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The Nature of the Bonding in Transition-Metal Compounds
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Metal d.pi.-ligand .pi. conflicts in octahedral oxo, carbyne, and carbonyl complexes
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What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Alkali Metal Covalent Bonding in Nickel Carbonyl Complexes ENi(CO)3−
inferred← citeshttps://doi.org/10.1002/ange.201908572openalex-snapshot
Transition‐Metal Chemistry of Alkaline‐Earth Elements: The Trisbenzene Complexes M(Bz)3(M=Sr, Ba)
inferred← citeshttps://doi.org/10.1002/ange.202002621openalex-snapshot
Side‐On Bonded Beryllium Dinitrogen Complexes
inferred← citeshttps://doi.org/10.1002/ange.202007241openalex-snapshot
Beryllium Atom Mediated Dinitrogen Activation via Coupling with Carbon Monoxide
inferred← citeshttps://doi.org/10.1002/ange.202012867openalex-snapshot
A Homoleptic Beryllium Carbonyl Complex with an End‐On and Side‐On Bridging Carbonyl Ligand
inferred← citeshttps://doi.org/10.1002/ange.202110704openalex-snapshot
Probing Redox Non‐Innocence in Iron–Carbene Complexes {Fe=C(H)Ar}10–11 by 1,2H and 13C Pulse Electron Paramagnetic Resonance
inferred← citeshttps://doi.org/10.1002/ange.202209658openalex-snapshot
On the Bonding Nature in the Crystalline Tri‐Thorium Cluster: Core‐Shell Syngenetic σ‐Aromaticity
inferred← citeshttps://doi.org/10.1002/ange.202418646openalex-snapshot
Aktivierung von Kohlenstoff‐Kohlenstoff Bindungen durch Chrom(I): Spaltung von Dialkinen durch einen 11‐Elektronenkomplex
inferred← citeshttps://doi.org/10.1002/ange.202418738openalex-snapshot
π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene
inferred← citeshttps://doi.org/10.1002/ange.3470057openalex-snapshot
A Borane Sandwich Analogue of Ferrocene
inferred← citeshttps://doi.org/10.1002/anie.200352080openalex-snapshot
A Stable Salt of the Tris(ethene)silver Cation: Structure and Characterization of [Ag(η2‐C2H4)3]+[Al{OC(CF3)3}4]−
inferred← citeshttps://doi.org/10.1002/anie.200352969openalex-snapshot
The Preparation and X‐ray Crystal Structure of [(AgI2)n]⋅n MF6 (M=Sb, As): Diiodine Acting as a Donor in the Planar Polymeric [(AgI2)n]n+
inferred← citeshttps://doi.org/10.1002/anie.200353477openalex-snapshot
Triple Bond to Lead: Synthesis and Characterization of the Plumbylidyne Complex trans‐[Br(PMe3)4MoPbC6H3‐2,6‐Trip2]
inferred← citeshttps://doi.org/10.1002/anie.200461725openalex-snapshot
Tungsten–Lead Triple Bonds: Syntheses, Structures, and Coordination Chemistry of the Plumbylidyne Complexes trans‐[X(PMe3)4WPb(2,6‐Trip2C6H3)]
inferred← citeshttps://doi.org/10.1002/anie.200462444openalex-snapshot
A Boryl Bridged Complex: An Unusual Coordination Mode of the BR2 Ligand
inferred← citeshttps://doi.org/10.1002/anie.200503649openalex-snapshot
Rhodium( I ) Complexes of a PBP Ambiphilic Ligand: Evidence for a Metal→Borane Interaction
inferred← citeshttps://doi.org/10.1002/anie.200503807openalex-snapshot
Boron in the Coordination Spheres of Three Transition‐Metal Atoms: Syntheses and Structures of Metalloborylenes Stabilized by a Transition‐Metal Base
inferred← citeshttps://doi.org/10.1002/anie.200603643openalex-snapshot
Platinum Complexes Featuring Terminally Bound Ga+ and In+ Ions
inferred← citeshttps://doi.org/10.1002/anie.200604335openalex-snapshot
Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids
inferred← citeshttps://doi.org/10.1002/anie.2006831openalex-snapshot
Homoleptic and Heteroleptic Carbones L1‐C‐L2
inferred← citeshttps://doi.org/10.1002/anie.200700278openalex-snapshot
More than Bystanders: The Effect of Olefins on Transition‐Metal‐Catalyzed Cross‐Coupling Reactions
inferred← citeshttps://doi.org/10.1002/anie.200702688openalex-snapshot
Homoleptic Silver(I) Acetylene Complexes
inferred← citeshttps://doi.org/10.1002/anie.200703515openalex-snapshot
Synthesis and Characterization of the Gold(I) Tris(ethylene) Complex [Au(C2H4)3][SbF6]
inferred← citeshttps://doi.org/10.1002/anie.200800827openalex-snapshot
Icon of Chemistry: The Periodic System of Chemical Elements in the New Century
inferred← citeshttps://doi.org/10.1002/anie.200801163openalex-snapshot
Hydrogen Storage in Microporous Metal–Organic Frameworks with Exposed Metal Sites
inferred← citeshttps://doi.org/10.1002/anie.200802490openalex-snapshot
GaI as Ligand in Transition‐Metal Complexes—An Alternative to CO or N2?
