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Mechanism of Si–H Bond Activation for Lewis Acid PBP-Ni-Catalyzed Hydrosilylation of CO2: The Role of the Linear SN2 Type Cooperation

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Structural and Spectroscopic Characterization of an Unprecedented Cationic Transition‐Metal η1‐Silane Complex
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Effective Fixation of CO2 by Iridium‐Catalyzed Hydrosilylation
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Experimental and Theoretical Investigations on the Catalytic Hydrosilylation of Carbon Dioxide with Ruthenium Nitrile Complexes
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CO2 Insertion into Metal–Carbon Bonds: A Computational Study of RhI Pincer Complexes
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Mild Reduction of Carbon Dioxide to Methane with Tertiary Silanes Catalyzed by Platinum and Palladium Silyl Pincer Complexes
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Highly Active and Selective Catalysis of Copper Diphosphine Complexes for the Transformation of Carbon Dioxide into Silyl Formate
inferredcites →https://doi.org/10.1016/j.molcata.2012.10.014openalex-snapshot
Catalytic synthesis of silyl formates with 1 atm of CO2 and their utilization for synthesis of formyl compounds and formic acid
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Anionische rutheniumcluster als katalysatoren bei der hydrosilylierung von kohlendioxid
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Carbon Dioxide Insertion into Group 9 and 10 Metal–Element σ Bonds
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Calculation of Reaction Free Energies in Solution: A Comparison of Current Approaches
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Mechanistic Studies on the Selective Reduction of CO2 to the Aldehyde Level by a Bis(phosphino)boryl (PBP)-Supported Nickel Complex
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The path of chemical reactions - the IRC approach
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Spectroscopic and chemical studies of nickel(II) hydrides
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How Does the Nickel Pincer Complex Catalyze the Conversion of CO2 to a Methanol Derivative? A Computational Mechanistic Study
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Relationship between the gas-phase entropies of molecules and their entropies of solvation in water and 1-octanol
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From Carbon Dioxide to Methane: Homogeneous Reduction of Carbon Dioxide with Hydrosilanes Catalyzed by Zirconium−Borane Complexes
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Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide
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Carbon Monoxide Activation via O-Bound CO Using Decamethylscandocinium–Hydridoborate Ion Pairs
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An Efficient Iridium Catalyst for Reduction of Carbon Dioxide to Methane with Trialkylsilanes
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Zinc Catalysts for On-Demand Hydrogen Generation and Carbon Dioxide Functionalization
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Catalytic CO2 Activation Assisted by Rhenium Hydride/B(C6F5)3 Frustrated Lewis Pairs—Metal Hydrides Functioning as FLP Bases
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A Case Study of the Mechanism of Alcohol-Mediated Morita Baylis–Hillman Reactions. The Importance of Experimental Observations
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The Real Role of N-Heterocyclic Carbene in Reductive Functionalization of CO2: An Alternative Understanding from Density Functional Theory Study
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Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO2
inferredcites →https://doi.org/10.1021/jp810292nopenalex-snapshot
Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions
inferredcites →https://doi.org/10.1021/ol301034jopenalex-snapshot
Copper-Catalyzed Formic Acid Synthesis from CO2 with Hydrosilanes and H2O
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Reactivity of Carbon Dioxide toward Zirconocene Cations
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Experimental and Computational Studies of the Reaction of Carbon Dioxide with Pincer-Supported Nickel and Palladium Hydrides
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trans-[RuIICl(MeCN)5][RuIIICl4(MeCN)2]: A Reactive Intermediate in the Homogeneous Catalyzed Hydrosilylation of Carbon Dioxide
inferredcites →https://doi.org/10.1039/c39810000213openalex-snapshot
Hydrosilylation of carbon dioxide catalysed by ruthenium complexes
inferredcites →https://doi.org/10.1039/c3cy00948copenalex-snapshot
Homogeneous catalytic reduction of CO 2 with hydrosilanes
inferredcites →https://doi.org/10.1039/c3sc22240copenalex-snapshot
CO2 as a C1-building block for the catalytic methylation of amines
inferredcites →https://doi.org/10.1039/c3sc50145kopenalex-snapshot
Decamethylscandocinium-hydrido-(perfluorophenyl)borate: fixation and tandem tris(perfluorophenyl)borane catalysed deoxygenative hydrosilation of carbon dioxide
inferredcites →https://doi.org/10.1039/c5cc09650bopenalex-snapshot
Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex
inferredcites →https://doi.org/10.1039/c5cp07803bopenalex-snapshot
Theoretical estimation of kinetic parameters for nucleophilic substitution reactions in solution: an application of a solution translational entropy model
inferredcites →https://doi.org/10.1039/c5cs00697jopenalex-snapshot
Complexes of ambiphilic ligands: reactivity and catalytic applications
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Functional group migrations between boron and metal centres within transition metal–borane and –boryl complexes and cleavage of H–H, E–H and E–E′ bonds
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A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
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Energy-adjusted a b i n i t i o pseudopotentials for the first row transition elements
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Toward reliable density functional methods without adjustable parameters: The PBE0 model
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Inhomogeneous Electron Gas
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BDEs of Ni(Ni±)−, Pd(Pd±)−, and Pt(Pt±)−X bonds
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Boron-Based Lewis Acid Transition Metal Complexes as Potential Bifunctional Catalysts

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Mechanistic Investigation and Machine Learning Exploration of Structure-Activity Relationship of Nhc-Mn Catalyzed the Ester Hydrosilylation Reaction
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Diverse Catalytic Systems and Mechanistic Pathways for Hydrosilylative Reduction of CO2
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Transition metal center effect on the mechanism of homogenous hydrogenation and dehydrogenation
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Mechanistic investigation and machine learning exploration of structure-activity relationship of NHC-Mn catalyzed ester hydrosilylation reaction
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DFT Quest of the Active Species of the Gallium-Mediated Coupling of Methylidenemalonates and Acetylenes
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Mechanism Insights into the Iridium(III)- and B(C 6 F 5 ) 3 -Catalyzed Reduction of CO 2 to the Formaldehyde Level with Tertiary Silanes
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Mechanistic Insight into the Ni-Catalyzed Kumada Cross-Coupling: Alkylmagnesium Halide Promotes C–F Bond Activation and Electron-Deficient Metal Center Slows Down β-H Elimination
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Ring Opening Reduction of Cyclic Anhydrides Catalyzed by Tris(pentafluorophenyl)borane Using Hydrosilanes as a Hydride Source
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The DFT Quest for Possible Reaction Pathways, Catalytic Species, and Regioselectivity in the InCl 3 -Catalyzed Cycloaddition of N -Tosyl Formaldimine with Olefins or Allenes
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Reduction of CO2 by Hydrosilanes in the Presence of Formamidinates of Group 13 and 12 Elements
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Catalytic transformation of CO 2 into C1 chemicals using hydrosilanes as a reducing agent
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Mechanism and origins of gold-catalyzed domino cyclization to spiroindolines: the role of periplanar cooperation and hydrogen bonding interactions
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Activation of Si–H and B–H bonds by Lewis acidic transition metals and p-block elements: same, but different
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6.1.45 Diphosphino–Boryl (PBP) Pincer Complexes
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Recent Advances in Homogeneous Catalytic Systems for CO2 Hydrosilylation and Related Transformations
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