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Non-Heme Fe(IV)–Oxo Intermediates

https://doi.org/10.1021/ar700066p
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Aqueous Fe IV O: Spectroscopic Identification and Oxo‐Group Exchange
inferredcites →https://doi.org/10.1002/ejic.200500476openalex-snapshot
Mechanism of Taurine: α‐Ketoglutarate Dioxygenase (TauD) from Escherichia coli
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Studies on the active site of deacetoxycephalosporin C synthase
inferredcites →https://doi.org/10.1007/s00775-005-0624-xopenalex-snapshot
The 2-His-1-carboxylate facial triad: a versatile platform for dioxygen activation by mononuclear non-heme iron(II) enzymes
inferredcites →https://doi.org/10.1016/0022-5193(82)90320-4openalex-snapshot
A stereochemical concept for the catalytic mechanism of prolylhydroxylase
inferredcites →https://doi.org/10.1016/0968-0896(96)00088-0openalex-snapshot
A single monomeric iron center in clavaminate synthase catalyzes three nonsuccessive oxidative transformations
inferredcites →https://doi.org/10.1016/j.bbrc.2005.08.193openalex-snapshot
Regulation of hypoxia-inducible factor 1 by prolyl and asparaginyl hydroxylases
inferredcites →https://doi.org/10.1016/j.chembiol.2006.09.012openalex-snapshot
Enzymatic Generation of the Antimetabolite γ,γ-Dichloroaminobutyrate by NRPS and Mononuclear Iron Halogenase Action in a Streptomycete
inferredcites →https://doi.org/10.1016/j.jinorgbio.2006.01.022openalex-snapshot
Stalking intermediates in oxygen activation by iron enzymes: Motivation and method
inferredcites →https://doi.org/10.1016/s0040-4020(01)80725-0openalex-snapshot
Cephalosporin biosynthesis: A branched pathway sensitive to an isotope effect
inferredcites →https://doi.org/10.1016/s0040-4020(01)81453-8openalex-snapshot
The ring expansion of penama to cephams: a possible biomimetic process
inferredcites →https://doi.org/10.1016/s0040-4020(99)00547-5openalex-snapshot
Product-substrate engineering by bacteria: Studies on clavaminate synthase, a trifunctional dioxygenase
inferredcites →https://doi.org/10.1016/s0092-8674(01)00507-4openalex-snapshot
C. elegans EGL-9 and Mammalian Homologs Define a Family of Dioxygenases that Regulate HIF by Prolyl Hydroxylation
inferredcites →https://doi.org/10.1016/s0945-053x(98)90009-9openalex-snapshot
Prolyl 4-hydroxylases and their protein disulfide isomerase subunit
inferredcites →https://doi.org/10.1016/s1074-5521(01)00090-4openalex-snapshot
Alternative oxidation by isopenicillin N synthase observed by X-ray diffraction
inferredcites →https://doi.org/10.1016/s1367-5931(02)00392-7openalex-snapshot
New reactions in clavulanic acid biosynthesis
inferredcites →https://doi.org/10.1021/bi00213a036openalex-snapshot
A non-heme iron protein with heme tendencies: An investigation of the substrate specificity of thymine hydroxylase
inferredcites →https://doi.org/10.1021/bi00213a037openalex-snapshot
Mechanism-based inactivation of thymine hydroxylase, an .alpha.-ketoglutarate-dependent dioxygenase, by 5-ethynyluracil
inferredcites →https://doi.org/10.1021/bi00222a034openalex-snapshot
Elucidation of the order of oxidations and identification of an intermediate in the multistep clavaminate synthase reaction
inferredcites →https://doi.org/10.1021/bi00479a023openalex-snapshot
Purification and characterization of clavaminate synthase from Streptomyces clavuligerus: an unusual oxidative enzyme in natural product biosynthesis
inferredcites →https://doi.org/10.1021/bi026499mopenalex-snapshot
(4-Hydroxyphenyl)pyruvate Dioxygenase from Streptomyces avermitilis: The Basis for Ordered Substrate Addition
inferredcites →https://doi.org/10.1021/bi030011fopenalex-snapshot
The First Direct Characterization of a High-Valent Iron Intermediate in the Reaction of an α-Ketoglutarate-Dependent Dioxygenase: A High-Spin Fe(IV) Complex in Taurine/α-Ketoglutarate Dioxygenase (TauD) from Escherichia coli
inferredcites →https://doi.org/10.1021/bi035656uopenalex-snapshot
Mechanism of Aromatic Amino Acid Hydroxylation
inferredcites →https://doi.org/10.1021/bi050227copenalex-snapshot
Kinetic Dissection of the Catalytic Mechanism of Taurine:α-Ketoglutarate Dioxygenase (TauD) from Escherichia coli
inferredcites →https://doi.org/10.1021/cr00105a001openalex-snapshot
Isopenicillin N synthase: mechanistic studies
inferredcites →https://doi.org/10.1021/cr020628nopenalex-snapshot
Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates
inferredcites →https://doi.org/10.1021/cr050313iopenalex-snapshot
Nature's Inventory of Halogenation Catalysts: Oxidative Strategies Predominate
inferredcites →https://doi.org/10.1021/cr9900275openalex-snapshot
Geometric and Electronic Structure/Function Correlations in Non-Heme Iron Enzymes
inferredcites →https://doi.org/10.1021/ed062p928openalex-snapshot
Key elements of the chemistry of cytochrome P-450: The oxygen rebound mechanism
inferredcites →https://doi.org/10.1021/ic048523lopenalex-snapshot
Rapid Freeze-Quench 57Fe Mössbauer Spectroscopy: Monitoring Changes of an Iron-Containing Active Site during a Biochemical Reaction
inferredcites →https://doi.org/10.1021/ja00077a035openalex-snapshot
Alkane functionalization at nonheme iron centers. Stoichiometric transfer of metal-bound ligands to alkane
inferredcites →https://doi.org/10.1021/ja00123a003openalex-snapshot
Characterization of a Novel, Stable Norcaradiene Adduct Resulting from the Inactivation of Thymine Hydroxylase by 5-Ethynyluracil
