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Probing the Degradation Mechanism of Li2MnO3 Cathode for Li-Ion Batteries

https://doi.org/10.1021/cm504257m
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/adma.200904247openalex-snapshot
Local Structure of Layered Oxide Electrode Materials for Lithium‐Ion Batteries
inferredcites →https://doi.org/10.1002/aenm.201200842openalex-snapshot
Atomic Structure of Li2MnO3 after Partial Delithiation and Re‐Lithiation
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Understanding the Rate Capability of High‐Energy‐Density Li‐Rich Layered Li 1.2 Ni 0.15 Co 0.1 Mn 0.55 O 2 Cathode Materials
inferredcites →https://doi.org/10.1002/aenm.201300998openalex-snapshot
Structural Changes in Li2MnO3 Cathode Material for Li‐Ion Batteries
inferredcites →https://doi.org/10.1002/anie.201201429openalex-snapshot
Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors
inferredcites →https://doi.org/10.1002/anie.201301236openalex-snapshot
Direct Atomic‐Resolution Observation of Two Phases in the Li 1.2 Mn 0.567 Ni 0.166 Co 0.067 O 2 Cathode Material for Lithium‐Ion Batteries
inferredcites →https://doi.org/10.1016/j.elecom.2013.08.022openalex-snapshot
Comments on stabilizing layered manganese oxide electrodes for Li batteries
inferredcites →https://doi.org/10.1016/j.jpowsour.2005.03.104openalex-snapshot
Overcharging manganese oxides: Extracting lithium beyond Mn4+
inferredcites →https://doi.org/10.1016/j.jpowsour.2013.11.103openalex-snapshot
Review on recent progress of nanostructured anode materials for Li-ion batteries
inferredcites →https://doi.org/10.1016/s0079-6786(97)81003-5openalex-snapshot
Manganese oxides for lithium batteries
inferredcites →https://doi.org/10.1016/s0378-7753(99)00066-xopenalex-snapshot
Lithium metal rechargeable cells using Li2MnO3 as the positive electrode
inferredcites →https://doi.org/10.1016/s0968-4328(99)00139-0openalex-snapshot
EELS analysis of cation valence states and oxygen vacancies in magnetic oxides
inferredcites →https://doi.org/10.1021/am404963uopenalex-snapshot
Nanoscale Lamellar Monoclinic Li2MnO3 Phase with Stacking Disordering in Lithium-Rich and Oxygen-Deficient Li1.07Mn1.93O4−δ Cathode Materials
inferredcites →https://doi.org/10.1021/cm030047uopenalex-snapshot
Mechanism of Electrochemical Activity in Li2MnO3
inferredcites →https://doi.org/10.1021/cm200250aopenalex-snapshot
Long-Range and Local Structure in the Layered Oxide Li1.2Co0.4Mn0.4O2
inferredcites →https://doi.org/10.1021/cm200831copenalex-snapshot
Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of a Solid Solution
inferredcites →https://doi.org/10.1021/cm2026703openalex-snapshot
Designing High-Capacity, Lithium-Ion Cathodes Using X-ray Absorption Spectroscopy
inferredcites →https://doi.org/10.1021/cm3027219openalex-snapshot
Density Functional Investigation on Li2MnO3
inferredcites →https://doi.org/10.1021/cm4000119openalex-snapshot
Correlation Between Oxygen Vacancy, Microstrain, and Cation Distribution in Lithium-Excess Layered Oxides During the First Electrochemical Cycle
inferredcites →https://doi.org/10.1021/cm4009392openalex-snapshot
Nanoscale Phase Separation, Cation Ordering, and Surface Chemistry in Pristine Li1.2Ni0.2Mn0.6O2for Li-Ion Batteries
inferredcites →https://doi.org/10.1021/cm801245ropenalex-snapshot
Synthesis, Characterization and Electrochemistry of Lithium Battery Electrodes: x Li 2 MnO 3 ·(1 − x )LiMn 0.333 Ni 0.333 Co 0.333 O 2 (0 ≤ x ≤ 0.7)
inferredcites →https://doi.org/10.1021/ja062027+openalex-snapshot
Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni 0.2 Li 0.2 Mn 0.6 ]O 2
inferredcites →https://doi.org/10.1021/ja108588yopenalex-snapshot
Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li 2 MnO 3 −LiCo 1/3 Ni 1/3 Mn 1/3 O 2
inferredcites →https://doi.org/10.1021/jz400032vopenalex-snapshot
High-Energy Cathode Materials (Li 2 MnO 3 –LiMO 2 ) for Lithium-Ion Batteries
inferredcites →https://doi.org/10.1021/nl500486yopenalex-snapshot
Mitigating Voltage Fade in Cathode Materials by Improving the Atomic Level Uniformity of Elemental Distribution
inferredcites →https://doi.org/10.1021/nl5038598openalex-snapshot
Evolution of Lattice Structure and Chemical Composition of the Surface Reconstruction Layer in Li1.2Ni0.2Mn0.6O2 Cathode Material for Lithium Ion Batteries
inferredcites →https://doi.org/10.1021/nn305065uopenalex-snapshot
Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries
inferredcites →https://doi.org/10.1038/35104644openalex-snapshot
Issues and challenges facing rechargeable lithium batteries
inferredcites →https://doi.org/10.1038/ncomms4529openalex-snapshot
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries
inferredcites →https://doi.org/10.1038/srep03094openalex-snapshot
High rate capability caused by surface cubic spinels in Li-rich layer-structured cathodes for Li-ion batteries
inferredcites →https://doi.org/10.1039/b417616mopenalex-snapshot
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
inferredcites →https://doi.org/10.1039/c1ee01131fopenalex-snapshot
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study
inferredcites →https://doi.org/10.1039/c2jm31286gopenalex-snapshot
Hollow core–shell structured porous Si–C nanocomposites for Li-ion battery anodes
inferredcites →https://doi.org/10.1039/c3ra41653dopenalex-snapshot
Improved electrochemical properties of Li[Li0.2Ni0.17Mn0.56Co0.07]O2 cathode material via micro-structural rearrangement
inferredcites →https://doi.org/10.1039/c3ta11040kopenalex-snapshot
Self-adjusted oxygen-partial-pressure approach to the improved electrochemical performance of electrode Li[Li0.14Mn0.47Ni0.25Co0.14]O2 for lithium-ion batteries
inferredcites →https://doi.org/10.1039/c4cp01799dopenalex-snapshot
Uncovering the roles of oxygen vacancies in cation migration in lithium excess layered oxides
inferredcites →https://doi.org/10.1039/c4cp02795gopenalex-snapshot
Migration of Mn cations in delithiated lithium manganese oxides
inferredcites →https://doi.org/10.1126/science.1246432openalex-snapshot
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries
inferredcites →https://doi.org/10.1149/1.1368896openalex-snapshot
Layered-to-Spinel Phase Transition in Li[sub x]MnO[sub 2]
inferredcites →https://doi.org/10.1149/1.1407994openalex-snapshot
Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries
inferredcites →https://doi.org/10.1149/1.3110803openalex-snapshot
Electrochemical Activities in Li[sub 2]MnO[sub 3]
inferredcites →https://doi.org/10.1149/2.034311jesopenalex-snapshot
Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density
inferredcites →https://doi.org/10.1149/2.080206jesopenalex-snapshot
Countering the Voltage Decay in High Capacity xLi2MnO3•(1–x)LiMO2Electrodes (M=Mn, Ni, Co) for Li+-Ion Batteries

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Disordered Cubic Spinel Structure in the Delithiated Li2MnO3 Revealed by Difference Pair Distribution Function Analysis
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X-Ray Absorption Spectroscopy Illustrates the Participation of Oxygen in the Electrochemical Cycling of Li4mn2o5
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Unveiling the Role of Oxygen Vacancy in Li2MnO3 upon Delithiation
