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The Combined C–H Functionalization/Cope Rearrangement: Discovery and Applications in Organic Synthesis

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/3527604693.ch16openalex-snapshot
Cyclopentane Construction by Rhodium(II)‐Mediated Intramolecular C–H Insertion
inferredcites →https://doi.org/10.1002/adsc.201100334openalex-snapshot
Iron‐Catalyzed CH Fuctionalization of Indoles
inferredcites →https://doi.org/10.1002/anie.200462227openalex-snapshot
Direct Synthesis of (+)‐Erogorgiaene through a Kinetic Enantiodifferentiating Step
inferredcites →https://doi.org/10.1002/anie.201006368openalex-snapshot
If CH Bonds Could Talk: Selective CH Bond Oxidation
inferredcites →https://doi.org/10.1002/anie.201007241openalex-snapshot
Oxidizing Directing Groups Enable Efficient and Innovative CH Activation Reactions
inferredcites →https://doi.org/10.1002/anie.201100134openalex-snapshot
One‐Step Catalytic Asymmetric Synthesis of Configurationally Stable Tröger Bases
inferredcites →https://doi.org/10.1002/anie.201103568openalex-snapshot
Computationally Guided Stereocontrol of the Combined CH Functionalization/Cope Rearrangement
inferredcites →https://doi.org/10.1002/chem.201101590openalex-snapshot
Rapid Access to α‐Alkoxy and α‐Amino Acid Derivatives through Safe Continuous‐Flow Generation of Diazoesters
inferredcites →https://doi.org/10.1007/128_2009_11openalex-snapshot
Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion
inferredcites →https://doi.org/10.1007/128_2009_19openalex-snapshot
Metal-Catalyzed Oxidations of C–H to C–N Bonds
inferredcites →https://doi.org/10.1007/b96886openalex-snapshot
Marine Natural Products from Pseudopterogorgia elisabethae: Structures, Biosynthesis, Pharmacology, and Total Synthesis
inferredcites →https://doi.org/10.1016/0040-4039(96)00823-4openalex-snapshot
Effect of diazoalkane structure on the stereoselectivity of rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed cyclopropanations
inferredcites →https://doi.org/10.1016/0957-4166(96)00220-0openalex-snapshot
Asymmetric [3.3]-sigmatropic rearrangements in organic synthesis
inferredcites →https://doi.org/10.1016/j.bmcl.2008.11.022openalex-snapshot
1-Naphthyl and 4-indolyl arylalkylamines as selective monoamine reuptake inhibitors
inferredcites →https://doi.org/10.1016/j.ccr.2007.08.019openalex-snapshot
High symmetry dirhodium(II) paddlewheel complexes as chiral catalysts
inferredcites →https://doi.org/10.1016/j.tet.2006.05.086openalex-snapshot
Application of the combined C–H activation/Cope rearrangement as a key step in the total syntheses of the assigned structure of (+)-elisabethadione and a (+)-p-benzoquinone natural product
inferredcites →https://doi.org/10.1016/j.tet.2008.11.059openalex-snapshot
Intermolecular C–H functionalization versus cyclopropanation of electron rich 1,1-disubstituted and trisubstituted alkenes
inferredcites →https://doi.org/10.1016/j.tet.2011.01.059openalex-snapshot
Kinetic and stereoselectivity effects of phosphite ligands in dirhodium catalysis
inferredcites →https://doi.org/10.1016/j.tetasy.2006.01.023openalex-snapshot
Direct synthesis of methyl 2-diazo-4-aryl-3-butenoates and their application to the enantioselective synthesis of 4-aryl-4-(1-naphthyl)-2-butenoates
inferredcites →https://doi.org/10.1016/s0022-328x(00)00599-4openalex-snapshot
Recent progress in asymmetric intermolecular CH activation by rhodium carbenoid intermediates
inferredcites →https://doi.org/10.1016/s0040-4020(01)82371-1openalex-snapshot
Tandem cyclopropanation/cope rearrangement: a general method for the construction of seven-membered rings
inferredcites →https://doi.org/10.1016/s0040-4020(96)00958-1openalex-snapshot
Highly stereoselectively cope rearrangements of enantiomerically pure, silylated syn-aldols
inferredcites →https://doi.org/10.1016/s0040-4039(00)00104-0openalex-snapshot
Effect of carbenoid structure on the reactions of rhodium-stabilized carbenoids with cycloheptatriene
inferredcites →https://doi.org/10.1021/ar800042popenalex-snapshot
Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation
inferredcites →https://doi.org/10.1021/cr00028a010openalex-snapshot
Organic Synthesis with .alpha.-Diazo Carbonyl Compounds
inferredcites →https://doi.org/10.1021/cr00061a001openalex-snapshot
Catalysis of the Cope and Claisen rearrangements
inferredcites →https://doi.org/10.1021/cr0200217openalex-snapshot
Catalytic Enantioselective C−H Activation by Means of Metal−Carbenoid-Induced C−H Insertion
inferredcites →https://doi.org/10.1021/cr100304nopenalex-snapshot
The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress
inferredcites →https://doi.org/10.1021/cr900005nopenalex-snapshot
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
inferredcites →https://doi.org/10.1021/cr900184eopenalex-snapshot
Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
inferredcites →https://doi.org/10.1021/cr900239nopenalex-snapshot
Catalytic Carbene Insertion into C−H Bonds
inferredcites →https://doi.org/10.1021/cr940066aopenalex-snapshot
Recent Advances in Asymmetric Catalytic Metal Carbene Transformations
inferredcites →https://doi.org/10.1021/ja00331a070openalex-snapshot
Design and reactivity of topologically unique, chiral phosphonamides. Remarkable diastereofacial selectivity in asymmetric olefination and alkylation
inferredcites →https://doi.org/10.1021/ja0160546openalex-snapshot
Catalytic Asymmetric Synthesis of Highly Functionalized Cyclopentenes by a [3 + 2] Cycloaddition
inferredcites →https://doi.org/10.1021/ja045173topenalex-snapshot
Metal Carbene-Promoted Sequential Transformations for the Enantioselective Synthesis of Highly Functionalized Cycloheptadienes
inferredcites →https://doi.org/10.1021/ja047185kopenalex-snapshot
Highly Diastereoselective and Enantioselective C−H Functionalization of 1,2-Dihydronaphthalenes: A Combined C−H Activation/Cope Rearrangement Followed by a Retro-Cope Rearrangement
inferredcites →https://doi.org/10.1021/ja056877lopenalex-snapshot
