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Climbing Nitrogenase: Toward a Mechanism of Enzymatic Nitrogen Fixation
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Outgoing claims: the papers this work cites, builds on, or argues with.
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ChemInform Abstract: Mechanism of Molybdenum Nitrogenase
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Metalloenzyme Active-Site Structure and Function through Multifrequency CW and Pulsed ENDOR
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The Chatt cycle and the mechanism of enzymic reduction of molecular nitrogen
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Hydrazine as a substrate and inhibitor of Azotobacter vinelandii nitrogenase
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Mid- to high-valent imido and nitrido complexes of iron
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Duplication and extension of the Thorneley and Lowe kinetic model for Klebsiella pneumoniae nitrogenase catalysis using a mathematica software platform
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Substrate Interactions with the Nitrogenase Active Site
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Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
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Electronic Structure and Reactivity of Three-Coordinate Iron Complexes
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Mechanistic Features and Structure of the Nitrogenase α-Gln195 MoFe Protein,
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Differential Effects on N2 Binding and Reduction, HD Formation, and Azide Reduction with α-195His- and α-191Gln-Substituted MoFe Proteins of Azotobacter vinelandii Nitrogenase
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Iron-sulfur clusters in the molybdenum-iron protein component of nitrogenase. Electron paramagnetic resonance of the carbon monoxide inhibited state
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Trapping a Hydrazine Reduction Intermediate on the Nitrogenase Active Site
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Diazene (HNNH) Is a Substrate for Nitrogenase: Insights into the Pathway of N2 Reduction
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Investigation of CO Binding and Release from Mo-Nitrogenase during Catalytic Turnover
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Spectroscopic Evidence for Changes in the Redox State of the Nitrogenase P-Cluster during Turnover
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Mechanism of Molybdenum Nitrogenase
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Structure−Function Relationships of Alternative Nitrogenases
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Testing if the Interstitial Atom,X, of the Nitrogenase Molybdenum−Iron Cofactor Is N or C: ENDOR, ESEEM, and DFT Studies of theS=3/2Resting State in Multiple Environments
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Chemical Activity of the Nitrogenase FeMo Cofactor with a Central Nitrogen Ligand: Density Functional Study
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Kinetic Isotope Effects on the Rate-Limiting Step of Heme Oxygenase Catalysis Indicate Concerted Proton Transfer/Heme Hydroxylation
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Trapping H - Bound to the Nitrogenase FeMo-Cofactor Active Site during H 2 Evolution: Characterization by ENDOR Spectroscopy
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An Organometallic Intermediate during Alkyne Reduction by Nitrogenase
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Intermediates Trapped during Nitrogenase Reduction of N⋮N, CH 3 −NNH, and H 2 N−NH 2
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Electron Inventory, Kinetic Assignment (En), Structure, and Bonding of Nitrogenase Turnover Intermediates with C2H2 and CO
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ENDOR Characterization of a Synthetic Diiron Hydrazido Complex as a Model for Nitrogenase Intermediates
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Identification of the CO-Binding Cluster in Nitrogenase MoFe Protein by ENDOR of 57Fe Isotopomers
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CO Binding to the FeMo Cofactor of CO-Inhibited Nitrogenase: 13CO and 1H Q-Band ENDOR Investigation