inferredcites →https://doi.org/10.1021/ja00302a026openalex-snapshot
Stereochemical fate of chiral methyl of valine in the ring expansion of penicillin N to deacetoxycephalosporin C
inferredcites →https://doi.org/10.1021/ja004025+openalex-snapshot
Spectroscopic Studies of Substrate Interactions with Clavaminate Synthase 2, a Multifunctional α-KG-Dependent Non-Heme Iron Enzyme: Correlation with Mechanisms and Reactivities
inferredcites →https://doi.org/10.1021/ja034248aopenalex-snapshot
Carbapenem Biosynthesis: Confirmation of Stereochemical Assignments and the Role of CarC in the Ring Stereoinversion Process from l -Proline
inferredcites →https://doi.org/10.1021/ja037288nopenalex-snapshot
Nonheme FeIVO Complexes That Can Oxidize the C−H Bonds of Cyclohexane at Room Temperature
inferredcites →https://doi.org/10.1021/ja037400hopenalex-snapshot
Evidence for Hydrogen Abstraction from C1 of Taurine by the High-Spin Fe(IV) Intermediate Detected during Oxygen Activation by Taurine:α-Ketoglutarate Dioxygenase (TauD)
inferredcites →https://doi.org/10.1021/ja037665wopenalex-snapshot
Synthesis of (3S,5R)-Carbapenam-3-carboxylic Acid and Its Role in Carbapenem Biosynthesis and the Stereoinversion Problem
inferredcites →https://doi.org/10.1021/ja039113jopenalex-snapshot
Direct Detection of Oxygen Intermediates in the Non-Heme Fe Enzyme Taurine/α-Ketoglutarate Dioxygenase
inferredcites →https://doi.org/10.1021/ja047899vopenalex-snapshot
The Unusual Bifunctional Catalysis of Epimerization and Desaturation by Carbapenem Synthase
inferredcites →https://doi.org/10.1021/ja048255qopenalex-snapshot
EXAFS Spectroscopic Evidence for an Fe═O Unit in the Fe(IV) Intermediate Observed during Oxygen Activation by Taurine:α-Ketoglutarate Dioxygenase
inferredcites →https://doi.org/10.1021/ja060151nopenalex-snapshot
Halogenation of Unactivated Carbon Centers in Natural Product Biosynthesis: Trichlorination of Leucine during Barbamide Biosynthesis
inferredcites →https://doi.org/10.1021/ja067899qopenalex-snapshot
Spectroscopic and Computational Evaluation of the Structure of the High-Spin Fe(IV)-Oxo Intermediates in Taurine: α-Ketoglutarate Dioxygenase from Escherichia coli and Its His99Ala Ligand Variant
inferredcites →https://doi.org/10.1038/318191a0openalex-snapshot
Isolation, sequence determination and expression in Escherichia coli of the isopenicillin N synthetase gene from Cephalosporium acremonium
inferredcites →https://doi.org/10.1038/42990openalex-snapshot
Structure of isopenicillinN synthase complexed with substrate and the mechanism ofpenicillin formation
inferredcites →https://doi.org/10.1038/44400openalex-snapshot
The reaction cycle of isopenicillin N synthase observed by X-ray diffraction
inferredcites →https://doi.org/10.1038/nature01048openalex-snapshot
AlkB-mediated oxidative demethylation reverses DNA damage in Escherichia coli
inferredcites →https://doi.org/10.1038/nature03797openalex-snapshot
Cryptic chlorination by a non-haem iron enzyme during cyclopropyl amino acid biosynthesis
inferredcites →https://doi.org/10.1038/nature04433openalex-snapshot
Histone demethylation by a family of JmjC domain-containing proteins
inferredcites →https://doi.org/10.1038/nature04544openalex-snapshot
Crystal structure of the non-haem iron halogenase SyrB2 in syringomycin biosynthesis
inferredcites →https://doi.org/10.1038/nature04837openalex-snapshot
The putative oncogene GASC1 demethylates tri- and dimethylated lysine 9 on histone H3
inferredcites →https://doi.org/10.1038/nature04853openalex-snapshot
The transcriptional repressor JHDM3A demethylates trimethyl histone H3 lysine 9 and lysine 36
inferredcites →https://doi.org/10.1038/nchembio856openalex-snapshot
Two interconverting Fe(IV) intermediates in aliphatic chlorination by the halogenase CytC3
inferredcites →https://doi.org/10.1038/nsmb712openalex-snapshot
The structural basis of cephalosporin formation in a mononuclear ferrous enzyme
inferredcites →https://doi.org/10.1039/b212270gopenalex-snapshot
Crystallographic studies on the reaction of isopenicillin N synthase with an unsaturated substrate analogue
inferredcites →https://doi.org/10.1039/b505964jopenalex-snapshot
The enzymology of clavam and carbapenem biosynthesis
inferredcites →https://doi.org/10.1039/c39860001305openalex-snapshot
Penicillin biosynthesis: the origin of hydroxy groups in β-lactams derived from unsaturated substrates
inferredcites →https://doi.org/10.1039/c39870001661openalex-snapshot
Use of the cyclopropylcarbinyl test to detect a radical-like intermediate in penicillin biosynthesis
inferredcites →https://doi.org/10.1039/c39870001736openalex-snapshot
Isolation of two novel intracellular β-lactams and a novel dioxygenase cyclising enzyme from Streptomyces clavuligerus
inferredcites →https://doi.org/10.1039/c39890000978openalex-snapshot
Evidence for epoxide formation from isopenicillin N synthase
inferredcites →https://doi.org/10.1039/c39930000500openalex-snapshot
A substrate analogue study on clavaminic acid synthase: possible clues to the biosynthetic origin of proclavamic acid
inferredcites →https://doi.org/10.1039/np9880500129openalex-snapshot
The biosynthesis of penicillins and cephalosporins
inferredcites →https://doi.org/10.1042/bj2220777openalex-snapshot
Stereochemistry of the incorporation of valine methyl groups into methylene groups in cephalosporin C.