inferred← citeshttps://doi.org/10.1002/anie.200805605openalex-snapshot
Substituent‐Free Gallium by Hydrogenolysis of Coordinated GaCp*: Synthesis and Structure of Highly Fluxional [Ru2(Ga)(GaCp*)7(H)3]
inferred← citeshttps://doi.org/10.1002/anie.200901022openalex-snapshot
Coordination and Activation of the BF Molecule
inferred← citeshttps://doi.org/10.1002/anie.201000841openalex-snapshot
Fashionably Late: Synthesis and Characterization of Transition‐Metal–Fluoroborylene Complexes
inferred← citeshttps://doi.org/10.1002/anie.201105097openalex-snapshot
Reversible Binding of Ethylene to Silylene–Phosphine Complexes at Room Temperature
inferred← citeshttps://doi.org/10.1002/anie.201302828openalex-snapshot
An Electron‐Precise, Tetrahedral μ3 Boride Complex
inferred← citeshttps://doi.org/10.1002/anie.201305505openalex-snapshot
Disentanglement of Donation and Back‐Donation Effects on Experimental Observables: A Case Study of Gold–Ethyne Complexes
inferred← citeshttps://doi.org/10.1002/anie.201308517openalex-snapshot
Palladium and Platinum η2‐Disilyne Complexes Bearing an Isolable Dialkyldisilyne as a Ligand
inferred← citeshttps://doi.org/10.1002/anie.201310436openalex-snapshot
A Novel Concept for the Synthesis of Multiply Doped Gold Clusters [(M@AunM′m)Lk]q+
inferred← citeshttps://doi.org/10.1002/anie.201310559openalex-snapshot
Syntheses and Structures of Terminal Arylalumylene Complexes
inferred← citeshttps://doi.org/10.1002/anie.201408453openalex-snapshot
Pd Uptake and H2S Sensing by an Amphoteric Metal–Organic Framework with a Soft Core and Rigid Side Arms
inferred← citeshttps://doi.org/10.1002/anie.201411374openalex-snapshot
No Need for a Re‐examination of the Electrostatic Notation of the Hydrogen Bonding: A Comment
inferred← citeshttps://doi.org/10.1002/anie.201606244openalex-snapshot
New Avenues in s‐Block Chemistry: Beryllium(0) Complexes
inferred← citeshttps://doi.org/10.1002/anie.201609515openalex-snapshot
A Square‐Planar Complex of Platinum(0)
inferred← citeshttps://doi.org/10.1002/anie.201709875openalex-snapshot
Triple Bonds Between Iron and Heavier Group 15 Elements in AFe(CO)3− (A=As, Sb, Bi) Complexes
inferred← citeshttps://doi.org/10.1002/anie.201713002openalex-snapshot
Barium as Honorary Transition Metal in Action: Experimental and Theoretical Study of Ba(CO)+ and Ba(CO)−
inferred← citeshttps://doi.org/10.1002/anie.201801531openalex-snapshot
Formation of Agostic Structures Driven by London Dispersion
inferred← citeshttps://doi.org/10.1002/anie.201801722openalex-snapshot
Bottleable Neutral Analogues of [B2H5]− as Versatile and Strongly Binding η2 Donor Ligands
inferred← citeshttps://doi.org/10.1002/anie.201802590openalex-snapshot
Octacarbonyl Anion Complexes of Group Three Transition Metals [TM(CO)8]− (TM=Sc, Y, La) and the 18‐Electron Rule
inferred← citeshttps://doi.org/10.1002/anie.201813022openalex-snapshot
Alkali Metal Covalent Bonding in Nickel Carbonyl Complexes ENi(CO)3−
