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The chemistry of .beta.-enaminonitriles as versatile reagents in heterocyclic synthesis

https://doi.org/10.1021/cr00022a002
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1,6‐Electrocyclization of 1‐Azatriene Derivatives
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Knoevenagel reaction of malononitrile with methyl ketone followed by double cyclization catalyzed by potassium fluoride‐coated alumina
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Synthesis of dihydrothieno[2,3‐b]pyridines based on titanium(IV) chloride‐mediated michael reactions of 2‐amino‐4,5‐dihydro‐3‐thiophenecarbonitriles with α,β‐unsaturated ketones
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Synthesis and Reactivity of Copper and Copper Containing Magnetically Separable Catalysts
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Late‐Stage Borylation Strategy for the Development of New Boron‐Based Retinoids
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Chemie der Enole und Enamine
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Syntheses with heterocyclic ?-enaminonitriles: An expeditious synthetic approach to polyfunctionally substituted 5-phenylsulfonylthiophenes and their fused derivatives
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[3+3] Cyclocondensation of 1-alkyl-substituted 3,4-dihydroisoquinolines with 2-aminomethylenecycloalkane-1,3-diones or aminomethylene malonates: A novel annelation reaction in the series of cyclic Schiff's bases
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Synthesis and evaluation of antimicrobial activity of 2-aminobenzothiazolomethyl naphthol derivatives
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One-pot synthesis of 2H-pyrano[2,3-d]pyrimidine derivatives
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Reactions of 2-(2-hetaryl)-2-(tetrahydrofuran-2-ylidene)acetonitriles with tertiary amines
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Heterocyclization reactions using malononitrile dimer (2-aminopropene-1,1,3-tricarbonitrile)
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3-Amino-4-(1-amino-2-cyanovinyl)furazans: synthesis and cyclization
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Recent progress of isocyanide-based multicomponent reactions in Iran
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Heterocyclizations of 2-aryl-3-arylamino-4,4,4-trifluoro-2-butenenitrile hydrates to 3-aryl-2-trifluoromethyl-4-quinolones and to 4-N-methylamino-3H-pyrazole-3-spiro-2′-(3′-aryl-3′-trifluoromethyl)oxiranes
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Acid catalysed enamine induced transformations of 1,3-dimethyl-5-formyluracil. A unique annulation reaction with enaminones
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A ready one-pot preparation for 7-oxa(or thia)-3,4,6-triazabenz[d,e]anthracene and 7-oxa-3,4,6,9-tetrazabenz[d,e]anthracene derivatives
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α,β-Unsaturated and Aryl Nitriles
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α,β-Unsaturated and Aryl Nitriles
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Four-coordinate organoboron compounds from β-enaminonitriles and diazonium salts
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Yb(OTf)3-catalyzed cyclization of an N-silylenamine with 2-methylene-1,3-cyclohexanedione to afford a 7,8-dihydroquinolin-5(6H)-one derivative and its application to the one-pot conversion to a 2,3,5-trisubstituted quinoline derivative
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“Clip-cycle” synthesis of 2-pyridazinones bearing enaminonitrile moiety from thioesters and dicyanohydrazones
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N-substituted pyrrolinones from enamines and α-dicarbonyls
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Structural sensitivity in phosphorylation of enamines—derivatives of β-aminocrotonic acid with diphenylchlorophosphine
