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Catalytic in Situ Hydrogenolysis of Lignin in Supercritical Ethanol: Effect of Phenol, Catalysts, and Reaction Temperature

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Paving the Way for Lignin Valorisation: Recent Advances in Bioengineering, Biorefining and Catalysis
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In Situ Observation of Cu–Ni Alloy Nanoparticle Formation by X‐Ray Diffraction, X‐Ray Absorption Spectroscopy, and Transmission Electron Microscopy: Influence of Cu/Ni Ratio
inferredcites →https://doi.org/10.1002/ceat.201000270openalex-snapshot
Lignin Depolymerization and Conversion: A Review of Thermochemical Methods
inferredcites →https://doi.org/10.1002/cssc.200900033openalex-snapshot
Hydrogen Transfer from Supercritical Methanol over a Solid Base Catalyst: A Model for Lignin Depolymerization
inferredcites →https://doi.org/10.1002/cssc.201200040openalex-snapshot
Solvent Effects on the Hydrogenolysis of Diphenyl Ether with Raney Nickel and their Implications for the Conversion of Lignin
inferredcites →https://doi.org/10.1002/cssc.201600237openalex-snapshot
Lignin Valorization through Catalytic Lignocellulose Fractionation: A Fundamental Platform for the Future Biorefinery
inferredcites →https://doi.org/10.1002/cssc.201601326openalex-snapshot
Valorization of Lignin to Simple Phenolic Compounds over Tungsten Carbide: Impact of Lignin Structure
inferredcites →https://doi.org/10.1016/j.apcata.2014.12.052openalex-snapshot
Zirconia catalysts (ZrO2 and Na-ZrO2) for the conversion of phenethyl phenyl ether (PPE) in supercritical water
inferredcites →https://doi.org/10.1016/j.apcata.2017.07.038openalex-snapshot
Optimization of nickel loading of mixed oxide catalyst ex-hydrotalcite for H2 production by methane decomposition
inferredcites →https://doi.org/10.1016/j.apcatb.2016.10.038openalex-snapshot
Efficient and versatile CuNi alloy nanocatalysts for the highly selective hydrogenation of furfural
inferredcites →https://doi.org/10.1016/j.apenergy.2014.12.025openalex-snapshot
Efficient base-catalyzed decomposition and in situ hydrogenolysis process for lignin depolymerization and char elimination
inferredcites →https://doi.org/10.1016/j.biortech.2014.12.021openalex-snapshot
Efficient and product-controlled depolymerization of lignin oriented by metal chloride cooperated with Pd/C
inferredcites →https://doi.org/10.1016/j.biortech.2015.09.112openalex-snapshot
Investigation on the structural effect of lignin during the hydrogenolysis process
inferredcites →https://doi.org/10.1016/j.biortech.2015.12.022openalex-snapshot
Hydro- and solvothermolysis of kraft lignin for maximizing production of monomeric aromatic chemicals
inferredcites →https://doi.org/10.1016/j.biortech.2016.04.029openalex-snapshot
High-quality bio-oil from one-pot catalytic hydrocracking of kraft lignin over supported noble metal catalysts in isopropanol system
inferredcites →https://doi.org/10.1016/j.biortech.2016.08.001openalex-snapshot
Investigation into the lignin decomposition mechanism by analysis of the pyrolysis product of Pinus radiata
inferredcites →https://doi.org/10.1016/j.biortech.2016.09.043openalex-snapshot
Insight into the solvent, temperature and time effects on the hydrogenolysis of hydrolyzed lignin
inferredcites →https://doi.org/10.1016/j.cej.2016.10.011openalex-snapshot
Production of phenolic hydrocarbons using catalytic depolymerization of empty fruit bunch (EFB)-derived organosolv lignin on Hβ-supported Ru
inferredcites →https://doi.org/10.1016/j.cej.2017.02.045openalex-snapshot
Depolymerization of concentrated sulfuric acid hydrolysis lignin to high-yield aromatic monomers in basic sub- and supercritical fluids
inferredcites →https://doi.org/10.1016/j.fuel.2015.12.051openalex-snapshot
High-yield and high-calorific bio-oil production from concentrated sulfuric acid hydrolysis lignin in supercritical ethanol
