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Living Polymerization of Conjugated Polar Alkenes Catalyzed by N-Heterocyclic Olefin-Based Frustrated Lewis Pairs
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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Coordination Chemistry of Ene‐1,1‐diamines and a Prototype “Carbodicarbene”
inferredcites →https://doi.org/10.1002/anie.201005534openalex-snapshot
Alane‐Based Classical and Frustrated Lewis Pairs in Polymer Synthesis: Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones into High‐Molecular‐Weight Polymers
inferredcites →https://doi.org/10.1002/anie.201202327openalex-snapshot
Nucleophilic Reactivities of Deoxy Breslow Intermediates: How Does Aromaticity Affect the Catalytic Activities of N‐Heterocyclic Carbenes?
inferredcites →https://doi.org/10.1002/anie.201409800openalex-snapshot
Frustrated Lewis Pair Chemistry: Development and Perspectives
inferredcites →https://doi.org/10.1002/anie.201502400openalex-snapshot
Elusive Silane–Alane Complex [SiH⋅⋅⋅Al]: Isolation, Characterization, and Multifaceted Frustrated Lewis Pair Type Catalysis
inferredcites →https://doi.org/10.1002/anie.201700625openalex-snapshot
An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal‐Free Dehydrogenation of Water
inferredcites →https://doi.org/10.1002/anie.201701780openalex-snapshot
Perfectly Alternating and Regioselective Copolymerization of Carbonyl Sulfide and Epoxides by Metal‐Free Lewis Pairs
inferredcites →https://doi.org/10.1002/anie.201703591openalex-snapshot
Expanding the Boundaries of Water‐Tolerant Frustrated Lewis Pair Hydrogenation: Enhanced Back Strain in the Lewis Acid Enables the Reductive Amination of Carbonyls
inferredcites →https://doi.org/10.1002/anie.201705100openalex-snapshot
Frustrated Lewis Pair Mediated 1,2‐Hydrocarbation of Alkynes
inferredcites →https://doi.org/10.1002/anie.201706226openalex-snapshot
Group 6 Transition‐Metal/Boron Frustrated Lewis Pair Templates Activate N 2 and Allow its Facile Borylation and Silylation
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Frustrated Lewis Pair‐Like Reactivity of Rare‐Earth Metal Complexes: 1,4‐Addition Reactions and Polymerizations of Conjugated Polar Alkenes
inferredcites →https://doi.org/10.1002/ijch.201400136openalex-snapshot
Lewis Pair Polymerization of Acrylic Monomers by N‐Heterocyclic Carbenes and B(C6F5)3
inferredcites →https://doi.org/10.1002/pola.28383openalex-snapshot
Controlled ring‐opening polymerization of l ‐lactide and ε‐caprolactone catalyzed by aluminum‐based L ewis pairs or L ewis acid alone
inferredcites →https://doi.org/10.1007/128_2012_372openalex-snapshot
Polymerization by Classical and Frustrated Lewis Pairs
inferredcites →https://doi.org/10.1016/0022-328x(95)05435-ropenalex-snapshot
Metallorganische verbindungen der lanthanoide XCVI. Ylidartige olefinkoordination in komplexen dreiwertiger 4f-elemente
inferredcites →https://doi.org/10.1016/s1387-7003(00)00129-5openalex-snapshot
Lewis acidity of tris(pentafluorophenyl)borane: crystal and molecular structure of B(C6F5)3·OPEt3
inferredcites →https://doi.org/10.1021/acs.macromol.6b00190openalex-snapshot
B(C6F5)3-Catalyzed Group Transfer Polymerization of N,N-Disubstituted Acrylamide Using Hydrosilane: Effect of Hydrosilane and Monomer Structures, Polymerization Mechanism, and Synthesis of α-End-Functionalized Polyacrylamides
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Organic Lewis Pairs Based on Phosphine and Electrophilic Silane for the Direct and Controlled Polymerization of Methyl Methacrylate: Experimental and Theoretical Investigations
