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Apicularen A and B, Cytotoxic 10-Membered Lactones with a Novel Mechanism of Action fromChondromyces Species (Myxobacteria): Isolation, Structure Elucidation, and Biosynthesis
Chirale Lactole, II. Racematspaltung und enantioselektive Acetalisierung mit der 2,3,3a,4,5,6,7,7a‐Octahydro‐7,8,8‐trimethyl‐4,7‐methanobenzofuran‐2‐yl‐Schutzgruppe
Chirale Lactole, VII. O,O‐ und O,N‐Acetalbildungsreaktionen der enantiomerenreinen exo‐anellierten Octahydro‐7,8,8‐trimethyl‐4,7‐methanobenzofuran‐2‐ol‐Schutzgruppe
Nonreductive Enantioselective Ring Opening of N‐(Methylsulfonyl)dicarboximides with Diisopropoxytitanium α,α,α′,α′‐Tetraaryl‐1,3‐dioxolane‐4,5‐dimethanolate
Antibiotics from Gliding Bacteria, LXXVIII. Ripostatin A, B, and C: Isolation and Structure and Structure Elucidation of Novel Metabolites from Sorangium cellulosum
Use of shift reagent with diastereomeric MTPA esters for determination of configuration and enantiomeric purity of secondary carbinols in 1H NMR spectroscopy
Absolute stereostructure of a 2,3,7,13-tetrahydroxyoctadecanoic acid, the framework of taurolipid B produced by a fresh-water protozoan, Tetrahymena thermophila
(R)-O-Aryllactic acids: Convenient chiral solvating agents for direct 1H NMR determination of the enantiomeric composition of amines and amino alcohols
The unusual presence of hydroxylated furanosesquiterpenes in the deep ocean tunicate Ritterella rete. Chemical interconversions and absolute stereochemistry
Metabolites from the sponge Plakortis simplex. Determination of absolute stereochemistry of plakortin. Isolation and stereostructure of three plakortin related compounds
Strongylodiols A, B and C, new cytotoxic acetylenic alcohols isolated from the Okinawan marine sponge of the genus Strongylophora as each enantiomeric mixture with a different ratio
Use of shift reagent with MTPA derivatives in 1H NMR spectroscopy. III. Determination of absolute configuration and enantiomeric purity of primary carbinols with chiral center at the C-2 position
Use of shift reagent with MTPA derivatives in 1H NMR spectroscopy. II. determination of absolute configuration and diastereomeric composition of secondary carbinols in epimeric mixture
Directed resolution of enantiomers via liquid chromatography of diastereomeric derivatives III. A convenient method to determine the absolute configuration of carboxylic acids R1R2HCCOOH
Über eine neue methode zur bestimmung der absoluten konfiguration von chiralen sekundären alkoholen und aminen: nmr-spektroskopie von diastereomeren estern und amiden der α-phenylbutter- und hydratropasäure
Determination of the absolute configuration of linear secondary alcohols adopting one enantiomer of the chiral anisotropic reagents, methoxy-(1-and 2-naphthyl)acetic acids
2-Methoxy-2-(1-naphthyl)propionic acid, a powerful chiral auxiliary for enantioresolution of alcohols and determination of their absolute configurations by the 1H NMR anisotropy method
Determination of the enantiomeric purity and the configuration of β-aminoalcohols using (R)-2-fluorophenylacetic acid (AFPA) and fluorine-19 NMR: application to β-blockers
Absolute configurations of 2-methoxy-2-(1-naphthyl)propionic acid and 2-methoxy-2-(2-naphthyl)propionic acid as determined by the phenylglycine methyl ester (PGME) method
Determination of absolute configuration of stereogenic carbinol centers in annonaceous acetogenins by proton and fluorine 19-NMR analysis of Mosher ester derivatives
Structure determination, conformational analysis, chemical stability studies, and antitumor evaluation of the cryptophycins. Isolation of 18 new analogs from Nostoc sp. strain GSV 224
Determination of the absolute configuration of a secondary hydroxy group in a chiral secondary alcohol using glycosidation shifts in carbon-13 nuclear magnetic resonance spectroscopy
