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Fluoride Ion Complexation and Sensing Using Organoboron Compounds

https://doi.org/10.1021/cr900401a
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Boron Chemistry Lights the Way: Optical Properties of Molecular and Polymeric Systems C.D.E. thanks EPSRC for a postgraduate studentship and Syngenta for a postgraduate scholarship, and T.B.M. thanks the University of Durham for support and Prof. Dr. K. Tamao for a preprint of ref. 32.
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inferred← citeshttps://doi.org/10.1002/ange.202509567openalex-snapshot
Modular Assembly of B(III)‐Coordinated Fluorophores with Quantitatively Predictable Photoinduced Electron Transfer for Chemosensing and Bioimaging
inferred← citeshttps://doi.org/10.1002/ange.202509778openalex-snapshot
Titanium‐Catalyzed C─X and C─H Borylation of Aryl Halides for the Synthesis of Bis(boronate)benzenes
inferred← citeshttps://doi.org/10.1002/ange.202512271openalex-snapshot
Feedstock‐Derived Thiophene Radical Anions Exhibiting Redox Stability at Extreme Potentials
inferred← citeshttps://doi.org/10.1002/ange.202523338openalex-snapshot
Temperature‐Responsive Near‐Infrared Emission Enabled by Reversible π‐Umpolung with an Alkenyl‐Strapped Diarylboryl Unit
inferred← citeshttps://doi.org/10.1002/anie.201106242openalex-snapshot
Sensing of Aqueous Fluoride Anions by Cationic Stibine–Palladium Complexes
inferred← citeshttps://doi.org/10.1002/anie.201201781openalex-snapshot
Double Cyclization/Aryl Migration Across an Alkyne Bond Enabled by Organoboryl and Diarylplatinum Groups
inferred← citeshttps://doi.org/10.1002/anie.201203788openalex-snapshot
π‐Expanded Borazine: An Ambipolar Conjugated B–π–N Macrocycle
inferred← citeshttps://doi.org/10.1002/anie.201207335openalex-snapshot
Confirmation of an Early Postulate: BCB Two‐Electron–Three‐Center Bonding in Organo(hydro)boranes
inferred← citeshttps://doi.org/10.1002/anie.201210236openalex-snapshot
Borylated Dibenzoborepin: Synthesis by Skeletal Rearrangement and Photochromism Based on Bora‐Nazarov Cyclization
inferred← citeshttps://doi.org/10.1002/anie.201300873openalex-snapshot
Formation of Azaborines by Photoelimination of B,N‐Heterocyclic Compounds
inferred← citeshttps://doi.org/10.1002/anie.201302818openalex-snapshot
α‐Boryl Isocyanides Enable Facile Preparation of Bioactive Boropeptides
inferred← citeshttps://doi.org/10.1002/anie.201304827openalex-snapshot
Tunable Photochromism in Air‐Stable, Robust Dithienylethene‐Containing Phospholes through Modifications at the Phosphorus Center
inferred← citeshttps://doi.org/10.1002/anie.201309707openalex-snapshot
Direct Synthetic Route to Functionalized 1,2‐Azaborinines
inferred← citeshttps://doi.org/10.1002/anie.201309937openalex-snapshot
Advances in Anion Supramolecular Chemistry: From Recognition to Chemical Applications
inferred← citeshttps://doi.org/10.1002/anie.201402815openalex-snapshot
Trihapto Ligation of a Borirene to a Single Metal Atom: A Heterocyclic Analogue of the η 3 ‐Cyclopropenyl Ligand
inferred← citeshttps://doi.org/10.1002/anie.201403247openalex-snapshot
Redox Chemistry of a Hydroxyphenyl‐Substituted Borane
inferred← citeshttps://doi.org/10.1002/anie.201403700openalex-snapshot
Highly Electron‐Deficient and Air‐Stable Conjugated Thienylboranes
inferred← citeshttps://doi.org/10.1002/anie.201403703openalex-snapshot
A Borinic Acid Polymer with Fluoride Ion‐ and Thermo‐responsive Properties that are Tunable over a Wide Temperature Range