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Living Ring-Opening Polymerization of Lactones by N-Heterocyclic Olefin/Al(C6F5)3 Lewis Pairs: Structures of Intermediates, Kinetics, and Mechanism
inferredcites →https://doi.org/10.1021/acs.macromol.7b01678openalex-snapshot
N-Heterocyclic Olefin-Based (Co)polymerization of a Challenging Monomer: Homopolymerization of ω-Pentadecalactone and Its Copolymers with γ-Butyrolactone, δ-Valerolactone, and ε-Caprolactone
inferredcites →https://doi.org/10.1021/acscatal.7b02875openalex-snapshot
Homoleptic Rare-Earth Aryloxide Based Lewis Pairs for Polymerization of Conjugated Polar Alkenes
inferredcites →https://doi.org/10.1021/ar500375jopenalex-snapshot
Frustrated Lewis Pairs: From Concept to Catalysis
inferredcites →https://doi.org/10.1021/cr9000258openalex-snapshot
Coordination Polymerization of Polar Vinyl Monomers by Single-Site Metal Catalysts
inferredcites →https://doi.org/10.1021/ja4069968openalex-snapshot
Ring-Opening Polymerization with Zn(C6F5)2-Based Lewis Pairs: Original and Efficient Approach to Cyclic Polyesters
inferredcites →https://doi.org/10.1021/ja412445nopenalex-snapshot
Probing Site Cooperativity of Frustrated Phosphine/Borane Lewis Pairs by a Polymerization Study
inferredcites →https://doi.org/10.1021/jacs.5b08658openalex-snapshot
From meso-Lactide to Isotactic Polylactide: Epimerization by B/N Lewis Pairs and Kinetic Resolution by Organic Catalysts
inferredcites →https://doi.org/10.1021/jacs.5b09502openalex-snapshot
Dual Catalysis for Selective Ring-Opening Polymerization of Lactones: Evolution toward Simplicity
inferredcites →https://doi.org/10.1021/jacs.5b12536openalex-snapshot
Small Molecule Activation by Intermolecular Zr(IV)-Phosphine Frustrated Lewis Pairs
inferredcites →https://doi.org/10.1021/jacs.5b13545openalex-snapshot
“Inverse” Frustrated Lewis Pairs – Activation of Dihydrogen with Organosuperbases and Moderate to Weak Lewis Acids
inferredcites →https://doi.org/10.1021/jacs.6b00819openalex-snapshot
Metal-Free sp 2 -C–H Borylation as a Common Reactivity Pattern of Frustrated 2-Aminophenylboranes
inferredcites →https://doi.org/10.1021/jacs.6b04046openalex-snapshot
Phospha-Claisen Type Reactions at Frustrated Lewis Pair Frameworks
inferredcites →https://doi.org/10.1021/jacs.6b04129openalex-snapshot
End of Frustration: Catalytic Precision Polymerization with Highly Interacting Lewis Pairs
inferredcites →https://doi.org/10.1021/jacs.6b07245openalex-snapshot
A Frustrated Lewis Pair Catalyzed Asymmetric Transfer Hydrogenation of Imines Using Ammonia Borane
inferredcites →https://doi.org/10.1021/jacs.6b13147openalex-snapshot
Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks
inferredcites →https://doi.org/10.1021/jacs.7b02548openalex-snapshot
CO-Reduction Chemistry: Reaction of a CO-Derived Formylhydridoborate with Carbon Monoxide, with Carbon Dioxide, and with Dihydrogen
inferredcites →https://doi.org/10.1021/jacs.7b05120openalex-snapshot
Single Electron Delivery to Lewis Pairs: An Avenue to Anions by Small Molecule Activation
inferredcites →https://doi.org/10.1021/jacs.7b06897openalex-snapshot
N-Heterocyclic Carbene Initiated Anionic Polymerization of (E,E)-Methyl Sorbate and Subsequent Ring-Closing to Cyclic Poly(alkyl sorbate)
inferredcites →https://doi.org/10.1021/jacs.7b07725openalex-snapshot
Frustrated Lewis Pair Polymers as Responsive Self-Healing Gels
inferredcites →https://doi.org/10.1021/jacs.7b11062openalex-snapshot
B–N Lewis Pair Functionalization of Anthracene: Structural Dynamics, Optoelectronic Properties, and O2 Sensitization
inferredcites →https://doi.org/10.1021/ma500047dopenalex-snapshot