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Breaking the N2 triple bond: insights into the nitrogenase mechanism
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Nitrogenase of Klebsiella pneumoniae. Hydrazine is a product of azide reduction
inferredcites →https://doi.org/10.1042/bj2720621openalex-snapshot
Klebsiella pneumoniae nitrogenase. Mechanism of acetylene reduction and its inhibition by carbon monoxide
inferredcites →https://doi.org/10.1073/pnas.0602130103openalex-snapshot
A methyldiazene (HNNCH 3 )-derived species bound to the nitrogenase active-site FeMo cofactor: Implications for mechanism
inferredcites →https://doi.org/10.1073/pnas.0603978103openalex-snapshot
How many metals does it take to fix N 2 ? A mechanistic overview of biological nitrogen fixation
inferredcites →https://doi.org/10.1073/pnas.0610975104openalex-snapshot
Connecting nitrogenase intermediates with the kinetic scheme for N 2 reduction by a relaxation protocol and identification of the N 2 binding state
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Principles of Pulse Electron Paramagnetic Resonance
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Structural basis of biological nitrogen fixation
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Diversity of Nitrogenase Systems in Diazotrophs
inferredcites →https://doi.org/10.1126/science.1073877openalex-snapshot
Nitrogenase MoFe-Protein at 1.16 Å Resolution: A Central Ligand in the FeMo-Cofactor
inferredcites →https://doi.org/10.1126/science.1085326openalex-snapshot
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
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Effects of homocitrate, homocitrate lactone, and fluorohomocitrate on nitrogenase in NifV- mutants of Azotobacter vinelandii
inferredcites →https://doi.org/10.1146/annurev.biochem.78.070907.103812openalex-snapshot
Mechanism of Mo-Dependent Nitrogenase
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Analysis of nitrogen fixation by a catalyst capable of transforming N2, CO2 and CH4 into amino acids under mild reactions conditions
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Enhanced nitrogen photofixation on Fe-doped TiO2 with highly exposed (1 0 1) facets in the presence of ethanol as scavenger
inferred← citeshttps://doi.org/10.1016/j.apcatb.2020.118984openalex-snapshot
1 T-phase molybdenum sulfide nanodots enable efficient electrocatalytic nitrogen fixation under ambient conditions
inferred← citeshttps://doi.org/10.1016/j.apcatb.2022.121277openalex-snapshot
Enabling efficient electrocatalytic conversion of N2 to NH3 by Ti3C2 MXene loaded with semi-metallic 1T′-MoS2 nanosheets
inferred← citeshttps://doi.org/10.1016/j.apmate.2024.100204openalex-snapshot
Recent developments in synthesis, properties, and applications of 2D Janus MoSSe and MoSe S(1-) alloys
inferred← citeshttps://doi.org/10.1016/j.apsusc.2020.146385openalex-snapshot
Self-supporting CoMoC nanoporous catalysts for N2 reduction reaction under ambient conditions
inferred← citeshttps://doi.org/10.1016/j.apsusc.2020.147372openalex-snapshot
Multiphasic 1T@2H MoSe2 as a highly efficient catalyst for the N2 reduction to NH3
inferred← citeshttps://doi.org/10.1016/j.bbabio.2013.04.003openalex-snapshot
Nitrogenase reduction of carbon-containing compounds
inferred← citeshttps://doi.org/10.1016/j.bbamcr.2015.01.025openalex-snapshot
Advanced paramagnetic resonance spectroscopies of iron–sulfur proteins: Electron nuclear double resonance (ENDOR) and electron spin echo envelope modulation (ESEEM)
inferred← citeshttps://doi.org/10.1016/j.cattod.2016.08.014openalex-snapshot
Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction
inferred← citeshttps://doi.org/10.1016/j.cattod.2018.12.029openalex-snapshot
Mo2TiC2 MXene: A Promising Catalyst for Electrocatalytic Ammonia Synthesis
inferred← citeshttps://doi.org/10.1016/j.cattod.2022.09.004openalex-snapshot
Mechanistic analysis of the dissociative reduction of nitrogen to ammonia by ZnMn2O4 catalyst derived from spent batteries
inferred← citeshttps://doi.org/10.1016/j.cbpa.2012.02.012openalex-snapshot
Electron transfer in nitrogenase catalysis
inferred← citeshttps://doi.org/10.1016/j.ccr.2010.01.005openalex-snapshot
Iron–dinitrogen coordination chemistry: Dinitrogen activation and reactivity
inferred← citeshttps://doi.org/10.1016/j.ccr.2011.12.012openalex-snapshot
The chemistry of univalent metal β-diketiminates