inferred← citeshttps://doi.org/10.1002/anie.201411814openalex-snapshot
A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of “Rather Labile” Fluoride Anions
inferred← citeshttps://doi.org/10.1002/anie.201411973openalex-snapshot
Developing Conjugated Polymers with High Electron Affinity by Replacing a CC Unit with a B ← N Unit
inferred← citeshttps://doi.org/10.1002/anie.201500487openalex-snapshot
Reversible 1,1‐Hydroboration: Boryl Insertion into a CN Bond and Competitive Elimination of HBR2 or RH
inferred← citeshttps://doi.org/10.1002/anie.201502678openalex-snapshot
A Planarized Triphenylborane Mesogen: Discotic Liquid Crystals with Ambipolar Charge‐Carrier Transport Properties
inferred← citeshttps://doi.org/10.1002/anie.201503219openalex-snapshot
Versatile Design Principles for Facile Access to Unstrained Conjugated Organoborane Macrocycles
inferred← citeshttps://doi.org/10.1002/anie.201504997openalex-snapshot
A Solution‐Processable Donor–Acceptor Compound Containing Boron(III) Centers for Small‐Molecule‐Based High‐Performance Ternary Electronic Memory Devices
inferred← citeshttps://doi.org/10.1002/anie.201505766openalex-snapshot
Stepwise Reduction of 9,10‐Bis(dimesitylboryl)anthracene
inferred← citeshttps://doi.org/10.1002/anie.201510946openalex-snapshot
Boron(III)‐Containing Donor–Acceptor Compound with Goldlike Reflective Behavior for Organic Resistive Memory Devices
inferred← citeshttps://doi.org/10.1002/anie.201611009openalex-snapshot
Fluoride Anion Complexation by a Triptycene‐Based Distiborane: Taking Advantage of a Weak but Observable C−H⋅⋅⋅F Interaction
inferred← citeshttps://doi.org/10.1002/anie.201701303openalex-snapshot
From Bidentate Gallium Lewis Acids to Supramolecular Complexes
inferred← citeshttps://doi.org/10.1002/anie.201701570openalex-snapshot
Selective and Reversible Fluoride Complexation from Water by a Cyclic Tri(phosphonio)methanide Dication
inferred← citeshttps://doi.org/10.1002/anie.201702296openalex-snapshot
Lanthanide Complexes that Respond to Changes in Cyanide Concentration in Water
inferred← citeshttps://doi.org/10.1002/anie.201704642openalex-snapshot
Reversible Photothermal Isomerization of Carborane‐Fused Azaborole to Borirane: Synthesis and Reactivity of Carbene‐Stabilized Carborane‐Fused Borirane
inferred← citeshttps://doi.org/10.1002/anie.201706346openalex-snapshot
Synthesis of a Doubly Boron‐Doped Perylene through NHC‐Borenium Hydroboration/C−H Borylation/Dehydrogenation
inferred← citeshttps://doi.org/10.1002/anie.201709494openalex-snapshot
Exploiting the Strong Hydrogen Bond Donor Properties of a Borinic Acid Functionality for Fluoride Anion Recognition
inferred← citeshttps://doi.org/10.1002/anie.201812696openalex-snapshot
Bidentate Boron Lewis Acids: Selectivity in Host–Guest Complex Formation
inferred← citeshttps://doi.org/10.1002/anie.201901171openalex-snapshot
In Situ Formation of Frustrated Lewis Pairs in a Water‐Tolerant Metal‐Organic Framework for the Transformation of CO 2
inferred← citeshttps://doi.org/10.1002/anie.201902231openalex-snapshot
Reversible Photoisomerization from Borepin to Boratanorcaradiene and Double Aryl Migration from Boron to Carbon
inferred← citeshttps://doi.org/10.1002/anie.201906497openalex-snapshot
Alternating Radical Stabilities: A Convergent Route to Terminal and Internal Boronates
inferred← citeshttps://doi.org/10.1002/anie.201906644openalex-snapshot
Different Modes of Anion Response Cause Circulatory Phase Transfer of a Coordination Cage with Controlled Directionality