Mechanistic Aspects of Initiation and Deactivation in N -Heterocyclic Olefin Mediated Polymerization of Acrylates with Alane as Activator
inferredcites →https://doi.org/10.1021/ma5019389openalex-snapshot
Chain Propagation and Termination Mechanisms for Polymerization of Conjugated Polar Alkenes by [Al]-Based Frustrated Lewis Pairs
inferredcites →https://doi.org/10.1021/mz500437yopenalex-snapshot
Controlled Divinyl Monomer Polymerization Mediated by Lewis Pairs: A Powerful Synthetic Strategy for Functional Polymers
inferredcites →https://doi.org/10.1021/om5011512openalex-snapshot
Establishing the Hydride Donor Abilities of Main Group Hydrides
inferredcites →https://doi.org/10.1039/c1cc11737hopenalex-snapshot
Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin
inferredcites →https://doi.org/10.1039/c2dt30427aopenalex-snapshot
Lewis pair polymerization by classical and frustrated Lewis pairs: acid, base and monomer scope and polymerization mechanism
inferredcites →https://doi.org/10.1039/c3dt00074eopenalex-snapshot
Dual catalysis: new approaches for the polymerization of lactones and polar olefins
inferredcites →https://doi.org/10.1039/c5py00662gopenalex-snapshot
Ion pairing effects in the zwitterionic ring opening polymerization of δ-valerolactone
inferredcites →https://doi.org/10.1039/c6cy01587eopenalex-snapshot
Insights into the mechanism for ring-opening polymerization of lactide catalyzed by Zn(C 6 F 5 ) 2 /organic superbase Lewis pairs
inferredcites →https://doi.org/10.1039/c7cc01440fopenalex-snapshot
Controlled ring-opening polymerization of α-amino acid N-carboxy-anhydride by frustrated amine/borane Lewis pairs
inferredcites →https://doi.org/10.1039/c7cs00154aopenalex-snapshot
Designing effective ‘frustrated Lewis pair’ hydrogenation catalysts
inferredcites →https://doi.org/10.1039/c7gc03261gopenalex-snapshot
Lewis pairs for ring-opening alternating copolymerization of cyclic anhydrides and epoxides
inferredcites →https://doi.org/10.1055/s-0033-1341248openalex-snapshot
Synthesis of Pyridine- and 2-Oxazoline-Functionalized Vinyl Polymers by Alane-Based Frustrated Lewis Pairs
inferredcites →https://doi.org/10.1098/rsta.2017.0003openalex-snapshot
Chemoselective Lewis pair polymerization of renewable multivinyl-functionalized γ-butyrolactones
inferredcites →https://doi.org/10.1126/science.aaf7229openalex-snapshot
The broadening reach of frustrated Lewis pair chemistry
inferredcites →https://doi.org/10.3390/molecules20069575openalex-snapshot
Reactivity of Amine/E(C6F5)3 (E = B, Al) Lewis Pairs toward Linear and Cyclic Acrylic Monomers: Hydrogenation vs. Polymerization
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Rapid and Scalable Access to Sequence‐Controlled DHDM Multiblock Copolymers by FLP Polymerization
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Lewis Pair Catalyzed Regioselective Polymerization of (E,E)‐Alkyl Sorbates for the Synthesis of (AB)n Sequenced Polymers
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One‐Step Synthesis of Lignin‐Based Triblock Copolymers as High‐Temperature and UV‐Blocking Thermoplastic Elastomers
inferred← citeshttps://doi.org/10.1002/anie.202202448openalex-snapshot
Single‐Step Expeditious Synthesis of Diblock Copolymers with Different Morphologies by Lewis Pair Polymerization‐Induced Self‐Assembly
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An Arbitrarily Regulated Monomer Sequence in Multi‐Block Copolymer Synthesis by Frustrated Lewis Pairs
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Topology Controlled All‐(Meth)acrylic Thermoplastic Elastomers by Multi‐Functional Lewis Pairs‐Mediated Polymerization
