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From Waste to Functional Additive: Toughening Epoxy Resin with Lignin

https://doi.org/10.1021/am500642n
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Synthesis of a bifunctional epoxy monomer containing biphenyl moiety and properties of its cured polymer with phenol novolac
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Thermoplastic toughening of epoxy resins: a critical review
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Thermoplastic toughening of epoxy resins: a critical review
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Ullmann's Encyclopedia of Industrial Chemistry
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Epoxy and hyperbranched polymer blends: Morphology and free volume
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Lignin as Renewable Raw Material
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LIGNIN POLYMERS AND COMPOSITES
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Influence of different carbon nanotubes on the mechanical properties of epoxy matrix composites – A comparative study
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Nanocomposites based on vapor-grown carbon nanofibers and an epoxy: Functionalization, preparation and characterization
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Characteristics of hemicellulose, cellulose and lignin pyrolysis
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Viscoelastic properties and determination of free volume fraction of multi-walled carbon nanotube/epoxy composite using dynamic mechanical thermal analysis
inferredcites →https://doi.org/10.1016/j.polymdegradstab.2013.06.008openalex-snapshot
Structural features and thermal degradation properties of various lignin macromolecules obtained from poplar wood (Populus albaglandulosa)
inferredcites →https://doi.org/10.1016/j.polymer.2006.10.047openalex-snapshot
Comparative study on the curing kinetics and mechanism of a lignin-based-epoxy/anhydride resin system
inferredcites →https://doi.org/10.1016/j.polymer.2008.01.037openalex-snapshot
Structure–property relationships of controlled epoxy networks with quantified levels of excess epoxy etherification
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Thermosetting (bio)materials derived from renewable resources: A critical review
inferredcites →https://doi.org/10.1016/s0014-3057(03)00036-3openalex-snapshot
Curing characteristics of carboxyl functionalized glucose resin and epoxy resin
inferredcites →https://doi.org/10.1021/am300425xopenalex-snapshot
Improved Lignin Polyurethane Properties with Lewis Acid Treatment
inferredcites →https://doi.org/10.1021/bm0500345openalex-snapshot
Lignin Esters for Use in Unsaturated Thermosets: Lignin Modification and Solubility Modeling
inferredcites →https://doi.org/10.1021/bm101449bopenalex-snapshot
Investigation of Aggregation and Assembly of Alkali Lignin Using Iodine as a Probe
inferredcites →https://doi.org/10.1021/bm4010172openalex-snapshot
Kraft Lignin Chain Extension Chemistry via Propargylation, Oxidative Coupling, and Claisen Rearrangement
inferredcites →https://doi.org/10.1021/ja01619a008openalex-snapshot
The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming Liquids
inferredcites →https://doi.org/10.1021/ma048465nopenalex-snapshot
Epoxy Nanocomposites with Highly Exfoliated Clay: Mechanical Properties and Fracture Mechanisms
inferredcites →https://doi.org/10.1021/ma070702+openalex-snapshot
Highly Cross-Linked Epoxy Resins: An Atomistic Molecular Dynamics Simulation Combined with a Mapping/Reverse Mapping Procedure
inferredcites →https://doi.org/10.1021/nn9010472openalex-snapshot
Enhanced Mechanical Properties of Nanocomposites at Low Graphene Content
inferredcites →https://doi.org/10.1021/sc4000835openalex-snapshot
A Renewable Lignin–Lactide Copolymer and Application in Biobased Composites
inferredcites →https://doi.org/10.1039/c2gc35933bopenalex-snapshot
Turning renewable resources into value-added polymer: development of lignin-based thermoplastic
inferredcites →https://doi.org/10.1039/c3ra40721gopenalex-snapshot