inferred← citeshttps://doi.org/10.1002/anie.201908572openalex-snapshot
Transition‐Metal Chemistry of Alkaline‐Earth Elements: The Trisbenzene Complexes M(Bz)3(M=Sr, Ba)
inferred← citeshttps://doi.org/10.1002/anie.202002621openalex-snapshot
Side‐On Bonded Beryllium Dinitrogen Complexes
inferred← citeshttps://doi.org/10.1002/anie.202007241openalex-snapshot
Beryllium Atom Mediated Dinitrogen Activation via Coupling with Carbon Monoxide
inferred← citeshttps://doi.org/10.1002/anie.202012867openalex-snapshot
A Homoleptic Beryllium Carbonyl Complex with an End‐On and Side‐On Bridging Carbonyl Ligand
inferred← citeshttps://doi.org/10.1002/anie.202110704openalex-snapshot
Probing Redox Non‐Innocence in Iron–Carbene Complexes {Fe=C(H)Ar}10–11 by 1,2H and 13C Pulse Electron Paramagnetic Resonance
inferred← citeshttps://doi.org/10.1002/anie.202209658openalex-snapshot
On the Bonding Nature in the Crystalline Tri‐Thorium Cluster: Core‐Shell Syngenetic σ‐Aromaticity
inferred← citeshttps://doi.org/10.1002/anie.202418646openalex-snapshot
Carbon‐Carbon Bond Activation at Chromium(I): An 11‐Electron Complex Cleaving Dialkynes
inferred← citeshttps://doi.org/10.1002/anie.202418738openalex-snapshot
π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene
inferred← citeshttps://doi.org/10.1002/anie.3470057openalex-snapshot
A Borane Sandwich Analogue of Ferrocene
inferred← citeshttps://doi.org/10.1002/aoc.1365openalex-snapshot
Mechanistic study on dimerization of acetylene with a Nieuwland catalyst
inferred← citeshttps://doi.org/10.1002/aoc.7356openalex-snapshot
Spectroscopic and electrochemical characterizations of copper complexes with thionine, azure C and azure A
inferred← citeshttps://doi.org/10.1002/asia.200900624openalex-snapshot
Thermodynamic Stability Versus Kinetic Lability of ZnS4 Core
inferred← citeshttps://doi.org/10.1002/ceur.70308openalex-snapshot
Extending the Boundaries With Electron‐Rich Tris(pyridyl)borates in Classical Silver and Gold Carbonyl Complexes
inferred← citeshttps://doi.org/10.1002/chem.200305467openalex-snapshot
Road Maps for Nitrogen‐Transfer Catalysis: The Challenge of the Osmium( VIII )‐Catalyzed Diamination
inferred← citeshttps://doi.org/10.1002/chem.200306056openalex-snapshot
Active Anionic Zero‐Valent Palladium Catalysts: Characterization by Density Functional Calculations
inferred← citeshttps://doi.org/10.1002/chem.200500248openalex-snapshot
A Theoretical Investigation of the Nonrigid Six‐Coordinate Compounds [Mo(R)F5], [W(R)F5], and Related Compounds
inferred← citeshttps://doi.org/10.1002/chem.200501551openalex-snapshot
Interactions of Neutral and Cationic Transition Metals with the Redox System of Hydroquinone and Quinone: Theoretical Characterization of the Binding Topologies, and Implications for the Formation of Nanomaterials
inferred← citeshttps://doi.org/10.1002/chem.200600324openalex-snapshot
Structure and Bonding in First‐Row Transition‐Metal Dicarbides: Are They Related to the Stability of Met‐cars?
