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The Wittig olefination reaction and modifications involving phosphoryl-stabilized carbanions. Stereochemistry, mechanism, and selected synthetic aspects

https://doi.org/10.1021/cr00094a007
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Condensation of?-hydroxy ketones with phosphorus ylides: A convenient synthesis of linear heterocyclic formation
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Phosphapalladacycle-Catalyzed Heck Reactions for Efficient Synthesis of Trisubstituted Olefins: Evidence for Palladium(0) Intermediates
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Synthesis and Hydrolysis of [Alkenyl(alkoxy)carbene]manganese Complexes: Evidence for a Transient Allylic Intermediate on the Way to α,β-Unsaturated Aldehydes
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Chiral Dilithiomethane Derivatives: Structure Determination and Application in Stereoselective Reactions
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Observation of a Betaine Lithium Salt Adduct During the Course of a Wittig Reaction
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New Retinoid Analogs from δ-Pyronene, a Natural Synthon
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Structural and Spectroscopic Evidence for the Occurrence ofgauche-Betaine Intermediates in the Thio Wittig Reaction
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An Efficient Synthesis of 5-(or 6-)Arylbenzoindolizidine and -quinolizidine Derivatives
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Synthesis of [18-11C/(13C)]linoleic acid
inferred← citeshttps://doi.org/10.1002/(sici)1099-1344(199805)41:5<411::aid-jlcr94>3.0.co;2-7openalex-snapshot
Synthesis of methyl (5Z,8Z,11Z,14Z,17Z)- and (5Z,8Z,11Z,14Z,17E)-[18-14C] eicosapentaenoate
inferred← citeshttps://doi.org/10.1002/(sici)1521-3757(19980216)110:4<467::aid-ange467>3.0.co;2-#openalex-snapshot
Dithioacetale als Einstieg in die Titan‐Alkyliden‐Chemie – eine neue effiziente Carbonylolefinierungsreaktion
inferred← citeshttps://doi.org/10.1002/(sici)1521-3757(19990115)111:1/2<97::aid-ange97>3.0.co;2-1openalex-snapshot
Die Struktur eines dilithiierten Phosphonats im Festkörper
inferred← citeshttps://doi.org/10.1002/(sici)1521-3757(19990401)111:7<1022::aid-ange1022>3.0.co;2-3openalex-snapshot
Domino-Hydroformylierungs-Wittig- Reaktionen
inferred← citeshttps://doi.org/10.1002/(sici)1521-3757(19990517)111:10<1574::aid-ange1574>3.0.co;2-iopenalex-snapshot
Stereospezifische Wanderung eines P-Atoms von einem N- zu einem Csp2-Zentrum: Ringerweiterung chiraler Diazaphospholidinoxide
inferred← citeshttps://doi.org/10.1002/(sici)1521-3757(19990601)111:11<1760::aid-ange1760>3.0.co;2-aopenalex-snapshot
Totalsynthese von (−)-Bafilomycin A1: Anwendung von diastereoselektiver Crotylborierung und Methylketon-Aldolreaktionen
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A Mechanistic Dichotomy Leading to a Ruthenium-Catalyzedcis-Addition for Stereoselective Formation of (Z)-Vinyl Bromides
inferred← citeshttps://doi.org/10.1002/(sici)1521-3773(19980302)37:4<453::aid-anie453>3.0.co;2-mopenalex-snapshot
Dithioacetals as an Entry to Titanium-Alkylidene Chemistry: A New and Efficient Carbonyl Olefination
inferred← citeshttps://doi.org/10.1002/(sici)1521-3773(20000117)39:2<360::aid-anie360>3.0.co;2-9openalex-snapshot
A Mechanistic Dichotomy Leading to a Ruthenium-Catalyzedcis-Addition for Stereoselective Formation of (Z)-Vinyl Bromides
inferred← citeshttps://doi.org/10.1002/047084289x.ra052openalex-snapshot
Allyldiphenylphosphine Oxide
inferred← citeshttps://doi.org/10.1002/047084289x.ra054openalex-snapshot
Allylidenetriphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rb059openalex-snapshot
Benzylidenetriphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rb305openalex-snapshot
Bromomethylenetriphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rc115openalex-snapshot
Chloromethyldiphenylphosphine Oxide
inferred← citeshttps://doi.org/10.1002/047084289x.rc134openalex-snapshot
Chloromethyltriphenylphosphonium Chloride
inferred← citeshttps://doi.org/10.1002/047084289x.rd127openalex-snapshot
Dichloromethylenetriphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rd303mopenalex-snapshot
(2-Dimethylaminoethyl)triphenylphosphonium Bromide
inferred← citeshttps://doi.org/10.1002/047084289x.rd347openalex-snapshot
Dimethyl Methylphosphonate
inferred← citeshttps://doi.org/10.1002/047084289x.rd406openalex-snapshot
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium Bromide
inferred← citeshttps://doi.org/10.1002/047084289x.rd406.pub2openalex-snapshot
(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium Bromide
inferred← citeshttps://doi.org/10.1002/047084289x.rd447openalex-snapshot
Diphenyl(vinyl)phosphine Oxide
inferred← citeshttps://doi.org/10.1002/047084289x.rd447.pub2openalex-snapshot
Diphenyl(vinyl)phosphine Oxide
inferred← citeshttps://doi.org/10.1002/047084289x.re023openalex-snapshot
(Ethoxycarbonylmethylene)triphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.re023.pub2openalex-snapshot
(Ethoxycarbonylmethylene)triphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.re024openalex-snapshot
(Ethoxycarbonylmethyl)triphenylphosphonium Bromide
inferred← citeshttps://doi.org/10.1002/047084289x.re123openalex-snapshot
Ethyltriphenylphosphonium Bromide
inferred← citeshttps://doi.org/10.1002/047084289x.rf030openalex-snapshot
Formylmethylenetriphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rm093openalex-snapshot
(Methoxycarbonylmethylene)triphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rm093.pub2openalex-snapshot
(Methoxycarbonylmethylene)triphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rm108openalex-snapshot
Methoxymethyl(diphenyl)phosphine Oxide
inferred← citeshttps://doi.org/10.1002/047084289x.rm110openalex-snapshot
Methoxymethylenetriphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rm186openalex-snapshot
Methylenetriphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rm186.pub2openalex-snapshot
Methylenetriphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rm292openalex-snapshot
N-Morpholinomethyldiphenylphosphine Oxide
inferred← citeshttps://doi.org/10.1002/047084289x.rn00160openalex-snapshot
Triethyl α-Phosphonomethanesulfonate
inferred← citeshttps://doi.org/10.1002/047084289x.rn00592openalex-snapshot
Bis(2,2,2-trifluoroethyl)bromophosphonoacetate
inferred← citeshttps://doi.org/10.1002/047084289x.rn00592.pub2openalex-snapshot
Bis(2,2,2-trifluoroethyl)bromophosphonaacetate
inferred← citeshttps://doi.org/10.1002/047084289x.rn00884openalex-snapshot
(p-Toluenesulfonylmethylene)triphenylphosphorane
inferred← citeshttps://doi.org/10.1002/047084289x.rn01110openalex-snapshot
Diethyl Allylphosphonate
inferred← citeshttps://doi.org/10.1002/047084289x.rp021openalex-snapshot
Pentacarbonyl(methoxyphenylcarbene)chromium(0)
inferred← citeshttps://doi.org/10.1002/047084289x.rt225openalex-snapshot
Triethyl Phosphonoacetate
inferred← citeshttps://doi.org/10.1002/047084289x.rt225.pub2openalex-snapshot
Triethyl Phosphonoacetate
inferred← citeshttps://doi.org/10.1002/047084289x.rt282openalex-snapshot
Trimethyl Phosphonoacetate
inferred← citeshttps://doi.org/10.1002/047084289x.rt282.pub2openalex-snapshot
Trimethyl Phosphonoacetate
inferred← citeshttps://doi.org/10.1002/0470862106.ia187openalex-snapshot
Phosphorus: Organophosphorus Chemistry
inferred← citeshttps://doi.org/10.1002/0471264180.or062.02openalex-snapshot
The Ramberg‐Bäcklund Reaction
inferred← citeshttps://doi.org/10.1002/0471264180.or072.02openalex-snapshot
Desulfonylation Reactions
inferred← citeshttps://doi.org/10.1002/0471264180.or078.03openalex-snapshot