A novel fluoro-terminated hyperbranched poly(phenylene oxide) (FHPPO): synthesis, characterization, and application in low-k epoxy materials
inferredcites →https://doi.org/10.1080/15583720903048227openalex-snapshot
Rubber-Toughened Epoxies: A Critical Review
inferredcites →https://doi.org/10.1081/mc-120004764openalex-snapshot
MODIFICATION OF LIGNIN*
inferredcites →https://doi.org/10.15376/biores.6.3.2492-2503openalex-snapshot
Synthesis and characterization of kraft lignin-based epoxy resins

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Metallo‐Deuteroporphyrin as a Biomimetic Catalyst for the Catalytic Oxidation of Lignin to Aromatics
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Synthesis, Characterization, and Cross‐Linking Strategy of a Quercetin‐Based Epoxidized Monomer as a Naturally‐Derived Replacement for BPA in Epoxy Resins
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The Effect of Residual Solvent N,N′‐Dimethylformamide on the Curing Reaction and Mechanical Properties of Epoxy and Lignin Epoxy Composites
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Carboxylated Lignin as an Effective Cohardener for Enhancing Strength and Toughness of Epoxy
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Functionalization of Lignin by Phosphorylation
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Functionalization of Lignin by Phosphorylation
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Lignin-based anti-UV functional materials: recent advances in preparation and application
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Verbesserung der thermischen Stabilität von MS-Polymeren
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Improving the Thermal Stability of MS Polymers with Lignin Fractions
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Lignin Reinforcement in Thermosets Composites
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inferred← citeshttps://doi.org/10.1016/j.polymer.2022.124973openalex-snapshot
Preparation of novel bio-based imine-containing phthalonitrile resin through the nucleophilic reaction in green solvent
inferred← citeshttps://doi.org/10.1016/j.polymer.2023.125763openalex-snapshot
Mechanical properties of reactive polyetherimide-modified tetrafunctional epoxy systems
inferred← citeshttps://doi.org/10.1016/j.polymer.2024.126994openalex-snapshot
High performance, self-healable and recyclable epoxy thermosets by integrating dynamic hindered urea bonds
inferred← citeshttps://doi.org/10.1016/j.polymertesting.2021.107053openalex-snapshot
Novel epoxy-ended hyperbranched polyether derived from xylitol as sustainable tougheners for epoxy resin
inferred← citeshttps://doi.org/10.1016/j.porgcoat.2018.08.001openalex-snapshot
Fatty acid-based cross-linkable polymethacrylate coatings
inferred← citeshttps://doi.org/10.1016/j.porgcoat.2019.04.076openalex-snapshot
Multi-nationality epoxy adhesives on trial for future nanocomposite developments
inferred← citeshttps://doi.org/10.1016/j.porgcoat.2019.105291openalex-snapshot
Epoxy adhesives toughened with waste tire powder, nanoclay, and phenolic resin for metal-polymer lap-joint applications
inferred← citeshttps://doi.org/10.1016/j.porgcoat.2020.106031openalex-snapshot
Hyperbranched polymers containing epoxy and imide structure
inferred← citeshttps://doi.org/10.1016/j.reactfunctpolym.2020.104514openalex-snapshot
Evaluation of cytotoxicity in vitro and properties of polysiloxane-based polyurethane/lignin elastomers
inferred← citeshttps://doi.org/10.1016/j.scitotenv.2020.138830openalex-snapshot
Application of biomass by-product lignin stabilized soils as sustainable Geomaterials: A review
inferred← citeshttps://doi.org/10.1016/j.seppur.2025.132478openalex-snapshot
Oxidative depolymerization of lignin in a Fixed-Bed tubular membrane reactor
inferred← citeshttps://doi.org/10.1016/j.surfcoat.2015.12.056openalex-snapshot
Comparative tribological and corrosion resistance properties of epoxy composite coatings reinforced with functionalized fullerene C60 and graphene
inferred← citeshttps://doi.org/10.1016/j.surfin.2026.109149openalex-snapshot
Multifunctional protection for magnesium alloys: A coating with integrated superhydrophobic, photothermal de-icing and self-healing properties