inferredcites →https://doi.org/10.1016/j.fuel.2016.05.104openalex-snapshot
Thermal conversion of lignin to phenols: Relevance between chemical structure and pyrolysis behaviors
inferredcites →https://doi.org/10.1016/j.fuel.2016.07.043openalex-snapshot
Effect of water–carbon dioxide ratio on the selectivity of phenolic compounds produced from alkali lignin in sub- and supercritical fluid mixtures
inferredcites →https://doi.org/10.1016/j.fuel.2017.08.031openalex-snapshot
Reductive de-polymerization of kraft lignin with formic acid at low temperatures using inexpensive supported Ni-based catalysts
inferredcites →https://doi.org/10.1016/j.fuproc.2017.03.020openalex-snapshot
Microwave-assisted selective cleavage of C C bond for lignin depolymerization
inferredcites →https://doi.org/10.1016/j.fuproc.2017.08.002openalex-snapshot
A facile method for char elimination during base-catalyzed depolymerization and hydrogenolysis of lignin
inferredcites →https://doi.org/10.1016/j.jiec.2016.01.001openalex-snapshot
Catalytic hydrodeoxygenation of simulated phenolic bio-oil to cycloalkanes and aromatic hydrocarbons over bifunctional metal/acid catalysts of Ni/HBeta, Fe/HBeta and NiFe/HBeta
inferredcites →https://doi.org/10.1016/j.jiec.2016.03.019openalex-snapshot
Hydrodeoxygenation of guaiacol over Pt loaded zeolitic materials
inferredcites →https://doi.org/10.1016/j.jiec.2017.06.026openalex-snapshot
In-situ catalytic pyrolysis of lignin in a bench-scale fixed bed pyrolyzer
inferredcites →https://doi.org/10.1016/j.jiec.2017.08.006openalex-snapshot
Efficient depolymerization of lignin in supercritical ethanol by a combination of metal and base catalysts
inferredcites →https://doi.org/10.1016/j.supflu.2016.12.015openalex-snapshot
Hydrothermal liquefaction of lignin in near-critical water in a new batch reactor: Influence of phenol and temperature
inferredcites →https://doi.org/10.1016/s0926-860x(02)00121-7openalex-snapshot
Development of heavy oil hydrocracking catalysts using amorphous silica-alumina and zeolites as catalyst supports
inferredcites →https://doi.org/10.1016/s0960-8524(03)00201-3openalex-snapshot
Effects of water on biodiesel fuel production by supercritical methanol treatment
inferredcites →https://doi.org/10.1016/s2095-4956(14)60109-1openalex-snapshot
Aqueous-phase catalytic hydrogenation of furfural to cyclopentanol over Cu-Mg-Al hydrotalcites derived catalysts: Model reaction for upgrading of bio-oil
inferredcites →https://doi.org/10.1021/acs.chemrev.5b00155openalex-snapshot
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
inferredcites →https://doi.org/10.1021/acssuschemeng.7b01615openalex-snapshot
Water-Assisted Selective Hydrodeoxygenation of Guaiacol to Cyclohexanol over Supported Ni and Co Bimetallic Catalysts
inferredcites →https://doi.org/10.1021/acssuschemeng.7b02790openalex-snapshot
Catalytic Depolymerization of Lignin and Woody Biomass in Supercritical Ethanol: Influence of Reaction Temperature and Feedstock
inferredcites →https://doi.org/10.1039/c3gc37056aopenalex-snapshot
Catalytic cleavage of lignin β-O-4 link mimics using copper on alumina and magnesia–alumina
inferredcites →https://doi.org/10.1039/c4gc01911copenalex-snapshot
A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass
inferredcites →https://doi.org/10.1039/c5gc01120eopenalex-snapshot
Ethanol as capping agent and formaldehyde scavenger for efficient depolymerization of lignin to aromatics
inferredcites →https://doi.org/10.1039/c5ra23041aopenalex-snapshot
Hydrogenation of lignin-derived phenolic compounds over step by step precipitated Ni/SiO 2
inferredcites →https://doi.org/10.1126/science.1246843openalex-snapshot
Lignin Valorization: Improving Lignin Processing in the Biorefinery

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Catalytic Valorization of Alkali Lignin into Aromatic Monomers Over Ni-Cu/Hzsm-5 Bimetallic Catalysts with Methanol as the Hydrogen Donor Solvent
inferred← citeshttps://doi.org/10.1002/cjce.24055openalex-snapshot