Additions and Corrections - Determination of the Absolute Configuration of a Secondary Hydroxy Group in a Chiral Secondary Alcohol Using Glycosidation Shifts in Carbon-13 Nuclear Magnetic Resonance Spectroscopy
Additions and Corrections - Determination of the Absolute Configuration of a Secondary Hydroxy Group in a Chiral Secondary Alcohol Using Glycosidation Shifts in Carbon-13 Nuclear Magnetic Resonance Spectroscopy
Nuclear magnetic resonance enantiomer regents. Configurational correlations via nuclear magnetic resonance chemical shifts of diastereomeric mandelate, O-methylmandelate, and .alpha.-methoxy-.alpha.-trifluoromethylphenylacetate (MTPA) esters
Nuclear magnetic resonance nonequivalence of diastereomeric esters of .alpha.-substituted phenylacetic acids for the determination of stereochemical purity
Are Both the (R)- and the (S)-MPA Esters Really Needed for the Assignment of the Absolute Configuration of Secondary Alcohols by NMR? The Use of a Single Derivative
Solid-State Nuclear Magnetic Resonance Spectroscopic and Quantum Chemical Investigation of 13C and 17O Chemical Shift Tensors, 17O Nuclear Quadrupole Coupling Tensors, and Bonding in Transition-Metal Carbonyl Complexes and Clusters
Fluorinated lactic acids: easily accessible reagents for the analysis of chiral compounds by fluorine-19 NMR spectroscopy. 19F NMR separation of the eight isomers of menthol
Chemistry of novel compounds with multifunctional carbon structure. 9. Molecular design, synthetic studies, and NMR investigation of several efficient chiral derivatizing reagents which give very large 19F NMR .DELTA..delta. values in enantiomeric excess determination
Protein tyrosine kinase inhibitory properties of planar polycyclics obtained from the marine sponge Xestospongia cf. carbonaria and from total synthesis
Determination of the absolute configuration of chiral secondary alcohols from tetra-O-acetylglucosidation-induced proton nuclear magnetic resonance shifts
Nuclear magnetic resonance determination of enantiomeric composition and absolute configuration of amines, alcohols, and thiols with .alpha.-[1-(9-anthryl)-2,2,2-trifluoroethoxy]acetic acid as a chiral derivatizing agent
Structure elucidation of (22E,24R,25R)-24-methyl-5α-cholest-22-ene-3β,4β,5,6α,8,14,15α,25,26-nonaol and (22E,24S)-24-methyl–5α-cholest-22-ene-3β,4β,5,6α,8,14,15α,25,28-nonaol, minor marine polyhydroxysteroids isolated from the starfish Archaster typicus
Identification of the Absolute Configuration of Pectenotoxin-6, a Polyether Macrolide Compound, by NMR Spectroscopic Method Using a Chiral Anisotropic Reagent, Phenylglycine Methyl Ester
Specialised metabolites as chemotaxonomic markers of Coptosapelta diffusa, supporting its delimitation as sisterhood phylogenetic relationships with Rubioideae
Determination of Absolute Configurations by Electronic CD Exciton Chirality, Vibrational CD, 1 H NMR Anisotropy, and X‐ray Crystallography Methods – Principles, Practices, and Reliability
A Three‐Step Chemoenzymatic Cascade Synthesis of Miconazole Analogues Based on the Asymmetric Synthesis of β‐Heteroaryl Amino Alcohols via Ketoreductases
Molekulare Grundlage für die Biosynthese von Elansolid: Beweise für eine einzigartige, durch ein Chinonmethid initiierte intramolekulare Diels‐Alder‐Cycloaddition/Makrolactonisierung
Molecular Basis of Elansolid Biosynthesis: Evidence for an Unprecedented Quinone Methide Initiated Intramolecular Diels–Alder Cycloaddition/Macrolactonization
PdII‐Catalyzed Domino Heterocyclization/Cross‐Coupling of α‐Allenols and α‐Allenic Esters: Efficient Preparation of Functionalized Buta‐1,3‐dienyl Dihydrofurans