Twofold Extrusion Reactions
inferred← citeshttps://doi.org/10.1002/0471264180.or089.01openalex-snapshot
Olefin Ring‐Closing Metathesis
inferred← citeshttps://doi.org/10.1002/0471264180.or095.01openalex-snapshot
The J ulia– K ocienski Olefination
inferred← citeshttps://doi.org/10.1002/0471264180.or106.01openalex-snapshot
Alkene Cross‐Metathesis Reactions
inferred← citeshttps://doi.org/10.1002/0471264180.or115.02openalex-snapshot
The Meyer–Schuster Rearrangement
inferred← citeshttps://doi.org/10.1002/0471264180.os074.01openalex-snapshot
(−)‐2‐O‐Benzyl‐L‐Glyceraldehyde and Ethyl (R,E)‐4‐O‐Benzyl‐4,5‐Dihydroxy‐2‐Pentenoate
inferred← citeshttps://doi.org/10.1002/0471264229.os088.14openalex-snapshot
Preparation of Horner‐Wadsworth‐Emmons Reagent: Methyl 2‐Benzyloxycarbonylamino‐2‐(Dimethoxy‐ Phosphinyl)Acetate
inferred← citeshttps://doi.org/10.1002/0471264229.os090.14openalex-snapshot
Direct Conversion of Benzylic and Allylic Alcohols to Diethyl Phosphonates
inferred← citeshttps://doi.org/10.1002/1099-0690(200004)2000:7<1131::aid-ejoc1131>3.0.co;2-1openalex-snapshot
Tandem Silylformylation/Wittig Olefination of Terminal Alkynes: Stereoselective Synthesis of 2,4-Dienoic Esters
inferred← citeshttps://doi.org/10.1002/1099-0690(200007)2000:14<2601::aid-ejoc2601>3.0.co;2-lopenalex-snapshot
The Wittig Reaction with Pyridylphosphoranes
inferred← citeshttps://doi.org/10.1002/1099-0690(200106)2001:12<2293::aid-ejoc2293>3.0.co;2-eopenalex-snapshot
Enantioselective Synthesis and Determination of the Absolute Configuration of Natural (−)-Elegansidiol
inferred← citeshttps://doi.org/10.1002/1521-3757(20000804)112:15<2866::aid-ange2866>3.0.co;2-6openalex-snapshot
Vollständige Stereoselektivität bei der durch Samarium(II)-iodid vermittelten Synthese von (E)-α,β-ungesättigten Estern und Amiden
inferred← citeshttps://doi.org/10.1002/1521-3757(20001215)112:24<4750::aid-ange4750>3.0.co;2-kopenalex-snapshot
Totalsynthese von Lankacyclinol
inferred← citeshttps://doi.org/10.1002/1521-3757(20010518)113:10<1967::aid-ange1967>3.0.co;2-sopenalex-snapshot
Dialkenylierung von Carbonylgruppen mit Alkenyllithiumverbindungen: Bildung von Cyclopentadienderivaten durch Reaktion von 1,4-Dilithio-1,3-dienen mit Ketonen und Aldehyden
inferred← citeshttps://doi.org/10.1002/1521-3757(20010803)113:15<2971::aid-ange2971>3.0.co;2-popenalex-snapshot
Methylenation of Aldehydes: Transition Metal Catalyzed Formation of Salt-Free Phosphorus Ylides
inferred← citeshttps://doi.org/10.1002/1521-3757(20020301)114:5<740::aid-ange740>3.0.co;2-ropenalex-snapshot
Konfigurative Stabilität und Stereoinformationstransfer in Reaktionen Enantiomeren-angereicherter Organolithium-Reagentien
inferred← citeshttps://doi.org/10.1002/1521-3773(20001215)39:24<4612::aid-anie4612>3.0.co;2-copenalex-snapshot
Total Synthesis of Lankacyclinol
inferred← citeshttps://doi.org/10.1002/1521-3773(20010518)40:10<1913::aid-anie1913>3.0.co;2-nopenalex-snapshot
Dialkenylation of Carbonyl Groups by Alkenyllithium Compounds: Formation of Cyclopentadiene Derivatives by the Reaction of 1,4-Dilithio-1,3-dienes with Ketones and Aldehydes
inferred← citeshttps://doi.org/10.1002/1521-3773(20010803)40:15<2887::aid-anie2887>3.0.co;2-qopenalex-snapshot
Methylenation of Aldehydes: Transition Metal Catalyzed Formation of Salt-Free Phosphorus Ylides We thank the Charette group (Université de Montréal) for generously sharing their chemicals and equipment. This research was supported by NSERC (Canada), F.C.A.R (Québec), the Foundation for Innovation,…
inferred← citeshttps://doi.org/10.1002/9780470147306.ch1openalex-snapshot
Stereochemistry and Mechanism in the Wittig Reaction
inferred← citeshttps://doi.org/10.1002/9780470638859.conrr332openalex-snapshot
Horner‐Wadsworth‐Emmons Olefination
inferred← citeshttps://doi.org/10.1002/9780470638859.conrr674openalex-snapshot
Wittig Reaction
