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Dyotropic Reactions: Mechanisms and Synthetic Applications

https://doi.org/10.1021/cr900209c
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Thermoneutral dyotropic transfer of hydrogen in a hydrocarbon
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Spectroscopic and Computational Studies on the Adenosylcobalamin-Dependent Methylmalonyl-CoA Mutase: Evaluation of Enzymatic Contributions to Co−C Bond Activation in the Co3+Ground State
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Co−C Bond Activation in Methylmalonyl-CoA Mutase by Stabilization of the Post-homolysis Product Co2+Cobalamin
inferredcites →https://doi.org/10.1021/ja058031nopenalex-snapshot
Theoretical Studies on Farnesyl Cation Cyclization: Pathways to Pentalenene
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Synthesis, X-ray Crystallography, and Computational Analysis of 1-Azafenestranes
inferredcites →https://doi.org/10.1021/ja0668421openalex-snapshot
In Search of Radical Intermediates in the Reactions Catalyzed by Lysine 2,3-Aminomutase and Lysine 5,6-Aminomutase
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Identification of a Rearranged-Substrate, Product Radical Intermediate and the Contribution of a Product Radical Trap in Vitamin B12 Coenzyme-Dependent Ethanolamine Deaminase Catalysis
inferredcites →https://doi.org/10.1021/ja803579zopenalex-snapshot
Concise Synthesis of Spirocyclic, Bridged γ-Butyrolactones via Stereospecific, Dyotropic Rearrangements of β-Lactones Involving 1,2-Acyl and δ-Lactone Migrations
inferredcites →https://doi.org/10.1021/ja963248qopenalex-snapshot
Transition Structures of the Ene Reactions of Cyclopropene
inferredcites →https://doi.org/10.1021/ja982753fopenalex-snapshot
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Identification of a Rearranged-Substrate, Product Radical Intermediate and the Contribution of a Product Radical Trap in Vitamin B 12 Coenzyme-Dependent Ethanolamine Deaminase Catalysis
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Interactions of Substrate and Product Radicals with CoII in Cobalamin and with the Active Site in Ethanolamine Deaminase, Characterized by ESE-EPR and 14N ESEEM Spectroscopies
inferredcites →https://doi.org/10.1021/ja991649aopenalex-snapshot
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inferredcites →https://doi.org/10.1021/jo00026a023openalex-snapshot
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inferredcites →https://doi.org/10.1021/jo00051a012openalex-snapshot
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inferredcites →https://doi.org/10.1021/jo00376a002openalex-snapshot
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inferredcites →https://doi.org/10.1021/jo01042a527openalex-snapshot
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inferredcites →https://doi.org/10.1021/jo062310ropenalex-snapshot
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inferredcites →https://doi.org/10.1021/om00105a018openalex-snapshot
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inferredcites →https://doi.org/10.1021/om00108a011openalex-snapshot
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inferredcites →https://doi.org/10.1039/c39890000345openalex-snapshot
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inferredcites →https://doi.org/10.1039/c39910000184openalex-snapshot
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inferredcites →https://doi.org/10.1039/jr9560000932openalex-snapshot
196. Long-range effects in alicyclic systems. Part I. The rates of rearrangement of some steroidal dibromides
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inferredcites →https://doi.org/10.1039/p19870002183openalex-snapshot
The 3,4-dihydro-2H-pyran approach to (+)-milbemycin β 3 . Part 1. An alternative synthesis of (2S,4S,6R,8R,9S)-2-formylmethyl-4-(dimethyl-t-butylsilyloxy)-8,9-dimethyl-1,7-dioxaspiro[5.5]undecane
inferredcites →https://doi.org/10.1039/p19870002189openalex-snapshot
The 3,4-dihydro-2H-pyran approach to (+)-milbemycin β 3 . Part 2. An improved synthesis of (2R,4S,6S,8R,9S)-2-[(5R)-(2E)-3-methyl-5-formyl-hex-2-en-1-yl]-8,9-dimethyl-4-(dimethyl-t-butylsilyloxy)-1,7-dioxaspiro[5.5]undecane
inferredcites →https://doi.org/10.1039/p29930001211openalex-snapshot
On intramolecular dyotropy: structural effects on reaction rates, crystal structure–molecular mechanics correlations and primary deuterium kinetic isotope effects. (Parameters for intramolecular recognition)
inferredcites →https://doi.org/10.1039/p29960001749openalex-snapshot
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A General Synthesis for 4-Alkyl-2,3-dihydrofurans
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Isomerization of C60 fullerenes
inferredcites →https://doi.org/10.1071/ch9840409openalex-snapshot
Chemistry of the Podocarpaceae. LXVI. Preparation and reactions of dimethyl 13,14,15,16-Tetranorlabd-8(17)-ene-12,19-dioate
inferredcites →https://doi.org/10.1073/pnas.87.8.3174openalex-snapshot
Vitamin B12S-promoted model rearrangement of methylmalonate to succinate is not a free radical reaction.