Combined C−H Activation/Cope Rearrangement as a Strategic Reaction in Organic Synthesis: Total Synthesis of (−)-Colombiasin A and (−)-Elisapterosin B
inferredcites →https://doi.org/10.1021/ja057768+openalex-snapshot
C−H Activation as a Strategic Reaction: Enantioselective Synthesis of 4-Substituted Indoles
inferredcites →https://doi.org/10.1021/ja103916topenalex-snapshot
Catalyst-Controlled Formal [4 + 3] Cycloaddition Applied to the Total Synthesis of (+)-Barekoxide and (−)-Barekol
inferredcites →https://doi.org/10.1021/ja111408vopenalex-snapshot
On the Mechanism and Selectivity of the Combined C−H Activation/Cope Rearrangement
inferredcites →https://doi.org/10.1021/ja201589kopenalex-snapshot
Diastereoselectively Switchable Enantioselective Trapping of Carbamate Ammonium Ylides with Imines
inferredcites →https://doi.org/10.1021/ja2051155openalex-snapshot
Combined C–H Functionalization/Cope Rearrangement with Vinyl Ethers as a Surrogate for the Vinylogous Mukaiyama Aldol Reaction
inferredcites →https://doi.org/10.1021/ja207664ropenalex-snapshot
Asymmeric Formal [3 + 3]-Cycloaddition Reactions of Nitrones with Electrophilic Vinylcarbene Intermediates
inferredcites →https://doi.org/10.1021/ja9078094openalex-snapshot
Rhodium-Catalyzed [3 + 2] Annulation of Indoles
inferredcites →https://doi.org/10.1021/ja971915popenalex-snapshot
Asymmetric Intermolecular Carbenoid C−H Insertions Catalyzed by Rhodium(II) (S)-N-(p-Dodecylphenyl)sulfonylprolinate
inferredcites →https://doi.org/10.1021/ja974201nopenalex-snapshot
Tandem Asymmetric Cyclopropanation/Cope Rearrangement. A Highly Diastereoselective and Enantioselective Method for the Construction of 1,4-Cycloheptadienes
inferredcites →https://doi.org/10.1021/ja9910715openalex-snapshot
Highly Regio-, Diastereo-, and Enantioselective C−H Insertions of Methyl Aryldiazoacetates into Cyclic N-Boc-Protected Amines. Asymmetric Synthesis of Novel C2-Symmetric Amines and threo-Methylphenidate
inferredcites →https://doi.org/10.1021/ja994136copenalex-snapshot
Catalytic Asymmetric C−H Activation of Alkanes and Tetrahydrofuran
inferredcites →https://doi.org/10.1021/jo00012a011openalex-snapshot
Stereoselective synthesis of seven-membered carbocycles by a tandem cyclopropanation/Cope rearrangement between rhodium(II)-stabilized vinylcarbenoids and dienes
inferredcites →https://doi.org/10.1021/jo048429mopenalex-snapshot
Catalytic Asymmetric Reactions for Organic Synthesis: The Combined C−H Activation/Siloxy-Cope Rearrangement
inferredcites →https://doi.org/10.1021/jo060779gopenalex-snapshot
Investigation into Factors Influencing Stereoselectivity in the Reactions of Heterocycles with Donor−Acceptor-Substituted Rhodium Carbenoids
inferredcites →https://doi.org/10.1021/jo0624694openalex-snapshot
Rhodium-Catalyzed Intramolecular C−H Insertion of α-Aryl-α-diazo Ketones
inferredcites →https://doi.org/10.1021/jo202119popenalex-snapshot
Total Synthesis of (−)-Virginiamycin M2: Application of Crotylsilanes Accessed by Enantioselective Rh(II) or Cu(I) Promoted Carbenoid Si–H Insertion
inferredcites →https://doi.org/10.1021/jo8010683openalex-snapshot
Synthesis of (−)-Hamigeran B
inferredcites →https://doi.org/10.1021/jo902644fopenalex-snapshot
Controlling Factors for C−H Functionalization versus Cyclopropanation of Dihydronaphthalenes
inferredcites →https://doi.org/10.1021/jo9914869openalex-snapshot
Novel Terpenoids from the West Indian Sea Whip Pseudopterogorgia elisabethae (Bayer). Elisapterosins A and B: Rearranged Diterpenes Possessing an Unprecedented Cagelike Framework1
inferredcites →https://doi.org/10.1021/np000196gopenalex-snapshot
Serrulatane Diterpenes with Antimycobacterial Activity Isolated from the West Indian Sea Whip Pseudopterogorgia elisabethae
inferredcites →https://doi.org/10.1021/ol035398topenalex-snapshot
seco-C/D Ring Analogues of Ergot Alkaloids. Synthesis via Intramolecular Heck and Ring-Closing Metathesis Reactions
inferredcites →https://doi.org/10.1021/ol050018kopenalex-snapshot
Enantioselective Double C−H Activation of Dihydronaphthalenes
inferredcites →https://doi.org/10.1021/ol200766topenalex-snapshot
Multicomponent Mannich Reactions with Boron Enolates Derived from Diazo Esters and 9-BBN
inferredcites →https://doi.org/10.1021/ol2026125openalex-snapshot
Multifunctionalized 3-Hydroxypyrroles in a Three-Step, One-Pot Cascade Process from Methyl 3-TBSO-2-diazo-3-butenoate and Nitrones
inferredcites →https://doi.org/10.1021/ol702218wopenalex-snapshot
Balance between Allylic C−H Activation and Cyclopropanation in the Reactions of Donor/Acceptor-Substituted Rhodium Carbenoids with trans-Alkenes
inferredcites →https://doi.org/10.1021/ol9903943openalex-snapshot
Catalytic Asymmetric Synthesis of Diarylacetates and 4,4-Diarylbutanoates. A Formal Asymmetric Synthesis of (+)-Sertraline
inferredcites →https://doi.org/10.1021/ol9905699openalex-snapshot
Catalytic Asymmetric Synthesis of Diarylacetates and 4,4-Diarylbutanoates. A Formal Asymmetric Synthesis of (+)-Sertraline
inferredcites →https://doi.org/10.1021/ol9905809openalex-snapshot
Catalytic Asymmetric Synthesis ofSyn-Aldol Products from Intermolecular C−H Insertions between Allyl Silyl Ethers and Methyl Aryldiazoacetates
inferredcites →https://doi.org/10.1021/ol991362iopenalex-snapshot
A Marine Diterpene with a Novel Tetracyclic Framework from the West Indian Gorgonian Octocoral Pseudopterogorgia elisabethae
inferredcites →https://doi.org/10.1038/nature06485openalex-snapshot
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
inferredcites →https://doi.org/10.1039/b901170fopenalex-snapshot
Application of donor/acceptor-carbenoids to the synthesis of natural products
inferredcites →https://doi.org/10.1039/c0cs00063aopenalex-snapshot
Direct Sp3α-C–H activation and functionalization of alcohol and ether
inferredcites →https://doi.org/10.1039/c0cs00070aopenalex-snapshot
Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions
inferredcites →https://doi.org/10.1039/c0cs00182aopenalex-snapshot
C–H functionalization logic in total synthesis
inferredcites →https://doi.org/10.1039/c0cs00217hopenalex-snapshot
Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes
inferredcites →https://doi.org/10.1039/c1ob05499fopenalex-snapshot
Enantioselective C–H carbene insertions with homogeneous and immobilized copper complexes
inferredcites →https://doi.org/10.1073/pnas.0307556101openalex-snapshot
Catalytic asymmetric reactions for organic synthesis: The combined C—H activation/Cope rearrangement
inferredcites →https://doi.org/10.1126/science.1183602openalex-snapshot
Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation
inferredcites →https://doi.org/10.2174/1385272802666220128232502openalex-snapshot
Rhodium-Stabilized Vinylcarbenoid Intermediates in Organic Synthesis

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4658962openalex-extracted
Divergent Synthesis of Cyclopentenyl- & 1,5-Divinyl-Ketones Via Gold-Catalyzed Oxidative Coupling of 1,3-Enynes with Various Olefins
inferred← citeshttps://doi.org/10.1002/9781118730379.ch12openalex-snapshot
Rhodium Carbenes
inferred← citeshttps://doi.org/10.1002/9781118730379.ch15openalex-snapshot
Cobalt‐Mediated Carbene Transfer Reactions
inferred← citeshttps://doi.org/10.1002/9781118792797.ch04openalex-snapshot
MetalMetal Bond‐Containing Complexes as Catalysts for CH Functionalization
inferred← citeshttps://doi.org/10.1002/9781119736424.ch12openalex-snapshot
ASYMMETRIC C–H FUNCTIONALIZATION OF C(sp 3 )–H BOND
inferred← citeshttps://doi.org/10.1002/9781119757153.ch5openalex-snapshot
Synthesis of N ‐Heterocycles via [3 + n] Cycloaddition Reactions of Vinyl Metal Carbene Intermediates
inferred← citeshttps://doi.org/10.1002/9783527678211.ch2openalex-snapshot
Fundamental Aspects of the Metal‐Catalyzed C–H Bond Functionalization by Diazocarbenes: Guiding Principles for Design of Catalyst with Non‐redox‐Active Metal (Such as Ca) and Non‐Innocent Ligand
inferred← citeshttps://doi.org/10.1002/9783527691920.ch10openalex-snapshot
Heterocycles Synthesis via Co‐Catalyzed CH Bond Functionalization
inferred← citeshttps://doi.org/10.1002/9783527809080.cataz04026openalex-snapshot
Cope rearrangement
inferred← citeshttps://doi.org/10.1002/9783527811908.ch13openalex-snapshot
Rhodium( II ) Tetracarboxylate‐Catalyzed Enantioselective C – H Functionalization Reactions
inferred← citeshttps://doi.org/10.1002/9783527828166.ch1openalex-snapshot
Rearrangement Reactions
inferred← citeshttps://doi.org/10.1002/9783527834242.chf0038openalex-snapshot
Ruthenium‐Catalyzed CH Activation in Target Oriented Synthesis of Natural Products and Active Pharmaceutical Intermediates
inferred← citeshttps://doi.org/10.1002/9783527834242.chf0085openalex-snapshot
Site‐Selective CH Functionalization with Diazo Compounds (Carbenes)
inferred← citeshttps://doi.org/10.1002/9783527834242.chf0174openalex-snapshot
Catalytic Aromatic CH Functionalization Involving Metal Carbene
inferred← citeshttps://doi.org/10.1002/9783527846849.ch14openalex-snapshot
Organocatalytic Reactions in Water
inferred← citeshttps://doi.org/10.1002/adsc.201300838openalex-snapshot
Unexpected Stereoselective Synthesis of (Z)‐β‐Alkenyl Substituted β‐Amino Phosphonates through β,γ‐Dihydrogen Shift Reaction Catalyzed by a Copper(I) Complex and Iodine [Cu(MeCN)4]PF6/I2
inferred← citeshttps://doi.org/10.1002/adsc.201500433openalex-snapshot
Synthesis of Pyridoisoindoles through Diazotization Followed by Intramolecular Cyclization from Pyridinylarylacetates in One Pot
inferred← citeshttps://doi.org/10.1002/adsc.201500769openalex-snapshot
Multiple Roles of the Pyrimidyl Group in the Rhodium‐Catalyzed Regioselective Synthesis and Functionalization of Indole‐3‐carboxylic Acid Esters
inferred← citeshttps://doi.org/10.1002/adsc.201501106openalex-snapshot
Enantioselective Carbene Cascade: An Effective Approach to Cyclopentadienes and Applications in Diels–Alder Reactions
inferred← citeshttps://doi.org/10.1002/adsc.201600883openalex-snapshot
Copper‐Catalyzed Difunctionalization of Terminal Alkynes with Diazo Esters and Amines to Construct β‐Enamino Esters
inferred← citeshttps://doi.org/10.1002/adsc.202000789openalex-snapshot
One‐Pot Tandem Protocol for the Synthesis of 1,3‐Bis(β‐aminoacrylate)‐Substituted 2‐Mercaptoimidazole Scaffolds
inferred← citeshttps://doi.org/10.1002/adsc.202000957openalex-snapshot
Silver‐Catalyzed Three‐Component Coupling Reaction of Amines, 2‐Isocyanobenzaldehydes, and 2,2,2‐Trifluorodiazoethane and Synthesis of Trifluoromethyl‐Substituted Indolo[1,2‐ c ]quinazolines
inferred← citeshttps://doi.org/10.1002/ajoc.201800472openalex-snapshot
Gold‐Catalyzed Site‐Selective C−H Bond Functionalization with Diazo Compounds
inferred← citeshttps://doi.org/10.1002/ajoc.202400356openalex-snapshot
Gold Catalyzed [3+2] Oxidative Annulation of 1,3‐Enynes with Indoles
inferred← citeshttps://doi.org/10.1002/ange.201204047openalex-snapshot
Alkynoate Synthesis through the Vinylogous Reactivity of Rhodium(II) Carbenoids
inferred← citeshttps://doi.org/10.1002/ange.201301509openalex-snapshot
Construction of Enantiomerically Enriched Diazo Compounds Using Diazo Esters as Nucleophiles: Chiral Lewis Base Catalysis
inferred← citeshttps://doi.org/10.1002/ange.201304310openalex-snapshot
Rhodium‐Catalyzed Tandem Cyclopropanation/Cope Rearrangement of 4‐Alkenyl‐1‐sulfonyl‐1,2,3‐triazoles with Dienes
inferred← citeshttps://doi.org/10.1002/ange.201306824openalex-snapshot
Enantioselective Palladium(II) Phosphate Catalyzed Three‐Component Reactions of Pyrrole, Diazoesters, and Imines
inferred← citeshttps://doi.org/10.1002/ange.201406712openalex-snapshot
Gold(I)‐Catalyzed Diazo Coupling: Strategy towards Alkene Formation and Tandem Benzannulation
inferred← citeshttps://doi.org/10.1002/ange.201500841openalex-snapshot
Composite Polymer/Oxide Hollow Fiber Contactors: Versatile and Scalable Flow Reactors for Heterogeneous Catalytic Reactions in Organic Synthesis
inferred← citeshttps://doi.org/10.1002/ange.201502553openalex-snapshot
Zinc‐Catalyzed Alkyne Oxidation/CH Functionalization: Highly Site‐Selective Synthesis of Versatile Isoquinolones and β‐Carbolines
inferred← citeshttps://doi.org/10.1002/ange.201504236openalex-snapshot