inferred← citeshttps://doi.org/10.1002/9780470682531.pat0066openalex-snapshot
Properties and Reactions of Phosphonic and Phosphinic Acids and their Derivatives
inferred← citeshttps://doi.org/10.1002/9780470682531.pat0105openalex-snapshot
Synthesis of Conjugated Dienes and Polyenes
inferred← citeshttps://doi.org/10.1002/9780470682531.pat0134openalex-snapshot
Syntheses and Uses of Isotopically Labelled Compounds Containing C C , C O or C N Groups
inferred← citeshttps://doi.org/10.1002/9780470682531.pat0377openalex-snapshot
1,1‐Bismetallated Species
inferred← citeshttps://doi.org/10.1002/9780470682531.pat0417openalex-snapshot
General and Theoretical Aspects of the Metal Enolates
inferred← citeshttps://doi.org/10.1002/9780470760321.ch12openalex-snapshot
(−)‐Reiswigin A
inferred← citeshttps://doi.org/10.1002/9780470988619.ch9openalex-snapshot
Detoxins
inferred← citeshttps://doi.org/10.1002/9780470988671.ch9openalex-snapshot
The Detection and Characterisation of Intermediates in Chemical Reactions
inferred← citeshttps://doi.org/10.1002/9781118354520.ch15openalex-snapshot
Catalytic Variants of Phosphine Oxide‐Mediated Organic Transformations
inferred← citeshttps://doi.org/10.1002/9781118662083.cot02-004openalex-snapshot
Formation of Alkenes by Wittig and Related Reactions
inferred← citeshttps://doi.org/10.1002/9781118681299.ch3openalex-snapshot
Stabilized Carbanions, Enamines and Ylides
inferred← citeshttps://doi.org/10.1002/9781118681299.ch4openalex-snapshot
Carbon–Carbon Double Bond Forming Reactions
inferred← citeshttps://doi.org/10.1002/9781118690659.ch13openalex-snapshot
Copper‐Mediated Alkenylation Reaction of Alkenyl Derivatives: A Straightforward Elaboration of 1,3‐Dienes
inferred← citeshttps://doi.org/10.1002/9781118735183.ch04openalex-snapshot
Diaminobenzene-Cored Fluorophores Exhibiting Highly Efficient Solid-State Luminescence
inferred← citeshttps://doi.org/10.1002/9781119951438.eibc0173openalex-snapshot
Phosphorus: Organophosphorus Chemistry
inferred← citeshttps://doi.org/10.1002/9783527603978.mst0423openalex-snapshot
Cyclodehydrogenation in the Synthesis of Graphene‐Type Molecules
inferred← citeshttps://doi.org/10.1002/9783527613540.ch06openalex-snapshot
Supramolecular Self‐Assembly Caused by Ionic Interactions
inferred← citeshttps://doi.org/10.1002/9783527613908.ch01openalex-snapshot
Introduction
inferred← citeshttps://doi.org/10.1002/9783527613908.ch02openalex-snapshot
C,P‐Carbon‐Substituted Phosphorus Ylides
inferred← citeshttps://doi.org/10.1002/9783527613908.ch06openalex-snapshot
The Wittig Reaction
inferred← citeshttps://doi.org/10.1002/9783527619399.ch3bopenalex-snapshot
Titanium—Carbene Mediated Reactions
inferred← citeshttps://doi.org/10.1002/9783527619405.ch3bopenalex-snapshot
Titanium–Carbene Mediated Reactions
inferred← citeshttps://doi.org/10.1002/9783527619979.ch17openalex-snapshot
Dithioacetals as an Entry to Titanium‐Alkylidene Chemistry: New and Efficient Carbonyl Olefination
inferred← citeshttps://doi.org/10.1002/9783527620784.ch17copenalex-snapshot
Dithioacetals as an Entry to Titanium‐Alkylidene Chemistry: New and Efficient Carbonyl Olefination
inferred← citeshttps://doi.org/10.1002/9783527625116.ch3openalex-snapshot
C
inferred← citeshttps://doi.org/10.1002/9783527629787.ch4openalex-snapshot
Poly(phenylenevinylenes)
inferred← citeshttps://doi.org/10.1002/9783527671304.ch9openalex-snapshot
Oxidations and Reductions in Domino Processes
inferred← citeshttps://doi.org/10.1002/9783527672240.ch3openalex-snapshot
Phosphorus Ylides and Related Compounds
inferred← citeshttps://doi.org/10.1002/9783527674107.ch12openalex-snapshot
Solvent and Additive Effects on Olefin Metathesis
inferred← citeshttps://doi.org/10.1002/9783527809080.cataz08211openalex-snapshot
Horner‐Wittig reaction
inferred← citeshttps://doi.org/10.1002/9783527828166.ch3openalex-snapshot