inferredcites →https://doi.org/10.1074/jbc.273.11.6508openalex-snapshot
Cloning, Sequencing, Expression, and Insertional Inactivation of the Gene for the Large Subunit of the Coenzyme B12-dependent Isobutyryl-CoA Mutase from Streptomyces cinnamonensis
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inferred← citeshttps://doi.org/10.1002/cphc.201100568openalex-snapshot
Isomerisation of CF2ClCH2Cl and CFCl2CH2F by Interchange of Cl and F Atoms with Analysis of the Unimolecular Reactions of Both Molecules
inferred← citeshttps://doi.org/10.1002/cphc.201901069openalex-snapshot
On the Role of Water as a Catalyst in Prebiotic Chemistry
inferred← citeshttps://doi.org/10.1002/ejoc.201402637openalex-snapshot
Six‐Membered Ring Formation from Lewis Acid Promoted Reactions of 2‐Substituted 2‐Alkenyl Amides and Esters of Ethenetricarboxylate
inferred← citeshttps://doi.org/10.1002/ejoc.201500561openalex-snapshot
Formal Dyotropic Rearrangements in Organometallic Transformations
inferred← citeshttps://doi.org/10.1002/ejoc.202300017openalex-snapshot
Carbofluorination of π‐Bonds and Related Reactions Involving Tandem C−C/C−F Bond Formation
inferred← citeshttps://doi.org/10.1002/ijch.202200122openalex-snapshot
Dyotropic Rearrangements in Organic Solvents, in the Gas Phase, and in Enzyme Catalysis
inferred← citeshttps://doi.org/10.1002/jcc.23736openalex-snapshot
A DFT study on proton transfers in hydrolysis reactions of phosphate dianion and sulfate monoanion
inferred← citeshttps://doi.org/10.1002/jcc.24317openalex-snapshot
Interplay between aromaticity and strain in double group transfer reactions to 1,2-benzyne
inferred← citeshttps://doi.org/10.1002/jcc.24844openalex-snapshot
Computational insights into the S3transfer reaction: A special case of double group transfer reaction featuring bicyclically delocalized aromatic transition state geometries
inferred← citeshttps://doi.org/10.1002/mas.21464openalex-snapshot
Copper‐catalyzed reactions: Research in the gas phase
inferred← citeshttps://doi.org/10.1002/mas.21654openalex-snapshot
ORGANOMETALLIC GAS‐PHASE ION CHEMISTRY AND CATALYSIS: INSIGHTS INTO THE USE OF METAL CATALYSTS TO PROMOTE SELECTIVITY IN THE REACTIONS OF CARBOXYLIC ACIDS AND THEIR DERIVATIVES
inferred← citeshttps://doi.org/10.1002/poc.3464openalex-snapshot
Mass spectrometric study of the decomposition pathways of canonical amino acids and α‐lactones in the gas phase
inferred← citeshttps://doi.org/10.1002/poc.3606openalex-snapshot
Infrared spectroscopic confirmation of α‐lactone formation in the dissociation of a gaseous amino acid
inferred← citeshttps://doi.org/10.1002/slct.201600525openalex-snapshot
Breaking the Isolated Pentagon Rule by Encapsulating Xe 2 in C 60 : The Guest Defines the Shape of the Host
inferred← citeshttps://doi.org/10.1002/slct.201600649openalex-snapshot
1,2‐Shift of Element‐Centered Groups (R n E) in Carbenoid Anions [R n ECF 2 CFCl] − and its Relevance for Nucleophilic Vinylic Substitution: a DFT Study
inferred← citeshttps://doi.org/10.1002/tcr.201600003openalex-snapshot
Organo- and Organometallic-Catalytic Intramolecular [1,5]-Hydride Transfer/Cyclization Process through C(sp3)-H Bond Activation
inferred← citeshttps://doi.org/10.1007/7081_2012_87openalex-snapshot
β-Lactams from Fischer Carbene Complexes: Scope, Limitations, and Reaction Mechanism
