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Mechanistic Insights on CO 2 Reduction Reactions at Platinum/[BMIM][BF 4 ] Interfaces from In Operando Spectroscopy

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Vibrational Spectroscopy at Electrified Interfaces
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Reduction of Carbon Dioxide to Formate at Low Overpotential Using a Superbase Ionic Liquid
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Molybdenum–Bismuth Bimetallic Chalcogenide Nanosheets for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Methanol
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Structure Sensitivity in the Electrocatalytic Reduction of CO2 with Gold Catalysts
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Stability and CO2 Capture Ability of Electrogenerated N‐Heterocyclic Carbene in Parent 1‐Butyl‐3‐methylimidazoliun Ionic Liquid (BMIm‐X): The Role of X−
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NMR Study of the Reductive Decomposition of [BMIm][NTf2] at Gold Electrodes and Indirect Electrochemical Conversion of CO2
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Transport Matters: Boosting CO2 Electroreduction in Mixtures of [BMIm][BF4]/Water by Enhanced Diffusion
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Direct Reduction of Carbon Dioxide to Formate in High‐Gas‐Capacity Ionic Liquids at Post‐Transition‐Metal Electrodes
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Highly selective electrocatalytic reduction of carbon dioxide to carbon monoxide on silver electrode with aqueous ionic liquids
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On the reactivity and stability of electrogenerated N-heterocyclic carbene in parent 1-butyl-3-methyl-1H-imidazolium tetrafluoroborate: Formation and use of N-heterocyclic carbene-CO2 adduct as latent catalyst
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Vibrational sum-frequency generation study of the CO2 electrochemical reduction at Pt/EMIM-BF4 solid/liquid interfaces
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Vibrational spectra of imidazolium tetrafluoroborate ionic liquids
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Quantitative vibrational sum-frequency generation spectroscopy of thin layer electrochemistry: CO on a Pt electrode
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Efficient Electrocatalytic Reduction of Carbon Dioxide in 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate and Water Mixtures
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Structural Transition in an Ionic Liquid Controls CO2 Electrochemical Reduction
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Theoretical Study of EMIM+ Adsorption on Silver Electrode Surfaces
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Is the Imidazolium Cation a Unique Promoter for Electrocatalytic Reduction of Carbon Dioxide?
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Carbon Dioxide Reduction in Room-Temperature Ionic Liquids: The Effect of the Choice of Electrode Material, Cation, and Anion
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Quantifying Double-Layer Potentials at Liquid–Gas Interfaces from Vibrational Sum-Frequency Generation
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Use of CO as a Cleaning Tool of Highly Active Surfaces in Contact with Ionic Liquids: Ni Deposition on Pt(111) Surfaces in IL
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Electric Field Effects in Electrochemical CO 2 Reduction
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CO2 Reduction Promoted by Imidazole Supported on a Phosphonium-Type Ionic-Liquid-Modified Au Electrode at a Low Overpotential
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In Situ Monitoring Using ATR-SEIRAS of the Electrocatalytic Reduction of CO 2 on Au in an Ionic Liquid/Water Mixture
inferredcites →https://doi.org/10.1021/acscatal.8b02846openalex-snapshot
Suppression of Competing Reaction Channels by Pb Adatom Decoration of Catalytically Active Cu Surfaces During CO2 Electroreduction
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Surface Atomic Arrangement Dependence of Electrochemical CO2 Reduction on Gold: Online Electrochemical Mass Spectrometric Study on Low-Index Au(hkl) Surfaces
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Surface Structure at the Ionic Liquid−Electrified Metal Interface
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Ionic Liquids and Dense Carbon Dioxide: A Beneficial Biphasic System for Catalysis
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Comparative Study of Imidazole and Pyridine Catalyzed Reduction of Carbon Dioxide at Illuminated Iron Pyrite Electrodes
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Introduction to Special Issue on Operando and In Situ Studies of Catalysis
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An IR study of the hydration of perchlorate, nitrate, iodide, bromide, chloride and sulfate anions in aqueous solution
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New Insights Into the Role of Imidazolium-Based Promoters for the Electroreduction of CO 2 on a Silver Electrode
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Crucial Role of Surface Hydroxyls on the Activity and Stability in Electrochemical CO2 Reduction
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Effect of Water on the Electrochemical Window and Potential Limits of Room-Temperature Ionic Liquids
inferredcites →https://doi.org/10.1021/je900789jopenalex-snapshot
The Conductivity of Imidazolium-Based Ionic Liquids from (−35 to 195) °C. A. Variation of Cation’s Alkyl Chain
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The 2-Position of Imidazolium Ionic Liquids: Substitution and Exchange
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A Systematic Investigation of Factors Influencing the Decarboxylation of Imidazolium Carboxylates
inferredcites →https://doi.org/10.1021/jp0476601openalex-snapshot
Ionic Conduction and Ion Diffusion in Binary Room-Temperature Ionic Liquids Composed of [emim][BF4] and LiBF4