inferred← citeshttps://doi.org/10.1016/j.tafmec.2018.08.007openalex-snapshot
Fabrication and evaluation of silica aerogel-epoxy nanocomposites: Fracture and toughening mechanisms
inferred← citeshttps://doi.org/10.1021/acs.biomac.1c00387openalex-snapshot
Enhancing the Radical Scavenging Activity and UV Resistance of Lignin Nanoparticles via Surface Mannich Amination toward a Biobased Antioxidant
inferred← citeshttps://doi.org/10.1021/acs.biomac.1c01204openalex-snapshot
Double-Interpenetrating-Network Lignin-based Epoxy Resin Adhesives for Resistance to Extreme Environment
inferred← citeshttps://doi.org/10.1021/acs.biomac.2c00289openalex-snapshot
Stabilization of Hybrid Adhesives and Sealants by Thermodynamic Tuning of Molecularly Optimized Lignin Bio-Additives: Small Changes, Big Effects
inferred← citeshttps://doi.org/10.1021/acs.biomac.5b00670openalex-snapshot
Biobased Epoxy Nanocomposites Derived from Lignin-Based Monomers
inferred← citeshttps://doi.org/10.1021/acs.iecr.4c02378openalex-snapshot
Controlling the Mechanical Properties of Catalyst-Free Epoxy Vitrimers via Designing Molecular Networks
inferred← citeshttps://doi.org/10.1021/acs.iecr.5c00154openalex-snapshot
Tunable Polyethylenimine-Interpenetrated Lignin-Derived Hard Carbons with Enhanced Plateau Capacity for Application in High-Performance Sodium-Ion Batteries
inferred← citeshttps://doi.org/10.1021/acs.iecr.7b04495openalex-snapshot
Toughening of Petroleum Based (DGEBA) Epoxy Resins with Various Renewable Resources Based Flexible Chains for High Performance Applications: A Review
inferred← citeshttps://doi.org/10.1021/acs.iecr.9b00547openalex-snapshot
Improved Mechanical and Thermal Properties of Trifunctional Epoxy Resins through Controlling Molecular Networks by Ionic Liquids
inferred← citeshttps://doi.org/10.1021/acs.macromol.1c01002openalex-snapshot
Disilyl Bis(Secondary Amine)-Enabled Epoxy Ring-Opening and Silylotropic N → O Migration Leading to Low Dielectric Epoxy Copolymers
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b01010openalex-snapshot
A Self-Healable High Glass Transition Temperature Bioepoxy Material Based on Vitrimer Chemistry
inferred← citeshttps://doi.org/10.1021/acsabm.3c00783openalex-snapshot
Lignin Modification for Enhanced Performance of Polymer Composites
inferred← citeshttps://doi.org/10.1021/acsaenm.5c00196openalex-snapshot
Enhancing Epoxy Toughness with a Bis-Hydroxy Urethane Diol Additive Derived from CO2-Based Ethylene Carbonate and Bio-Based Diamine
inferred← citeshttps://doi.org/10.1021/acsami.9b20417openalex-snapshot
Structure–Property Relationship of Stereolithography Resins Containing Polysiloxane Core–Shell Nanoparticles
inferred← citeshttps://doi.org/10.1021/acsapm.2c00674openalex-snapshot
A Quercetin-Derived Polybasic Acid Hardener for Reprocessable and Degradable Epoxy Resins Based on Transesterification
inferred← citeshttps://doi.org/10.1021/acsapm.4c01744openalex-snapshot
Effect of Methoxy Groups on the Structure–Properties Relationship of Lignin-Derived Recyclable Epoxy Thermosets
inferred← citeshttps://doi.org/10.1021/acsomega.2c07812openalex-snapshot
New Approach to Shape Memory Polymer Composite Production Using Alkaline Lignin-Reinforced Epoxy-Based Shape Memory Polymers
inferred← citeshttps://doi.org/10.1021/acsomega.7b02042openalex-snapshot
Toughening Anhydride-Cured Epoxy Resins Using Fatty Alkyl-Anhydride-Grafted Epoxidized Soybean Oil
inferred← citeshttps://doi.org/10.1021/acsomega.9b02282openalex-snapshot
Renewable Coumarin-Derived Network as a Toughening Structure for Petroleum-Based Epoxy Resins
inferred← citeshttps://doi.org/10.1021/acssuschemeng.0c08882openalex-snapshot
Materials Based on Technical Bulk Lignin
inferred← citeshttps://doi.org/10.1021/acssuschemeng.2c06990openalex-snapshot
Rigid-and-Flexible, Degradable, Fully Biobased Thermosets from Lignin and Soybean Oil: Synthesis and Properties
inferred← citeshttps://doi.org/10.1021/acssuschemeng.5b00343openalex-snapshot
Exploring the Application of Sustainable Poly(propylene carbonate) Copolymer in Toughening Epoxy Thermosets
inferred← citeshttps://doi.org/10.1021/acssuschemeng.6b00049openalex-snapshot