inferred← citeshttps://doi.org/10.1016/j.ccr.2016.07.005openalex-snapshot
Exploring the role of pendant amines in transition metal complexes for the reduction of N2 to hydrazine and ammonia
inferred← citeshttps://doi.org/10.1016/j.ccr.2017.02.018openalex-snapshot
Impact of ligands and media on the structure and properties of biological and biomimetic iron-sulfur clusters
inferred← citeshttps://doi.org/10.1016/j.ccr.2020.213606openalex-snapshot
Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes
inferred← citeshttps://doi.org/10.1016/j.cdc.2026.101222openalex-snapshot
Synthesis and characterization of single crystal XRD of polymeric sodium ferric EDTA monohydrate complex by solvent evaporation approach
inferred← citeshttps://doi.org/10.1016/j.cej.2022.139515openalex-snapshot
Valence engineering at the interface of MoS2/Mo2C heterostructure for bionic nitrogen reduction
inferred← citeshttps://doi.org/10.1016/j.comptc.2021.113418openalex-snapshot
Assessment of density functional theory in studying on the transition states of a Diiron-mediated N N bond cleavage reaction
inferred← citeshttps://doi.org/10.1016/j.cplett.2010.09.003openalex-snapshot
Molecular hydrogen assisted transport of H atoms
inferred← citeshttps://doi.org/10.1016/j.cplett.2015.09.050openalex-snapshot
A theoretical study on single-electron reduction of a thiolate-bridged diiron diazene complex
inferred← citeshttps://doi.org/10.1016/j.cplett.2016.08.011openalex-snapshot
Studies on the electronic structure of thiolate-bridged diiron complexes and their single-electron reduction reactions
inferred← citeshttps://doi.org/10.1016/j.csbj.2020.12.004openalex-snapshot
Molecular mechanisms of electron transfer employed by native proteins and biological-inorganic hybrid systems
inferred← citeshttps://doi.org/10.1016/j.febslet.2012.01.037openalex-snapshot
Crystal structure of cce_0566 from Cyanothece 51142, a protein associated with nitrogen fixation in the DUF269 family
inferred← citeshttps://doi.org/10.1016/j.fuel.2022.126434openalex-snapshot
Bottlebrush polymeric catalyst: Boosting activity for CO2/epoxide copolymerization
inferred← citeshttps://doi.org/10.1016/j.ica.2024.122270openalex-snapshot
Chinese-Lantern shaped [MnII2MnIII6NaI3] cluster assembled from Schiff base and azide bridges: Synthesis, magnetic study and catecholase-like activity
inferred← citeshttps://doi.org/10.1016/j.jcat.2019.02.008openalex-snapshot
CO methanation on ruthenium flat and stepped surfaces: Key role of H-transfers and entropy revealed by ab initio molecular dynamics
inferred← citeshttps://doi.org/10.1016/j.jcat.2020.05.034openalex-snapshot
Engineering the coordination environment enables molybdenum single-atom catalyst for efficient oxygen reduction reaction
inferred← citeshttps://doi.org/10.1016/j.jclepro.2021.129377openalex-snapshot
Photocatalytic nitrogen-oxide conversion in red soil
inferred← citeshttps://doi.org/10.1016/j.jcou.2022.101979openalex-snapshot
Highly active bifunctional dual-arm organoboron catalysts bearing cooperative intramolecular structures for the copolymerization of CO2 and epoxides
inferred← citeshttps://doi.org/10.1016/j.jechem.2018.09.008openalex-snapshot
Strain engineering the D-band center for Janus MoSSe edge: Nitrogen fixation
inferred← citeshttps://doi.org/10.1016/j.jechem.2026.05.006openalex-snapshot
Recent advances in atomically engineered catalysts for sustainable ammonia electrosynthesis
inferred← citeshttps://doi.org/10.1016/j.jelechem.2022.117049openalex-snapshot
Recent advances in transition metal sulfide-based electrocatalysts and photocatalysts for nitrogen fixation
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2013.08.033openalex-snapshot
A review of complexes of ambivalent and ambiphilic Lewis acid/bases with symmetry signatures and an alternative notation for these non-innocent ligands
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2014.09.018openalex-snapshot
Hydrazine complexes of ruthenium with cyclopentadienyl and indenyl ligands: Preparation and reactivity
inferred← citeshttps://doi.org/10.1016/j.joule.2017.07.007openalex-snapshot
Production of Liquid Solar Fuels and Their Use in Fuel Cells
inferred← citeshttps://doi.org/10.1016/j.molstruc.2026.146231openalex-snapshot
Ligand effect on the structures and redox properties of the incomplete cubane-type Mo-Fe-S clusters
inferred← citeshttps://doi.org/10.1016/j.nanoen.2019.104187openalex-snapshot
