization of Preformed Four‐Membered Carbocycles
inferred← citeshttps://doi.org/10.1002/cjoc.202300525openalex-snapshot
Modular Synthesis of Multi‐substituted Cyclobutanones Enabled by Oxyallyl Cations†
inferred← citeshttps://doi.org/10.1002/cjoc.70107openalex-snapshot
Molecular Editing of Cycloketones via Deoxygenative Coupling Enabled by Dual Photoexcited Palladium and Photoredox Catalysis
inferred← citeshttps://doi.org/10.1002/cssc.202002032openalex-snapshot
Visible‐Light Photoredox‐Catalyzed Ring‐Opening Carboxylation of Cyclic Oxime Esters with CO2
inferred← citeshttps://doi.org/10.1002/ejic.202300192openalex-snapshot
Nickelacyclobutanes: Versatile Reactivity and Role as Catalytic Intermediates
inferred← citeshttps://doi.org/10.1002/ejoc.201900111openalex-snapshot
Recent Advances of Biphenylene: Synthesis, Reactions and Uses
inferred← citeshttps://doi.org/10.1002/ejoc.202001007openalex-snapshot
Mechanism and Regioselectivity of Intramolecular [2+2] Cycloaddition of Ene–Ketenes: A DFT Study
inferred← citeshttps://doi.org/10.1002/ejoc.202001137openalex-snapshot
Direct Transformation of Alkylarenes into N‐(Pyridine‐2‐yl)amides by C(sp3)–C(sp3) Bond Cleavage
inferred← citeshttps://doi.org/10.1002/ejoc.202001270openalex-snapshot
Decarbonylative Issues Involved in Ru(II)‐Catalyzed [6+2−1] Annulation Reaction of Hydroxychromone with Alkyne: A DFT Study
inferred← citeshttps://doi.org/10.1002/ejoc.202301225openalex-snapshot
Catalytic Asymmetric Ring Opening Reactions of Vinylcyclopropanes
inferred← citeshttps://doi.org/10.1002/ejoc.202501188openalex-snapshot
Single‐Atom Skeletal Editing of Aromatics: Advances in Carbon‐to‐Nitrogen and Nitrogen‐to‐Carbon Transmutation
inferred← citeshttps://doi.org/10.1002/hlca.202100184openalex-snapshot
Nickel‐Catalyzed Ring Expansion of Cyclobutanones towards Indanones
inferred← citeshttps://doi.org/10.1002/tcr.202300331openalex-snapshot
Electrochemical C−H/C−C Bond Oxygenation: A Potential Technology for Plastic Depolymerization
inferred← citeshttps://doi.org/10.1007/s11030-021-10363-8openalex-snapshot
Iron-catalyzed intermolecular cross-dehydrogenative C(sp3)–H/C(sp)–H coupling of pyrimidine bearing 4-thiazolidinones with terminal alkynes
inferred← citeshttps://doi.org/10.1007/s11426-018-9333-xopenalex-snapshot
Recent advances in Ni−Al bimetallic catalysis for unreactive bond transformation
inferred← citeshttps://doi.org/10.1007/s11426-021-1062-yopenalex-snapshot
Cobalt-catalyzed atom-economical, diastereo- and enantioselective coupling of aldimines and cyclopropanols
inferred← citeshttps://doi.org/10.1007/s11426-021-1068-2openalex-snapshot
Bimetallic anchoring catalysis for C-H and C-C activation
inferred← citeshttps://doi.org/10.1007/s11426-022-1251-4openalex-snapshot
Cobalt-catalyzed divergent functionalization of N-sulfonyl amines via β-carbon elimination
inferred← citeshttps://doi.org/10.1007/s11426-024-2075-6openalex-snapshot
Electro-reductive carboxylation of acyclic C(sp3)–C(sp3) bonds in aromatic hydrocarbons with CO2
inferred← citeshttps://doi.org/10.1016/j.cclet.2021.04.006openalex-snapshot
Mechanism and selectivity of nickel-catalyzed [3 + 2] cycloaddition of cyclopropenones and α,β-unsaturated ketones: A computational study
inferred← citeshttps://doi.org/10.1016/j.cclet.2022.02.079openalex-snapshot
Diastereodivergent [4 + 2] annulation of biphenylenes with enones via nickel(0)-catalyzed C C bond activation
inferred← citeshttps://doi.org/10.1016/j.cclet.2022.02.082openalex-snapshot
DUPLICATE: Diastereodivergent [4 + 2] annulation of biphenylenes with enones via nickel(0)-catalyzed CC bond activation
inferred← citeshttps://doi.org/10.1016/j.cclet.2026.113394openalex-snapshot
Visible-light photocatalyzed redox-neutral carboxylation of C−C bonds in ketone derivatives with CO2
inferred← citeshttps://doi.org/10.1016/j.ccr.2020.213213openalex-snapshot
Metal-mediated cleavage of unsaturated C-C bonds
inferred← citeshttps://doi.org/10.1016/j.cej.2026.176236openalex-snapshot