Lignin in Ethylene Glycol and Poly(ethylene glycol): Fortified Lubricants with Internal Hydrogen Bonding
inferred← citeshttps://doi.org/10.1021/acssuschemeng.6b00639openalex-snapshot
Biomass-Derived γ-Valerolactone-Based Solvent Systems for Highly Efficient Dissolution of Various Lignins: Dissolution Behavior and Mechanism Study
inferred← citeshttps://doi.org/10.1021/acssuschemeng.6b01369openalex-snapshot
Sheet-Like Lignin Particles as Multifunctional Fillers in Polypropylene
inferred← citeshttps://doi.org/10.1021/acssuschemeng.6b01446openalex-snapshot
Renewable Epoxy Networks Derived from Lignin-Based Monomers: Effect of Cross-Linking Density
inferred← citeshttps://doi.org/10.1021/acssuschemeng.6b01785openalex-snapshot
Competitive Interactions in Aromatic Polymer/Lignosulfonate Blends
inferred← citeshttps://doi.org/10.1021/acssuschemeng.6b01967openalex-snapshot
Efficient Toughening of Epoxy–Anhydride Thermosets with a Biobased Tannic Acid Derivative
inferred← citeshttps://doi.org/10.1021/acssuschemeng.7b01481openalex-snapshot
High Modulus, Strength, and Toughness Polyurethane Elastomer Based on Unmodified Lignin
inferred← citeshttps://doi.org/10.1021/acssuschemeng.8b00443openalex-snapshot
Renewable Epoxy Thermosets from Fully Lignin-Derived Triphenols
inferred← citeshttps://doi.org/10.1021/acssuschemeng.8b01962openalex-snapshot
Formaldehyde-Free Method for Incorporating Lignin into Epoxy Thermosets
inferred← citeshttps://doi.org/10.1021/acssuschemeng.9b03535openalex-snapshot
Controlled Preparation of Corncob Lignin Nanoparticles and their Size-Dependent Antioxidant Properties: Toward High Value Utilization of Lignin
inferred← citeshttps://doi.org/10.1021/bk-2021-1385.ch002openalex-snapshot
Modification of Epoxies
inferred← citeshttps://doi.org/10.1038/s41578-021-00363-3openalex-snapshot
Bio-based polymers with performance-advantaged properties
inferred← citeshttps://doi.org/10.1038/s41598-022-25695-0openalex-snapshot
Self-extracted corn-stalk cellulose/epoxy resin composites
inferred← citeshttps://doi.org/10.1038/srep43596openalex-snapshot
All Biomass and UV Protective Composite Composed of Compatibilized Lignin and Poly (Lactic-acid)
inferred← citeshttps://doi.org/10.1039/c5gc01418bopenalex-snapshot
Foamed lignin–silicone bio-composites by extrusion and then compression molding
inferred← citeshttps://doi.org/10.1039/c5ra11093aopenalex-snapshot
Non-corrosive green lubricants: strengthened lignin–[choline][amino acid] ionic liquids interaction via reciprocal hydrogen bonding
inferred← citeshttps://doi.org/10.1039/c6ra16418hopenalex-snapshot
Structure, morphology and properties of epoxy networks with dangling chains cured by anhydride
inferred← citeshttps://doi.org/10.1039/c6tc03772kopenalex-snapshot
Unique pure barium titanate foams with three-dimensional interconnecting pore channels and their high-k cyanate ester resin composites at very low barium titanate loading
inferred← citeshttps://doi.org/10.1039/c7gc02322gopenalex-snapshot
Eugenol bio-based epoxy thermosets: from cloves to applied materials
inferred← citeshttps://doi.org/10.1039/c7gc03552gopenalex-snapshot
Renewable thermoset polymers based on lignin and carbohydrate derived monomers
inferred← citeshttps://doi.org/10.1039/c7ra06798dopenalex-snapshot
Synthesis and properties of an intrinsic flame retardant silicone rubber containing phosphaphenanthrene structure
inferred← citeshttps://doi.org/10.1039/c7ra08531aopenalex-snapshot
Lignin-derived carbon nanosheets for high-capacitance supercapacitors
inferred← citeshttps://doi.org/10.1039/c7ra08536bopenalex-snapshot
Bio-inspired electrochemical corrosion coatings derived from graphene/natural lacquer composites
inferred← citeshttps://doi.org/10.1039/c8nr03261kopenalex-snapshot
Revisiting graphene–polymer nanocomposite for enhancing anticorrosion performance: a new insight into interface chemistry and diffusion model
inferred← citeshttps://doi.org/10.1039/c8ra01740aopenalex-snapshot
Simultaneous reinforcement and toughness improvement of an epoxy–phenolic network with a hyperbranched polysiloxane modifier
inferred← citeshttps://doi.org/10.1039/c8ra05598jopenalex-snapshot