An Inexpensive and Recyclable Silver‐Foil Catalyst for the Cyclopropanation of Alkenes with Diazoacetates under Mechanochemical Conditions
inferred← citeshttps://doi.org/10.1002/ange.201505993openalex-snapshot
Copper‐Catalyzed Formation of α‐Alkoxycycloalkenones from N‐Tosylhydrazones
inferred← citeshttps://doi.org/10.1002/ange.201506902openalex-snapshot
The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium‐to‐Gold Transmetalation
inferred← citeshttps://doi.org/10.1002/ange.201509711openalex-snapshot
Reaction of Diazo Compounds with Difluorocarbene: An Efficient Approach towards 1,1‐Difluoroolefins
inferred← citeshttps://doi.org/10.1002/ange.201602024openalex-snapshot
Rapid Construction of a Benzo‐Fused Indoxamycin Core Enabled by Site‐Selective C−H Functionalizations
inferred← citeshttps://doi.org/10.1002/ange.201603661openalex-snapshot
Palladium(II)‐Catalyzed Tandem Synthesis of Acenes Using Carboxylic Acids as Traceless Directing Groups
inferred← citeshttps://doi.org/10.1002/ange.201605438openalex-snapshot
Catalytic Asymmetric Synthesis of Cyclopentyl β‐Amino Esters by [3+2] Cycloaddition of Enecarbamates with Electrophilic Metalloenolcarbene Intermediates
inferred← citeshttps://doi.org/10.1002/ange.201605502openalex-snapshot
Stabilization of a Chiral Dirhodium Carbene by Encapsulation and a Discussion of the Stereochemical Implications
inferred← citeshttps://doi.org/10.1002/ange.201606139openalex-snapshot
Gold‐Catalyzed Formal [4+1]/[4+3] Cycloadditions of Diazo Esters with Triazines
inferred← citeshttps://doi.org/10.1002/ange.201608937openalex-snapshot
(C6F5)3B Catalyzed Chemoselective and ortho‐Selective Substitution of Phenols with α‐Aryl α‐Diazoesters
inferred← citeshttps://doi.org/10.1002/ange.201810410openalex-snapshot
Bimetallic Rhodium(II)/Indium(III) Relay Catalysis for Tandem Insertion/Asymmetric Claisen Rearrangement
inferred← citeshttps://doi.org/10.1002/ange.201905533openalex-snapshot
Asymmetric Catalytic Formal 1,4‐Allylation of β,γ‐Unsaturated α‐Ketoesters: Allylboration/Oxy‐Cope Rearrangement
inferred← citeshttps://doi.org/10.1002/ange.201909872openalex-snapshot
A Carbene‐Extended ATRA Reaction
inferred← citeshttps://doi.org/10.1002/ange.201911614openalex-snapshot
Tandem Cross‐Coupling/Spirocyclization/Mannich‐Type Reactions of 3‐(2‐Isocyanoethyl)indoles with Diazo Compounds toward Polycyclic Spiroindolines
inferred← citeshttps://doi.org/10.1002/ange.201914354openalex-snapshot
Rhodium‐Catalyzed Enantioselective [4+2] Cycloadditions of Vinylcarbenes with Dienes
inferred← citeshttps://doi.org/10.1002/ange.202004328openalex-snapshot
Brønsted Acid Catalyzed Friedel–Crafts‐Type Coupling and Dedinitrogenation Reactions of Vinyldiazo Compounds
inferred← citeshttps://doi.org/10.1002/ange.202208874openalex-snapshot
Enantioselective para‐C(sp2)−H Functionalization of Alkyl Benzene Derivatives via Cooperative Catalysis of Gold/Chiral Brønsted Acid**
inferred← citeshttps://doi.org/10.1002/ange.202212546openalex-snapshot
Chiral Bismuth‐Rhodium Paddlewheel Complexes Empowered by London Dispersion: The C−H Functionalization Nexus
inferred← citeshttps://doi.org/10.1002/ange.202305864openalex-snapshot
Enantioselective Synthesis of Biscyclopropanes Using Alkynes as Dicarbene Equivalents
inferred← citeshttps://doi.org/10.1002/ange.202406936openalex-snapshot
Gold‐Catalyzed Arylative Cope Rearrangement
inferred← citeshttps://doi.org/10.1002/ange.6267376openalex-snapshot
Cobalt‐Catalyzed Enantioselective Vinyl Carbene Annulation: A Versatile Platform for Semisaturated Heterocycles
inferred← citeshttps://doi.org/10.1002/anie.201204047openalex-snapshot
Alkynoate Synthesis through the Vinylogous Reactivity of Rhodium(II) Carbenoids
inferred← citeshttps://doi.org/10.1002/anie.201301509openalex-snapshot
Construction of Enantiomerically Enriched Diazo Compounds Using Diazo Esters as Nucleophiles: Chiral Lewis Base Catalysis
inferred← citeshttps://doi.org/10.1002/anie.201304310openalex-snapshot
Rhodium‐Catalyzed Tandem Cyclopropanation/Cope Rearrangement of 4‐Alkenyl‐1‐sulfonyl‐1,2,3‐triazoles with Dienes
inferred← citeshttps://doi.org/10.1002/anie.201306824openalex-snapshot
Enantioselective Palladium(II) Phosphate Catalyzed Three‐Component Reactions of Pyrrole, Diazoesters, and Imines
inferred← citeshttps://doi.org/10.1002/anie.201406712openalex-snapshot
Gold(I)‐Catalyzed Diazo Coupling: Strategy towards Alkene Formation and Tandem Benzannulation
inferred← citeshttps://doi.org/10.1002/anie.201500841openalex-snapshot
Composite Polymer/Oxide Hollow Fiber Contactors: Versatile and Scalable Flow Reactors for Heterogeneous Catalytic Reactions in Organic Synthesis
inferred← citeshttps://doi.org/10.1002/anie.201502553openalex-snapshot
Zinc‐Catalyzed Alkyne Oxidation/CH Functionalization: Highly Site‐Selective Synthesis of Versatile Isoquinolones and β‐Carbolines
inferred← citeshttps://doi.org/10.1002/anie.201504236openalex-snapshot
An Inexpensive and Recyclable Silver‐Foil Catalyst for the Cyclopropanation of Alkenes with Diazoacetates under Mechanochemical Conditions
inferred← citeshttps://doi.org/10.1002/anie.201505993openalex-snapshot
Copper‐Catalyzed Formation of α‐Alkoxycycloalkenones from N‐Tosylhydrazones
inferred← citeshttps://doi.org/10.1002/anie.201506902openalex-snapshot
The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium‐to‐Gold Transmetalation
inferred← citeshttps://doi.org/10.1002/anie.201509711openalex-snapshot
Reaction of Diazo Compounds with Difluorocarbene: An Efficient Approach towards 1,1‐Difluoroolefins
inferred← citeshttps://doi.org/10.1002/anie.201602024openalex-snapshot
Rapid Construction of a Benzo‐Fused Indoxamycin Core Enabled by Site‐Selective C−H Functionalizations
inferred← citeshttps://doi.org/10.1002/anie.201603661openalex-snapshot
Palladium(II)‐Catalyzed Tandem Synthesis of Acenes Using Carboxylic Acids as Traceless Directing Groups
inferred← citeshttps://doi.org/10.1002/anie.201605438openalex-snapshot
Catalytic Asymmetric Synthesis of Cyclopentyl β‐Amino Esters by [3+2] Cycloaddition of Enecarbamates with Electrophilic Metalloenolcarbene Intermediates