Olefination, Metathesis, and Epoxidation Reactions
inferred← citeshttps://doi.org/10.1002/9783527830237.ch10openalex-snapshot
Phosphorus Reagents for Two‐, Three‐, and Four‐Carbon Homologation of Carbonyl Compounds to Functionalized Olefins
inferred← citeshttps://doi.org/10.1002/9783527830237.ch2openalex-snapshot
Lithium Carbenoids in Homologation Chemistry
inferred← citeshttps://doi.org/10.1002/9783527830237.ch20openalex-snapshot
Dehomologation and Ring Contraction Strategies
inferred← citeshttps://doi.org/10.1002/9783527830664.ch8openalex-snapshot
Quaternary Ammonium, Phosphonium, and Tertiary Sulfonium Salts as Hydrogen‐Bonding Catalysts
inferred← citeshttps://doi.org/10.1002/9783527834242.chf0011openalex-snapshot
Pd‐Catalyzed CH Olefination Reactions
inferred← citeshttps://doi.org/10.1002/adma.19920040608openalex-snapshot
Donor–acceptor substituted polyenes: Orientation in mono‐ and multilayers
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Tuning Solid‐State Emissions via Twists and Turns in Polymorphic Self‐ and Cross‐Coupled Dianthrylethenes
inferred← citeshttps://doi.org/10.1002/adsc.200404306openalex-snapshot
Rhodium‐Catalyzed, Three‐Component Reaction of Diazo Compounds with Amines and Azodicarboxylates
inferred← citeshttps://doi.org/10.1002/adsc.200404338openalex-snapshot
Efficient and Scalable Protocol for the Z‐Selective Synthesis of Unsaturated Esters by HornerWadsworthEmmons Olefination
inferred← citeshttps://doi.org/10.1002/adsc.200505196openalex-snapshot
Practical Synthesis of (E)‐α,β‐Unsaturated Esters from Aldehydes
inferred← citeshttps://doi.org/10.1002/adsc.200700377openalex-snapshot
Catalytic Asymmetric 1, 3‐Dipolar Cycloaddition Reaction of Nitrones with α′‐Phosphoric Enones by a Chiral Ligand‐ Copper(II) Triflate Complex
inferred← citeshttps://doi.org/10.1002/adsc.200800542openalex-snapshot
Nickel‐Catalyzed Synthesis of Phosphonium Salts from Aryl Halides and Triphenylphosphine
inferred← citeshttps://doi.org/10.1002/adsc.200900011openalex-snapshot
A Direct Amine‐Palladium Acetate Cocatalyzed Saegusa Oxidation Reaction of Unmodified Aldehydes to α,β‐Unsaturated Aldehydes
inferred← citeshttps://doi.org/10.1002/adsc.200900438openalex-snapshot
First Copper‐Catalyzed Intramolecular Amidation in Substituted 4‐Iodopyrazoles Leading to the Synthesis of Pyrazolo[4,3‐b]‐ pyridin‐5‐ones
inferred← citeshttps://doi.org/10.1002/adsc.201000142openalex-snapshot
Michael Reaction of Nitroalkanes with β‐Nitroacrylates under a Solid Promoter: Advanced Regio‐ and Diastereoselective Synthesis of Nitro‐Functionalized α,β‐Unsaturated Esters and 1,3‐Butadiene‐2‐carboxylates
inferred← citeshttps://doi.org/10.1002/adsc.201100140openalex-snapshot
Mechanistic Switch via Subtle Ligand Modulation: Palladium‐Catalyzed Synthesis of α,β‐Substituted Styrenes via CH Bond Functionalization
inferred← citeshttps://doi.org/10.1002/adsc.201100420openalex-snapshot
Highly (≥98%) Stereo‐ and Regioselective Trisubstituted Alkene Synthesis of Wide Applicability via 1‐Halo‐1‐alkyne Hydro‐ boration–Tandem Negishi–Suzuki Coupling or Organoborate Migratory Insertion
inferred← citeshttps://doi.org/10.1002/adsc.201200167openalex-snapshot
Sodium Sulfinate‐Mediated trans‐Stilbene Formation from Benzylic Halides
inferred← citeshttps://doi.org/10.1002/adsc.201200295openalex-snapshot
Copper‐Catalyzed Synthesis of Alkylphosphonates from H ‐Phosphonates and N ‐Tosylhydrazones
inferred← citeshttps://doi.org/10.1002/adsc.201200420openalex-snapshot
Palladium(II)‐Catalyzed Hydration of Alkynylphosphonates to β‐Ketophosphonates
inferred← citeshttps://doi.org/10.1002/adsc.201200759openalex-snapshot
A New Type of Stereoselectivity in Baeyer–Villiger Reactions: Access to E‐ and Z‐Olefins
inferred← citeshttps://doi.org/10.1002/adsc.201300302openalex-snapshot