inferred← citeshttps://doi.org/10.1007/s00706-018-2184-0openalex-snapshot
Theoretical study on the elimination kinetics in the gas phase of allyl methyl compounds
inferred← citeshttps://doi.org/10.1007/s00894-014-2304-7openalex-snapshot
Aromaticity of azines through dyotropic double hydrogen transfer reaction
inferred← citeshttps://doi.org/10.1007/s00894-015-2869-9openalex-snapshot
Dyotropic rearrangement of bridgehead substituents in closed dithienylethenes; conjugated verses non-conjugated analogues
inferred← citeshttps://doi.org/10.1007/s11426-016-0076-6openalex-snapshot
Recent advances in terpenoid syntheses from China
inferred← citeshttps://doi.org/10.1016/b978-0-08-100023-6.00003-8openalex-snapshot
Discodermolide
inferred← citeshttps://doi.org/10.1016/b978-0-12-822723-7.00001-7openalex-snapshot
Aromaticity in molecules and transition structures: from atomic and molecular orbitals to simple ring current models
inferred← citeshttps://doi.org/10.1016/j.chempr.2018.10.019openalex-snapshot
Designing Reactions with Post-Transition-State Bifurcations: Asynchronous Nitrene Insertions into C–C σ Bonds
inferred← citeshttps://doi.org/10.1016/j.comptc.2024.114790openalex-snapshot
Theoretical predictions on In-Plane aromaticity in double hydrogen transfer reactions between ethane and ethylene
inferred← citeshttps://doi.org/10.1016/j.ijms.2013.07.010openalex-snapshot
CH and CC bond activation reactions in silver alkynyl cluster cations, RCCAg2+
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2016.02.017openalex-snapshot
Quantum mechanical investigation on acceleration of electrocyclic reactions through transition metal catalysis
inferred← citeshttps://doi.org/10.1016/j.tet.2012.05.093openalex-snapshot
Laboratory evolution of stereoselective enzymes as a means to expand the toolbox of organic chemists
inferred← citeshttps://doi.org/10.1016/j.tet.2014.06.025openalex-snapshot
Protecting group-free syntheses of natural products and biologically active compounds
inferred← citeshttps://doi.org/10.1016/j.tet.2016.11.031openalex-snapshot
Putative biosynthetic cycloadditions en route to the diterpenoid (+)-chatancin
inferred← citeshttps://doi.org/10.1016/j.tetlet.2026.156214openalex-snapshot
Computational evidence for dyotropic rearrangement in hypervalent iodine-mediated migratory gem-difluorination
inferred← citeshttps://doi.org/10.1021/acs.accounts.1c00459openalex-snapshot
Biomimetic Synthesis of Natural Products: A Journey To Learn, To Mimic, and To Be Better
inferred← citeshttps://doi.org/10.1021/acs.accounts.1c00664openalex-snapshot
Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds
inferred← citeshttps://doi.org/10.1021/acs.chemrev.4c00661openalex-snapshot
Nitrogen-Based Organofluorine Functional Molecules: Synthesis and Applications
inferred← citeshttps://doi.org/10.1021/acs.jctc.0c00172openalex-snapshot
Construction of Two-Dimensional Potential Energy Surfaces of Reactions with Post-Transition-State Bifurcations
inferred← citeshttps://doi.org/10.1021/acs.joc.3c02407openalex-snapshot
Enantioselective Total Synthesis of (−)-Vinigrol: The Evolution of a Transannular Diels–Alder Strategy
inferred← citeshttps://doi.org/10.1021/acs.joc.5b01274openalex-snapshot
Stone–Wales Rearrangements in Hydrocarbons: From Planar to Bowl-Shaped Substrates
inferred← citeshttps://doi.org/10.1021/acs.joc.9b01081openalex-snapshot