inferredcites →https://doi.org/10.1021/jp201886mopenalex-snapshot
Electrochemical Oxidation of Hydrogen on Basal Plane Platinum Electrodes in Imidazolium Ionic Liquids
inferredcites →https://doi.org/10.1021/jp210542vopenalex-snapshot
In Situ Spectroscopic Examination of a Low Overpotential Pathway for Carbon Dioxide Conversion to Carbon Monoxide
inferredcites →https://doi.org/10.1021/jp7120752openalex-snapshot
Structures of Ionic Liquids with Different Anions Studied by Infrared Vibration Spectroscopy
inferredcites →https://doi.org/10.1021/la5009076openalex-snapshot
Switching the Reaction Course of Electrochemical CO 2 Reduction with Ionic Liquids
inferredcites →https://doi.org/10.1039/b106900dopenalex-snapshot
Molecular states of water in room temperature ionic liquidsElectronic Supplementary Information available. See http://www.rsc.org/suppdata/cp/b1/b106900d/
inferredcites →https://doi.org/10.1039/c2cc32011hopenalex-snapshot
Formic acid electro-synthesis from carbon dioxide in a room temperature ionic liquid
inferredcites →https://doi.org/10.1039/c4cp05409aopenalex-snapshot
Cyclic voltammetry using silver as cathode material: a simple method for determining electro and chemical features and solubility values of CO 2 in ionic liquids
inferredcites →https://doi.org/10.1039/c5cp02008eopenalex-snapshot
Activation of CO 2 by ionic liquid EMIM–BF 4 in the electrochemical system: a theoretical study
inferredcites →https://doi.org/10.1039/c5cp02361kopenalex-snapshot
Surface structured platinum electrodes for the electrochemical reduction of carbon dioxide in imidazolium based ionic liquids
inferredcites →https://doi.org/10.1039/c5sc04158aopenalex-snapshot
Very highly efficient reduction of CO 2 to CH 4 using metal-free N-doped carbon electrodes
inferredcites →https://doi.org/10.1039/c6sc03194copenalex-snapshot
Porous dendritic copper: an electrocatalyst for highly selective CO 2 reduction to formate in water/ionic liquid electrolyte
inferredcites →https://doi.org/10.1039/c7cp00118eopenalex-snapshot
Effects of water on low-overpotential CO 2 reduction in ionic liquid studied by sum-frequency generation spectroscopy
inferredcites →https://doi.org/10.1039/c8cp02662aopenalex-snapshot
Electrocatalytic studies on imidazolium based ionic liquids: defining experimental conditions
inferredcites →https://doi.org/10.1063/1.1712435openalex-snapshot
Infrared Spectra of the Hydrogen-Bonded Carboxylic Acids
inferredcites →https://doi.org/10.1063/1.2359446openalex-snapshot
Vibrational sum frequency generation studies of the (2×2)→(√19×√19) phase transition of CO on Pt(111) electrodes
inferredcites →https://doi.org/10.1080/02603599708032729openalex-snapshot
Photo-Induced Generation of Dihydrogen and Reduction of Carbon Dioxide Using Transition Metal Complexes
inferredcites →https://doi.org/10.1126/science.1209786openalex-snapshot
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
inferredcites →https://doi.org/10.1126/science.aad4998openalex-snapshot
Combining theory and experiment in electrocatalysis: Insights into materials design
inferredcites →https://doi.org/10.1149/1.1394035openalex-snapshot
Electrochemical Reduction of Carbon Dioxide at a Platinum Electrode in Acetonitrile-Water Mixtures
inferredcites →https://doi.org/10.1149/1.1568740openalex-snapshot
Electrochemistry of 1-Butyl-3-methyl-1H-imidazolium Tetrafluoroborate Ionic Liquid
inferredcites →https://doi.org/10.1149/2.004303jesopenalex-snapshot
Water Enhancement of CO2Conversion on Silver in 1-Ethyl-3-Methylimidazolium Tetrafluoroborate

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Exploring the Potential of Nitrogen-Doped Graphene-Coated Copper Foam in Co2 Reduction Reactions
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Imidazolium‐Functionalized Cationic Covalent Triazine Frameworks Stabilized Copper Nanoparticles for Enhanced CO2 Electroreduction
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Role of H2O for CO2 Reduction Reactions at Platinum/Electrolyte Interfaces in Imidazolium Room‐Temperature Ionic Liquids
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Performance of Transition Metals in Imidazolium‐Assisted CO2 Reduction in Acetonitrile
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Mechanism of efficient electroreduction of CO2 to CO at Ag electrode in imidazolium-based ionic liquids/acetonitrile solution
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Tuning the selectivity for C1 products: Methanol and formate at low overpotential scale using optimal Sn/CuO@N-CNT nanostructure
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Effect of additives in aqueous electrolytes on CO2 electroreduction
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Electrocatalytic reduction of CO2 in neat and water-containing imidazolium-based ionic liquids
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Effect of anion in diluted imidazolium-based ionic liquid/buffer electrolytes for CO2 electroreduction on copper
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A tiny pore-confined solid-liquid interface for in-situ ToF-SIMS electrochemistry of nitrobenzoic acid
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Electrochemical CO2 reduction catalyzed by organic/inorganic hybrids
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Extractive desulfurization of fuels using modified ionic liquids with magnetic graphene oxide from refused dry cell batteries
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In–depth understanding on the mechanism of ionic liquid-assisted enhancement of electrochemical CO2 reduction to formic acid
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Structure effects of imidazolium ionic liquids on integrated CO2 absorption and transformation to dimethyl carbonate
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Portrayal of dynamic desulfurization of coal by one-pot assorted imidazolium-based ionic liquids
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Ionic liquid electrolytes enhanced CO2 electroreduction to C1 chemicals: Principles and progress