Capture of In Situ Generated Diazo Compounds or Copper Carbenoids by Triphenylphosphine: Selective Synthesis of trans ‐ Alkenes and Unsymmetric Azines via Reaction of Aldehydes with Ketone‐Derived N ‐Tosylhydrazones
inferred← citeshttps://doi.org/10.1002/adsc.201300760openalex-snapshot
Nickel‐ or Palladium‐Catalyzed Stereoselective Synthesis of Tetrasubstituted Olefinic Indolines‐Fused Triazoles: Extension to the Spiroindoline Core
inferred← citeshttps://doi.org/10.1002/adsc.201300835openalex-snapshot
Sodium Iodide/tert‐Butyl(dimethyl)silyl Chloride‐Induced Isomerization of 2,3‐Allenols to 2(E)‐Enals
inferred← citeshttps://doi.org/10.1002/adsc.201300904openalex-snapshot
Biomimetic Aerobic CH Olefination of Cyclic Enaminones at Room Temperature: Development toward the Synthesis of 1,3,5‐Trisubstituted Benzenes
inferred← citeshttps://doi.org/10.1002/adsc.201300917openalex-snapshot
Iridium(I)‐Catalyzed Direct CH Bond Alkylation of the C‐7 Position of Indolines with Alkenes
inferred← citeshttps://doi.org/10.1002/adsc.201300950openalex-snapshot
Reversible P(III)/P(V) Redox: Catalytic Aza‐Wittig Reaction for the Synthesis of 4(3 H )‐Quinazolinones and the Natural Product Vasicinone
inferred← citeshttps://doi.org/10.1002/adsc.201400190openalex-snapshot
Palladium‐Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H‐Phosphonates
inferred← citeshttps://doi.org/10.1002/adsc.201500529openalex-snapshot
Integrated Process of Aerobic Oxidation–Olefination–Asymmetric CC Bond Formation Catalyzed by Robust Heterogeneous Gold/Palladium and Chirally Modified Rhodium Nanoparticles
inferred← citeshttps://doi.org/10.1002/adsc.201601024openalex-snapshot
Base‐Promoted Addition of Arylacetonitriles to Terminal Alkynes: Regio‐ and Stereoselective Access to Disubstituted Acrylonitriles
inferred← citeshttps://doi.org/10.1002/adsc.201700850openalex-snapshot
Oxidative Phosphorylation of N‐Aryl Glycine Amides via sp3 C−H Functionalization
inferred← citeshttps://doi.org/10.1002/adsc.201700886openalex-snapshot
Catalyst‐ and Oxidant‐Free Desulfonative C−P Couplings for the Synthesis of Phosphine Oxides and Phosphonates
inferred← citeshttps://doi.org/10.1002/adsc.201701640openalex-snapshot
A Tunable Route to Prepare α,β‐Unsaturated Esters and α,β‐Unsaturated‐γ‐Keto Esters through Copper‐Catalyzed Coupling of Alkenyl Boronic Acids with Phosphorus Ylides
inferred← citeshttps://doi.org/10.1002/adsc.201800486openalex-snapshot
Allenylphosphine Oxides as Starting Materials for the Synthesis of Conjugated Enynes: Boosting the Catalytic Performance by MOF Encapsulated Palladium Nanoparticles
inferred← citeshttps://doi.org/10.1002/adsc.201800804openalex-snapshot
DDQ‐Promoted Allylic C−H Phosphorylation of 1,3‐Diarylpropenes
inferred← citeshttps://doi.org/10.1002/adsc.201900755openalex-snapshot
Synthesis of Functionalized Spirocyclic Indolines by Visible Light‐Induced One‐Pot Sequential Difluoromethylative Dearomatization, Hydroxylation, and Substitution Reactions
inferred← citeshttps://doi.org/10.1002/adsc.201901562openalex-snapshot
cis‐Selective Transfer Semihydrogenation of Alkynes by Merging Visible‐Light Catalysis with Cobalt Catalysis
inferred← citeshttps://doi.org/10.1002/adsc.201901591openalex-snapshot
Still–Gennari Olefination and its Applications in Organic Synthesis
inferred← citeshttps://doi.org/10.1002/adsc.202000370openalex-snapshot
Recent Progress on Reductive Coupling of Nitroarenes by Using Organosilanes as Convenient Reductants
inferred← citeshttps://doi.org/10.1002/adsc.202000730openalex-snapshot
Stereoselective Construction of ( E,Z )‐1,3‐Dienes and Its Application in Natural Product Synthesis
inferred← citeshttps://doi.org/10.1002/adsc.202100189openalex-snapshot
The Trityl‐Cation Mediated Phosphine Oxides Reduction
inferred← citeshttps://doi.org/10.1002/adsc.202100226openalex-snapshot
Silver‐Catalyzed Oxyphosphorylation of Unactivated Alkynes