Synthesis of Strained Tricyclic β‐Lactams by Intramolecular [2+2] Cycloaddition Reactions of 2‐Azetidinone‐Tethered Enallenols: Control of Regioselectivity by Selective Alkene Substitution
Preparation of α‐Aminobenzylphosphonic Acids with a Stereogenic Quaternary Carbon Atom via Microscopically Configurationally Stable α‐Aminobenzyllithiums
Metal‐Catalyzed Cyclization of β‐ and γ‐Allenols Derived from D ‐Glyceraldehyde—Synthesis of Enantiopure Dihydropyrans and Tetrahydrooxepines: An Experimental and Theoretical Study
Montecrinanes A–C: Triterpenes with an Unprecedented Rearranged Tetracyclic Skeleton from Celastrus vulcanicola. Insights into Triterpenoid Biosynthesis Based on DFT Calculations
Design of Selenium‐Based Chiral Chemical Probes for Simultaneous Enantio‐ and Chemosensing of Chiral Carboxylic Acids with Remote Stereogenic Centers by NMR Spectroscopy
1,2‐Dihydro‐1‐hydroxy‐2,3,1‐benzodiazaborine Bearing an Acridine Moiety as a Circular Dichroism Probe for Determination of Absolute Configuration of Mono‐Alcohols
Absolute Configuration Determination of Chiral API Molecules by MicroED Analysis of Cocrystal Powders Formed Based on Cocrystal Propensity Prediction Calculations**
MαNP acid, a powerful chiral molecular tool for preparation of enantiopure alcohols by resolution and determination of their absolute configurations by the 1H NMR anisotropy method
Synthesis of enantiopure phthalides including 3‐butylphthalide, a fragrance component of celery oil, and determination of their absolute configurations
Application of chiral technology in a pharmaceutical company. Enantiomeric separation and spectroscopic studies of key asymmetric intermediates using a combination of techniques. Phenylglycidols
Determination of the enantiomeric excess of chiral carboxylic acids by 31P NMR with phosphorylated derivatizing agents from C2‐symmetrical diamines containing the (S)‐α‐phenylethyl group
The origin of an unusually large 19F chemical shift difference between the diastereomeric α‐cyano‐α‐fluoro‐p‐tolylacetic acid (CFTA) esters of 3′,4′,5,7‐tetra‐O‐methylepicatechin
Molecular tweezers for enantiodiscrimination in NMR: Di‐(R,R)‐1‐[10‐(1‐hydroxy‐2,2,2‐trifluoroethyl)‐9‐anthryl]‐2,2,2‐trifluoroethyl benzenedicarboxylates
First isolation of disubstituted cis‐5,6‐dihydro‐1,10‐phenanthrolines. lipase‐mediated resolution of cis‐ and trans‐phenoxy alcohol isomers and assignment of absolute stereochemistry via cd and nmr spectroscopy
Evaluation of (R)‐(−)‐α‐methoxy phenyl acetic acid as a chiral shift reagent for resolution and determination of R and S enantiomers of modafinil in bulk drugs and formulations by 1H NMR spectroscopy
Enantiomeric Discrimination of Isoxazoline Fused β‐amino Acid Derivatives using (18‐Crown‐6)‐2,3,11,12‐tetracarboxylic Acid as a Chiral NMR Solvating Agent
Enantioselective high‐performance liquid chromatography combined with spectroscopic methods and theoretical calculations: A valid strategy to determine the absolute configuration of eugenol derivatives
Diastereotopic Fluorines of CF 2 Group as Stereochemical Probes for Empirical 19 F NMR‐Based Assignment of Absolute Configuration of an Epimeric Center. 21,21‐Difluorothevinols
On the Configurational Stability of Chiral Heteroatom‐Substituted [D1]Methylpalladium Complexes as Intermediates of Stille and Suzuki–Miyaura Cross‐Coupling Reactions
Stereoselective Synthesis of γ‐(Acyloxy)carboxylic Acids and γ‐Lactones Featuring the Switch of Stereopreference of Candida antarctica Lipase B in Sodium γ‐Hydroxycarboxylate Homologues
Assignment of absolute configuration of cyclic secondary amines by NMR techniques using Mosher's method: a general procedure exemplified with (−)‐isoanabasine
Differentiation of enantiomers by 2D NMR spectroscopy at 1 T using residual dipolar couplings
showing the first 200 of 974
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