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Application of ionic liquids in CO2 capture and conversion: A review
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Sum frequency generation spectroscopy: Probing chemical reactions at surfaces and interfaces
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A DFT study on [BMIM] [BF4]/H2O mixtures for enhanced CO2 electroreduction on Ag(111)
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Fundamental aspects in CO2 electroreduction reaction and solutions from in situ vibrational spectroscopies
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Optical Spectroscopy of Surfaces, Interfaces, and Thin Films
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Multiscale CO 2 Electrocatalysis to C 2+ Products: Reaction Mechanisms, Catalyst Design, and Device Fabrication
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Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis
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Ionic Liquids Promoted Transformation of Carbon Dioxide
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Ionic Liquids-Promoted Electrocatalytic Reduction of Carbon Dioxide
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Adsorption Electro-Neutralization of Ionic Liquids in Thorium-MOFs for Enhanced Photocatalytic CO2 Reduction
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Temperature Effects on CO2 Electroreduction Pathways in an Imidazolium-Based Ionic Liquid on Pt Electrode
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Imidazolium- and Pyrrolidinium-Based Ionic Liquids as Cocatalysts for CO2 Electroreduction in Model Molecular Electrocatalysis
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Cations of Ionic Liquid Electrolytes Can Act as a Promoter for CO2 Electrocatalysis through Reactive Intermediates and Electrostatic Stabilization
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Suppressing Co-Ion Generation via Cationic Proton Donors to Amplify Driving Forces for Electrochemical CO 2 Reduction
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Direct Observation of Surface-Bound Intermediates in CO/CO 2 Reduction on a Polycrystalline Cu Electrode Using Broad-Band SFG Spectroscopy
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Potential-Induced Adsorption and Structuring of Water at the Pt(111) Electrode Surface in Contact with an Ionic Liquid
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A Perspective into Operando Methods for Probing Catalytic Interfaces
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Selectivities of Stepped Cu–M (M = Pt, Ni, Pd, Zn, Ag, Au) Bimetallic Surface Environment for C1 and C2 Pathways
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Principal Descriptors of Ionic Liquid Co-catalysts for the Electrochemical Reduction of CO2
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Fe3O4/Fe1–xS Composites Enable Efficient Asymmetric C–C Coupling for CO2 Electrocatalytic Reduction to C2H6
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Selective CO2 Reduction to Ethylene Using Imidazolium-Functionalized Copper
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Water-In-Salt Environment Reduces the Overpotential for Reduction of CO2 to CO2– in Ionic Liquid/Water Mixtures
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Modifying Copper Local Environment with Electrolyte Additives to Alter CO2 Electroreduction vs Hydrogen Evolution
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Cu/Au(111) Surfaces and AuCu Intermetallics for Electrocatalytic Reduction of CO2 in Ionic Liquid Electrolytes
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Descriptors for Electrochemical CO2 Reduction in Imidazolium-Based Electrolytes
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CuAg Alloy Catalyst for Modulating the Activity of C–N Coupling toward Acetamide and Urea Synthesis via Explicit pH-Dependent Water and Induced Ionic Liquid Cations Models
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Efficient CO 2 Electroreduction to C 2 + Products on Hydroxide-Metal Catalysts via Enhanced Asymmetric C–C coupling
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What It Takes for Imidazolium Cations to Promote Electrochemical Reduction of CO 2
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Insight into the Role of Entropy in Promoting Electrochemical CO2 Reduction by Imidazolium Cations
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Synergistic Effects of the Electric Field Induced by Imidazolium Rotation and Hydrogen Bonding in Electrocatalysis of CO 2
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Alkali Cation Inhibition of Imidazolium-Mediated Electrochemical CO2 Reduction on Silver
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Product Selectivity Switching between CO and Formate in Electrocatalytic CO2 Reduction Driven by Ionic Liquid-Induced Reorientation of CO2 over Cathode
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Inert is not inactive: origin of carbon dioxide electroreduction activity over a carbon current collector-based electrode
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Reactive capture and electrochemical conversion of CO 2 with ionic liquids and deep eutectic solvents
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Selective conversion of carbon dioxide to formate using few-layer nitrogen-doped graphene on copper foam with enhanced suppression of the hydrogen evolution reaction
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Design of nanostructured 2D (photo-)electrocatalysts for biomass valorization coupled with H 2 production
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Integrated CO 2 capture and conversion: dual-functional materials, mechanisms, and pathways to industrial decarbonization
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How to select heterogeneous CO 2 reduction electrocatalyst
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Imidazolium-Based Materials for CO2 Electroreduction
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