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Sequential Radical‐Anionic Polymerizations via Consecutive Photo‐Reduction
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Homogeneous and Heterogeneous Frustrated Lewis Pairs for the Activation and Transformation of CO2
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From Zn(C6F5)2 to ZnEt2‐based Lewis Pairs: Significantly Improved Catalytic Activity and Monomer Adaptability for the Ring‐opening Polymerization of Lactones
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Design and Synthesis of Heterogeneous Frustrated Lewis Pairs for Hydrogenation: From Molecular Immobilization to Defects Engineering
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Synthetic Strategies of N‐Heterocyclic Olefin (NHOs) and Their Recent Application of Organocatalytic Reactions and Beyond
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One‐Pot Transformation of Lignin and Lignin Model Compounds into Benzimidazoles
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Mesoionic N‐Heterocyclic Olefins as Initiators for the Lewis Pair Polymerization of Epoxides
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Frustrated Lewis Pair Systems
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N-heterocyclic olefins catalyzed ring-opening polymerization of N-tosyl aziridines
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Lewis Pair Radical Polymerization “On-Water”
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Precise Synthesis of Ultra-High-Molecular-Weight Polymers Bearing Pendant Vinyl Groups by Living Lewis Pair Polymerization
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Dual Organocatalysts for Highly Active and Selective Synthesis of Linear Poly(γ-butyrolactone)s with High Molecular Weights
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Living and Chemoselective (Co)polymerization of Polar Divinyl Monomers Mediated by Bulky Lewis Pairs
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Lewis Pair Polymerization of Renewable Indenone to Erythro-Ditactic High-Tg Polymers with an Upcycling Avenue
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Anionic Polymerization of Polar Conjugated Diene Monomers with Phosphine as the Initiator and Subsequent Ring Closure without Highly Dilute Conditions
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Intramolecularly Cooperative Catalysis for Copolymerization of Cyclic Thioanhydrides and Epoxides: A Dual Activation Strategy to Well-Defined Polythioesters
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Stepwise Polymerization of Biomass Furan Derivatives to Linear Poly(silyl Ether)s Catalyzed by Frustrated Lewis Pairs
inferred← citeshttps://doi.org/10.1021/acscatal.8b01847openalex-snapshot
Switchable C–H Silylation of Indoles Catalyzed by a Thermally Induced Frustrated Lewis Pair
inferred← citeshttps://doi.org/10.1021/acscatal.8b03017openalex-snapshot
Catalytic Lewis Pair Polymerization of Renewable Methyl Crotonate to High-Molecular-Weight Polymers
inferred← citeshttps://doi.org/10.1021/acscatal.9b03226openalex-snapshot
Recent Trends in Catalytic Polymerizations
inferred← citeshttps://doi.org/10.1021/acsmacrolett.6c00317openalex-snapshot
Neutral Silicon-Based Lewis Pairs for Living Polymerization of N , N -Dialkylacrylamide Monomers
inferred← citeshttps://doi.org/10.1021/acspolymersau.2c00001openalex-snapshot
Zinc-Mediated Allylation-Lactonization One-Pot Reaction to Methylene Butyrolactones: Renewable Monomers for Sustainable Acrylic Polymers with Closed-Loop Recyclability