inferred← citeshttps://doi.org/10.1002/chem.200700539openalex-snapshot
Experimental Studies on the trans ‐Influence of Boryl Ligands in Square‐Planar Platinum(II) Complexes
inferred← citeshttps://doi.org/10.1002/chem.200700547openalex-snapshot
Can Electrophilicity Act as a Measure of the Redox Potential of First‐Row Transition Metal Ions?
inferred← citeshttps://doi.org/10.1002/chem.200701265openalex-snapshot
Understanding Lead Chemistry from Topological Insights: The Transition between Holo‐ and Hemidirected Structures within the [Pb(CO)n]2+ Model Series
inferred← citeshttps://doi.org/10.1002/chem.200701390openalex-snapshot
Divalent Carbon(0) Chemistry, Part 1: Parent Compounds
inferred← citeshttps://doi.org/10.1002/chem.200701392openalex-snapshot
Divalent Carbon(0) Chemistry, Part 2: Protonation and Complexes with Main Group and Transition Metal Lewis Acids
inferred← citeshttps://doi.org/10.1002/chem.200801045openalex-snapshot
Effect of Doped Transition Metal on Reversible Hydrogen Release/Uptake from NaAlH4
inferred← citeshttps://doi.org/10.1002/chem.200900100openalex-snapshot
Silver–Ethene Complexes [Ag(η2‐C2H4)n][Al(ORF)4] with n=1, 2, 3 (RF=Fluorine‐Substituted Group)
inferred← citeshttps://doi.org/10.1002/chem.200900791openalex-snapshot
Transition‐Metal Complexes [(PMe3)2Cl2M(E)] and [(PMe3)2(CO)2M(E)] with Naked Group 14 Atoms (E=C–Sn) as Ligands; Part 1: Parent Compounds
inferred← citeshttps://doi.org/10.1002/chem.200901344openalex-snapshot
The Stereospecific Ligand Exchange at a Pseudo‐Benzylic T‐4 Iridium Centre in Planar‐Chiral Cycloiridium (η6‐Arene)tricarbonylchromium Complexes
inferred← citeshttps://doi.org/10.1002/chem.200901594openalex-snapshot
Multiple Reaction Pathways in Rhodium‐Catalyzed Hydrosilylations of Ketones
inferred← citeshttps://doi.org/10.1002/chem.200903348openalex-snapshot
Scission of Carbon Monoxide Using TaR3, R=(N(tBu)Ph) or OSi(tBu)3: A DFT Investigation
inferred← citeshttps://doi.org/10.1002/chem.201102159openalex-snapshot
Yb(OTf)3‐ or AuI‐Catalyzed Domino Intramolecular Hydroamination and Ring‐Opening of Sulfonamide‐Substituted 1,1‐Vinylidenecyclopropanediesters
inferred← citeshttps://doi.org/10.1002/chem.201103497openalex-snapshot
Alternative Reaction Pathways in Domino Reactions of Hydrazinediidozirconium Complexes with Alkynes
inferred← citeshttps://doi.org/10.1002/chem.201200741openalex-snapshot
Transition‐Metal Complexes of Tetrylones [(CO)5W‐E(PPh3)2] and Tetrylenes [(CO)5W‐NHE] (E=C–Pb): A Theoretical Study
inferred← citeshttps://doi.org/10.1002/chem.201200782openalex-snapshot
A Computational Approach to Tuning the Photochemistry of Platinum(IV) Anticancer Agents
inferred← citeshttps://doi.org/10.1002/chem.201200870openalex-snapshot
Hapticity Uncovered: Real‐Space Bonding Indicators for Zincocene Chemistry
inferred← citeshttps://doi.org/10.1002/chem.201204544openalex-snapshot
A Systematic Investigation of Coinage Metal Carbonyl Complexes Stabilized by Fluorinated Alkoxy Aluminates
inferred← citeshttps://doi.org/10.1002/chem.201501499openalex-snapshot
Influence of the Homopolar Dihydrogen Bonding CH⋅⋅⋅HC on Coordination Geometry: Experimental and Theoretical Studies
inferred← citeshttps://doi.org/10.1002/chem.201504475openalex-snapshot