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Enamines as Synthons in the Synthesis of Heterocycles
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The Literature of Heterocyclic Chemistry, Part V
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6-Dimethylamino 1H-Pyrazolo[3,4-d]pyrimidine derivatives as new inhibitors of inflammatory mediators in intact cells
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Selective oligomerization of nitriles having α-hydrogen catalyzed by alkali
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Synthesis of Substituted Pyridines via Formal (3+3) Cycloaddition of Enamines with Unsaturated Aldehydes and Ketones
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Facile Synthesis of 2-Methylnicotinonitrile through Degenerate Ring Transformation of Pyridinium Salts
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Metal- and Solvent-Free Synthesis of Substituted Pyrimidines via an NH4I-Promoted Three-Component Tandem Reaction
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Cu-Catalyzed Highly Selective Ritter-Type Reaction of Enaminonitriles with Cycloketoxime Esters: A Direct Route to Diverse α-Tertiary Amines
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Ambient-Light-Promoted Three-Component Annulation: Synthesis of Perfluoroalkylated Pyrimidines
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Annulation of β-Enaminonitriles with Alkynes via Rh III -Catalyzed C–H Activation: Direct Access to Highly Substituted 1-Naphthylamines and Naphtho[1,8- bc ]pyridines
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Novel Multicomponent Synthesis of Pyridine–Pyrimidines and Their Bis-Derivatives Catalyzed by Triazine Diphosphonium Hydrogen Sulfate Ionic Liquid Supported on Functionalized Nanosilica
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Novel Isocyanide-Based Three-Component One-Pot Synthesis of Cyanophenylamino-acetamide Derivatives
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Microwave-Assisted Combinatorial Synthesis of New 3-Pyrimidin-5-ylpropanamides via a Solvent-Dependent Chemoselective Reaction
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Crystallographic/Experimental Electron Density Characterizations and Reactions with Nucleophiles of β-Enaminonitriles Possessing a Pyrrolobenzazepine Core
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Direct Synthesis of Polysubstituted Quinoline Derivatives by InBr3-Promoted Dimerization of 2-Ethynylaniline Derivatives
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Stereoselective and Catalytic Access to β-Enaminones: An Entry to Pyrimidines
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InBr3-Promoted Divergent Approach to Polysubstituted Indoles and Quinolines from 2-Ethynylanilines: Switch from an Intramolecular Cyclization to an Intermolecular Dimerization by a Type of Terminal Substituent Group
inferred← citeshttps://doi.org/10.1021/jo801090hopenalex-snapshot
Me3SiCl-Promoted Three-Component Coupling Reaction of a Functionalized Enamine, an Acetal, and an Alkyne: An Unprecedented Approach to the Synthesis of Tetrasubstituted Pyridines via a [3 + 2 + 1] Intermolecular Cyclization
inferred← citeshttps://doi.org/10.1021/jo990313gopenalex-snapshot
A Simple and Versatile Route to Novel Conjugated β-Enaminonitriles and Their Application for the Highly Regioselective Synthesis of Nicotinonitriles Using a Vilsmeier-Type Reagent
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New Approach to the Practical Synthesis of Tri- or Tetrasubstituted Pyrimidine Derivatives: A Four-Component Coupling Reaction from a Functionalized Silane, Two Types of Aromatic Nitriles, and Acetals
inferred← citeshttps://doi.org/10.1021/ol052994+openalex-snapshot
One-Step, Three-Component Synthesis of Pyridines and 1,4-Dihydropyridines with Manifold Medicinal Utility