Homogeneously catalyzed depolymerization of lignin from organosolv medium: Characterization, optimization, and minimization of coke formation
inferred← citeshttps://doi.org/10.1002/cssc.202301912openalex-snapshot
Hydrogen‐transfer strategy in lignin refinery: Towards sustainable and versatile value‐added biochemicals
inferred← citeshttps://doi.org/10.1002/cssc.202401399openalex-snapshot
Heterogeneously Catalyzed Reductive Depolymerization of Lignin to Value‐Added Chemicals
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Study of Mo‐based sepiolite catalyst on depolymerization of lignin under supercritical ethanol
inferred← citeshttps://doi.org/10.1002/est2.547openalex-snapshot
Application of palm oil frond activated carbon for biobattery electrodes
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Machine learning‐assisted modeling of catalytic hydrogenolysis of lignin into monomeric products over Ni–Cu/ HZSM ‐5 bimetallic catalysts using methanol as H‐donating solvent
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Thermochemical and Catalytic Conversion of Lignin
inferred← citeshttps://doi.org/10.1007/s12155-025-10868-2openalex-snapshot
Advancements in Heterogeneous Biobased and Bio-Composite Catalysts: A Comprehensive Review on Synthesis, Characterizations, and Applications in Biodiesel Production
inferred← citeshttps://doi.org/10.1007/s13399-020-00849-0openalex-snapshot
Insights into catalytic valorization of different lignin feedstocks into liquid fuels with microwave heating in hydrogen-donor solvents
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A comprehensive review on lignin obtained from agro-residues: potential source of useful chemicals
inferred← citeshttps://doi.org/10.1016/j.apcatb.2026.126505openalex-snapshot
Synergistic catalysis on Ru nanoparticles with satellite single atoms enables selective valorization of lignin into guaiacols
inferred← citeshttps://doi.org/10.1016/j.biortech.2019.121860openalex-snapshot
Hydrocarbon rich bio-oil production, thermal behavior analysis and kinetic study of microwave-assisted co-pyrolysis of microwave-torrefied lignin with low density polyethylene
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Catalytic hydrogenolysis of lignin in ethanol/isopropanol over an activated carbon supported nickel-copper catalyst
inferred← citeshttps://doi.org/10.1016/j.biortech.2021.125941openalex-snapshot
Catalytic hydrogenolysis of alkali lignin in supercritical ethanol over copper monometallic catalyst supported on a chromium-based metal–organic framework for the efficient production of aromatic monomers
inferred← citeshttps://doi.org/10.1016/j.ces.2025.121328openalex-snapshot
Temperature regulating the directional catalytic transfer hydrogenolysis of lignin over a in situ topologically prepared NiRu/Al2O3
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The chemical and physical properties of lignin bio-oils, facts and needs
inferred← citeshttps://doi.org/10.1016/j.enconman.2020.113227openalex-snapshot
Effect of Mo content in Mo/Sepiolite catalyst on catalytic depolymerization of Kraft lignin under supercritical ethanol
inferred← citeshttps://doi.org/10.1016/j.fuel.2020.119474openalex-snapshot
Highly selective catalytic hydrocracking >CH-O- bridged bonds in an alkali lignin over Ni/Hβ
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Catalytic ethanolysis of Xilinguole lignite over layered and mesoporous metal oxide composites to platform chemicals
inferred← citeshttps://doi.org/10.1016/j.fuel.2022.125548openalex-snapshot
Valorization of lignin to phenols over highly dispersed NiRu/Al2O3 without extra H2: Effect of reaction conditions and insight into the resulting phenols distributions
inferred← citeshttps://doi.org/10.1016/j.fuproc.2019.02.022openalex-snapshot
Selective cleavage of C O bond in benzyl phenyl ether over Pd/AC at room temperature
inferred← citeshttps://doi.org/10.1016/j.indcrop.2021.114008openalex-snapshot