inferredcites →https://doi.org/10.1073/pnas.0504412102openalex-snapshot
SyrB2 in syringomycin E biosynthesis is a nonheme Fe II α-ketoglutarate- and O 2 -dependent halogenase
inferredcites →https://doi.org/10.1073/pnas.0604005103openalex-snapshot
Direct spectroscopic detection of a C-H-cleaving high-spin Fe(IV) complex in a prolyl-4-hydroxylase
inferredcites →https://doi.org/10.1073/pnas.0605067103openalex-snapshot
Spectroscopic and electronic structure studies of aromatic electrophilic attack and hydrogen-atom abstraction by non-heme iron enzymes
inferredcites →https://doi.org/10.1073/pnas.0636830100openalex-snapshot
An Fe IV O complex of a tetradentate tripodal nonheme ligand
inferredcites →https://doi.org/10.1073/pnas.262589799openalex-snapshot
Reversal of DNA alkylation damage by two human dioxygenases
inferredcites →https://doi.org/10.1073/pnas.96.14.7905openalex-snapshot
Role of the nonheme Fe(II) center in the biosynthesis of the plant hormone ethylene
inferredcites →https://doi.org/10.1074/jbc.274.32.22131openalex-snapshot
Evidence for 4-Hydroxyproline in Viral Proteins
inferredcites →https://doi.org/10.1080/10409230490440541openalex-snapshot
Fe(II)/α-Ketoglutarate-Dependent Hydroxylases and Related Enzymes
inferredcites →https://doi.org/10.1126/science.1059796openalex-snapshot
Targeting of HIF-α to the von Hippel-Lindau Ubiquitylation Complex by O 2 -Regulated Prolyl Hydroxylation
inferredcites →https://doi.org/10.1126/science.1059817openalex-snapshot
HIFα Targeted for VHL-Mediated Destruction by Proline Hydroxylation: Implications for O 2 Sensing
inferredcites →https://doi.org/10.1126/science.1066373openalex-snapshot
A Conserved Family of Prolyl-4-Hydroxylases That Modify HIF
inferredcites →https://doi.org/10.1126/science.1133417openalex-snapshot
Chemical and Spectroscopic Evidence for an Fe V -Oxo Complex
inferredcites →https://doi.org/10.1126/science.299.5609.1037openalex-snapshot
Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)=O Complex

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Heme-Feii and Heme-Feiii – Role of Histidine Residue
inferred← citeshttps://doi.org/10.2139/ssrn.4807567openalex-extracted
Heme-Feii and Heme-Feiii – Role of Histidine Residue
inferred← citeshttps://doi.org/10.1002/0470028637.met228openalex-snapshot
Nonheme Iron Halogenases
inferred← citeshttps://doi.org/10.1002/9780470602577.ch2openalex-snapshot
Proton‐Coupled Electron Transfer in Hydrogen and Hydride Transfer Reactions
inferred← citeshttps://doi.org/10.1002/9781118482469.ch1openalex-snapshot
Reactive Species
inferred← citeshttps://doi.org/10.1002/9781118482469.ch2openalex-snapshot
Acid–Base Properties
inferred← citeshttps://doi.org/10.1002/9781118482469.ch6openalex-snapshot
High‐Valent Cr, Mn, and Fe Species
inferred← citeshttps://doi.org/10.1002/9781118571811.ch5openalex-snapshot
Rational Design of Protein Cages for Alternative Enzymatic Functions
inferred← citeshttps://doi.org/10.1002/9781118596784.ssd045openalex-snapshot
Enzymatic Halogenation in Stereoselective Synthesis
inferred← citeshttps://doi.org/10.1002/9781118898277.ch10openalex-snapshot
Terminal Metal–Oxo Species with Unusual Spin States
inferred← citeshttps://doi.org/10.1002/9781118898277.ch15openalex-snapshot
High‐Spin and Low‐Spin States in {FeNO}7, FeIV=O, and FeIII–OOH Complexes and Their Correlations to Reactivity
inferred← citeshttps://doi.org/10.1002/9781118898277.ch7openalex-snapshot
Principles and Prospects of Spin‐States Reactivity in Chemistry and Bioinorganic Chemistry
inferred← citeshttps://doi.org/10.1002/9781118898277.ch9openalex-snapshot
Catalytic Function and Mechanism of Heme and Nonheme Iron(IV)–Oxo Complexes in Nature
inferred← citeshttps://doi.org/10.1002/9781119379256.ch11openalex-snapshot
Regioselectivity of Non‐heme Iron Catalysts for CH Activation
inferred← citeshttps://doi.org/10.1002/9781119379256.ch13openalex-snapshot
Alkane Oxidation with Biologically Inspired Nonheme Iron Catalysts Based in the Triazacyclononane Ligand Scaffold
inferred← citeshttps://doi.org/10.1002/9781119379256.ch14openalex-snapshot
The Nature of High‐Valent Oxometal Intermediates of Iron‐Aminopyridine Mediated Oxidations
inferred← citeshttps://doi.org/10.1002/9781119951438.eibc0655openalex-snapshot
Nonheme Iron Halogenases
inferred← citeshttps://doi.org/10.1002/9781119951438.eibc2344openalex-snapshot
Biomimetic High‐Valent Mononuclear Nonheme Iron‐Oxo Chemistry
inferred← citeshttps://doi.org/10.1002/9783527625468.ch3openalex-snapshot
Iron Complexes and Dioxygen Activation
inferred← citeshttps://doi.org/10.1002/9783527639861.ch31openalex-snapshot
Oxyfunctionalization of CC Multiple Bonds
inferred← citeshttps://doi.org/10.1002/9783527673278.ch6openalex-snapshot
Oxidation Catalysis with High‐Valent Nonheme Iron Complexes
inferred← citeshttps://doi.org/10.1002/9783527824137.ch13openalex-snapshot
Remote Oxidation of Aliphatic CH Bonds with Biologically Inspired Catalysts
inferred← citeshttps://doi.org/10.1002/9783527834242.chf0047openalex-snapshot
Iron‐Catalyzed CH Halogenation
inferred← citeshttps://doi.org/10.1002/9783527834242.chf0223openalex-snapshot
High‐Valent Oxomanganese Complexes of Relevance in Oxyfunctionalization of Hydrocarbons
inferred← citeshttps://doi.org/10.1002/9783527834242.chf0226openalex-snapshot
Contemporary Concepts to Decipher the Reactivity of Paramagnetic Transition Metal Catalysts
inferred← citeshttps://doi.org/10.1002/9783527834242.chf0230openalex-snapshot
Iron Catalyzed CH Amination
inferred← citeshttps://doi.org/10.1002/9783527834242.chf0239openalex-snapshot
Iron‐Catalyzed CH Bond Hydroxylation
inferred← citeshttps://doi.org/10.1002/adma.201104467openalex-snapshot
Double Action: Toward Phosphorescence Ratiometric Sensing of Chromium Ion
inferred← citeshttps://doi.org/10.1002/adsc.201100267openalex-snapshot
Chiral Bioinspired Non‐Heme Iron Complexes for Enantioselective Epoxidation of α,β‐Unsaturated Ketones
inferred← citeshttps://doi.org/10.1002/advs.202202679openalex-snapshot
New Deferric Amine Compounds Efficiently Chelate Excess Iron to Treat Iron Overload Disorders and to Prevent Ferroptosis
inferred← citeshttps://doi.org/10.1002/advs.202310333openalex-snapshot
Enhanced Reactivities of Iron(IV)‐Oxo Porphyrin Species in Oxidation Reactions Promoted by Intramolecular Hydrogen‐Bonding
inferred← citeshttps://doi.org/10.1002/advs.76328openalex-snapshot
Computation‐Guided Tunnel Engineering Enhances O 2 Transport and H 2 O 2 Resistance of Fe(II)/α‐Ketoglutarate‐Dependent Dioxygenases
inferred← citeshttps://doi.org/10.1002/advs.77944openalex-snapshot
cis ‐Carboxylate Enhancement of Mn(III)‐OH Hydrogen Atom Abstraction through PCET Thermodynamics
inferred← citeshttps://doi.org/10.1002/ajoc.202200060openalex-snapshot
Recent Advances in First‐Row Transition‐Metal‐Mediated C−H Halogenation of (Hetero)arenes and Alkanes
inferred← citeshttps://doi.org/10.1002/ange.1885847openalex-snapshot
Second‐Sphere Aromatic Substitutions That Tune H‐Atom Transfer Reactivity Observed for a Series of S = 1 Nonheme Fe IV =O Complexes: An Enthalpy‐Entropy Compensation Effect
inferred← citeshttps://doi.org/10.1002/ange.200705880openalex-snapshot
Experiment and Theory Reveal the Fundamental Difference between Two‐State and Single‐State Reactivity Patterns in Nonheme FeIVO versus RuIVO Oxidants
inferred← citeshttps://doi.org/10.1002/ange.200801832openalex-snapshot
Proton‐ and Reductant‐Assisted Dioxygen Activation by a Nonheme Iron(II) Complex to Form an Oxoiron(IV) Intermediate
inferred← citeshttps://doi.org/10.1002/ange.200802219openalex-snapshot
An Inverted and More Oxidizing Isomer of [FeIV(O)(tmc)(NCCH3)]2+
inferred← citeshttps://doi.org/10.1002/ange.200802346openalex-snapshot
Hydrogen Atom Abstraction and Hydride Transfer Reactions by Iron(IV)–Oxo Porphyrins
inferred← citeshttps://doi.org/10.1002/ange.200802672openalex-snapshot
Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts
inferred← citeshttps://doi.org/10.1002/ange.200804029openalex-snapshot
A Two‐State Reactivity Model Explains Unusual Kinetic Isotope Effect Patterns in CH Bond Cleavage by Nonheme Oxoiron(IV) Complexes
inferred← citeshttps://doi.org/10.1002/ange.200805342openalex-snapshot
Shape‐Selective Interception by Hydrocarbons of the O2‐Derived Oxidant of a Biomimetic Nonheme Iron Complex
inferred← citeshttps://doi.org/10.1002/ange.200805670openalex-snapshot
Water as an Oxygen Source in the Generation of Mononuclear Nonheme Iron(IV) Oxo Complexes
inferred← citeshttps://doi.org/10.1002/ange.200805977openalex-snapshot
Was ist wirklich nötig, um Komplexe später Übergangsmetalle mit terminalen Oxo‐Liganden zu stabilisieren?