inferred← citeshttps://doi.org/10.1021/ol900382jopenalex-snapshot
An Unprecedented Approach to 4,5-Disubstituted Pyrimidine Derivatives by a ZnCl2-Catalyzed Three-Component Coupling Reaction
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Amino Effect on the Protonation of β-Aminoacrylonitrile
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Synthesis of Enamino Nitrile of a New Type, 2-Hetaryl-2-(2-pyrrolidinylidene)acetonitriles, and Their Tautomerism
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Synthesis of pyrimidines by direct condensation of amides and nitriles
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Synthesis of 2,3,4,6-Tetrasubstituted Pyridines as Precursors to Bicycles and Polycycles
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Heterocyclic sulfones. Part IV. A novel synthesis of pyrrole and fused heterocyclic sulfones
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Synthesis of novel 5-amino-6-ethoxy-2-alkylpyrimidine-4-carbonitriles
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A supported palladium nanocatalyst for copper free acyl Sonogashira reactions: One-pot multicomponent synthesis of N-containing heterocycles
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Anchored palladium nanoparticles onto single walled carbon nanotubes: Efficient recyclable catalyst for N-containing heterocycles
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An efficient synthetic route to carbocyclic enaminonitriles via Lewis acid catalysed domino-ring-opening-cyclisation (DROC) of donor–acceptor cyclopropanes with malononitrile
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Sc(OTf) 3 -mediated 1,3-dipolar cycloaddition–ring cleavage–rearrangement: a highly stereoselective access to Z-β-enaminonitriles
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The synthesis of carbonyl 2-amino-pyrimidines via tandem regioselective heterocyclization of 1,3-diynes with guanidine and selective oxidation
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Direct access to pyrimidines through organocatalytic inverse-electron-demand Diels–Alder reaction of ketones with 1,3,5-triazine
inferred← citeshttps://doi.org/10.1039/c5ra24292dopenalex-snapshot
KO t Bu-promoted synthesis of multi-substituted 4-aminopyrimidines from benzonitriles and aliphatic amides
inferred← citeshttps://doi.org/10.1039/c5ra26931hopenalex-snapshot
Acid-promoted rapid solvent-free access to substituted 1,4-dihydropyridines from β-ketothioamides
inferred← citeshttps://doi.org/10.1039/c5ra27069copenalex-snapshot
Brønsted acid-promoted synthesis of common heterocycles and related bio-active and functional molecules
inferred← citeshttps://doi.org/10.1039/c6cc05304aopenalex-snapshot
An efficient construction of N,N-bicyclic pyrazolidinones comprising enaminonitriles via asymmetric [3+2] cycloaddition
inferred← citeshttps://doi.org/10.1039/c9nj05200copenalex-snapshot
Theoretical and experimental study of the coordination ability of 4,6-dimethylpyrimidinylhydrazone diacetylmonooxime towards Ni( ii ), Mn( ii ), Fe( iii ) and Co( iii ) ions
inferred← citeshttps://doi.org/10.1039/c9qo00619bopenalex-snapshot
Utilization of nitriles as the nitrogen source: practical and economical construction of 4-aminopyrimidine and β-enaminonitrile skeletons
inferred← citeshttps://doi.org/10.1039/c9ra10866aopenalex-snapshot
Temperature controlled condensation of nitriles: efficient and convenient synthesis of β-enaminonitriles, 4-aminopyrimidines and 4-amidinopyrimidines in one system
inferred← citeshttps://doi.org/10.1039/d2ra04936hopenalex-snapshot
Condensation of acrylonitrile and aryl acetonitrile: construction of α-amino-β-cyano cyclohexene skeletons
inferred← citeshttps://doi.org/10.1039/d3ob00915gopenalex-snapshot
Access to 2-pyridinones comprising enaminonitriles via AgOAc promoted cascade reactions of thioesters with aminomethylene malononitriles