inferred← citeshttps://doi.org/10.1002/anie.201910908openalex-snapshot
Pushing the Lewis Acidity Boundaries of Boron Compounds With Non‐Planar Triarylboranes Derived from Triptycenes
inferred← citeshttps://doi.org/10.1002/anie.201914958openalex-snapshot
Phosphonium Boranes for the Selective Transport of Fluoride Anions across Artificial Phospholipid Membranes
inferred← citeshttps://doi.org/10.1002/anie.202000406openalex-snapshot
Synthesis and Reactivity of Cationic Boron Complexes Distorted by Pyridine‐based Pincer Ligands: Isolation of a Photochemical Hofmann–Martius‐type Intermediate
inferred← citeshttps://doi.org/10.1002/anie.202001145openalex-snapshot
Planar Chiral Organoboranes with Thermoresponsive Emission and Circularly Polarized Luminescence: Integration of Pillar[5]arenes with Boron Chemistry
inferred← citeshttps://doi.org/10.1002/anie.202001520openalex-snapshot
Iridium‐Catalysed C−H Borylation of Heteroarenes: Balancing Steric and Electronic Regiocontrol
inferred← citeshttps://doi.org/10.1002/anie.202001904openalex-snapshot
Enhancing the Acceptor Character of Conjugated Organoborane Macrocycles: A Highly Electron‐Deficient Hexaboracyclophane
inferred← citeshttps://doi.org/10.1002/anie.202003119openalex-snapshot
Controlled Generation of 9‐Boratriptycene by Lewis Adduct Dissociation: Accessing a Non‐Planar Triarylborane
inferred← citeshttps://doi.org/10.1002/anie.202007610openalex-snapshot
Persistent Room Temperature Phosphorescence from Triarylboranes: A Combined Experimental and Theoretical Study
inferred← citeshttps://doi.org/10.1002/anie.202013692openalex-snapshot
Phenylpyridyl‐Fused Boroles: A Unique Coordination Mode and Weak B−N Coordination‐Induced Dual Fluorescence
inferred← citeshttps://doi.org/10.1002/anie.202100295openalex-snapshot
Dithiophene‐Fused Oxadiborepins and Azadiborepins: A New Class of Highly Fluorescent Heteroaromatics
inferred← citeshttps://doi.org/10.1002/anie.202112342openalex-snapshot
Taming the Lewis Superacidity of Non‐Planar Boranes: C−H Bond Activation and Non‐Classical Binding Modes at Boron
inferred← citeshttps://doi.org/10.1002/anie.202114586openalex-snapshot
Redox‐Active Heteroatom‐Functionalized Polyacetylenes
inferred← citeshttps://doi.org/10.1002/anie.202200612openalex-snapshot
A New Platform of B/N‐Doped Cyclophanes: Access to a π‐Conjugated Block‐Type B 3 N 3 Macrocycle with Strong Dipole Moment and Unique Optoelectronic Properties
inferred← citeshttps://doi.org/10.1002/anie.202205506openalex-snapshot
A Three‐Dimensional Inorganic Analogue of 9,10‐Diazido‐9,10‐Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability
inferred← citeshttps://doi.org/10.1002/anie.202207067openalex-snapshot
The Impact of Boron Hybridisation on Photocatalytic Processes
inferred← citeshttps://doi.org/10.1002/anie.202209394openalex-snapshot
Olefin–Borane Interactions in Donor–π–Acceptor Fluorophores that Undergo Frustrated‐Lewis‐Pair‐Type Reactions
inferred← citeshttps://doi.org/10.1002/anie.202209539openalex-snapshot
Regioselective Transition‐Metal‐Free C(sp2)−H Borylation: A Subject of Practical and Ongoing Interest in Synthetic Organic Chemistry
inferred← citeshttps://doi.org/10.1002/anie.202213615openalex-snapshot
Dynamic B/N Lewis Pairs: Insights into the Structural Variations and Photochromism via Light‐Induced Fluorescence to Phosphorescence Switching
inferred← citeshttps://doi.org/10.1002/anie.202303725openalex-snapshot
Photodissociative Modules that Control Dual‐Emission Properties in Donor–π–Acceptor Organoborane Fluorophores