inferred← citeshttps://doi.org/10.1002/ange.200900552openalex-snapshot
Biomimetische Trispyrazolylborat‐Eisen‐Komplexe
inferred← citeshttps://doi.org/10.1002/ange.200900863openalex-snapshot
A Synthetic High‐Spin Oxoiron(IV) Complex: Generation, Spectroscopic Characterization, and Reactivity
inferred← citeshttps://doi.org/10.1002/ange.201000004openalex-snapshot
The Fundamental Role of Exchange‐Enhanced Reactivity in CH Activation by S=2 Oxo Iron(IV) Complexes
inferred← citeshttps://doi.org/10.1002/ange.201001850openalex-snapshot
Analysis of Reaction Channels for Alkane Hydroxylation by Nonheme Iron(IV)–Oxo Complexes
inferred← citeshttps://doi.org/10.1002/ange.201007692openalex-snapshot
Nuclear Resonance Vibrational Spectroscopy on the FeIVO S=2 Non‐Heme Site in TMG3tren: Experimentally Calibrated Insights into Reactivity
inferred← citeshttps://doi.org/10.1002/ange.201102146openalex-snapshot
CH Bond Activation of Methanol and Ethanol by a High‐Spin FeIVO Biomimetic Complex
inferred← citeshttps://doi.org/10.1002/ange.201108398openalex-snapshot
Wasserstoffatomabstraktion von A bis Y: Reaktionsmuster nach der Valenzstrukturtheorie
inferred← citeshttps://doi.org/10.1002/ange.201200901openalex-snapshot
The Reaction of a High‐Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide
inferred← citeshttps://doi.org/10.1002/ange.201202487openalex-snapshot
An Iron(III) Iodosylbenzene Complex: A Masked Non‐Heme FeVO
inferred← citeshttps://doi.org/10.1002/ange.201208044openalex-snapshot
A Tetracarbene–Oxoiron(IV) Complex
inferred← citeshttps://doi.org/10.1002/ange.201210020openalex-snapshot
Photoassisted Generation of a Dinuclear Iron(III) Peroxo Species and Oxygen‐Atom Transfer
inferred← citeshttps://doi.org/10.1002/ange.201305994openalex-snapshot
Enhanced Reactivity of a Biomimetic Iron(II) α‐Keto Acid Complex through Immobilization on Functionalized Gold Nanoparticles
inferred← citeshttps://doi.org/10.1002/ange.201402537openalex-snapshot
Highly Reactive Nonheme Iron(III) Iodosylarene Complexes in Alkane Hydroxylation and Sulfoxidation Reactions
inferred← citeshttps://doi.org/10.1002/ange.201405874openalex-snapshot
Spectroscopic Capture and Reactivity of a Low‐Spin Cobalt(IV)‐Oxo Complex Stabilized by Binding Redox‐Inactive Metal Ions
inferred← citeshttps://doi.org/10.1002/ange.201407156openalex-snapshot
A cis‐Divacant Octahedral and Mononuclear Iron(IV) Imide
inferred← citeshttps://doi.org/10.1002/ange.201501437openalex-snapshot
CH Activation of Benzene by a Photoactivated NiII(azide): Formation of a Transient Nickel Nitrido Complex
inferred← citeshttps://doi.org/10.1002/ange.201502229openalex-snapshot
Olefin cis‐Dihydroxylation and Aliphatic CH Bond Oxygenation by a Dioxygen‐Derived Electrophilic Iron–Oxygen Oxidant
inferred← citeshttps://doi.org/10.1002/ange.201505796openalex-snapshot
Mononuclear Nonheme Iron(III)‐Iodosylarene and High‐Valent Iron‐Oxo Complexes in Olefin Epoxidation Reactions
inferred← citeshttps://doi.org/10.1002/ange.201507463openalex-snapshot
Nitrene Insertion into CC and CH Bonds of Diamide Diimine Ligands Ligated to Chromium and Iron
inferred← citeshttps://doi.org/10.1002/ange.201507835openalex-snapshot
Struktur der Dioxygenase AsqJ: mechanistische Einblicke in die Eintopf‐Mehrstufen‐Biosynthese eines Chinolonantibiotikums
inferred← citeshttps://doi.org/10.1002/ange.201507933openalex-snapshot
A Highly Reactive Seven‐Coordinate Osmium(V) Oxo Complex: [OsV(O)(qpy)(pic)Cl]2+
inferred← citeshttps://doi.org/10.1002/ange.201509914openalex-snapshot
Hydroxylation versus Halogenation of Aliphatic C−H Bonds by a Dioxygen‐Derived Iron–Oxygen Oxidant: Functional Mimicking of Iron Halogenases
inferred← citeshttps://doi.org/10.1002/ange.201600507openalex-snapshot
Oxidationsreaktionen mit bioinspirierten einkernigen Nicht‐Häm‐Oxidometallkomplexen
inferred← citeshttps://doi.org/10.1002/ange.201603978openalex-snapshot
Mononuclear Nonheme High‐Spin (S=2) versus Intermediate‐Spin (S=1) Iron(IV)–Oxo Complexes in Oxidation Reactions
inferred← citeshttps://doi.org/10.1002/ange.201612299openalex-snapshot
Two Exceptional Homoleptic Iron(IV) Tetraalkyl Complexes
inferred← citeshttps://doi.org/10.1002/ange.201701319openalex-snapshot
Accelerated Oxygen Atom Transfer and C−H Bond Oxygenation by Remote Redox Changes in Fe3Mn‐Iodosobenzene Adducts
inferred← citeshttps://doi.org/10.1002/ange.201702009openalex-snapshot
The Dynamics of the Reaction of FeO+ and H2: A Model for Inorganic Oxidation
inferred← citeshttps://doi.org/10.1002/ange.201707872openalex-snapshot
A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N3O Macrocyclic Ligand
inferred← citeshttps://doi.org/10.1002/ange.201802779openalex-snapshot