inferred← citeshttps://doi.org/10.1002/anie.201605502openalex-snapshot
Stabilization of a Chiral Dirhodium Carbene by Encapsulation and a Discussion of the Stereochemical Implications
inferred← citeshttps://doi.org/10.1002/anie.201606139openalex-snapshot
Gold‐Catalyzed Formal [4+1]/[4+3] Cycloadditions of Diazo Esters with Triazines
inferred← citeshttps://doi.org/10.1002/anie.201608937openalex-snapshot
(C6F5)3B Catalyzed Chemoselective and ortho‐Selective Substitution of Phenols with α‐Aryl α‐Diazoesters
inferred← citeshttps://doi.org/10.1002/anie.201810410openalex-snapshot
Bimetallic Rhodium(II)/Indium(III) Relay Catalysis for Tandem Insertion/Asymmetric Claisen Rearrangement
inferred← citeshttps://doi.org/10.1002/anie.201905533openalex-snapshot
Asymmetric Catalytic Formal 1,4‐Allylation of β,γ‐Unsaturated α‐Ketoesters: Allylboration/Oxy‐Cope Rearrangement
inferred← citeshttps://doi.org/10.1002/anie.201909872openalex-snapshot
A Carbene‐Extended ATRA Reaction
inferred← citeshttps://doi.org/10.1002/anie.201911614openalex-snapshot
Tandem Cross‐Coupling/Spirocyclization/Mannich‐Type Reactions of 3‐(2‐Isocyanoethyl)indoles with Diazo Compounds toward Polycyclic Spiroindolines
inferred← citeshttps://doi.org/10.1002/anie.201914354openalex-snapshot
Rhodium‐Catalyzed Enantioselective [4+2] Cycloadditions of Vinylcarbenes with Dienes
inferred← citeshttps://doi.org/10.1002/anie.202004328openalex-snapshot
Brønsted Acid Catalyzed Friedel–Crafts‐Type Coupling and Dedinitrogenation Reactions of Vinyldiazo Compounds
inferred← citeshttps://doi.org/10.1002/anie.202208874openalex-snapshot
Enantioselective para ‐C(sp 2 )−H Functionalization of Alkyl Benzene Derivatives via Cooperative Catalysis of Gold/Chiral Brønsted Acid**
inferred← citeshttps://doi.org/10.1002/anie.202212546openalex-snapshot
Chiral Bismuth‐Rhodium Paddlewheel Complexes Empowered by London Dispersion: The C−H Functionalization Nexus
inferred← citeshttps://doi.org/10.1002/anie.202305864openalex-snapshot
Enantioselective Synthesis of Biscyclopropanes Using Alkynes as Dicarbene Equivalents
inferred← citeshttps://doi.org/10.1002/anie.202406936openalex-snapshot
Gold‐Catalyzed Arylative Cope Rearrangement
inferred← citeshttps://doi.org/10.1002/anie.6267376openalex-snapshot
Cobalt‐Catalyzed Enantioselective Vinyl Carbene Annulation: A Versatile Platform for Semisaturated Heterocycles
inferred← citeshttps://doi.org/10.1002/asia.202401239openalex-snapshot
Light‐Induced Transformations of Donor‐Donor Diazo Compounds Derived from N‐Sulfonylhydrazones
inferred← citeshttps://doi.org/10.1002/bkcs.11283openalex-snapshot
Synthesis of 3a,7a‐Dihydroindoles via Rhodium‐catalyzed Intermolecular Formal [3 + 2] Transannulation Reactions of Triazoles with Alkyl‐substituted Benzene Derivatives
inferred← citeshttps://doi.org/10.1002/chem.201203217openalex-snapshot
Reactivity of Stabilized Vinyl Diazo Derivatives toward Unsaturated Hydrocarbons: Regioselective Gold‐Catalyzed Carbon–Carbon Bond Formation
inferred← citeshttps://doi.org/10.1002/chem.201501106openalex-snapshot
Rhodium(III)‐Catalyzed [4+1] Annulation of Aromatic and Vinylic Carboxylic Acids with Allenes: An Efficient Method Towards Vinyl‐Substituted Phthalides and 2‐Furanones
inferred← citeshttps://doi.org/10.1002/chem.201502073openalex-snapshot
Base‐Promoted/Gold‐Catalyzed Intramolecular Highly Selective and Controllable Detosylative Cyclization
inferred← citeshttps://doi.org/10.1002/chem.201503511openalex-snapshot
Synthesis of 8‐Aminoquinolines by Using Carbamate Reagents: Facile Installation and Deprotection of Practical Amidating Groups
inferred← citeshttps://doi.org/10.1002/chem.201602440openalex-snapshot
Asymmetric Total Synthesis of (−)‐Erogorgiaene and Its C‐11 Epimer and Investigation of Their Antimycobacterial Activity
inferred← citeshttps://doi.org/10.1002/chem.201700101openalex-snapshot
Synthesis of 2,2,2,‐Trichloroethyl Aryl‐ and Vinyldiazoacetates by Palladium‐Catalyzed Cross‐Coupling
inferred← citeshttps://doi.org/10.1002/chem.201700643openalex-snapshot
Electronic Control on Linear versus Branched Alkylation of 2‐/3‐Aroylbenzofurans with Acrylates: Combined DFT and Synthetic Studies
inferred← citeshttps://doi.org/10.1002/chem.201704759openalex-snapshot
Copper‐ or Thermally Induced Divergent Outcomes: Synthesis of 4‐Methyl 2H‐Chromenes and Spiro‐4H‐Pyrazoles
inferred← citeshttps://doi.org/10.1002/chem.202003950openalex-snapshot
Dirhodium Complexes as Panchromatic Sensitizers, Electrocatalysts, and Photocatalysts
inferred← citeshttps://doi.org/10.1002/chem.202202820openalex-snapshot
Efficient Synthesis of Diaryl Quaternary Centers by Rh(II)/Xantphos Catalyzed Relay C−H Functionalization and Allylic Alkylation
inferred← citeshttps://doi.org/10.1002/chem.202403509openalex-snapshot
Oxydiazomethylation of Alkenes via Photoredox Catalysis
inferred← citeshttps://doi.org/10.1002/cjoc.202400896openalex-snapshot
Lantern‐Like Diplatinum( III )‐Catalyzed Redox‐Free Borylation or Silylation of Alkynes
inferred← citeshttps://doi.org/10.1002/cmtd.202500108openalex-snapshot
Chemo‐Divergent Friedel–Crafts Alkylation and Friedel–Crafts Acylation of Arenes with α ‐Diazo Ketones Tuned by Reaction Conditions
inferred← citeshttps://doi.org/10.1002/cssc.201300485openalex-snapshot
Solvent‐Free and Catalysts‐Free Chemistry: A Benign Pathway to Sustainability
inferred← citeshttps://doi.org/10.1002/ejoc.201700641openalex-snapshot
Recent Applications of Rh‐ and Pd‐Catalyzed C(sp 3 )–H Functionalization in Natural Product Total Synthesis
inferred← citeshttps://doi.org/10.1002/ejoc.202000126openalex-snapshot
Application of the Brook Rearrangement in Tandem with Single Electron Transfer Oxidative and Radical Processes
inferred← citeshttps://doi.org/10.1002/ejoc.202001528openalex-snapshot
Non‐Canonical Reactivity of Gold Carbene with Alkyne: An Overview of the Mechanistic Premise
inferred← citeshttps://doi.org/10.1002/ejoc.202400555openalex-snapshot
Chemoselective and Triggered Decomposition of Diazo Esters by the [(IMes)Rh2(OAc)4] Complex: En Route to Assisted Tandem Catalysis from Mixtures of Diazo Compounds