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Impact of Stacking Faults and Li Substitution in LixMnO3 (0 ≤ x ≤ 2) Structural Transformations upon Delithiation
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Operando EPR for Simultaneous Monitoring of Anionic and Cationic Redox Processes in Li-Rich Metal Oxide Cathodes
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Tailoring Anisotropic Li-Ion Transport Tunnels on Orthogonally Arranged Li-Rich Layered Oxide Nanoplates Toward High-Performance Li-Ion Batteries
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Impact of Oxygen Defects on Electrochemical Processes and Charge Compensation of Li-Rich Cathode Material Li 1.2 Mn 0.6 Ni 0.2 O 2−δ
inferred← citeshttps://doi.org/10.1021/acsaem.3c00630openalex-snapshot
Effects of Ball Milling on the Electrochemical Capacity and Interfacial Stability of Li2MnO3 Cathode Materials
inferred← citeshttps://doi.org/10.1021/acsaem.8b00812openalex-snapshot
Optimizing the Structural Evolution of Li-Rich Oxide Cathode Materials via Microwave-Assisted Pre-Activation
inferred← citeshttps://doi.org/10.1021/acsami.0c10768openalex-snapshot
Cation-Disorder-Assisted Reversible Topotactic Phase Transition between Antifluorite and Rocksalt Toward High-Capacity Lithium-Ion Batteries
inferred← citeshttps://doi.org/10.1021/acsami.2c15054openalex-snapshot
Understanding the Effects of Tetrahedral Site Occupancy by the Zn Dopant in Li-NMCs toward High-Voltage Compositional–Structural–Mechanical Stability via Operando and 3D Atom Probe Tomography Studies
inferred← citeshttps://doi.org/10.1021/acsami.4c10466openalex-snapshot
Insights from Ab Initio Molecular Dynamics on the Interface Reaction between Electrolyte and Li2MnO3 Cathode during the Charging Process
inferred← citeshttps://doi.org/10.1021/acsami.6b06733openalex-snapshot
Mitigating Voltage Decay of Li-Rich Cathode Material via Increasing Ni Content for Lithium-Ion Batteries
inferred← citeshttps://doi.org/10.1021/acsami.6b07259openalex-snapshot
Surface Morphology and Surface Stability against Oxygen Loss of the Lithium-Excess Li2MnO3 Cathode Material as a Function of Lithium Concentration
inferred← citeshttps://doi.org/10.1021/acsami.9b20754openalex-snapshot
Influence of Synthesis Routes on the Crystallography, Morphology, and Electrochemistry of Li 2 MnO 3
inferred← citeshttps://doi.org/10.1021/acsenergylett.1c00203openalex-snapshot
An Overview of Cation-Disordered Lithium-Excess Rocksalt Cathodes
inferred← citeshttps://doi.org/10.1021/acsenergylett.2c02507openalex-snapshot
Stabilizing a Li–Mn–O Cathode by Blocking Lattice O Migration through a Nanoscale Phase Complex
inferred← citeshttps://doi.org/10.1021/acsenergylett.4c01129openalex-snapshot
High Entropy Oxides: Mapping the Landscape from Fundamentals to Future Vistas
inferred← citeshttps://doi.org/10.1021/acsenergylett.9b02799openalex-snapshot
Quantifying the Capacity Contributions during Activation of Li 2 MnO 3
inferred← citeshttps://doi.org/10.1021/acssuschemeng.9b01719openalex-snapshot
Simple Water Treatment Strategy To Optimize the Li2MnO3 Activation of Lithium-Rich Cathode Materials
inferred← citeshttps://doi.org/10.1021/jacs.2c02927openalex-snapshot
17O NMR Spectroscopy in Lithium-Ion Battery Cathode Materials: Challenges and Interpretation
inferred← citeshttps://doi.org/10.1038/ncomms13598openalex-snapshot
A stable lithium-rich surface structure for lithium-rich layered cathode materials
inferred← citeshttps://doi.org/10.1038/ncomms14101openalex-snapshot
Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries
inferred← citeshttps://doi.org/10.1038/ncomms9014openalex-snapshot
Visualizing nanoscale 3D compositional fluctuation of lithium in advanced lithium-ion battery cathodes