Polyethylene upcycling to selective monoaromatics: Revisiting porosity-acidity roles in ZSM-5 frameworks
inferred← citeshttps://doi.org/10.1016/j.checat.2023.100530openalex-snapshot
Photocatalytic deconstructive aliphatic carbon–carbon bond cleavage and functionalization of unactivated alcohols
inferred← citeshttps://doi.org/10.1016/j.chempr.2019.11.009openalex-snapshot
Selective C-C Bond Scission of Ketones via Visible-Light-Mediated Cerium Catalysis
inferred← citeshttps://doi.org/10.1016/j.chempr.2019.12.013openalex-snapshot
Deconstructive Functionalization of Ketones via an LMCT-Promoted C–C Cleavage
inferred← citeshttps://doi.org/10.1016/j.chempr.2024.08.005openalex-snapshot
Enantioselective desymmetrization and parallel kinetic resolution of cyclopropanes via C–C activation: Synthesis of chiral β-lactams
inferred← citeshttps://doi.org/10.1016/j.chempr.2025.102622openalex-snapshot
Downsizing Lactams via Rh-Catalyzed C–C Activation
inferred← citeshttps://doi.org/10.1016/j.isci.2022.104505openalex-snapshot
Homologation of aryl ketones to long-chain ketones and aldehydes via C–C bond cleavage
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2017.12.036openalex-snapshot
Theoretical insight into the mechanisms of palladium-catalyzed intramolecular insertion of alkenes into the carbon-nitrogen bond of β-lactam
inferred← citeshttps://doi.org/10.1016/j.jscs.2024.101848openalex-snapshot
Selective C–C bond cleavage of cycloketoximes via iminyl radicals and distal carbon radicals through photocatalysis
inferred← citeshttps://doi.org/10.1016/j.mcat.2025.115055openalex-snapshot
Theoretical studies on the mechanism of Rh-catalyzed [(3+2+2)] cycloisomerization reactions of dienophile-substituted alkylidenecyclopropanes
inferred← citeshttps://doi.org/10.1016/j.mcat.2025.115097openalex-snapshot
DFT mechanistic study of Rh(I)-catalyzed C–C bond activation in benzocyclopentane alkoxy derivatives: Effects of substituents, ligands, and additives
inferred← citeshttps://doi.org/10.1016/j.tet.2018.09.034openalex-snapshot
Computational study of Rh(I)-Catalyzed Cycloaddition–Fragmentation of N-cyclopropylacrylamides
inferred← citeshttps://doi.org/10.1016/j.tet.2019.130563openalex-snapshot
Rh(I)-catalyzed ring-opening of cyclobutanols via C–C bond activation: Synthesis of cis-olefin with a remote aldehyde
inferred← citeshttps://doi.org/10.1016/j.tet.2019.130818openalex-snapshot
Acid-promoted cleavage of the C–C double bond of N-(2-Hydroxylphenyl)enaminones for the synthesis of benzoxazoles
inferred← citeshttps://doi.org/10.1016/j.tetlet.2019.02.040openalex-snapshot
Total synthesis of penta-Me amurensin H and diptoindonesin G featuring a Rh-catalyzed carboacylation/aromatization cascade enabled by C C activation
inferred← citeshttps://doi.org/10.1016/j.tetlet.2021.153116openalex-snapshot
An expedient synthesis of cyanoformates via DAST-mediated C C bond cleavage of α-oximino-β-ketoesters
inferred← citeshttps://doi.org/10.1016/j.tetlet.2021.153132openalex-snapshot
Pyridine-directed carbon–carbon single bond activation: Rhodium-catalyzed decarbonylation of aryl and heteroaromatic ketones
inferred← citeshttps://doi.org/10.1016/j.tetlet.2022.153656openalex-snapshot
Facile synthesis of δ-ketoesters via formal two-carbon insertion into β-ketoesters
inferred← citeshttps://doi.org/10.1016/j.tetlet.2023.154887openalex-snapshot
Direct amidation of 1-aryl-2,2,2-trifluoroethanones with isothiocyanates via C–C bond cleavage strategy
inferred← citeshttps://doi.org/10.1016/j.trechm.2019.12.002openalex-snapshot
Carbon‒Carbon Bond Activation of Ketones
inferred← citeshttps://doi.org/10.1021/acs.accounts.2c00400openalex-snapshot
Deconstructive Synthesis of Bridged and Fused Rings via Transition-Metal-Catalyzed “Cut-and-Sew” Reactions of Benzocyclobutenones and Cyclobutanones
inferred← citeshttps://doi.org/10.1021/acs.accounts.3c00230openalex-snapshot
Transition-Metal-Catalyzed C–C Bond Formation from C–C Activation
inferred← citeshttps://doi.org/10.1021/acs.accounts.4c00417openalex-snapshot