Visible Light/Molecular-Iodine-Mediated Intermolecular Spirolactonization Reaction of Olefins with Cyclic Ketones
inferred← citeshttps://doi.org/10.1021/acs.joc.9b02784openalex-snapshot
Stepwise Mechanism for the Bromination of Arenes by a Hypervalent Iodine Reagent
inferred← citeshttps://doi.org/10.1021/acs.jpca.5c02657openalex-snapshot
Theoretical Investigation of Isomerization and Dissociation Reactions in the CF3CH2Cl ⇄ CF2ClCH2F System
inferred← citeshttps://doi.org/10.1021/acs.oprd.0c00453openalex-snapshot
An Easy, Convenient, and Safe Process for the Synthesis of Lofexidine Hydrochloride
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c01616openalex-snapshot
Discovery of a Formal Dyotropic Rearrangement during Acid-Mediated Dioxabicyclo[4.2.1]nonanone Formation
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c01051openalex-snapshot
Rh(III)-Catalyzed Indole Dearomative 1,2-Alkoxyl Shift Rearrangement
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b01621openalex-snapshot
From Hydrindane to Decalin: A Mild Transformation through a Dyotropic Ring Expansion
inferred← citeshttps://doi.org/10.1021/acscatal.0c04108openalex-snapshot
A Pioneering Career in Catalysis: Manfred T. Reetz
inferred← citeshttps://doi.org/10.1021/acscatal.3c02864openalex-snapshot
Access to Amino Lactones through Palladium-Catalyzed Oxyamination with Aromatic Amines as the Nitrogen Source
inferred← citeshttps://doi.org/10.1021/acscatal.6c05353openalex-snapshot
From α,β-Unsaturated Amide to Enamide: Intramolecular Alkene Translocation via Iridium-Catalyzed Transfer Hydrogenation
inferred← citeshttps://doi.org/10.1021/acscatal.6c05835openalex-snapshot
Silylium-Ion-Promoted Cycloisomerization of Silicon-Tethered Enynes
inferred← citeshttps://doi.org/10.1021/acsorginorgau.5c00085openalex-snapshot
The Role of 1,2-Palladium Migration/Insertion on C(sp3)–H Functionalization
inferred← citeshttps://doi.org/10.1021/ar100159hopenalex-snapshot
Photochemistry of Group 6 Fischer Carbene Complexes: Beyond the Photocarbonylation Reaction
inferred← citeshttps://doi.org/10.1021/ja209163wopenalex-snapshot
Mechanistic Investigations of the ZnCl 2 -Mediated Tandem Mukaiyama Aldol Lactonization: Evidence for Asynchronous, Concerted Transition States and Discovery of 2-Oxopyridyl Ketene Acetal Variants
inferred← citeshttps://doi.org/10.1021/ja303414aopenalex-snapshot
Dyotropic Rearrangements of Fused Tricyclic β-Lactones: Application to the Synthesis of (−)-Curcumanolide A and (−)-Curcumalactone
inferred← citeshttps://doi.org/10.1021/ja3043245openalex-snapshot
Effect of Isotopically Sensitive Branching on Product Distribution for Pentalenene Synthase: Support for a Mechanism Predicted by Quantum Chemistry
inferred← citeshttps://doi.org/10.1021/ja503520topenalex-snapshot
Mn-Catalyzed Three-Component Reactions of Imines/Nitriles, Grignard Reagents, and Tetrahydrofuran: An Expedient Access to 1,5-Amino/Keto Alcohols
inferred← citeshttps://doi.org/10.1021/ja511236dopenalex-snapshot
Mechanistic Studies of Copper(I)-Catalyzed 1,3-Halogen Migration
inferred← citeshttps://doi.org/10.1021/jacs.1c01856openalex-snapshot
Computational Exploration of the Mechanism of Critical Steps in the Biomimetic Synthesis of Preuisolactone A, and Discovery of New Ambimodal (5 + 2)/(4 + 2) Cycloadditions
inferred← citeshttps://doi.org/10.1021/jacs.2c02487openalex-snapshot