inferred← citeshttps://doi.org/10.1002/ijch.201900168openalex-snapshot
Enantioselective Catalysis of an Anionic Oxy‐Cope Rearrangement Enabled by Synergistic Ion Binding
inferred← citeshttps://doi.org/10.1002/slct.201802824openalex-snapshot
p ‐Dodecylbenzenesulfonic Acid: An Efficient Brønsted Acid‐Surfactant‐Combined Catalyst to Carry out Diverse Organic Transformations in Aqueous Medium
inferred← citeshttps://doi.org/10.1002/slct.202200531openalex-snapshot
Recent Advances in the Synthesis of 5‐Membered N ‐Heterocycles via Rhodium Catalysed Cascade Reactions
inferred← citeshttps://doi.org/10.1002/slct.202405088openalex-snapshot
Catalyst Free Chemoselective Carbene Insertion Into COO─H Bond Over ─OH of Salicylic Acid
inferred← citeshttps://doi.org/10.1007/978-3-031-52850-7_33openalex-snapshot
Cope-Umlagerung
inferred← citeshttps://doi.org/10.1007/978-3-319-03979-4_68openalex-snapshot
Cope rearrangement
inferred← citeshttps://doi.org/10.1007/978-3-662-49496-7_2openalex-snapshot
Recent Advances in Non-directed C(sp3)–H Bond Functionalization
inferred← citeshttps://doi.org/10.1007/s11172-021-3208-1openalex-snapshot
Synthesis of heterocyclic systems involving [3,3]-sigmatropic rearrangements
inferred← citeshttps://doi.org/10.1007/s11426-020-9794-3openalex-snapshot
Synergy of activating substrate and introducing C-H···O interaction to achieve Rh2(II)-catalyzed asymmetric cycloisomerization of 1,n-enynes
inferred← citeshttps://doi.org/10.1016/b978-0-08-097742-3.00704-7openalex-snapshot
7.03 Asymmetric C–H Functionalization by Transition Metal-Catalyzed Carbene Transfer Reactions
inferred← citeshttps://doi.org/10.1016/b978-0-12-817905-5.00010-xopenalex-snapshot
Utilization of Rh-carbenoid C H insertion reactions for the synthesis of bioactive natural products
inferred← citeshttps://doi.org/10.1016/b978-0-12-819848-3.00013-xopenalex-snapshot
Microwave-assisted catalyst-free organic synthesis
inferred← citeshttps://doi.org/10.1016/b978-0-12-820206-7.00157-8openalex-snapshot
Synthetic Applications of Carbene and Nitrene C H Insertion
inferred← citeshttps://doi.org/10.1016/b978-0-12-820586-0.00014-5openalex-snapshot
Ultrasonication under catalyst-free condition: an advanced synthetic technique toward the green synthesis of bioactive heterocycles
inferred← citeshttps://doi.org/10.1016/b978-0-323-95893-6.00007-4openalex-snapshot
Visible light-driven organic synthesis: an introduction
inferred← citeshttps://doi.org/10.1016/b978-0-323-96025-0.00168-xopenalex-snapshot
Cope, Oxy-Cope and Anionic Oxy-Cope Rearrangements
inferred← citeshttps://doi.org/10.1016/b978-0-443-31482-7.00122-3openalex-snapshot
One or More =CH, =CC, and/or C=C Bond(s) Formed by Rearrangement
inferred← citeshttps://doi.org/10.1016/bs.adomc.2016.07.002openalex-snapshot
The Selection of Catalysts for Metal Carbene Transformations
inferred← citeshttps://doi.org/10.1016/j.cclet.2014.12.014openalex-snapshot
Divergent pathways of β,γ-unsaturated α-diazocarbonyl compounds catalyzed by dirhodium and Lewis acids catalysts separately or in combination
inferred← citeshttps://doi.org/10.1016/j.checat.2022.01.004openalex-snapshot
The merger of vinyl-N-triftosylhydrazones and silver catalysis to enable stereoselective vinylcyclopropanation of alkenes
inferred← citeshttps://doi.org/10.1016/j.checat.2022.10.016openalex-snapshot
Catalytic reactions for enantioselective transfers of donor-substituted carbenes
inferred← citeshttps://doi.org/10.1016/j.gresc.2021.10.001openalex-snapshot
Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2017.07.013openalex-snapshot
Exploring energetics of dirhodium paddlewheel complexes with π-ligands of different topologies
inferred← citeshttps://doi.org/10.1016/j.mcat.2021.111980openalex-snapshot
DFT quest for mechanism and stereoselectivity in B(C6F5)3-catalyzed cyclopropanation of alkenes with aryldiazoacetates
inferred← citeshttps://doi.org/10.1016/j.mcat.2022.112574openalex-snapshot
DFT rationalization of metal-catalyst-controlled coupling of carbazole with diazo-naphthalen-2(1H)-one
inferred← citeshttps://doi.org/10.1016/j.rechem.2022.100301openalex-snapshot
Efficient synthesis of functionalized 2-iminothiazolines by ultrasonication under solvent-free conditions and access to 5-aryl-2-iminothiazolines
inferred← citeshttps://doi.org/10.1016/j.tet.2019.01.016openalex-snapshot
Application of carbene chemistry in the synthesis of organofluorine compounds
inferred← citeshttps://doi.org/10.1016/j.tet.2019.04.061openalex-snapshot
Aryl vinyl cyclopropane Cope rearrangements
inferred← citeshttps://doi.org/10.1016/j.tet.2019.05.040openalex-snapshot
Gold-catalyzed chemoselective formal (3+2)-Annulation reaction between β-naphthols and methyl aryldiazoacetate
inferred← citeshttps://doi.org/10.1016/j.tet.2020.131063openalex-snapshot
Regioselective synthesis of carboxylic and fluoromethyl tetrazoles enabled by silver-catalyzed cycloaddition of diazoacetates and aryl diazonium salts
inferred← citeshttps://doi.org/10.1016/j.tet.2023.133558openalex-snapshot
Sc(OTf)3-promoted formal insertion of 4-diazo-1,4-dihydroisoquinolin-3-ones into C–H bond of 1,3-dicarbonyl compounds: Synthesis of 2-(3-oxo-1,2,3,4-tetrahydroisoquinolin-4-yl)-1,3-diarylpropane-1,3-diones
inferred← citeshttps://doi.org/10.1016/j.tetlet.2013.10.090openalex-snapshot
When C–H bond functionalization meets visible-light photoredox catalysis
inferred← citeshttps://doi.org/10.1016/j.tetlet.2014.06.085openalex-snapshot
Enantioselective synthesis of decalin structures with all-carbon quaternary centers via one-pot sequential Cope/Rauhut–Currier reaction
inferred← citeshttps://doi.org/10.1016/j.tetlet.2014.09.126openalex-snapshot
Rh(II) acetate catalyzed cyclopropanation of styrenes with enaldiazo esters: diastereoselective synthesis of enal-cyclopropanes
inferred← citeshttps://doi.org/10.1016/j.tetlet.2016.02.078openalex-snapshot
Intermolecular cyclization of N-methylanilines and maleimides to tetrahydroquinolines via K2S2O8 promoted C(sp3)–H activation
inferred← citeshttps://doi.org/10.1016/j.tetlet.2016.12.077openalex-snapshot