A Bis(μ‐oxido)dinickel(III) Complex with a Triplet Ground State
inferred← citeshttps://doi.org/10.1002/ange.201805511openalex-snapshot
cPCET versus HAT: A Direct Theoretical Method for Distinguishing X–H Bond‐Activation Mechanisms
inferred← citeshttps://doi.org/10.1002/ange.201807844openalex-snapshot
Enzymkaskadenreaktionen in der Biosynthese
inferred← citeshttps://doi.org/10.1002/ange.201810227openalex-snapshot
Probing Hydrogen Bonding Interactions to Iron‐Oxido/Hydroxido Units by 57Fe Nuclear Resonance Vibrational Spectroscopy
inferred← citeshttps://doi.org/10.1002/ange.201812758openalex-snapshot
Trapping of a Highly Reactive Oxoiron(IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide
inferred← citeshttps://doi.org/10.1002/ange.201901608openalex-snapshot
Direct Observation of Primary C−H Bond Oxidation by an Oxido‐Iron(IV) Porphyrin π‐Radical Cation Complex in a Fluorinated Carbon Solvent
inferred← citeshttps://doi.org/10.1002/ange.201903465openalex-snapshot
Activation of a Non‐Heme FeIII‐OOH by a Second FeIII to Hydroxylate Strong C−H Bonds: Possible Implications for Soluble Methane Monooxygenase
inferred← citeshttps://doi.org/10.1002/ange.201905325openalex-snapshot
A Terminal Iridium Oxo Complex with a Triplet Ground State
inferred← citeshttps://doi.org/10.1002/ange.201905416openalex-snapshot
Hydrogen by Deuterium Substitution in an Aldehyde Tunes the Regioselectivity by a Nonheme Manganese(III)–Peroxo Complex
inferred← citeshttps://doi.org/10.1002/ange.201906978openalex-snapshot
Highly Selective and Catalytic Oxygenations of C−H and C=C Bonds by a Mononuclear Nonheme High‐Spin Iron(III)‐Alkylperoxo Species
inferred← citeshttps://doi.org/10.1002/ange.202004639openalex-snapshot
Fast Hydrocarbon Oxidation by a High‐Valent Nickel–Fluoride Complex
inferred← citeshttps://doi.org/10.1002/ange.202015896openalex-snapshot
A Pseudotetrahedral Terminal Oxoiron(IV) Complex: Mechanistic Promiscuity in C−H Bond Oxidation Reactions
inferred← citeshttps://doi.org/10.1002/ange.202112063openalex-snapshot
Structural Insight into the Catalytic Mechanism of the Endoperoxide Synthase FtmOx1
inferred← citeshttps://doi.org/10.1002/ange.202309362openalex-snapshot
An S=1 Iron(IV) Intermediate Revealed in a Non‐Heme Iron Enzyme‐Catalyzed Oxidative C−S Bond Formation
inferred← citeshttps://doi.org/10.1002/ange.202401694openalex-snapshot
Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C−H Oxidation
inferred← citeshttps://doi.org/10.1002/ange.202419953openalex-snapshot
Bridging the Oxo Wall: A New Perspective on High‐valent Metal‐Oxo Species and Their Reactivity in Mn, Fe, and Co Complexes
inferred← citeshttps://doi.org/10.1002/ange.202524718openalex-snapshot
Nonheme Fe Enzyme‐Catalyzed Enantiodivergent Nitrogen Migration: Directed Evolution and Computational Study of Isopenicillin N Synthases for Biocatalytic Synthesis of Arylglycines
inferred← citeshttps://doi.org/10.1002/anie.1885847openalex-snapshot
Second‐Sphere Aromatic Substitutions That Tune H‐Atom Transfer Reactivity Observed for a Series of S = 1 Nonheme Fe IV =O Complexes: An Enthalpy‐Entropy Compensation Effect
inferred← citeshttps://doi.org/10.1002/anie.200705880openalex-snapshot
Experiment and Theory Reveal the Fundamental Difference between Two‐State and Single‐State Reactivity Patterns in Nonheme FeIVO versus RuIVO Oxidants
inferred← citeshttps://doi.org/10.1002/anie.200801832openalex-snapshot
Proton‐ and Reductant‐Assisted Dioxygen Activation by a Nonheme Iron(II) Complex to Form an Oxoiron(IV) Intermediate
inferred← citeshttps://doi.org/10.1002/anie.200802219openalex-snapshot
An Inverted and More Oxidizing Isomer of [FeIV(O)(tmc)(NCCH3)]2+
inferred← citeshttps://doi.org/10.1002/anie.200802346openalex-snapshot
Hydrogen Atom Abstraction and Hydride Transfer Reactions by Iron(IV)–Oxo Porphyrins
inferred← citeshttps://doi.org/10.1002/anie.200802672openalex-snapshot
Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts
inferred← citeshttps://doi.org/10.1002/anie.200804029openalex-snapshot
A Two‐State Reactivity Model Explains Unusual Kinetic Isotope Effect Patterns in CH Bond Cleavage by Nonheme Oxoiron(IV) Complexes
inferred← citeshttps://doi.org/10.1002/anie.200805342openalex-snapshot
Shape‐Selective Interception by Hydrocarbons of the O 2 ‐Derived Oxidant of a Biomimetic Nonheme Iron Complex
inferred← citeshttps://doi.org/10.1002/anie.200805670openalex-snapshot
Water as an Oxygen Source in the Generation of Mononuclear Nonheme Iron(IV) Oxo Complexes
inferred← citeshttps://doi.org/10.1002/anie.200805977openalex-snapshot
What Does it Really Take to Stabilize Complexes of Late Transition Metals with Terminal Oxo Ligands?