inferred← citeshttps://doi.org/10.1038/s41467-018-05802-4openalex-snapshot
Understanding voltage decay in lithium-excess layered cathode materials through oxygen-centred structural arrangement
inferred← citeshttps://doi.org/10.1038/s41467-020-17126-3openalex-snapshot
Highly reversible oxygen redox in layered compounds enabled by surface polyanions
inferred← citeshttps://doi.org/10.1038/s41467-020-18285-zopenalex-snapshot
Dislocation and oxygen-release driven delithiation in Li2MnO3
inferred← citeshttps://doi.org/10.1038/s41560-019-0508-xopenalex-snapshot
Gradient Li-rich oxide cathode particles immunized against oxygen release by a molten salt treatment
inferred← citeshttps://doi.org/10.1039/c5ra28082fopenalex-snapshot
Improvement of the cyclic deterioration and structural evolution of Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2 cathode material by controlling initial charging voltages
inferred← citeshttps://doi.org/10.1039/c6cp00088fopenalex-snapshot
Underlying mechanisms of the synergistic role of Li 2 MnO 3 and LiNi 1/3 Co 1/3 Mn 1/3 O 2 in high-Mn, Li-rich oxides
inferred← citeshttps://doi.org/10.1039/c6ta11151copenalex-snapshot
Direct observation of layered-to-spinel phase transformation in Li 2 MnO 3 and the spinel structure stabilised after the activation process
inferred← citeshttps://doi.org/10.1039/c7ta03049eopenalex-snapshot
Structural transformations in Li 2 MnSiO 4 : evidence that a Li intercalation material can reversibly cycle through a disordered phase
inferred← citeshttps://doi.org/10.1039/c7ta05971jopenalex-snapshot
Insights into the stable layered structure of a Li-rich cathode material for lithium-ion batteries
inferred← citeshttps://doi.org/10.1039/c7ta07659bopenalex-snapshot
Mitigating the capacity and voltage decay of lithium-rich layered oxide cathodes by fabricating Ni/Mn graded surface
inferred← citeshttps://doi.org/10.1039/c7ta10887gopenalex-snapshot
A novel strategy to significantly enhance the initial voltage and suppress voltage fading of a Li- and Mn-rich layered oxide cathode material for lithium-ion batteries
inferred← citeshttps://doi.org/10.1039/c8cp02492hopenalex-snapshot
Polyhedral perspectives on the capacity limit of cathode compounds for lithium-ion batteries: a case study for Li 6 CoO 4
inferred← citeshttps://doi.org/10.1039/c8cp03390kopenalex-snapshot
Systematic analysis of electron energy-loss near-edge structures in Li-ion battery materials
inferred← citeshttps://doi.org/10.1039/c8cp04181dopenalex-snapshot
Enhanced electrochemical performance of Li-rich cathode materials through microstructural control
inferred← citeshttps://doi.org/10.1039/c8me00025eopenalex-snapshot
Li- and Mn-rich layered oxide cathode materials for lithium-ion batteries: a review from fundamentals to research progress and applications
inferred← citeshttps://doi.org/10.1039/c8ta11807hopenalex-snapshot
Improving the oxygen redox stability of NaCl-type cation disordered Li 2 MnO 3 in a composite structure of Li 2 MnO 3 and spinel-type LiMn 2 O 4
inferred← citeshttps://doi.org/10.1039/d0ma00395fopenalex-snapshot
Universal solid-state oxygen redox in antifluorite lithium oxides via transition metal doping
inferred← citeshttps://doi.org/10.1039/d0ta05101bopenalex-snapshot
Suppression of voltage-decay in Li 2 MnO 3 cathode via reconstruction of layered-spinel coexisting phases
inferred← citeshttps://doi.org/10.1039/d1qi00896jopenalex-snapshot
Anionic redox behaviors of layered Li-rich oxide cathodes
inferred← citeshttps://doi.org/10.1039/d1ta00108fopenalex-snapshot
Optimized electron occupancy of solid-solution transition metals for suppressing the oxygen evolution of Li 2 MnO 3