Switchable 1,2-Rearrangement Enables Expedient Synthesis of Structurally Diverse Fluorine-Containing Scaffolds
inferred← citeshttps://doi.org/10.1021/jacs.2c06578openalex-snapshot
Migrative Carbofluorination of Saturated Amides Enabled by Pd-Based Dyotropic Rearrangement
inferred← citeshttps://doi.org/10.1021/jacs.3c06158openalex-snapshot
Diverting the 5-exo-Trig Oxypalladation to Formally 6-endo-Trig Fluorocycloetherification Product through 1,2-O/Pd(IV) Dyotropic Rearrangement
inferred← citeshttps://doi.org/10.1021/jacs.3c13371openalex-snapshot
Tethering Three Radical Cascades for Controlled Termination of Radical Alkyne peri-Annulations: Making Phenalenyl Ketones without Oxidants
inferred← citeshttps://doi.org/10.1021/jacs.4c02924openalex-snapshot
Editing Tetrasubstituted Carbon: Dual C–O Bond Functionalization of Tertiary Alcohols Enabled by Palladium-Based Dyotropic Rearrangement
inferred← citeshttps://doi.org/10.1021/jacs.4c06526openalex-snapshot
Stereospecific Phosphination and Thioetherification of Organoboronic Esters
inferred← citeshttps://doi.org/10.1021/jacs.4c07900openalex-snapshot
Concise Total Syntheses of ( − )-Crinipellins A and B Enabled by a Controlled Cargill Rearrangement
inferred← citeshttps://doi.org/10.1021/jacs.4c13298openalex-snapshot
Facile Synthesis of Housanes by an Unexpected Strategy
inferred← citeshttps://doi.org/10.1021/jacs.4c13359openalex-snapshot
Chemoselective Pd-Based Dyotropic Rearrangement: Fluorocyclization and Regioselective Wacker Reaction of Homoallylic Amides
inferred← citeshttps://doi.org/10.1021/jacs.4c15764openalex-snapshot
Chemoselectivity in Pd-Based Dyotropic Rearrangement: Development and Application in Total Synthesis of Pheromones
inferred← citeshttps://doi.org/10.1021/jacs.4c17818openalex-snapshot
Characterization and Engineering of a Bisabolene Synthase Reveal an Unusual Hydride Shift and Key Residues Critical for Mono-, Bi-, and Tricyclic Sesquiterpenes Formation
inferred← citeshttps://doi.org/10.1021/jacs.5b03718openalex-snapshot
Computational and Experimental Investigations of the Formal Dyotropic Rearrangements of Himbert Arene/Allene Cycloadducts
inferred← citeshttps://doi.org/10.1021/jacs.5b07858openalex-snapshot
Mollenynes B–E from the Marine Sponge Spirastrella mollis. Band-Selective Heteronuclear Single Quantum Coherence for Discrimination of Bromo–Chloro Regioisomerism in Natural Products
inferred← citeshttps://doi.org/10.1021/jacs.5c01108openalex-snapshot
Pd-Catalyzed Strain-Releasing Dyotropic Rearrangement: Ring-Expanding Amidofluorination of Methylenecyclobutanes
inferred← citeshttps://doi.org/10.1021/jacs.6b03720openalex-snapshot
A Bioinspired Cyclization Sequence Enables the Asymmetric Total Synthesis of Dictyoxetane
inferred← citeshttps://doi.org/10.1021/jacs.7b05574openalex-snapshot
Nickel-Catalyzed C–H Silylation of Arenes with Vinylsilanes: Rapid and Reversible β-Si Elimination
inferred← citeshttps://doi.org/10.1021/jacs.7b07706openalex-snapshot
A Unifying Synthesis Approach to the C18-, C19-, and C20-Diterpenoid Alkaloids
inferred← citeshttps://doi.org/10.1021/jacs.7b07792openalex-snapshot
Enantiospecific Solvolytic Functionalization of Bromochlorides
inferred← citeshttps://doi.org/10.1021/jacs.8b00821openalex-snapshot
Stereospecific Ring Contraction of Bromocycloheptenes through Dyotropic Rearrangements via Nonclassical Carbocation–Anion Pairs