inferred← citeshttps://doi.org/10.1002/anie.202307540openalex-snapshot
Direct Light‐Enabled Access to α‐Boryl Radicals: Application in the Stereodivergent Synthesis of Allyl Boronic Esters**
inferred← citeshttps://doi.org/10.1002/anie.202313379openalex-snapshot
Boron‐Nitrogen Lewis Pairs in the Assembly of Supramolecular Macrocycles, Molecular Cages, Polymers, and 3D Materials
inferred← citeshttps://doi.org/10.1002/anie.202317614openalex-snapshot
Catalyst‐Free Regioselective Diborylation of Aryllithium with Tetra( o ‐tolyl)diborane(4)
inferred← citeshttps://doi.org/10.1002/anie.202404149openalex-snapshot
Cyclic Azahelicene Dimers Showing Bright Circularly Polarized Luminescence and Selective Fluoride Recognition
inferred← citeshttps://doi.org/10.1002/anie.202405158openalex-snapshot
Anion‐Responsive Colorimetric and Fluorometric Red‐Shift in Triarylborane Derivatives: Dual Role of Phenazaborine as Lewis Acid and Electron Donor
inferred← citeshttps://doi.org/10.1002/anie.202405412openalex-snapshot
Bis‐ Ortho ‐Donor‐Modification of Boracyclic π‐Electron Systems beyond Steric Protection to Produce Thermally Activated Delayed Fluorescence Materials
inferred← citeshttps://doi.org/10.1002/anie.202418546openalex-snapshot
B,N‐Embedded Helical Nanographenes Showing an Ion‐Triggered Chiroptical Switching Function
inferred← citeshttps://doi.org/10.1002/anie.202421931openalex-snapshot
Atropisomerism in Triarylboranes: Lewis Base Assisted Rotation at C−B Stereogenic Axis in Asymmetrical Boron Lewis Acids
inferred← citeshttps://doi.org/10.1002/anie.202502582openalex-snapshot
Gem ‐Diboronic Acids: A Motif for Anion Recognition in Competitive Media
inferred← citeshttps://doi.org/10.1002/anie.202509567openalex-snapshot
Modular Assembly of B(III)‐Coordinated Fluorophores with Quantitatively Predictable Photoinduced Electron Transfer for Chemosensing and Bioimaging
inferred← citeshttps://doi.org/10.1002/anie.202509778openalex-snapshot
Titanium‐Catalyzed C─X and C─H Borylation of Aryl Halides for the Synthesis of Bis(boronate)benzenes
inferred← citeshttps://doi.org/10.1002/anie.202512271openalex-snapshot
Feedstock‐Derived Thiophene Radical Anions Exhibiting Redox Stability at Extreme Potentials
inferred← citeshttps://doi.org/10.1002/anie.202523338openalex-snapshot
Temperature‐Responsive Near‐Infrared Emission Enabled by Reversible π‐Umpolung with an Alkenyl‐Strapped Diarylboryl Unit
inferred← citeshttps://doi.org/10.1002/aoc.3858openalex-snapshot
Synthesis, physicochemical characterization, geometric structure and molecular docking of new biologically active ferrocene based Schiff base ligand with transition metal ions
inferred← citeshttps://doi.org/10.1002/aoc.4688openalex-snapshot
Isophorone‐boronate ester: A simple chemosensor for optical detection of fluoride anion
inferred← citeshttps://doi.org/10.1002/aoc.4718openalex-snapshot
Organoboron Schiff bases as cell‐staining fluorescent probes: Synthesis, Chemio‐photophysical characterization, DFT, and X‐ray structures
inferred← citeshttps://doi.org/10.1002/asia.201300872openalex-snapshot
Effect of the Substitution Pattern on the Intramolecular Charge‐Transfer Emissions in Organoboron‐Based Biphenyls, Diphenylacetylenes, and Stilbenes
inferred← citeshttps://doi.org/10.1002/asia.201301123openalex-snapshot
A Pyrene Derivative for Hg2+‐Selective Fluorescent Sensing and Its Application in In Vivo Imaging
inferred← citeshttps://doi.org/10.1002/asia.201301670openalex-snapshot
Phosphorus‐Containing Materials for Organic Electronics