Recent Advances in Electrochemical Carboxylation with CO 2
inferred← citeshttps://doi.org/10.1021/acs.accounts.4c00510openalex-snapshot
Ligand-to-Metal Charge Transfer (LMCT) Catalysis: Harnessing Simple Cerium Catalysts for Selective Functionalization of Inert C–H and C–C Bonds
inferred← citeshttps://doi.org/10.1021/acs.accounts.5c00014openalex-snapshot
Skeletal Modification via Activation of Relatively Unstrained C–C Bonds
inferred← citeshttps://doi.org/10.1021/acs.accounts.7b00108openalex-snapshot
Oxygenation via C–H/C–C Bond Activation with Molecular Oxygen
inferred← citeshttps://doi.org/10.1021/acs.chemrev.0c00151openalex-snapshot
C–C Bond Cleavages of Cyclopropenes: Operating for Selective Ring-Opening Reactions
inferred← citeshttps://doi.org/10.1021/acs.chemrev.0c00167openalex-snapshot
Creating Stereocenters within Acyclic Systems by C–C Bond Cleavage of Cyclopropanes
inferred← citeshttps://doi.org/10.1021/acs.chemrev.0c00569openalex-snapshot
Cleavage of Carbon–Carbon σ-Bonds of Four-Membered Rings
inferred← citeshttps://doi.org/10.1021/acs.chemrev.1c00256openalex-snapshot
Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis
inferred← citeshttps://doi.org/10.1021/acs.chemrev.3c00219openalex-snapshot
Carbon–Carbon Bond Cleavage for Late-Stage Functionalization
inferred← citeshttps://doi.org/10.1021/acs.chemrev.6c00360openalex-snapshot
Successive Ring Expansion Strategies for the Synthesis of Macrocycles and Medium-Sized Rings
inferred← citeshttps://doi.org/10.1021/acs.chemrev.7b00382openalex-snapshot
Transition-Metal-Catalyzed Cross-Couplings through Carbene Migratory Insertion
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.1c02127openalex-snapshot
The Role of AQ in the Regioselectivity of Strong Alkyl C–O Bond Activation Catalyzed by Pd(OAc)2: A Density Functional Theory Mechanistic Study
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c03065openalex-snapshot
ortho-Fluoro or ortho Effect? Oxidative Addition of Zerovalent Nickel into the C–CN Bond of Substituted Benzonitriles
inferred← citeshttps://doi.org/10.1021/acs.joc.0c00982openalex-snapshot
Serendipitous Synthesis of Pyridoquinazolinones via an Oxidative C–C Bond Cleavage
inferred← citeshttps://doi.org/10.1021/acs.joc.0c01614openalex-snapshot
Ru(II)-Catalyzed Tunable Cascade Reaction via C–H/C–C Bond Cleavage
inferred← citeshttps://doi.org/10.1021/acs.joc.0c02700openalex-snapshot
Palladium-Catalyzed C–C Bond Activation of Cyclopropenone: Modular Access to Trisubstituted α,β-Unsaturated Esters and Amides
inferred← citeshttps://doi.org/10.1021/acs.joc.0c02832openalex-snapshot
C–C Bond Cleavage Initiated Cascade Reaction of β-Enaminones: One-Pot Synthesis of 5-Hydroxy-1H-pyrrol-2(5H)-ones
inferred← citeshttps://doi.org/10.1021/acs.joc.3c01750openalex-snapshot
Pd-Catalyzed Formal [2 + 2]-Retrocyclization of Cyclobutanols via 2-Fold Csp 3 –Csp 3 Bond Cleavage
inferred← citeshttps://doi.org/10.1021/acs.joc.4c00295openalex-snapshot
Carbene-Catalyzed [4+2] Cycloaddition of Cyclobutenones and Isatins for Quick Access to Chiral Chlorine-Containing Spirocyclic δ-Lactones
inferred← citeshttps://doi.org/10.1021/acs.joc.4c01988openalex-snapshot
Stereoselective Synthesis of (Z)-Acrylic Nitriles from the Ruthenium-Catalyzed Coupling Reaction of Nitriles with Unsaturated Carbonyl Compounds via C–C Bond Cleavage
inferred← citeshttps://doi.org/10.1021/acs.joc.5c00059openalex-snapshot
Computational Exploration of Intramolecular Cycloaddition of Cyclobutanone with Alkene Catalyzed by Rhodium Versus Nickel: The Origins of Selectivities
inferred← citeshttps://doi.org/10.1021/acs.joc.5c00497openalex-snapshot
Regiodivergent Annulation Reactions of Chalcones to Indenones and Indanones with C1 Reagents
inferred← citeshttps://doi.org/10.1021/acs.joc.5c00883openalex-snapshot
Phosphine-Catalyzed Nucleophilic Ring Opening of Cyclopropenones with Sulfoximines to Access N-α,β-Unsaturated Acyl Sulfoximines
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