Visible light photoredox catalysis with N-hydroxyphthalimide for [4+2] cyclization between N-methylanilines and maleimides
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.07.021openalex-snapshot
Simultaneous Ring-Opened THF and insertion of diazoketone derived carbene into carbonyl O-H: Synthesis for β-keto enol ethers
inferred← citeshttps://doi.org/10.1016/j.tetlet.2024.154918openalex-snapshot
Divergent synthesis of cyclopentenyl- & 1,5-divinyl-ketones via gold-catalyzed oxidative coupling of 1,3-enynes with various olefins
inferred← citeshttps://doi.org/10.1016/j.ultsonch.2016.09.023openalex-snapshot
Recent developments on ultrasound assisted catalyst-free organic synthesis
inferred← citeshttps://doi.org/10.1021/acs.accounts.4c00214openalex-snapshot
Quantum Chemical Interrogation of Reactions Promoted by Dirhodium Tetracarboxylate Catalysts─Mechanism, Selectivity, and Nonstatistical Dynamic Effects
inferred← citeshttps://doi.org/10.1021/acs.accounts.6b00029openalex-snapshot
Speeding Up Sigmatropic Shifts—To Halve or to Hold
inferred← citeshttps://doi.org/10.1021/acs.chemrev.7b00264openalex-snapshot
Metal-Involving Synthesis and Reactions of Oximes
inferred← citeshttps://doi.org/10.1021/acs.joc.0c01974openalex-snapshot
Blue Light-Promoted Formal [4+1]-Annulation of Diazoacetates with o-Aminoacetophenones: Synthesis of Polysubstituted Indolines and Computational Study
inferred← citeshttps://doi.org/10.1021/acs.joc.2c02624openalex-snapshot
Rhodium(I)-Catalyzed Direct Enantioselective C–H Functionalization of Indoles
inferred← citeshttps://doi.org/10.1021/acs.joc.3c00735openalex-snapshot
Modulating Escape Channels of Cycloheptatrienyl Rhodium Carbenes To Form Semibullvalene
inferred← citeshttps://doi.org/10.1021/acs.joc.3c02319openalex-snapshot
Cope Rearrangement of 1-Acyl-2-vinylcyclopropanes to Cyclohept-4-Enones
inferred← citeshttps://doi.org/10.1021/acs.joc.4c00705openalex-snapshot
Modular Synthesis of Tetrasubstituted Vinyl Sulfides via One-Pot Sequential Carbene Transfer Reaction from Thiols with α-Diazo Carbonyl Compounds
inferred← citeshttps://doi.org/10.1021/acs.joc.4c01682openalex-snapshot
Molecular Dynamics of the Davies Ambimodal C–H Functionalization/Cope Rearrangement Reaction
inferred← citeshttps://doi.org/10.1021/acs.joc.5b00891openalex-snapshot
Synthesis of 2-Alkoxyaryl-2-aryl Enamines via Tandem Copper-Catalyzed Cycloaddition and Rhodium-Catalyzed Alkoxyarylation from Alkynes, N-Sulfonyl Azides, and Aryl Ethers
inferred← citeshttps://doi.org/10.1021/acs.joc.5c01946openalex-snapshot
Regioselective Ortho -Azidation of Anilines via Quinone Imine Ketals: A One-Pot Approach to Proton Pump Inhibitors
inferred← citeshttps://doi.org/10.1021/acs.joc.6b02176openalex-snapshot
Copper(II)-Catalyzed Benzylic C(sp3)–H Aerobic Oxidation of (Hetero)Aryl Acetimidates: Synthesis of Aryl-α-ketoesters
inferred← citeshttps://doi.org/10.1021/acs.joc.7b01423openalex-snapshot
Route to Substituted Furan-2(5H)-ones from cyclo-Alkenecarboxylic Acids and Acrylates via C–H Activation
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02064openalex-snapshot
Copper-Catalyzed Intramolecular Annulation of Conjugated Enynones to Substituted 1H-Indenes and Mechanistic Studies
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02127openalex-snapshot
Annulation of a Highly Functionalized Diazo Building Block with Indoles under Sc(OTf)3/Rh2(OAc)4 Multicatalysis through Michael Addition/Cyclization Sequence
inferred← citeshttps://doi.org/10.1021/acs.joc.9b02428openalex-snapshot
Finding Opportunities from Surprises and Failures. Development of Rhodium-Stabilized Donor/Acceptor Carbenes and Their Application to Catalyst-Controlled C–H Functionalization
inferred← citeshttps://doi.org/10.1021/acs.joc.9b02760openalex-snapshot
Copper-Catalyzed Cascade Cyclization Reactions of Diazo Compounds with tert-Butyl Nitrite and Alkynes: One-Pot Synthesis of Isoxazoles
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00688openalex-snapshot
(PNP)Cobalt-Catalyzed Olefination of Diazoalkanes
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00378openalex-snapshot
DFT Study on the Rhodium(II)-Catalyzed C–H Functionalization of Indoles: Enol versus Oxocarbenium Ylide
inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00730openalex-snapshot
Acquiring a Prognostic Power in Co2(CO)6-Mediated, Cobaltocene-Induced Radical Dimerizations of Propargyl Triflates
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c01113openalex-snapshot
Enantioselective Catalytic Cyclopropanation–Rearrangement Approach to Chiral Spiroketals
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c02352openalex-snapshot
Intermolecular [5 + 1]-Cycloaddition between Vinyl Diazo Compounds and tert-Butyl Nitrite to 1,2,3-Triazine 1-Oxides and Their Further Transformation to Isoxazoles
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c00477openalex-snapshot
Highly Stereoselective Synthesis of Tetrasubstituted Vinyl Selenides via Rhodium-Catalyzed [1,4]-Acyl Migration of Selenoesters and Diazo Compounds
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c04356openalex-snapshot
Rhodium-Catalyzed Allylic C–H Functionalization of Unactivated Alkenes with α-Diazocarbonyl Compounds
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c00185openalex-snapshot
Visible-Light-Induced Siloxycarbene Addition to N═N of Azodicarboxylates: Synthesis of Acyl Hydrazides from Acylsilanes
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c03656openalex-snapshot
Oxy-pyridinium Ylides Mediated 1,4-Pyridyl/Aryl Translocation
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b02037openalex-snapshot
Copper-Catalyzed Diazo Cross-/Homo-Coupling toward Tetrasubstituted Olefins and Applications on the Synthesis of Maleimide Derivatives
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b02912openalex-snapshot
Cyclopentadiene Construction via Rh-Catalyzed Carbene/Alkyne Metathesis Terminated with Intramolecular Formal [3 + 2] Cycloaddition
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b03231openalex-snapshot