inferred← citeshttps://doi.org/10.1002/asia.201801682openalex-snapshot
Synthesis of Tetracoordinate Boron‐Fused Benzoaceanthrylene Analogs via Tandem Electrophilic C−H Borylation
inferred← citeshttps://doi.org/10.1002/asia.201900016openalex-snapshot
Doping the Backbone of π‐Conjugated Polymers with Tricoordinate Boron: Synthetic Strategies and Emerging Applications
inferred← citeshttps://doi.org/10.1002/asia.202000958openalex-snapshot
Panchromatic Organoboron Molecules with Tunable Absorption Spectra
inferred← citeshttps://doi.org/10.1002/asia.202300714openalex-snapshot
A Lewis Acid‐Base Pair Catalyzed Dearomative Transformation of Unprotected Indoles via B−H Bond Activation
inferred← citeshttps://doi.org/10.1002/asia.202400724openalex-snapshot
Naphthalene Diimide and Bis‐Heteroleptic Ru(II) Complex‐Based Hybrid Molecule with 3‐in‐1 Functionalities
inferred← citeshttps://doi.org/10.1002/asia.202401196openalex-snapshot
Syntheses of Variants of π(σ) Aromatic Modified N‐Methyl N‐Confused Porphyrinoids with Adaptive Properties
inferred← citeshttps://doi.org/10.1002/bio.2564openalex-snapshot
A colorimetric and fluorescent probe for fluoride ions based on 6‐acetyl‐2‐naphthol
inferred← citeshttps://doi.org/10.1002/bio.3044openalex-snapshot
A highly sensitive and selective fluorescent probe for fluoride anions based on intramolecular charge transfer
inferred← citeshttps://doi.org/10.1002/bio.3048openalex-snapshot
A selective chromofluorogenic chemodosimeter for fluoride ions based on distyrylbenzenes derivatives containing dual Si–O groups
inferred← citeshttps://doi.org/10.1002/bio.3290openalex-snapshot
A highly selective colorimetric and fluorescent dual‐modal probe for the rapid determination of fluoride anions
inferred← citeshttps://doi.org/10.1002/bio.3667openalex-snapshot
Synthesis, structure and density functional theory calculations of a novel photoluminescent trisarylborane–bismuth(III) complex
inferred← citeshttps://doi.org/10.1002/bkcs.10790openalex-snapshot
Triarylboryl‐Functionalized Oxadiazole as a Host Material with Electron Transporting Property for Green PhOLEDs
inferred← citeshttps://doi.org/10.1002/bkcs.11595openalex-snapshot
Quinolinol‐based Al/Triarylborane Dyad Assembly: Alteration of Electronic Transition States Mediated by Fluoride Anion Binding
inferred← citeshttps://doi.org/10.1002/ceur.202500135openalex-snapshot
Boron‐Doped Polycyclic Aromatic Hydrocarbons: Synthesis and Functional Properties
inferred← citeshttps://doi.org/10.1002/chem.201002861openalex-snapshot
Turn‐On Fluorescence Sensing of Cyanide Ions in Aqueous Solution at Parts‐per‐Billion Concentrations
inferred← citeshttps://doi.org/10.1002/chem.201101701openalex-snapshot
Unsymmetrically Substituted 9,10‐Dihydro‐9,10‐diboraanthracenes as Versatile Building Blocks for Boron‐Doped π‐Conjugated Systems
inferred← citeshttps://doi.org/10.1002/chem.201104020openalex-snapshot
Charge‐Transfer Interactions in Tris‐Donor–Tris‐Acceptor Hexaarylbenzene Redox Chromophores
inferred← citeshttps://doi.org/10.1002/chem.201200761openalex-snapshot
Convenient Syntheses and Photophysical Properties of 1‐Thio‐ and 1‐Seleno‐1,3‐Butadiene Fluorophores in Rigid Dibenzobarrelene and Benzobarrelene Skeletons
inferred← citeshttps://doi.org/10.1002/chem.201201547openalex-snapshot
Synthesis, Coupling, and Condensation Reactions of 1,2‐Diborylated Benzenes: An Experimental and Quantum‐Chemical Study
inferred← citeshttps://doi.org/10.1002/chem.201201719openalex-snapshot