Band structure engineering of bioinspired Fe doped SrMoO4 for enhanced photocatalytic nitrogen reduction performance
inferred← citeshttps://doi.org/10.1016/j.nanoen.2020.104681openalex-snapshot
Boosting electrosynthesis of ammonia on surface-engineered MXene Ti3C2
inferred← citeshttps://doi.org/10.1016/j.pnsc.2025.11.004openalex-snapshot
Enhancing photocatalytic nitrogen fixation through controlled acid corrosion of 1D TiO2 nanobelts
inferred← citeshttps://doi.org/10.1016/j.poly.2021.115193openalex-snapshot
N N bond cleavage upon reduction and protonation of phenylazophenylate coordinated to ruthenium complex
inferred← citeshttps://doi.org/10.1016/j.soilbio.2018.05.008openalex-snapshot
Dose-response relationships between environmentally-relevant H2 concentrations and the biological sinks of H2, CH4 and CO in soil
inferred← citeshttps://doi.org/10.1016/s1872-2067(18)63104-3openalex-snapshot
Photocatalytic nitrogen fixation: An attractive approach for artificial photocatalysis
inferred← citeshttps://doi.org/10.1021/acs.accounts.4c00068openalex-snapshot
Construction and Function of Thiolate-Bridged Diiron NxHy Nitrogenase Model Complexes
inferred← citeshttps://doi.org/10.1021/acs.accounts.5b00213openalex-snapshot
Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes
inferred← citeshttps://doi.org/10.1021/acs.biochem.5b00216openalex-snapshot
Docking and Migration of Carbon Monoxide in Nitrogenase: The Case for Gated Pockets from Infrared Spectroscopy and Molecular Dynamics
inferred← citeshttps://doi.org/10.1021/acs.biochem.8b00509openalex-snapshot
The Critical E4 State of Nitrogenase Catalysis
inferred← citeshttps://doi.org/10.1021/acs.chemrev.9b00556openalex-snapshot
Reduction of Substrates by Nitrogenases
inferred← citeshttps://doi.org/10.1021/acs.chemrev.9b00650openalex-snapshot
The Spectroscopy of Nitrogenases
inferred← citeshttps://doi.org/10.1021/acs.energyfuels.5c03815openalex-snapshot
Minireview on Perovskite Oxide-Based Materials toward Enhanced Electrocatalytic Nitrate Reduction for Ammonia Synthesis: Advances and Perspectives
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.0c02382openalex-snapshot
Determination of the N–H Bond Dissociation Free Energy in a Pyridine(diimine)molybdenum Complex Prepared by Proton-Coupled Electron Transfer
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c00322openalex-snapshot
Tuning Catalyst Selectivity for Ammonia vs Hydrogen: An Investigation into the Coprecipitation of Mo and Fe Sulfides
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c02445openalex-snapshot
Synthesis of Bis(silylene) Iron Chlorides and Their Catalytic Activity for Dinitrogen Silylation
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b01002openalex-snapshot
Computational Study of Metal–Dinitrogen Keggin-Type Polyoxometalate Complexes [PW11O39MIIN2)]5– (M = Ru, Os, Re, Ir): Bonding Nature and Dinitrogen Splitting
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b01962openalex-snapshot
Heterobimetallic Ti/Co Complexes That Promote Catalytic N–N Bond Cleavage
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b02124openalex-snapshot
Preface for Small-Molecule Activation: From Biological Principles to Energy Applications. Part 2: Small Molecules Related to the Global Nitrogen Cycle
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b02841openalex-snapshot
Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b02908openalex-snapshot
Electronic Structures of the [Fe(N2)(SiPiPr3)]+1/0/–1 Electron Transfer Series: A Counterintuitive Correlation between Isomer Shifts and Oxidation States
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c03810openalex-snapshot
Nickel Incorporation into Fresh Iron Sulfide Precipitates Modulates Selectivity in Nitrite, Carbon Dioxide, and Proton Reduction
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6b02813openalex-snapshot
Dangling and Hydrolyzed Ligand Arms in [Mn3] and [Mn6] Coordination Assemblies: Synthesis, Characterization, and Functional Activity
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b00512openalex-snapshot
Spectroscopic and Computational Studies of Spin States of Iron(IV) Nitrido and Imido Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.8b02433openalex-snapshot
Requirements for Lewis Acid-Mediated Capture and N–N Bond Cleavage of Hydrazine at Iron
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.9b01672openalex-snapshot
Electronic and Structural Comparisons between Iron(II/III) and Ruthenium(II/III) Imide Analogs