inferred← citeshttps://doi.org/10.1039/d6gc01583bopenalex-snapshot
Sustainable photoelectrochemical activation of acetonitrile via transient alkynylnitrile intermediates
inferred← citeshttps://doi.org/10.1039/d6qo00022copenalex-snapshot
β- and Z -selective metal-free cyanation of ynamides: a direct approach to piperidines fused to arenes
inferred← citeshttps://doi.org/10.1039/p19950000417openalex-snapshot
Synthetic reactions of 2-(2-amino-3-cyano-4H-[1]benzopyran-4-yl)propane-1,3-dinitrile with reactive methylene compounds
inferred← citeshttps://doi.org/10.1080/00304940809458096openalex-snapshot
5-CARBETHOXY- AND 5-ACETYLPYRAZOLES AS PRECURSORS FOR THE SYNTHESIS OF SOME NOVEL 1-p-CHLOROPHENYLPYRAZOLE-3-CARBONITRILES
inferred← citeshttps://doi.org/10.1080/00397910701397144openalex-snapshot
Ultrasound‐Assisted Synthesis of β‐Enaminonitriles in the Presence of Base
inferred← citeshttps://doi.org/10.1080/00397911.2018.1484488openalex-snapshot
Mannich condensations of activated cyclic enamines
inferred← citeshttps://doi.org/10.1080/00397911.2019.1631347openalex-snapshot
Heterogeneous gold(I)-catalyzed cyclization between ynals and amidines: An efficient and practical synthesis of 2,4-disubstituted pyrimidines
inferred← citeshttps://doi.org/10.1080/10406638.2022.2094974openalex-snapshot
Baker’s Yeast Promoted One-Pot Synthesis of New 1,2,4-Triazolpyrimido-1,3,4-Oxadiazoles: Investigation of Antioxidant and Antimicrobial Activity
inferred← citeshttps://doi.org/10.1080/10406638.2022.2136214openalex-snapshot
Fe3O4/CuO/ZnO@MWCNT MNCs Promoted the Green Synthesis of Indenopyrimidin-1,2,4-Triazoles as Hybrid Molecules
inferred← citeshttps://doi.org/10.1080/10406638.2022.2162552openalex-snapshot
Baker’s Yeast Promoted Facile Synthesis of Spirooxadiazepines Using Multicomponent Reactions of Ninhydrin: Investigation of Biological Activity
inferred← citeshttps://doi.org/10.1080/10406638.2023.2249196openalex-snapshot
Synthesis of New Bioactive Triazolpyrimidine Derivatives Using Multicomponent Reactions of Hydrazonoyl Chloride
inferred← citeshttps://doi.org/10.1080/10426509408018390openalex-snapshot
1,2-DIHYDRO-2-(4-METHOXYPHENYL)-2-SULPHIDE-1,3,2-DIAZAPHOSPHORIN-4(3H)-THIONES FROM 3-AMINOPROPENENITRILE DERIVATIVES AND LA WESSON'S REAGENT
inferred← citeshttps://doi.org/10.1080/17415990600755131openalex-snapshot
β-Aminocrotononitrile in heterocyclic synthesis: Synthesis of polysubstituted pyridines as precursors to bicycles and polycycles
inferred← citeshttps://doi.org/10.1081/scc-100104407openalex-snapshot
RAPID AND EFFICIENT SYNTHESIS OF 2-[3-CYANO-4-(2-ARYLIDEN)-5, 5-DIMETHYL-5H-FURAN-2-YLIDENE]-MALONONITRILE UNDER FOCUSED MICROWAVE IRRADIATION
inferred← citeshttps://doi.org/10.1081/scc-120018775openalex-snapshot
Heterocyclic Synthesis with Activated Nitriles: An Expeditious Synthetic Approach to Polyfunctionally Substituted Pyrroles, Heterocyclopyrimidines and Coumarins
inferred← citeshttps://doi.org/10.1107/s0108270105016070openalex-snapshot
The twofold interpenetrated three-connected three-dimensional (10,3)-net in 2-aminoethene-1,1,2-tricarbonitrile
inferred← citeshttps://doi.org/10.1107/s1600536806043005openalex-snapshot
7-Amino-1-(3-bromophenyl)-3-cyanopyrazolo[4,3-d]pyrimidine
inferred← citeshttps://doi.org/10.1107/s1600536809001251openalex-snapshot
N-Cyclohexyl-3-(4-hydroxy-6-oxo-1,6-dihydropyrimidin-5-yl)-3-p-tolylpropanamide
inferred← citeshttps://doi.org/10.1107/s1600536809001391openalex-snapshot
N-Cyclopentyl-3-(4-hydroxy-6-oxo-1,6-dihydropyrimidin-5-yl)-3-p-tolylpropanamide
inferred← citeshttps://doi.org/10.1107/s1600536809003821openalex-snapshot
3-(4-Bromophenyl)-3-(4-hydroxy-6-oxo-1,6-dihydropyrimidin-5-yl)-N-[(S)-1-phenylethyl]propanamide
inferred← citeshttps://doi.org/10.1107/s1600536809004693openalex-snapshot
N-(1-Naphthyl)-10H-9-oxa-1,3-diazaanthracen-4-amine
inferred← citeshttps://doi.org/10.1107/s1600536809048338openalex-snapshot