inferred← citeshttps://doi.org/10.1021/jacs.0c01127openalex-snapshot
Compounded Sequence Control in Polymerization of One-Pot Mixtures of Highly Reactive Acrylates by Differentiating Lewis Pairs
inferred← citeshttps://doi.org/10.1021/jacs.1c00561openalex-snapshot
Synchronous Control of Chain Length/Sequence/Topology for Precision Synthesis of Cyclic Block Copolymers from Monomer Mixtures
inferred← citeshttps://doi.org/10.1021/jacs.2c08173openalex-snapshot
Photoinduced Ion-Pair Inner-Sphere Electron Transfer-Reversible Addition–Fragmentation Chain Transfer Polymerization
inferred← citeshttps://doi.org/10.1021/jacs.4c07818openalex-snapshot
Frustrated Lewis Pair-Promoted Organocatalytic Transformation of Hydrosilanes into Silanols with Water Oxidant
inferred← citeshttps://doi.org/10.1021/jacs.6c01713openalex-snapshot
Perfectly Alternating Copolymerizations of Methacrylates and Coumarin to Robust C–C Main-Chain Polymers with Full Degradability and Depolymerizability
inferred← citeshttps://doi.org/10.1038/s41428-023-00868-4openalex-snapshot
B(C6F5)3-based Lewis pair-catalyzed acrylate polymerization: Lewis base effects on pairing interactions
inferred← citeshttps://doi.org/10.1038/s41467-021-25069-6openalex-snapshot
Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
inferred← citeshttps://doi.org/10.1038/s41557-022-01097-7openalex-snapshot
Recyclable cyclic bio-based acrylic polymer via pairwise monomer enchainment by a trifunctional Lewis pair
inferred← citeshttps://doi.org/10.1038/s41557-025-01751-wopenalex-snapshot
Vinyl polymers with fully degradable carbon backbones enabled by aromatization-driven C–C bond cleavage
inferred← citeshttps://doi.org/10.1039/9781788015738-00473openalex-snapshot
Organopolymerization of Acrylic Monomers
inferred← citeshttps://doi.org/10.1039/9781839162442-00129openalex-snapshot
Other Directions for FLP Hydrogenations
inferred← citeshttps://doi.org/10.1039/c8dt03941kopenalex-snapshot
Living/controlled ring-opening (co)polymerization of lactones by Al-based catalysts with different sidearms
inferred← citeshttps://doi.org/10.1039/c8py00784eopenalex-snapshot
Polarized olefins as enabling (co)catalysts for the polymerization of γ-butyrolactone
inferred← citeshttps://doi.org/10.1039/c8py01090kopenalex-snapshot
An efficient strategy for achieving controlled ring-opening polymerization of O -carboxyanhydrides via amine initiation in collaboration with metal-alkoxide catalysis
inferred← citeshttps://doi.org/10.1039/c8py01257aopenalex-snapshot
Facile synthesis of cylindrical molecular brushes via Lewis pair-mediated polymerization
inferred← citeshttps://doi.org/10.1039/c9cc02900aopenalex-snapshot
Enantioselective reduction of N -alkyl ketimines with frustrated Lewis pair catalysis using chiral borenium ions
inferred← citeshttps://doi.org/10.1039/c9cc06316aopenalex-snapshot
Synthesis, properties & applications of N-heterocyclic olefins in catalysis
inferred← citeshttps://doi.org/10.1039/c9cc06402hopenalex-snapshot
Highly efficient cyclotrimerization of isocyanates using N-heterocyclic olefins under bulk conditions
inferred← citeshttps://doi.org/10.1039/c9py00427kopenalex-snapshot
Living polymerization of acrylamides catalysed by N -heterocyclic olefin-based Lewis pairs
inferred← citeshttps://doi.org/10.1039/c9py00626eopenalex-snapshot
Chemoselective and living/controlled polymerization of polar divinyl monomers by N-heterocyclic olefin based classical and frustrated Lewis pairs
inferred← citeshttps://doi.org/10.1039/c9py01621jopenalex-snapshot
Anionic polymerization of acrylic thioester by using organic base
inferred← citeshttps://doi.org/10.1039/c9py01852bopenalex-snapshot