inferred← citeshttps://doi.org/10.1021/jo2012175openalex-snapshot
Switching between Concerted and Stepwise Mechanisms for Dyotropic Rearrangements of β-Lactones Leading to Spirocyclic, Bridged γ-Butyrolactones
inferred← citeshttps://doi.org/10.1021/jo301864hopenalex-snapshot
Analogies between Synthetic and Biosynthetic Reactions in Which [1,2]-Alkyl Shifts Are Combined with Other Events: Dyotropic, Schmidt, and Carbocation Rearrangements
inferred← citeshttps://doi.org/10.1021/jo3024208openalex-snapshot
Triple Shifts and Thioether Assistance in Rearrangements Associated with an Unusual Biomethylation of the Sterol Side Chain
inferred← citeshttps://doi.org/10.1021/jo400837nopenalex-snapshot
Noyori Hydrogenation: Aromaticity, Synchronicity, and Activation Strain Analysis
inferred← citeshttps://doi.org/10.1021/jo401106mopenalex-snapshot
Lewis Acid-Promoted Cyclization Reactions of Alkenyl Ethenetricarboxylates: Stereoselective Synthesis of 2-Oxotetrahydrofurans and 2-Oxopyrrolidines
inferred← citeshttps://doi.org/10.1021/jo500233zopenalex-snapshot
Nonclassical CH−π Supramolecular Interactions in Artemisinic Acid Favor a Single Conformation, Yielding High Diastereoselectivity in the Reduction with Diazene
inferred← citeshttps://doi.org/10.1021/jo902685xopenalex-snapshot
Dissecting a Dyotropic Rearrangement
inferred← citeshttps://doi.org/10.1021/jp4032767openalex-snapshot
Unimolecular Isomerization of CH2FCD2Cl via the Interchange of Cl and F Atoms: Assignment of the Threshold Energy to the 1,2-Dyotropic Rearrangement
inferred← citeshttps://doi.org/10.1021/jp412299popenalex-snapshot
Effects of CF3 and CH3 Groups on the Threshold Energy for the Unimolecular Interchange Reaction of Cl- and F-Atoms in CF3CHFCH2Cl and CH3CHFCH2Cl
inferred← citeshttps://doi.org/10.1021/ol200910zopenalex-snapshot
Trapping Intermediates in an [8 + 2] Cycloaddition Reaction with the Help of DFT Calculations
inferred← citeshttps://doi.org/10.1021/om1000875openalex-snapshot
Unimolecular Reactions of Organocuprates and Organoargentates
inferred← citeshttps://doi.org/10.1021/om301019sopenalex-snapshot
Studies of 1,2-Dihalo Shifts in Carbon–Carbon, Carbon–Silicon, and Silicon–Silicon Systems: A Computational Study
inferred← citeshttps://doi.org/10.1038/nature12492openalex-snapshot
Alkane desaturation by concerted double hydrogen atom transfer to benzyne
inferred← citeshttps://doi.org/10.1038/s41557-021-00698-yopenalex-snapshot
C–C bond activation enabled by dyotropic rearrangement of Pd(iv) species
inferred← citeshttps://doi.org/10.1038/s41557-023-01236-8openalex-snapshot
Copper-catalysed difluorocarbene transfer enables modular synthesis
inferred← citeshttps://doi.org/10.1038/s41557-025-01834-8openalex-snapshot
Oxygen transposition of formamide to α-aminoketone moiety in a carbene-initiated domino reaction
inferred← citeshttps://doi.org/10.1038/s42004-018-0099-7openalex-snapshot
Triple photochemical domino reaction of a tetrafluorostilbene terminating in double fluorine atom transfer
inferred← citeshttps://doi.org/10.1038/s44160-025-00979-1openalex-snapshot
Concerted 1,3-migration through regiodivergent consecutive 1,2-rearrangements using palladium catalysis
inferred← citeshttps://doi.org/10.1039/b917107jopenalex-snapshot
The carbocation continuum in terpene biosynthesis—where are the secondary cations?