inferred← citeshttps://doi.org/10.1002/anie.200900552openalex-snapshot
Biomimetic Trispyrazolylborato Iron Complexes
inferred← citeshttps://doi.org/10.1002/anie.200900863openalex-snapshot
A Synthetic High‐Spin Oxoiron(IV) Complex: Generation, Spectroscopic Characterization, and Reactivity
inferred← citeshttps://doi.org/10.1002/anie.201000004openalex-snapshot
The Fundamental Role of Exchange‐Enhanced Reactivity in CH Activation by S=2 Oxo Iron(IV) Complexes
inferred← citeshttps://doi.org/10.1002/anie.201001850openalex-snapshot
Analysis of Reaction Channels for Alkane Hydroxylation by Nonheme Iron(IV)–Oxo Complexes
inferred← citeshttps://doi.org/10.1002/anie.201007692openalex-snapshot
Nuclear Resonance Vibrational Spectroscopy on the FeIVO S=2 Non‐Heme Site in TMG3tren: Experimentally Calibrated Insights into Reactivity
inferred← citeshttps://doi.org/10.1002/anie.201102146openalex-snapshot
CH Bond Activation of Methanol and Ethanol by a High‐Spin FeIVO Biomimetic Complex
inferred← citeshttps://doi.org/10.1002/anie.201108398openalex-snapshot
Hydrogen‐Abstraction Reactivity Patterns from A to Y: The Valence Bond Way
inferred← citeshttps://doi.org/10.1002/anie.201200901openalex-snapshot
The Reaction of a High‐Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide
inferred← citeshttps://doi.org/10.1002/anie.201202487openalex-snapshot
An Iron(III) Iodosylbenzene Complex: A Masked Non‐Heme FeVO
inferred← citeshttps://doi.org/10.1002/anie.201208044openalex-snapshot
A Tetracarbene–Oxoiron(IV) Complex
inferred← citeshttps://doi.org/10.1002/anie.201210020openalex-snapshot
Photoassisted Generation of a Dinuclear Iron(III) Peroxo Species and Oxygen‐Atom Transfer
inferred← citeshttps://doi.org/10.1002/anie.201305994openalex-snapshot
Enhanced Reactivity of a Biomimetic Iron(II) α‐Keto Acid Complex through Immobilization on Functionalized Gold Nanoparticles
inferred← citeshttps://doi.org/10.1002/anie.201402537openalex-snapshot
Highly Reactive Nonheme Iron(III) Iodosylarene Complexes in Alkane Hydroxylation and Sulfoxidation Reactions
inferred← citeshttps://doi.org/10.1002/anie.201405874openalex-snapshot
Spectroscopic Capture and Reactivity of a Low‐Spin Cobalt(IV)‐Oxo Complex Stabilized by Binding Redox‐Inactive Metal Ions
inferred← citeshttps://doi.org/10.1002/anie.201407156openalex-snapshot
A cis ‐Divacant Octahedral and Mononuclear Iron(IV) Imide
inferred← citeshttps://doi.org/10.1002/anie.201501437openalex-snapshot
CH Activation of Benzene by a Photoactivated Ni II (azide): Formation of a Transient Nickel Nitrido Complex
inferred← citeshttps://doi.org/10.1002/anie.201502229openalex-snapshot
Olefin cis‐Dihydroxylation and Aliphatic CH Bond Oxygenation by a Dioxygen‐Derived Electrophilic Iron–Oxygen Oxidant
inferred← citeshttps://doi.org/10.1002/anie.201505796openalex-snapshot
Mononuclear Nonheme Iron(III)‐Iodosylarene and High‐Valent Iron‐Oxo Complexes in Olefin Epoxidation Reactions
inferred← citeshttps://doi.org/10.1002/anie.201507463openalex-snapshot
Nitrene Insertion into CC and CH Bonds of Diamide Diimine Ligands Ligated to Chromium and Iron
inferred← citeshttps://doi.org/10.1002/anie.201507835openalex-snapshot
Structure of the Dioxygenase AsqJ: Mechanistic Insights into a One‐Pot Multistep Quinolone Antibiotic Biosynthesis
inferred← citeshttps://doi.org/10.1002/anie.201507933openalex-snapshot
A Highly Reactive Seven‐Coordinate Osmium(V) Oxo Complex: [OsV(O)(qpy)(pic)Cl]2+
inferred← citeshttps://doi.org/10.1002/anie.201509914openalex-snapshot
Hydroxylation versus Halogenation of Aliphatic C−H Bonds by a Dioxygen‐Derived Iron–Oxygen Oxidant: Functional Mimicking of Iron Halogenases
inferred← citeshttps://doi.org/10.1002/anie.201600507openalex-snapshot
Oxidation Reactions with Bioinspired Mononuclear Non‐Heme Metal–Oxo Complexes
inferred← citeshttps://doi.org/10.1002/anie.201603978openalex-snapshot
Mononuclear Nonheme High‐Spin (S=2) versus Intermediate‐Spin (S=1) Iron(IV)–Oxo Complexes in Oxidation Reactions
inferred← citeshttps://doi.org/10.1002/anie.201612299openalex-snapshot
Two Exceptional Homoleptic Iron(IV) Tetraalkyl Complexes
inferred← citeshttps://doi.org/10.1002/anie.201701319openalex-snapshot
Accelerated Oxygen Atom Transfer and C−H Bond Oxygenation by Remote Redox Changes in Fe3Mn‐Iodosobenzene Adducts
inferred← citeshttps://doi.org/10.1002/anie.201702009openalex-snapshot
The Dynamics of the Reaction of FeO+ and H2: A Model for Inorganic Oxidation
inferred← citeshttps://doi.org/10.1002/anie.201707872openalex-snapshot
A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N 3 O Macrocyclic Ligand
inferred← citeshttps://doi.org/10.1002/anie.201802779openalex-snapshot
A Bis(μ‐oxido)dinickel(III) Complex with a Triplet Ground State
inferred← citeshttps://doi.org/10.1002/anie.201805511openalex-snapshot
cPCET versus HAT: A Direct Theoretical Method for Distinguishing X–H Bond‐Activation Mechanisms
inferred← citeshttps://doi.org/10.1002/anie.201807844openalex-snapshot
Enzymatic Cascade Reactions in Biosynthesis
inferred← citeshttps://doi.org/10.1002/anie.201810227openalex-snapshot
Probing Hydrogen Bonding Interactions to Iron‐Oxido/Hydroxido Units by 57Fe Nuclear Resonance Vibrational Spectroscopy
inferred← citeshttps://doi.org/10.1002/anie.201812758openalex-snapshot
Trapping of a Highly Reactive Oxoiron(IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide
inferred← citeshttps://doi.org/10.1002/anie.201901608openalex-snapshot
Direct Observation of Primary C−H Bond Oxidation by an Oxido‐Iron(IV) Porphyrin π‐Radical Cation Complex in a Fluorinated Carbon Solvent
inferred← citeshttps://doi.org/10.1002/anie.201903465openalex-snapshot
Activation of a Non‐Heme FeIII‐OOH by a Second FeIII to Hydroxylate Strong C−H Bonds: Possible Implications for Soluble Methane Monooxygenase
inferred← citeshttps://doi.org/10.1002/anie.201905325openalex-snapshot
A Terminal Iridium Oxo Complex with a Triplet Ground State