(E)-2-(1,3-Diphenylallylidene)malononitrile
inferred← citeshttps://doi.org/10.1134/s1070363225601498openalex-snapshot
Synthesis, Structure, and Bromination of 3-(Arylamino)-2-(4-arylthiazol-2-yl)acrylonitriles
inferred← citeshttps://doi.org/10.1134/s1070428011050137openalex-snapshot
6,7-Dimethoxy-3,4-dihydroisoquinolin-1(2H)-ylidenoacetonitrile in some fusion reactions
inferred← citeshttps://doi.org/10.1134/s1070428017060124openalex-snapshot
Synthesis and solid-state fluorescence of 2-alkylamino-4-aminopyridine-3,5-dicarbonitriles
inferred← citeshttps://doi.org/10.1139/v05-143openalex-snapshot
One-pot conversion of β-aminocrotononitrile to secondary enaminonitriles including chiral ones Application to synthesis
inferred← citeshttps://doi.org/10.1177/10241221261446763openalex-snapshot
Antibacterial evaluation, quantum chemical computation, and pharmacological studies of some arylidenemalononitrile and ethyl 2-cyano-3-phenylacrylate derivatives: In vitro and in silico approach
inferred← citeshttps://doi.org/10.1177/174751989902300713openalex-snapshot
Synthesis of 2,3,4,6-Tetrasubstituted Pyridines as Precursors to Bicycles and Polycycles
inferred← citeshttps://doi.org/10.1246/bcsj.71.2387openalex-snapshot
An Easy Direct Conversion of Pyridine- and Pyrimidine-Thiones into Multi-Fused Heterocyclic Compounds
inferred← citeshttps://doi.org/10.17721/1728-2209.2025.1(60).12openalex-snapshot
C-NUCLEOPHILIC MODIFICATION OF 2-(4-OXO-3,4-DIHYDRO-2-QUINAZOLINYL)-2-(TETRAHYDRO-2-FURANYLIDENE)ACETORINTHRILES
inferred← citeshttps://doi.org/10.2174/138527211794519041openalex-snapshot
Recent Progress in the Synthesis and Applications of Heterocycles Derived from Enaminonitriles
inferred← citeshttps://doi.org/10.3184/030823404323000396openalex-snapshot
Synthesis of Novel Derivatives of 4-Amino-3,5-Dicyanopyrazole
inferred← citeshttps://doi.org/10.3389/fspas.2022.876870openalex-snapshot
Molecular Precursors of the RNA-World in Space: New Nitriles in the G+0.693−0.027 Molecular Cloud
inferred← citeshttps://doi.org/10.3390/ijms26157105openalex-snapshot
Facile Synthesis of Polysubstituted Pyridines via Metal-Free [3+3] Annulation Between Enamines and β,β-Dichloromethyl Peroxides
inferred← citeshttps://doi.org/10.3390/molecules16010298openalex-snapshot
A Route to Dicyanomethylene Pyridines and Substituted Benzonitriles Utilizing Malononitrile Dimer as a Precursor
inferred← citeshttps://doi.org/10.3390/photochem2020031openalex-snapshot
Phototransformations of 2,3-Diamino-2-Butenedinitrile (DAMN) Monomers Isolated in Low-Temperature Argon Matrix
inferred← citeshttps://doi.org/10.3987/com-06-10686openalex-snapshot
A Ready One-pot Preparation for Pteridine and Isoxazolo[3,4-d]pyrimidine Derivatives
inferred← citeshttps://doi.org/10.3987/com-07-11073openalex-snapshot
Chemistry of Nitroenamines. Synthesis of Pyrrolizine Derivatives
inferred← citeshttps://doi.org/10.3987/rev-21-973openalex-snapshot
A Comprehensive Study of Pyrimidine and Its Medicinal Applications
inferred← citeshttps://doi.org/10.4103/0975-7406.199337openalex-snapshot
Synthesis of some novel pyrazolo[3,4-d] pyrimidin-4(5H)-one derivatives as potential antimicrobial agent
inferred← citeshttps://doi.org/10.4236/ijoc.2011.14035openalex-snapshot
A Simple and Efficient Procedure for a 2-Pyridones Synthesis under Solvent-Free Conditions
inferred← citeshttps://doi.org/10.59287/as-proceedings.240openalex-snapshot
Insights into the Crystal Structure, Hirshfeld Surface, and Void Analysis of a Malononitrile Derivative Compound
inferred← citeshttps://doi.org/10.59287/as-proceedings.348openalex-snapshot
Quantum Chemical Insights into 2-[2-(Benzyloxy)benzylidene] malononitrile: DFT Analysis, MEP Surface Mapping, and HOMO-LUMO Energies
inferred← citeshttps://doi.org/10.70675/0530eba3z4f4fz4ad3z889bz0213651d162eopenalex-snapshot
Synthèse et application de synthons originaux de type 2-aminoacrylonitriles
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