Regioselective, stereoselective, and living polymerization of divinyl pyridine monomers using rare earth catalysts
inferred← citeshttps://doi.org/10.1039/d0py00572jopenalex-snapshot
Binuclear aluminum Lewis acid and its behavior in the polymerization of methyl methacrylate and n -butyl acrylate
inferred← citeshttps://doi.org/10.1039/d0qi01067gopenalex-snapshot
A computational study of the reactivity of rare-earth/phosphorus Lewis pairs toward polymerization of conjugated polar alkenes
inferred← citeshttps://doi.org/10.1039/d1cc03940gopenalex-snapshot
Brush-like polymers: design, synthesis and applications
inferred← citeshttps://doi.org/10.1039/d1py00579kopenalex-snapshot
Controlled and efficient polymerization of methyl methacrylate catalyzed by pyridinylidenaminophosphine based Lewis pairs
inferred← citeshttps://doi.org/10.1039/d1py00924aopenalex-snapshot
Living polymerization of naturally renewable butyrolactone-based vinylidenes mediated by a frustrated Lewis pair
inferred← citeshttps://doi.org/10.1039/d2dt00691jopenalex-snapshot
Ferrocene tethered boramidinate frustrated Lewis pairs: stepwise capture of CO 2 and CO
inferred← citeshttps://doi.org/10.1039/d3cs00115fopenalex-snapshot
Organoboron-mediated polymerizations
inferred← citeshttps://doi.org/10.1039/d3py00301aopenalex-snapshot
Phosphonium ylide/organoaluminum-based Lewis pairs for the highly efficient living/controlled polymerization of alkyl (meth)acrylates
inferred← citeshttps://doi.org/10.1039/d3py00546aopenalex-snapshot
Insights into the interaction between bis(aryloxide)alkylaluminum and N-heterocyclic carbene: from an abnormal Lewis adduct to a frustrated Lewis pair for efficient polymerizations of biomass-derived acrylic monomers
inferred← citeshttps://doi.org/10.1039/d3py01231jopenalex-snapshot
N , N ′-Bis(imidazolyl)guanidinylphosphines: powerful initiators for conjugate-addition polymerization of Michael-type monomers
inferred← citeshttps://doi.org/10.1039/d3qo00733bopenalex-snapshot
Frustrated-radical-pair-initiated atom transfer radical addition of perfluoroalkyl halides to alkenes
inferred← citeshttps://doi.org/10.1039/d4py01067aopenalex-snapshot
A dual-initiating organic frustrated Lewis pair catalyst for living polymerizations of (bio)acrylates to facilitate the synthesis of metal-free multiblock copolymers
inferred← citeshttps://doi.org/10.1039/d5py00224aopenalex-snapshot
Homo(co)polymerization of bio-derived long alkyl chain methacrylate and methyl methacrylate using a readily accessible aminophosphine-based Lewis pair
inferred← citeshttps://doi.org/10.1039/d5py00789eopenalex-snapshot
Rapid and living polymerization of renewable methylene butyrolactones via borane/phosphine Lewis pairs
inferred← citeshttps://doi.org/10.1039/d5sc90195bopenalex-snapshot
A reflection on frustrated Lewis pairs 20 years on: the gift that keeps on giving
inferred← citeshttps://doi.org/10.1039/d5ta09913gopenalex-snapshot
Bonding-regulated construction of covalent organic framework-supported frustrated Lewis pairs for 1,4-hydrosilylation of α,β-unsaturated ketones
inferred← citeshttps://doi.org/10.1139/cjc-2024-0254openalex-snapshot
Frustrated Lewis pairs reactivity across the periodic table: The 2024 Catalysis Award Lecture
inferred← citeshttps://doi.org/10.6023/a23050196openalex-snapshot
Research Progress in Precision Polymerization of Polar Olefin Monomers by Lewis Pairs★
inferred← citeshttps://doi.org/10.6023/cjoc202305019openalex-snapshot
Silylene/Organoaluminum Lewis Pair System and the Initiation Property for Polymerization of (Meth)acrylates
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