A review for lignin valorization: Challenges and perspectives in catalytic hydrogenolysis
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Pyrolysis oil upgrading via hydrotreatment to produce alternative fuel using ZrO2-supported catalysts and isopropanol as a solvent
inferred← citeshttps://doi.org/10.1016/j.joei.2019.05.014openalex-snapshot
Hydrothermal depolymerization of alkali lignin to high-yield monomers over nickel nitrate modified commercial hydrotalcites catalyst
inferred← citeshttps://doi.org/10.1016/j.joei.2025.102244openalex-snapshot
Roles of bimetallic catalysts and mesoporous supports in enhancing product selectivity in lignin hydrogenolysis and catalyst stability
inferred← citeshttps://doi.org/10.1016/j.mcat.2019.110642openalex-snapshot
Hierarchical mesoporous ZSM-5 supported nickel catalyst for the catalytic hydrodeoxygenation of anisole to cyclohexane
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Catalytic transfer hydrogenolysis of lignin α-O-4 model compound 4-(benzyloxy)phenol and lignin over Pt/HNbWO6/CNTs catalyst
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Base-free transfer hydrogenation of menthone by sub- and supercritical alcohols
inferred← citeshttps://doi.org/10.1021/acs.energyfuels.3c04637openalex-snapshot
Lignin Catalytic Depolymerization for Guaiacols and Alkylphenols over Co–Zr/Sepiolite under Supercritical Ethanol
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Bio-Oil Production by Depolymerization and Hydrodeoxygenation of Lignins over Mg–Ni–Mo/Activated Charcoal in Supercritical Ethanol
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Novel Nonprecious Metal Loading Multi-Metal Oxide Catalysts for Lignin Depolymerization
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Effect of Reduction Treatments of Mo/Sepiolite Catalyst on Lignin Depolymerization under Supercritical Ethanol
inferred← citeshttps://doi.org/10.1021/acs.iecr.4c02617openalex-snapshot
Recent Advances in Depolymerization and High-Value Utilization of Lignin: A Review
inferred← citeshttps://doi.org/10.1021/acssuschemeng.0c05362openalex-snapshot
Nonprecious Metal/Bimetallic Catalytic Hydrogenolysis of Lignin in a Mixed-Solvent System
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Antimicrobial Properties of Corn Stover Lignin Fractions Derived from Catalytic Transfer Hydrogenolysis in Supercritical Ethanol with a Ru/C Catalyst
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Microwave Assisted Depolymerization of Alkaline Lignin over Hydrotalcite-Based CuNiAl Mixed Oxides
inferred← citeshttps://doi.org/10.1039/d1gc01521dopenalex-snapshot
Controlling bacterial contamination during fuel ethanol fermentation using thermochemically depolymerized lignin bio-oils
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Lignin to value-added chemicals and advanced materials: extraction, degradation, and functionalization
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A silica-supported palladium oxide catalyst (PdO@MCM-41) selectively cleaves ether linkages in lignin model compounds and alkali lignin via intramolecular hydrogen transfer
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Supercritical fluids in chemistry
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Catalytic reductive depolymerization of corncob lignin to produce bio-oil via formic acid/ethanol system
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Machine learning-assisted modeling of catalytic hydrogenolysis of lignin into monomeric products over Ni-Cu/HZSM-5 bimetallic catalysts using methanol as H-donating solvent
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Catalytic Transfer Hydrogenolysis Reactions for Lignin Valorization to Fuels and Chemicals
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Biorefinery : lignin liquefaction to produce green aromatic chemicals
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