inferred← citeshttps://doi.org/10.1039/d3cp01935gopenalex-snapshot
Highly activated oxygen redox enabling large-capacity Li-rich layered manganese-based oxide cathodes
inferred← citeshttps://doi.org/10.1039/d3ee04199aopenalex-snapshot
Multi-angle tracking synthetic kinetics of phase evolution in Li-rich Mn-based cathodes
inferred← citeshttps://doi.org/10.1039/d3sc03220eopenalex-snapshot
Layered transition metal oxides (LTMO) for oxygen evolution reactions and aqueous Li-ion batteries
inferred← citeshttps://doi.org/10.1039/d3ta06692dopenalex-snapshot
The grain morphology and surface properties of a Li-rich Li 2 MnO 3 cathode material: a first-principles study
inferred← citeshttps://doi.org/10.1039/d4ra06047dopenalex-snapshot
Enhancing the capacity of Mn-rich cathodes by kinetics control for lithium-ion batteries
inferred← citeshttps://doi.org/10.1039/d4ta04598jopenalex-snapshot
Insights into the interface reaction between electrolyte and Li 2 MnO 3 from ab initio molecular dynamics simulations
inferred← citeshttps://doi.org/10.1039/d5ta03794hopenalex-snapshot
Demystifying charge-compensation mechanisms and oxygen dimerization in Li-rich Li 2 NiO 3 cathodes
inferred← citeshttps://doi.org/10.1039/d5ta04998aopenalex-snapshot
Strain regulation of microscopic processes in lithium-rich cathodes: thermodynamics and kinetics
inferred← citeshttps://doi.org/10.1063/1.4963379openalex-snapshot
A valence state evaluation of a positive electrode material in an Li-ion battery with first-principles K- and L-edge XANES spectral simulations and resonance photoelectron spectroscopy
inferred← citeshttps://doi.org/10.1088/0256-307x/38/6/068202openalex-snapshot
LiCoO2 Epitaxial Film Enabling Precise Analysis of Interfacial Degradations
inferred← citeshttps://doi.org/10.1088/1361-6463/aa6245openalex-snapshot
Plasma processes in the preparation of lithium-ion battery electrodes and separators
inferred← citeshttps://doi.org/10.1088/1674-1056/27/6/066107openalex-snapshot
Scanning transmission electron microscopy: A review of high angle annular dark field and annular bright field imaging and applications in lithium-ion batteries
inferred← citeshttps://doi.org/10.1093/jmicro/dfag034openalex-snapshot
Atomic-scale STEM characterization of Li-ion battery materials using orientation-controlled single-crystalline specimens
inferred← citeshttps://doi.org/10.1093/nsr/nwaf202openalex-snapshot
Revealing the chemical separated two-phase structure in lithium-manganese-rich cathode
inferred← citeshttps://doi.org/10.1149/2.0111514jesopenalex-snapshot
Review—Li-Rich Layered Oxide Cathodes for Next-Generation Li-Ion Batteries: Chances and Challenges
inferred← citeshttps://doi.org/10.1149/2.0261802jesopenalex-snapshot
Interfacial Atomic Structures of Single-Phase Li2MnO3Thin Film with Superior Initial Charge-Discharge Behavior
inferred← citeshttps://doi.org/10.1149/2.0351701jesopenalex-snapshot
Review—Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes
inferred← citeshttps://doi.org/10.1149/2.0461701jesopenalex-snapshot
Review—Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes
inferred← citeshttps://doi.org/10.20964/2016.07.35openalex-snapshot
One-step Synthesis of Low-cost and High Active LiMnO Cathode Materials
inferred← citeshttps://doi.org/10.2109/jcersj2.25040openalex-snapshot
Advanced positive electrode materials for lithium-ion batteries
inferred← citeshttps://doi.org/10.3390/ma13010040openalex-snapshot
Effect of Different Composition on Voltage Attenuation of Li-Rich Cathode Material for Lithium-Ion Batteries
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