inferred← citeshttps://doi.org/10.1002/anie.201905416openalex-snapshot
Hydrogen by Deuterium Substitution in an Aldehyde Tunes the Regioselectivity by a Nonheme Manganese(III)–Peroxo Complex
inferred← citeshttps://doi.org/10.1002/anie.201906978openalex-snapshot
Highly Selective and Catalytic Oxygenations of C−H and C=C Bonds by a Mononuclear Nonheme High‐Spin Iron(III)‐Alkylperoxo Species
inferred← citeshttps://doi.org/10.1002/anie.202004639openalex-snapshot
Fast Hydrocarbon Oxidation by a High‐Valent Nickel–Fluoride Complex
inferred← citeshttps://doi.org/10.1002/anie.202015896openalex-snapshot
A Pseudotetrahedral Terminal Oxoiron(IV) Complex: Mechanistic Promiscuity in C−H Bond Oxidation Reactions
inferred← citeshttps://doi.org/10.1002/anie.202112063openalex-snapshot
Structural Insight into the Catalytic Mechanism of the Endoperoxide Synthase FtmOx1
inferred← citeshttps://doi.org/10.1002/anie.202309362openalex-snapshot
An S=1 Iron(IV) Intermediate Revealed in a Non‐Heme Iron Enzyme‐Catalyzed Oxidative C−S Bond Formation
inferred← citeshttps://doi.org/10.1002/anie.202401694openalex-snapshot
Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C−H Oxidation
inferred← citeshttps://doi.org/10.1002/anie.202419953openalex-snapshot
Bridging the Oxo Wall: A New Perspective on High‐valent Metal‐Oxo Species and Their Reactivity in Mn, Fe, and Co Complexes
inferred← citeshttps://doi.org/10.1002/anie.202524718openalex-snapshot
Nonheme Fe Enzyme‐Catalyzed Enantiodivergent Nitrogen Migration: Directed Evolution and Computational Study of Isopenicillin N Synthases for Biocatalytic Synthesis of Arylglycines
inferred← citeshttps://doi.org/10.1002/anse.70121openalex-snapshot
Analytical and Spectroscopic Tools for Studying Enzyme Transition States
inferred← citeshttps://doi.org/10.1002/asia.201601170openalex-snapshot
Biologically Inspired C−H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes
inferred← citeshttps://doi.org/10.1002/bkcs.12300openalex-snapshot
Theoretical Study on the Aliphatic C─H Bond Activation by a Mononuclear Manganese( III ) Iodosylbenzene Complex
inferred← citeshttps://doi.org/10.1002/bkcs.12417openalex-snapshot
Deuterium kinetic isotope effects as redox mechanistic criterions
inferred← citeshttps://doi.org/10.1002/cbic.201000562openalex-snapshot
Gene Disruption and Biochemical Characterization of Verruculogen Synthase of Aspergillus fumigatus
inferred← citeshttps://doi.org/10.1002/cbic.201300345openalex-snapshot
More than just a Halogenase: Modification of Fatty Acyl Moieties by a Trifunctional Metal Enzyme
inferred← citeshttps://doi.org/10.1002/cbic.202000743openalex-snapshot
Isopenicillin N Synthase: Crystallographic Studies
inferred← citeshttps://doi.org/10.1002/cbic.202200081openalex-snapshot
Synthesis of 6,6‐ and 7,7‐Difluoro‐1‐acetamidopyrrolizidines and Their Oxidation Catalyzed by the Nonheme Fe Oxygenase LolO
inferred← citeshttps://doi.org/10.1002/cbic.202200257openalex-snapshot
Second Coordination Sphere Effects on the Mechanistic Pathways for Dioxygen Activation by a Ferritin: Involvement of a Tyr Radical and the Identification of a Cation Binding Site
inferred← citeshttps://doi.org/10.1002/cbic.202300119openalex-snapshot
Coordination Dynamics of Iron is a Key Player in the Catalysis of Non‐heme Enzymes
inferred← citeshttps://doi.org/10.1002/cbic.202400307openalex-snapshot
New Frontiers in Nonheme Enzymatic Oxyferryl Species
inferred← citeshttps://doi.org/10.1002/cbic.202400788openalex-snapshot
Recent Insights into the Reaction Mechanisms of Non‐Heme Diiron Enzymes Containing Oxoiron(IV) Complexes
inferred← citeshttps://doi.org/10.1002/cbic.202400953openalex-snapshot
Revealing the Monooxygenase Mechanism for Selective Ring Cleavage of Anthraquinone by BTG13 through Multiscale Simulations
inferred← citeshttps://doi.org/10.1002/cctc.201200266openalex-snapshot
Selective Catalytic Oxidation of CH Bonds with Molecular Oxygen
inferred← citeshttps://doi.org/10.1002/cctc.201402642openalex-snapshot
Biomimetic Oxidation with Fe‐ZSM‐5 and H 2 O 2 ? Identification of an Active, Extra‐Framework Binuclear Core and an Fe III OOH Intermediate with Resonance‐Enhanced Raman Spectroscopy
inferred← citeshttps://doi.org/10.1002/cctc.202100393openalex-snapshot
Mechanism of Oxidative Ring‐Closure as Part of the Hygromycin Biosynthesis Step by a Nonheme Iron Dioxygenase
inferred← citeshttps://doi.org/10.1002/ceur.202400067openalex-snapshot
Mechanism of Substrate Activation by Tryptophan Hydroxylase: A Computational Study
inferred← citeshttps://doi.org/10.1002/chem.200700513openalex-snapshot
Biomimetic Hydrocarbon Oxidation Catalyzed by Nonheme Iron(III) Complexes with Peracids: Evidence for an FeVO Species
inferred← citeshttps://doi.org/10.1002/chem.200802338openalex-snapshot
Generating CuII–Oxyl/CuIII–Oxo Species from CuI–α‐Ketocarboxylate Complexes and O2: In Silico Studies on Ligand Effects and CH‐Activation Reactivity
inferred← citeshttps://doi.org/10.1002/chem.200802597openalex-snapshot
Olefin‐Dependent Discrimination between Two Nonheme HOFeVO Tautomeric Species in Catalytic H2O2 Epoxidations
inferred← citeshttps://doi.org/10.1002/chem.200900211openalex-snapshot
Origin of the Correlation of the Rate Constant of Substrate Hydroxylation by Nonheme Iron(IV)–oxo Complexes with the Bond‐Dissociation Energy of the CH Bond of the Substrate
inferred← citeshttps://doi.org/10.1002/chem.200901296openalex-snapshot
Iron‐Promoted ortho‐ and/or ipso‐Hydroxylation of Benzoic Acids with H2O2
inferred← citeshttps://doi.org/10.1002/chem.201103294openalex-snapshot
The Photochemistry of [Fe III N 3 (cyclam‐ac)]PF 6 at 266 nm
inferred← citeshttps://doi.org/10.1002/chem.201200105openalex-snapshot
Intramolecular Gas‐Phase Reactions of Synthetic Nonheme Oxoiron(IV) Ions: Proximity and Spin‐State Reactivity Rules
inferred← citeshttps://doi.org/10.1002/chem.201300107openalex-snapshot