inferred← citeshttps://doi.org/10.1039/c0dt00508hopenalex-snapshot
Gas phase synthesis and reactivity of dimethylaurate
inferred← citeshttps://doi.org/10.1039/c0ob00167hopenalex-snapshot
Quantum chemical dissection of the classic terpinyl/pinyl/bornyl/camphyl cation conundrum—the role of pyrophosphate in manipulating pathways to monoterpenes
inferred← citeshttps://doi.org/10.1039/c1np00006copenalex-snapshot
Biosynthesis via carbocations: Theoretical studies on terpene formation
inferred← citeshttps://doi.org/10.1039/c2cc30914aopenalex-snapshot
Rearrangement from the heteroantiaromatic borole to the heteroaromatic azaborine motif
inferred← citeshttps://doi.org/10.1039/c2cc33676fopenalex-snapshot
Verification of stereospecific dyotropic racemisation of enantiopure d and l-1,2-dibromo-1,2-diphenylethane in non-polar media
inferred← citeshttps://doi.org/10.1039/c2cc38704bopenalex-snapshot
Reversible aryl migrations in metallated ureas: controlled inversion of configuration at a quaternary carbon atom
inferred← citeshttps://doi.org/10.1039/c2ob26241jopenalex-snapshot
Theoretical and experimental exploration of the photochemistry of resveratrol: beyond the simple double bond isomerization
inferred← citeshttps://doi.org/10.1039/c3cc44073gopenalex-snapshot
Iodine recycling via 1,3-migration in iodoindoles under metal catalysis
inferred← citeshttps://doi.org/10.1039/c3cs60452gopenalex-snapshot
How cyclobutanes are assembled in nature – insights from quantum chemistry
inferred← citeshttps://doi.org/10.1039/c3cs60457hopenalex-snapshot
Allenes and computational chemistry: from bonding situations to reaction mechanisms
inferred← citeshttps://doi.org/10.1039/c3ob42005aopenalex-snapshot
Pentalenene formation mechanisms redux
inferred← citeshttps://doi.org/10.1039/c4cc03450copenalex-snapshot
A metal-free dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of organoboronic acids
inferred← citeshttps://doi.org/10.1039/c4cc07311hopenalex-snapshot
Is it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?
inferred← citeshttps://doi.org/10.1039/c4cp00346bopenalex-snapshot
Combined activation strain model and energy decomposition analysis methods: a new way to understand pericyclic reactions
inferred← citeshttps://doi.org/10.1039/c4cs00055bopenalex-snapshot
The activation strain model and molecular orbital theory: understanding and designing chemical reactions
inferred← citeshttps://doi.org/10.1039/c4nj02300eopenalex-snapshot
In silico study on the mechanism of formation of hydrazine and nitrogen in the reactions of excess hydroxylamine with 2,4-dinitrophenyl diethyl phosphate
inferred← citeshttps://doi.org/10.1039/c5dt00942aopenalex-snapshot
Copper mediated decyano decarboxylative coupling of cyanoacetate ligands: Pesci versus Lewis acid mechanism
inferred← citeshttps://doi.org/10.1039/c5dt03918eopenalex-snapshot
Functionalized alkynyl-chlorogermanes: hydrometallation, Ge–Cl bond activation, Ge–H bond formation and chlorine-tert-butyl exchange via a transient germyl cation
inferred← citeshttps://doi.org/10.1039/c5ra25482eopenalex-snapshot
Type-I dyotropic rearrangement for 1,2-disubstituted cyclohexanes: substitution effect on activation energy
inferred← citeshttps://doi.org/10.1039/c6cs00935bopenalex-snapshot
Recent applications of the 1,2-carbon atom migration strategy in complex natural product total synthesis
inferred← citeshttps://doi.org/10.1039/c7cp03820hopenalex-snapshot
Reactions between microhydrated superoxide anions and formic acid
inferred← citeshttps://doi.org/10.1039/c7np00005gopenalex-snapshot
Dyotropic rearrangements in natural product total synthesis and biosynthesis