Rh(III)-Catalyzed [4 + 2] Annulation of Indoles with Diazo Compounds: Access to Pyrimido[1,6-a]indole-1(2H)-ones
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c03321openalex-snapshot
Conformationally Restricted Amino Cyclopropane-Fused Lactones from Mannich Bases
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b01298openalex-snapshot
Enantioselective Intermolecular C–H Functionalization of Allylic and Benzylic sp3 C–H Bonds Using N-Sulfonyl-1,2,3-triazoles
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b02532openalex-snapshot
Bu4NI-Catalyzed Cross-Coupling between Sulfonyl Hydrazides and Diazo Compounds To Construct β-Carbonyl Sulfones Using Molecular Oxygen
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b03681openalex-snapshot
Metal-Free C–H Functionalization of Alkanes by Aryldiazoacetates
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b01073openalex-snapshot
Synthesis of Donor/Acceptor-Substituted Diazo Compounds in Flow and Their Application in Enantioselective Dirhodium-Catalyzed Cyclopropanation and C–H Functionalization
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b00739openalex-snapshot
Formation of Tertiary Alcohols from the Rhodium-Catalyzed Reactions of Donor/Acceptor Carbenes with Esters
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01353openalex-snapshot
Rhodium-Catalyzed Asymmetric Dearomative [4 + 3]-Cycloaddition of Vinylindoles with Vinyldiazoacetates: Access to Cyclohepta[ b ]indoles
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01362openalex-snapshot
Rhodium-Catalyzed Intermolecular C–H Functionalization as a Key Step in the Synthesis of Complex Stereodefined β-Arylpyrrolidines
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01541openalex-snapshot
Rhodium(I)-Catalyzed Coupling–Cyclization of C═O Bonds with α-Diazoketones
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01812openalex-snapshot
Cu(I)-Catalyzed Coupling and Cycloisomerization of Diazo Compounds with Terminal Yne-Alkylidenecyclopropanes: Synthesis of Functionalized Cyclopenta[b]naphthalene Derivatives
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b01988openalex-snapshot
Boron-Catalyzed O–H Bond Insertion of α-Aryl α-Diazoesters in Water
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b02446openalex-snapshot
Mild Dirhodium(II)-Catalyzed Chemo- and Regioselective Azidation of Arenes
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b02613openalex-snapshot
Zn(OAc)2-Catalyzed C3-Carbonylacetylation of Indoles with α-Diazoketones Involving Wolff Rearrangement
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b00307openalex-snapshot
Rhodium-Catalyzed Coupling–Cyclization of Alkenyldiazoacetates with o-Alkenyl Arylisocyanides: A General Route to Carbazoles
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b00382openalex-snapshot
Catalyst-Free gem-Difunctionalization of Fluoroalkyl-Substituted Diazo Compound with Diselenide or Disulfide and NFSI
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b01196openalex-snapshot
Co(II)-Catalyzed Regioselective Pyridine C–H Coupling with Diazoacetates
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b03005openalex-snapshot
Carbocation Lewis Acid TrBF4-Catalyzed 1,2-Hydride Migration: Approaches to (Z)-α,β-Unsaturated Esters and α-Branched β-Ketocarbonyls
inferred← citeshttps://doi.org/10.1021/acscatal.1c01051openalex-snapshot
Catalyst-Directed Divergent Catalytic Approaches to Expand Structural and Functional Scaffold Diversity via Metallo-Enolcarbene Intermediates
inferred← citeshttps://doi.org/10.1021/acscatal.1c02674openalex-snapshot
Diverse Reactions of Vinyl Diazo Compounds with Quinone Oxonium Ions, Quinone Imine Ketals, and Eschenmoser’s Salt
inferred← citeshttps://doi.org/10.1021/acscatal.1c04766openalex-snapshot
N-Heterocyclic Carbene–Nickel-Catalyzed Regioselective Diarylation of Aliphatic-1,3-Dienes
inferred← citeshttps://doi.org/10.1021/acscatal.2c04115openalex-snapshot
In Situ Kinetic Studies of Rh(II)-Catalyzed C–H Functionalization to Achieve High Catalyst Turnover Numbers
inferred← citeshttps://doi.org/10.1021/acscatal.2c04832openalex-snapshot
Rh(II)-Catalyzed Enynal Cycloisomerization for the Generation of Vinyl Carbene: Divergent Access to Polycyclic Heterocycles
inferred← citeshttps://doi.org/10.1021/acscatal.4c01291openalex-snapshot
Construction of Diazo Compounds via Catalytic [3 + 2] Annulation of Vinyldiazoacetates and Their Synthetic Applications
inferred← citeshttps://doi.org/10.1021/acscatal.6b00048openalex-snapshot
Divergent Synthesis of Carbo- and Heterocycles via Gold-Catalyzed Reactions
inferred← citeshttps://doi.org/10.1021/acscatal.6c00560openalex-snapshot
Enantioselective Synthesis of Axially Chiral Spiro[3.3]heptanes by Site-Selective C–H Functionalization
inferred← citeshttps://doi.org/10.1021/acscatal.7b00978openalex-snapshot
Catalytic Dinuclear Nickel Spin Crossover Mechanism and Selectivity for Alkyne Cyclotrimerization
inferred← citeshttps://doi.org/10.1021/acscatal.8b02822openalex-snapshot
Selective C(sp3)–H Bond Insertion in Carbene/Alkyne Metathesis Reactions. Enantioselective Construction of Dihydroindoles
inferred← citeshttps://doi.org/10.1021/acscatal.8b04144openalex-snapshot
Selective Vinylogous Reactivity of Carbene Intermediate in Gold-Catalyzed Alkyne Carbocyclization: Synthesis of Indenols
inferred← citeshttps://doi.org/10.1021/acscatal.9b04595openalex-snapshot
In Situ Kinetic Studies of Rh(II)-Catalyzed Asymmetric Cyclopropanation with Low Catalyst Loadings
inferred← citeshttps://doi.org/10.1021/acscentsci.6c00925openalex-snapshot
Fischer Indole Synthesis Inspired De Novo and Modular Assembly of Indolines
inferred← citeshttps://doi.org/10.1021/ja3092399openalex-snapshot
Rhodium-Catalyzed Enantioselective Vinylogous Addition of Enol Ethers to Vinyldiazoacetates
inferred← citeshttps://doi.org/10.1021/ja401731dopenalex-snapshot
Sequential C–H Functionalization Reactions for the Enantioselective Synthesis of Highly Functionalized 2,3-Dihydrobenzofurans
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