Synthesis, Characterization, and Reactivity of Cobalt(III)–Oxygen Complexes Bearing a Macrocyclic N‐Tetramethylated Cyclam Ligand
inferred← citeshttps://doi.org/10.1002/chem.201300520openalex-snapshot
Synthetic, Spectroscopic, and DFT Studies of Iron Complexes with Iminobenzo(semi)quinone Ligands: Implications for o‐Aminophenol Dioxygenases
inferred← citeshttps://doi.org/10.1002/chem.201301641openalex-snapshot
Mononuclear Manganese–Peroxo and Bis(μ‐oxo)dimanganese Complexes Bearing a Common N‐Methylated Macrocyclic Ligand
inferred← citeshttps://doi.org/10.1002/chem.201404918openalex-snapshot
Differences and Comparisons of the Properties and Reactivities of Iron(III)–hydroperoxo Complexes with Saturated Coordination Sphere
inferred← citeshttps://doi.org/10.1002/chem.201406441openalex-snapshot
Tailoring RuII Pyridine/Triazole Oxygenation Catalysts and Using Photoreactivity to Probe their Electronic Properties
inferred← citeshttps://doi.org/10.1002/chem.201406485openalex-snapshot
Characterization and Reactivity of a Terminal Nickel(III)–Oxygen Adduct
inferred← citeshttps://doi.org/10.1002/chem.201500644openalex-snapshot
Structure and Mechanism Leading to Formation of the Cysteine Sulfinate Product Complex of a Biomimetic Cysteine Dioxygenase Model
inferred← citeshttps://doi.org/10.1002/chem.201700960openalex-snapshot
Photolysis of a High‐Spin Azidoiron(III) Complex Studied by Time‐Resolved Fourier‐Transform Infrared Spectroscopy
inferred← citeshttps://doi.org/10.1002/chem.201701059openalex-snapshot
Interplay of Electronic Cooperativity and Exchange Coupling in Regulating the Reactivity of Diiron(IV)‐oxo Complexes towards C−H and O−H Bond Activation
inferred← citeshttps://doi.org/10.1002/chem.201702302openalex-snapshot
Selectivity of C−H versus C−F Bond Oxygenation by Homo‐ and Heterometallic Fe4, Fe3Mn, and Mn4 Clusters
inferred← citeshttps://doi.org/10.1002/chem.201800380openalex-snapshot
Axial vs. Equatorial Ligand Rivalry in Controlling the Reactivity of Iron(IV)‐Oxo Species: Single‐State vs. Two‐State Reactivity
inferred← citeshttps://doi.org/10.1002/chem.201806430openalex-snapshot
Interplay Between Steric and Electronic Effects: A Joint Spectroscopy and Computational Study of Nonheme Iron(IV)‐Oxo Complexes
inferred← citeshttps://doi.org/10.1002/chem.201900492openalex-snapshot
Conformational Dynamics Underlies Different Functions of Human KDM7 Histone Demethylases
inferred← citeshttps://doi.org/10.1002/chem.201902048openalex-snapshot
NMR Reveals That a Highly Reactive Nonheme FeIV=O Complex Retains Its Six‐Coordinate Geometry and S=1 State in Solution
inferred← citeshttps://doi.org/10.1002/chem.201902423openalex-snapshot
Non‐Heme FeII Diastereomeric Complexes Bearing a Hexadentate Ligand: Unexpected Consequences for the Spin State and Catalytic Oxidation Properties
inferred← citeshttps://doi.org/10.1002/chem.201903035openalex-snapshot
A Combined Experimental and Theoretical Study of the Versatile Reactivity of an Oxocerium(IV) Complex: Concerted Versus Reductive Addition
inferred← citeshttps://doi.org/10.1002/chem.201903783openalex-snapshot
Can a Mononuclear Iron(III)‐Superoxo Active Site Catalyze the Decarboxylation of Dodecanoic Acid in UndA to Produce Biofuels?
inferred← citeshttps://doi.org/10.1002/chem.201904314openalex-snapshot
Spin‐Forbidden Reactivity of Transition Metal Oxo Species: Exploring the Potential Energy Surfaces
inferred← citeshttps://doi.org/10.1002/chem.201905119openalex-snapshot
Second‐Coordination Sphere Effects on Selectivity and Specificity of Heme and Nonheme Iron Enzymes
inferred← citeshttps://doi.org/10.1002/chem.202002158openalex-snapshot
A Stable Homoleptic Organometallic Iron(IV) Complex
inferred← citeshttps://doi.org/10.1002/chem.202004019openalex-snapshot
What Determines the Selectivity of Arginine Dihydroxylation by the Nonheme Iron Enzyme OrfP?
inferred← citeshttps://doi.org/10.1002/chem.202004633openalex-snapshot
Structurally Modelling the 2‐His‐1‐Carboxylate Facial Triad with a Bulky N , N,O Phenolate Ligand
inferred← citeshttps://doi.org/10.1002/chem.202100791openalex-snapshot
Electrostatic Perturbations from the Protein Affect C−H Bond Strengths of the Substrate and Enable Negative Catalysis in the TmpA Biosynthesis Enzyme
inferred← citeshttps://doi.org/10.1002/chem.202101045openalex-snapshot
Pathways of the Extremely Reactive Iron(IV)‐oxido complexes with Tetradentate Bispidine Ligands
inferred← citeshttps://doi.org/10.1002/chem.202101174openalex-snapshot
What Is the Catalytic Mechanism of Enzymatic Histone N‐Methyl Arginine Demethylation and Can It Be Influenced by an External Electric Field?
inferred← citeshttps://doi.org/10.1002/chem.202101878openalex-snapshot
Structure and Functional Differences of Cysteine and 3‐Mercaptopropionate Dioxygenases: A Computational Study
inferred← citeshttps://doi.org/10.1002/chem.202103295openalex-snapshot
Nonheme Iron Imido Complexes Bearing a Non‐Innocent Ligand: A Synthetic Chameleon Species in Oxidation Reactions
inferred← citeshttps://doi.org/10.1002/chem.202103452openalex-snapshot
Non‐Heme‐Iron‐Mediated Selective Halogenation of Unactivated Carbon−Hydrogen Bonds
inferred← citeshttps://doi.org/10.1002/chem.202103982openalex-snapshot
Biodegradation of Herbicides by a Plant Nonheme Iron Dioxygenase: Mechanism and Selectivity of Substrate Analogues
inferred← citeshttps://doi.org/10.1002/chem.202104167openalex-snapshot
Electrostatic Perturbations in the Substrate‐Binding Pocket of Taurine/α‐Ketoglutarate Dioxygenase Determine its Selectivity
inferred← citeshttps://doi.org/10.1002/chem.202300271openalex-snapshot
Reactivity Differences of Trigonal Pyramidal Nonheme Iron(IV)‐Oxo and Iron(III)‐Oxo Complexes: Experiment and Theory
inferred← citeshttps://doi.org/10.1002/chem.202303955openalex-snapshot
Catalytic Oxidation of Methanol to Formaldehyde Catalyzed by Iron Complex with N3S3‐type Tripodal Ligand
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