inferred← citeshttps://doi.org/10.1039/c8qo00729bopenalex-snapshot
Nickel catalyzed regio- and stereoselective arylation and methylation of allenamides via coupling reactions. An experimental and computational study
inferred← citeshttps://doi.org/10.1039/d0cp05000hopenalex-snapshot
Effects of electrostatic drag on the velocity of hydrogen migration – pre- and post-transition state enthalpy/entropy compensation
inferred← citeshttps://doi.org/10.1039/d1cc06365kopenalex-snapshot
Hydroboration of vinyl halides with mesitylborane: a direct access to (mesityl)(alkyl)haloboranes
inferred← citeshttps://doi.org/10.1039/d1ob02150hopenalex-snapshot
On the mechanism of the dyotropic expansion of hydrindanes into decalins
inferred← citeshttps://doi.org/10.1039/d1qo01591eopenalex-snapshot
Elucidating the selectivity of dyotropic rearrangements of β-lactones: a computational survey
inferred← citeshttps://doi.org/10.1039/d2cc00233gopenalex-snapshot
Understanding the reactivity of frustrated Lewis pairs with the help of the activation strain model–energy decomposition analysis method
inferred← citeshttps://doi.org/10.1039/d2qo01740gopenalex-snapshot
Aconitine synthesis studies. A modeling construction of the functionalized BCDE tetracyclic ring system
inferred← citeshttps://doi.org/10.1039/d2ra03399bopenalex-snapshot
Organic transformations in the confined space of porous organic cage CC2; catalysis or inhibition
inferred← citeshttps://doi.org/10.1039/d3ob02052eopenalex-snapshot
Dehydration of alcohols catalyzed by copper( ii ) sulfate: type II dyotropic reactions and stepwise mechanisms
inferred← citeshttps://doi.org/10.1039/d3sc03222aopenalex-snapshot
Rearrangement of a carboxy-substituted spiro[4.4]nonatriene to annulated fulvenes through a Pd( ii )-mediated 1,5-vinyl shift
inferred← citeshttps://doi.org/10.1039/d4cp00029copenalex-snapshot
Breaking the plane: B 5 H 5 is a three-dimensional structure
inferred← citeshttps://doi.org/10.1039/d4ra02821jopenalex-snapshot
A concise and stereoselective synthesis of the BCDF tetracyclic ring system of C 19 -diterpenoid alkaloids
inferred← citeshttps://doi.org/10.1039/d5cc04941eopenalex-snapshot
Synthesis and reactivity of a small distibacycle featuring an Au–Sb bimetallic linkage
inferred← citeshttps://doi.org/10.1039/d6cs00145aopenalex-snapshot
Functional group translocation: moving functionalities without changing molecular scaffolds
inferred← citeshttps://doi.org/10.1055/a-2640-7480openalex-snapshot
The Cargill-Type Rearrangement in Natural Product Synthesis
inferred← citeshttps://doi.org/10.1126/science.adg3182openalex-snapshot
Oxidative rearrangement of 1,1-disubstituted alkenes to ketones
inferred← citeshttps://doi.org/10.1126/science.adw3340openalex-snapshot
Leveraging triatropic rearrangements for stereoselective skeletal reshuffling
inferred← citeshttps://doi.org/10.1139/cjc-2016-0293openalex-snapshot
Computational study of the threshold energy for the 1,2-interchange of X and R (X, R = halogens, pseudohalogens, and monovalent hydrocarbon groups) on CH2XCH2R
inferred← citeshttps://doi.org/10.1515/pac-2018-1010openalex-snapshot
Glossary of terms used in physical organic chemistry (IUPAC Recommendations 2021)
inferred← citeshttps://doi.org/10.3762/bjoc.21.125openalex-snapshot
Transition-state aromaticity and its relationship with reactivity in pericyclic reactions
inferred← citeshttps://doi.org/10.3987/com-18-s(f)5openalex-snapshot
CsF-Promoted Desilylation and Ring-Contraction Reaction of Electron-Deficient 3-Silyl-2H-chromenes to 2-Benzylbenzofurans
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