inferred← citeshttps://doi.org/10.1002/adsc.202100902openalex-snapshot
A Cross‐Coupling Reaction Between Aliphatic Aldehydes And Sulfonium Salts
inferred← citeshttps://doi.org/10.1002/adsc.202200533openalex-snapshot
Metal‐Free Site‐Selective Direct Oxidative Phosphorylation of Pyrazolones
inferred← citeshttps://doi.org/10.1002/adsc.202300159openalex-snapshot
Manganese‐Mediated Reductive Alkylation of Thiazolyl‐Phosphonium Salts
inferred← citeshttps://doi.org/10.1002/adsc.202301146openalex-snapshot
Synthesis of Styrenes and E‐Stilbenes by Palladium‐Catalyzed Vinylation of Aryl Iodides with 1,2‐Dibromoethane
inferred← citeshttps://doi.org/10.1002/adsc.202400847openalex-snapshot
1‐Alkynylphosphorus Compounds in Organic Synthesis, 2010–2024
inferred← citeshttps://doi.org/10.1002/adsc.202401331openalex-snapshot
Photoinduced Methylthio Radical Generation from Methylthiophosphonium Salt
inferred← citeshttps://doi.org/10.1002/adsc.70000openalex-snapshot
Chemoselective Acylation/Wittig or β‐Acylation Reactions: Diversity‐Oriented Synthesis of Indandione‐Tethered Benzofurans and β‐Acylated Arylidene Indandiones
inferred← citeshttps://doi.org/10.1002/adsc.70233openalex-snapshot
Chemoenzymatic Synthesis of Alkenes from Alcohols or Amines by One‐Pot Laccase‐Mediated Oxidations and Wittig Reaction in Water
inferred← citeshttps://doi.org/10.1002/adsc.70243openalex-snapshot
Emergence of Phosphinium Radical Cations as Intermediates for Organic Radical Generation
inferred← citeshttps://doi.org/10.1002/adsc.70803openalex-snapshot
Beyond Wittig: Phosphonium Ylides and Salts as Catalysts and Precursors in Radical Chemistry
inferred← citeshttps://doi.org/10.1002/advs.75663openalex-snapshot
Photocatalytic Synthesis of Pentafluorosulfanyl Ketones, Acetals, and BCP Motifs Utilizing SF 6
inferred← citeshttps://doi.org/10.1002/ajoc.201500261openalex-snapshot
Triphenylphosphine/2,3‐Dichloro‐5,6‐dicyanobenzoquinone (PPh 3 /DDQ) System for Conversion of Alcohols and Thiols into Trialkyl Phosphonates
inferred← citeshttps://doi.org/10.1002/ajoc.201500285openalex-snapshot
Regiochemistry‐Directed Syntheses of Polyhydroxylated Alkaloids from Chiral Aziridines
inferred← citeshttps://doi.org/10.1002/ajoc.201600055openalex-snapshot
Carbonylation of Csp3−H Bonds through Oxidative Wittig‐Type Reaction: An Unprecedented Version of Wittig Reaction
inferred← citeshttps://doi.org/10.1002/ajoc.201600515openalex-snapshot
Synthetic Studies Toward the Crassifoside F: Synthesis of Oxygen‐Rich Bicyclic Core
inferred← citeshttps://doi.org/10.1002/ajoc.201800325openalex-snapshot
Phosphine‐Catalyzed Reactions with Unsaturated Carbonyl Compounds
inferred← citeshttps://doi.org/10.1002/ajoc.201800586openalex-snapshot
Alkene Synthesis Using Phosphonium Ylides as Umpolung Reagents
inferred← citeshttps://doi.org/10.1002/ajoc.202000193openalex-snapshot
Synthetic Applications of Cyclopropene and Cyclopropenone: Recent Progress and Developments
inferred← citeshttps://doi.org/10.1002/ajoc.202200701openalex-snapshot
Direct Irradiation of (E)‐Styrylpyridin‐2(1H)‐ones to (Z)‐Isomers with Visible Light
inferred← citeshttps://doi.org/10.1002/ajoc.202300544openalex-snapshot
Visible‐Light‐Induced Denitroalkylation of β‐Nitrostyrenes with Alkyl Boronic Acids
inferred← citeshttps://doi.org/10.1002/ajoc.202400122openalex-snapshot
Photoinduced Alkenylation of Alkenyl Sulfones with EDA Complexes between NHPI Esters and HE
inferred← citeshttps://doi.org/10.1002/ajoc.202400333openalex-snapshot
Synthesis of 2‐Pyrones by Base‐Induced [3+3] Annulation Reaction of Phenacyl Phosphonium Ylides with Cyclopropenones
inferred← citeshttps://doi.org/10.1002/ajoc.70488openalex-snapshot
Convenient Synthesis of Acrylanilides via K 2 CO 3 ‐Mediated Deacylative Olefination of Acetoacetanilides
inferred← citeshttps://doi.org/10.1002/ange.19901021118openalex-snapshot
Organische Synthese — wohin?