inferred← citeshttps://doi.org/10.1021/acs.jpca.8b02089openalex-snapshot
Efficient Nitrogen Fixation via a Redox-Flexible Single-Iron Site with Reverse-Dative Iron → Boron σ Bonding
inferred← citeshttps://doi.org/10.1021/acs.jpcc.6b02821openalex-snapshot
Interaction of Iron–Sulfur Clusters with N2: Biomimetic Systems in the Gas Phase
inferred← citeshttps://doi.org/10.1021/acs.organomet.0c00471openalex-snapshot
Coordination-Induced N–H Bond Weakening in a Molybdenum Pyrrolidine Complex: Isotopic Labeling Provides Insight into the Pathway for H2 Evolution
inferred← citeshttps://doi.org/10.1021/acs.organomet.5b00391openalex-snapshot
Synthesis and Protonation of N-Heterocyclic-Carbene-Supported Dinitrogen Complexes of Molybdenum(0)
inferred← citeshttps://doi.org/10.1021/acsami.0c06744openalex-snapshot
High-Performance Electrocatalytic Conversion of N2 to NH3 Using 1T-MoS2 Anchored on Ti3C2 MXene under Ambient Conditions
inferred← citeshttps://doi.org/10.1021/acsanm.0c02380openalex-snapshot
Theoretical Screening of Single Atoms Supported on Two-Dimensional Nb2CN2 for Nitrogen Fixation
inferred← citeshttps://doi.org/10.1021/acscatal.3c02410openalex-snapshot
Enroute to the Carbon-Neutrality Goals via the Targeted Development of Ammonia as a Potential Nitrogen-Based Energy Carrier
inferred← citeshttps://doi.org/10.1021/acscatal.7b00439openalex-snapshot
Photon-Driven Nitrogen Fixation: Current Progress, Thermodynamic Considerations, and Future Outlook
inferred← citeshttps://doi.org/10.1021/acscatal.8b01232openalex-snapshot
Adlayer Dynamics Drives CO Activation in Ru-Catalyzed Fischer–Tropsch Synthesis
inferred← citeshttps://doi.org/10.1021/acscatal.9b02741openalex-snapshot
Homogeneous Metallic Oligomer Catalyst with Multisite Intramolecular Cooperativity for the Synthesis of CO2-Based Polymers
inferred← citeshttps://doi.org/10.1021/acsnano.6b06472openalex-snapshot
Photoprompted Hot Electrons from Bulk Cross-Linked Graphene Materials and Their Efficient Catalysis for Atmospheric Ammonia Synthesis
inferred← citeshttps://doi.org/10.1021/acsomega.1c03715openalex-snapshot
EDA–NOCV Calculation for Efficient N2 Binding to the Reduced Ni3S8 Complex: Estimation of Ni–N2 Intrinsic Interaction Energies
inferred← citeshttps://doi.org/10.1021/acsomega.1c05238openalex-snapshot
Estimations of Fe–N2 Intrinsic Interaction Energies of Iron–Sulfur/Nitrogen–Carbon Sites: A Deeper Bonding Insight by EDA-NOCV Analysis of a Model Complex of the Nitrogenase Cofactor
inferred← citeshttps://doi.org/10.1021/acsomega.2c04472openalex-snapshot
Dinitrogen Binding and Activation: Bonding Analyses of Stable V(III/I)–N2–V(III/I) Complexes by the EDA–NOCV Method from the Perspective of Vanadium Nitrogenase
inferred← citeshttps://doi.org/10.1021/acssuschemeng.1c01208openalex-snapshot
Enhanced Photofixation of Dinitrogen to Ammonia over a Biomimetic Metal (Fe,Mo)-Doped Mesoporous MCM-41 Zeolite Catalyst under Ambient Conditions
inferred← citeshttps://doi.org/10.1021/acssuschemeng.2c06460openalex-snapshot
Work Function-Tailored Nitrogenase-like Fe Double-Atom Catalysts on Transition Metal Dichalcogenides for Nitrogen Fixation
inferred← citeshttps://doi.org/10.1021/acssuschemeng.7b01912openalex-snapshot
Enhanced Nitrogen Photofixation over LaFeO3 via Acid Treatment
inferred← citeshttps://doi.org/10.1021/ar900254xopenalex-snapshot
Decoding the Nitrogenase Mechanism: The Homologue Approach
inferred← citeshttps://doi.org/10.1021/bi400834aopenalex-snapshot
Use of Electron Paramagnetic Resonance To Solve Biochemical Problems
inferred← citeshttps://doi.org/10.1021/bi901092zopenalex-snapshot
Trapping an Intermediate of Dinitrogen (N2) Reduction on Nitrogenase
inferred← citeshttps://doi.org/10.1021/cr100085kopenalex-snapshot
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications
inferred← citeshttps://doi.org/10.1021/cr300463yopenalex-snapshot
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
inferred← citeshttps://doi.org/10.1021/cr400461popenalex-snapshot
Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase
inferred← citeshttps://doi.org/10.1021/cr400641xopenalex-snapshot
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage
inferred← citeshttps://doi.org/10.1021/ic1015884openalex-snapshot
Electronic Dimensions of FeMo-co, the Active Site of Nitrogenase, and Its Catalytic Intermediates
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