Synthesis of a lignin-based phosphorus-containing flame retardant and its application in polyurethane
inferred← citeshttps://doi.org/10.1039/c8ra08302aopenalex-snapshot
Nanostructured thin lignin-derived carbon sheets as excellent reinforcement fillers in polypropylene
inferred← citeshttps://doi.org/10.1039/c9nj06373kopenalex-snapshot
A hyperbranched polymer from tung oil for the modification of epoxy thermoset with simultaneous improvement in toughness and strength
inferred← citeshttps://doi.org/10.1039/c9ta05028kopenalex-snapshot
Cyclophosphazene-based hybrid polymer electrolytes obtained via epoxy–amine reaction for high-performance all-solid-state lithium-ion batteries
inferred← citeshttps://doi.org/10.1039/d0gc02417aopenalex-snapshot
Improving fast pyrolysis of lignin using three additives with different modes of action
inferred← citeshttps://doi.org/10.1039/d1ma00841bopenalex-snapshot
Tannin as a renewable raw material for adhesive applications: a review
inferred← citeshttps://doi.org/10.1039/d1na00757bopenalex-snapshot
Enhancing the mechanical strength and toughness of epoxy resins with linear POSS nano-modifiers
inferred← citeshttps://doi.org/10.1039/d1ra09049fopenalex-snapshot
A phosphorus-containing imidazole derivative towards the liquid oxygen compatibility and toughness of epoxy resin
inferred← citeshttps://doi.org/10.1039/d2sm01126copenalex-snapshot
Influence of dodecyl surfactants on the cross-linking, plasticization and damping behavior of epoxy novolac resins
inferred← citeshttps://doi.org/10.1039/d3gc03441kopenalex-snapshot
Recent progress of biomass in conventional wood adhesives: a review
inferred← citeshttps://doi.org/10.1039/d3gc03680dopenalex-snapshot
Organic transformation of lignin into mussel-inspired glues: next-generation 2K adhesive for setting corals under saltwater
inferred← citeshttps://doi.org/10.1039/d4gc00745jopenalex-snapshot
From waste to resource: advancements in sustainable lignin modification
inferred← citeshttps://doi.org/10.1063/5.0196825openalex-snapshot
From technical lignin to native lignin: Depolymerization, functionalization, and applications
inferred← citeshttps://doi.org/10.1080/00405000.2023.2300592openalex-snapshot
A review of emerging bio-based constituents for natural fiber polymer composites
inferred← citeshttps://doi.org/10.1080/03602559.2016.1253742openalex-snapshot
Recent Development of Biobased Epoxy Resins: A Review
inferred← citeshttps://doi.org/10.1080/09506608.2021.1915936openalex-snapshot
Advances in the development of biobased epoxy resins: insight into more sustainable materials and future applications
inferred← citeshttps://doi.org/10.1080/15583724.2026.2679738openalex-snapshot
Chemistry, Structural Design, Properties and Future Perspectives of High-Performance Polymers from Renewable Biomass
inferred← citeshttps://doi.org/10.1088/1757-899x/377/1/012172openalex-snapshot
Thermo-mechanical stability of epoxy composites induced with surface silanized recycled carbon fibers
inferred← citeshttps://doi.org/10.1088/2053-1591/ab24efopenalex-snapshot
Liquid oxygen compatibility and toughness of epoxy resin modified by a novel hyperbranched polysiloxane
inferred← citeshttps://doi.org/10.1155/2022/1363481openalex-snapshot
Lignin as Green Filler in Polymer Composites: Development Methods, Characteristics, and Potential Applications
inferred← citeshttps://doi.org/10.1177/00952443241295581openalex-snapshot
Extreme impact enhancement of epoxy using a sulfosuccinate-based anionic surfactant as a new modifier
inferred← citeshttps://doi.org/10.1177/07316844261424667openalex-snapshot
Curing behaviour, mechanical and thermal properties of unmodified lignin–epoxy composites using a bio-based phenalkamine hardener
inferred← citeshttps://doi.org/10.1177/0954008316656743openalex-snapshot
Epoxy matrix toughness improvement via reactive bio-resin alloying
inferred← citeshttps://doi.org/10.15244/pjoes/100495openalex-snapshot
Life Cycle Perspective of Liquid Epoxy Resin Use in the Automotive Industry
inferred← citeshttps://doi.org/10.1680/jgrma.19.00026openalex-snapshot
Progress in development of epoxy resin systems based on biomass resources
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