inferred← citeshttps://doi.org/10.1002/ange.19901021253openalex-snapshot
Neue Benzyl(β‐oxido)phosphor‐ und ‐arsen‐Ylide: Reaktivität und Stereoselektivität bei der Wittig‐Reaktion
inferred← citeshttps://doi.org/10.1002/ange.19931050634openalex-snapshot
Synthese, Struktur und Thermolyse eines 3‐Methoxycarbonyl‐1,2λ5‐oxaphosphetans
inferred← citeshttps://doi.org/10.1002/ange.19941060518openalex-snapshot
Kinetische Enantiomerentrennung des Acrolein‐Dimers durch asymmetrische Horner‐Wadsworth‐Emmons‐Reaktionen
inferred← citeshttps://doi.org/10.1002/ange.19941061529openalex-snapshot
Säurekatalysierte Olefinierung von Benzaldehyd
inferred← citeshttps://doi.org/10.1002/ange.19941062026openalex-snapshot
Synthese, Struktur und Thermolyse eines tetrakoordinierten 1,2λ4‐Oxathietans
inferred← citeshttps://doi.org/10.1002/ange.19951070422openalex-snapshot
[(PhCH2)2NLi · CH2PPh3]2 – der erste eindeutig charakterisierte Komplex zwischen einem neutralen Phosphor‐Ylid und einer Lithiumverbindung: Isolierung, Struktur und ab‐initio‐Rechnungen
inferred← citeshttps://doi.org/10.1002/ange.19951071811openalex-snapshot
Cer( III )‐chlorid‐unterstützte nucleophile Addition von Organolithiumreagentien an α‐Alkyl‐β‐ketophosphinoxide: eine neue Methode für die Synthese stereochemisch definierter trisubstituierter Olefine
inferred← citeshttps://doi.org/10.1002/ange.19961080304openalex-snapshot
Stereokontrolle in der organischen Synthese durch Verwendung der Diphenylphosphorylgruppe
inferred← citeshttps://doi.org/10.1002/ange.19961081024openalex-snapshot
N‐apicale 1, 2λ5‐Azaphosphetidine mit P‐Pentakoordination und ihre N‐äquatorialen Pseudorotamere
inferred← citeshttps://doi.org/10.1002/ange.19961082129openalex-snapshot
Über die Struktur eines lithiierten Phosphanoxids in Lösung und in festem Zustand
inferred← citeshttps://doi.org/10.1002/ange.19971090313openalex-snapshot
Eine neue asymmetrische Formylierung von Aldehyden
inferred← citeshttps://doi.org/10.1002/ange.19971090633openalex-snapshot
Eine neue asymmetrische Formylierung von Aldehyden
inferred← citeshttps://doi.org/10.1002/ange.19971092112openalex-snapshot
Das erste lithiierte Phosphanoxid mit Li‐C‐Bindungen: Synthese und Struktur von [{Ph2P(O)CHLiC(H)MeEt}4]
inferred← citeshttps://doi.org/10.1002/ange.19971092230openalex-snapshot
2,2,6,6‐Tetrakis(4‐chlorphenyl)‐3,7‐dimethyl‐4‐phenyl‐1,5‐dioxa‐4λ5‐phosphaspiro[3.3]heptan: Synthese und Strukturen der drei Diastereomere sowie doppelte Olefinabspaltung
inferred← citeshttps://doi.org/10.1002/ange.200290033openalex-snapshot
Catalytic Electronic Activation: Indirect “Wittig” Reaction of Alcohols
inferred← citeshttps://doi.org/10.1002/ange.200390241openalex-snapshot
A Catalytic Carbon–Phosphorus Ylide Reaction: Phosphane‐Catalyzed Annulation of Allylic Compounds with Electron‐Deficient Alkenes
inferred← citeshttps://doi.org/10.1002/ange.200501983openalex-snapshot
Sphingolactone: selektive und irreversibel wirkende Inhibitoren der neutralen Sphingomyelinase
inferred← citeshttps://doi.org/10.1002/ange.200601872openalex-snapshot
Kaskadenreaktionen in der Totalsynthese
inferred← citeshttps://doi.org/10.1002/ange.200604013openalex-snapshot
A Highly Regio‐ and Stereoselective Vinylogous Horner–Wadsworth–Emmons Route to Densely Substituted 1,3‐Butadienes
inferred← citeshttps://doi.org/10.1002/ange.200604389openalex-snapshot
Efficient Trapping of Oxonium Ylides with Imines: A Highly Diastereoselective Three‐Component Reaction for the Synthesis of β‐Amino‐α‐hydroxyesters with Quaternary Stereocenters
inferred← citeshttps://doi.org/10.1002/ange.200800994openalex-snapshot
Palladium Catalysts for the Formylation of Vinyl Triflates To Form α,β‐Unsaturated Aldehydes
inferred← citeshttps://doi.org/10.1002/ange.200902525openalex-snapshot
Recycling the Waste: The Development of a Catalytic Wittig Reaction
inferred← citeshttps://doi.org/10.1002/ange.200907248openalex-snapshot
Total Synthesis of (+)‐Clavolonine, (−)‐Deacetylfawcettiine, and (+)‐Acetylfawcettiine
inferred← citeshttps://doi.org/10.1002/ange.201000896openalex-snapshot
Improving the Atom Efficiency of the Wittig Reaction by a “Waste as Catalyst/Co‐catalyst” Strategy
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