Thermodynamics and Conformations in the Formation of Excited States and Their Interconversions for Twisted Donor‐Substituted Tridurylboranes
inferred← citeshttps://doi.org/10.1002/chem.201202280openalex-snapshot
Boron‐Doped Tri(9,10‐anthrylene)s: Synthesis, Structural Characterization, and Optoelectronic Properties
inferred← citeshttps://doi.org/10.1002/chem.201202732openalex-snapshot
A PEGylated Fluorescent Turn‐On Sensor for Detecting Fluoride Ions in Totally Aqueous Media and Its Imaging in Live Cells
inferred← citeshttps://doi.org/10.1002/chem.201202827openalex-snapshot
Synthesis, One‐ and Two‐Photon Photophysical and Excited‐State Properties, and Sensing Application of a New Phosphorescent Dinuclear Cationic Iridium(III) Complex
inferred← citeshttps://doi.org/10.1002/chem.201203887openalex-snapshot
Borylated Arylisoquinolines: Photophysical Properties and Switching Behavior of Promising Tunable Fluorophores
inferred← citeshttps://doi.org/10.1002/chem.201204375openalex-snapshot
Dithiazolo[5,4‐ b :4′,5′‐ d ]phosphole: A Highly Luminescent Electron‐Accepting Building Block
inferred← citeshttps://doi.org/10.1002/chem.201300472openalex-snapshot
Decoration of Gold Nanoparticles by a Double‐Armed Calix[4]pyrrole: A Receptor‐Decorated Nanoensemble for Anion Sensing and Extraction
inferred← citeshttps://doi.org/10.1002/chem.201301330openalex-snapshot
Synthesis of Silicon‐Functionalized Dibenzosilaborins by Intramolecular BH/CH Dehydrogenative Cyclization and Their Tunable Photophysical and Chemical Properties by Silyl Groups
inferred← citeshttps://doi.org/10.1002/chem.201302801openalex-snapshot
Allosteric Indicator Displacement Enzyme Assay for a Cyanogenic Glycoside
inferred← citeshttps://doi.org/10.1002/chem.201403975openalex-snapshot
Triarylboranes with a 2‐Dimesitylboryl‐2’‐(N,N‐dimethylamino)biphenyl Core Unit: Structure–Property Correlations and Sensing Abilities to Discriminate Between F− and CN− Ions
inferred← citeshttps://doi.org/10.1002/chem.201404784openalex-snapshot
Photochromic Dithienylethene‐Containing Triarylborane Derivatives: Facile Approach to Modulate Photochromic Properties with Multi‐addressable Functions
inferred← citeshttps://doi.org/10.1002/chem.201404806openalex-snapshot
N‐Heterocyclic Carbene Formation Induced Fluorescent and Colorimetric Sensing of Fluoride Using Perimidinium Derivatives
inferred← citeshttps://doi.org/10.1002/chem.201405578openalex-snapshot
A Halogen‐Bonding Bis‐triazolium Rotaxane for Halide‐Selective Anion Recognition
inferred← citeshttps://doi.org/10.1002/chem.201405621openalex-snapshot
D–π–A Triarylboron Compounds with Tunable Push–Pull Character Achieved by Modification of Both the Donor and Acceptor Moieties
inferred← citeshttps://doi.org/10.1002/chem.201405691openalex-snapshot
Tunable Photochromism in the Robust Dithienylethene‐Containing Phospholes: Design, Synthesis, Characterization, Electrochemistry, Photophysics, and Photochromic Studies
inferred← citeshttps://doi.org/10.1002/chem.201405803openalex-snapshot
Platinum trans‐Bis(borirene) Complexes Displaying Coplanarity and Communication Across a Platinum Metal Center
inferred← citeshttps://doi.org/10.1002/chem.201500406openalex-snapshot
Highly Luminescent Microporous Organic Polymer with Lewis Acidic Boron Sites on the Pore Surface: Ratiometric Sensing and Capture of F− Ions
inferred← citeshttps://doi.org/10.1002/chem.201500835openalex-snapshot
Highly Lewis Acidic Arylboronate Esters Capable of Colorimetric Turn‐On Response
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