Observation of Main‐Group Tricarbonyls [B(CO)3] and [C(CO)3]+ Featuring a Tilted One‐Electron Donor Carbonyl Ligand
inferred← citeshttps://doi.org/10.1002/chem.201601392openalex-snapshot
Comparison of Hydrogen and Gold Bonding in [XHX]−, [XAuX]−, and Isoelectronic [NgHNg]+, [NgAuNg]+ (X=Halogen, Ng=Noble Gas)
inferred← citeshttps://doi.org/10.1002/chem.201801410openalex-snapshot
Relativistic Effects on Donor–Acceptor Interactions in Coinage Metal Carbonyl Complexes [TM(CO)n]+ (TM=Cu, Ag, Au; n=1, 2)
inferred← citeshttps://doi.org/10.1002/chem.201803139openalex-snapshot
Coordination of Asymmetric Diborenes towards Cationic Coinage Metals (Au, Ag, Cu)
inferred← citeshttps://doi.org/10.1002/chem.201805260openalex-snapshot
Octacarbonyl Anion Complexes of the Late Lanthanides Ln(CO)8− (Ln=Tm, Yb, Lu) and the 32‐Electron Rule
inferred← citeshttps://doi.org/10.1002/chem.201902625openalex-snapshot
Octacarbonyl Ion Complexes of Actinides [An(CO)8]+/− (An=Th, U) and the Role of f Orbitals in Metal–Ligand Bonding
inferred← citeshttps://doi.org/10.1002/chem.201905552openalex-snapshot
Filling a Gap: The Coordinatively Saturated Group 4 Carbonyl Complexes TM(CO)8 (TM=Zr, Hf) and Ti(CO)7
inferred← citeshttps://doi.org/10.1002/chem.202001062openalex-snapshot
N‐ Heterocyclic Silylenes as Ligands in Transition Metal Carbonyl Chemistry: Nature of Their Bonding and Supposed Innocence
inferred← citeshttps://doi.org/10.1002/chem.202001585openalex-snapshot
Alkaline Earth Metals Activate N2 and CO in Cubic Complexes Just Like Transition Metals: A Conceptual Density Functional Theory and Energy Decomposition Analysis Study
inferred← citeshttps://doi.org/10.1002/chem.202002986openalex-snapshot
The Valence Orbitals of the Alkaline‐Earth Atoms
inferred← citeshttps://doi.org/10.1002/chem.202003934openalex-snapshot
Group 6 Hexacarbonyls as Ligands for the Silver Cation: Syntheses, Characterization, and Analysis of the Bonding Compared with the Isoelectronic Group 5 Hexacarbonylates
inferred← citeshttps://doi.org/10.1002/chem.202004041openalex-snapshot
Chemical Bonding in Homoleptic Carbonyl Cations [M{Fe(CO)5}2]+ (M=Cu, Ag, Au)
inferred← citeshttps://doi.org/10.1002/chem.202300483openalex-snapshot
Trapping of a Transient Base‐Stabilised Alumylene and Alumylene‐Type Reactivity of a Self‐Stabilising Dialumene towards Organic Azides
inferred← citeshttps://doi.org/10.1002/chin.200017247openalex-snapshot
ChemInform Abstract: The Nature of the Bonding in Transition Metal Compounds
inferred← citeshttps://doi.org/10.1002/cphc.200500720openalex-snapshot
Theoretical Investigation of the Decarbonylation of Acetaldehyde by Fe+ and Cr+
inferred← citeshttps://doi.org/10.1002/cphc.200800208openalex-snapshot
First and Second Proton Affinities of Carbon Bases
inferred← citeshttps://doi.org/10.1002/cphc.201101065openalex-snapshot
Bonding of Gold with Unsaturated Species
inferred← citeshttps://doi.org/10.1002/cphc.202000113openalex-snapshot
Substituent Effect Parameters: Extending the Applications to Organometallic Chemistry
inferred← citeshttps://doi.org/10.1002/cphc.202000529openalex-snapshot
Dioxygen Binding to all 3d, 4d, and 5d Transition Metals from Coupled‐Cluster Theory
inferred← citeshttps://doi.org/10.1002/cphc.202200835openalex-snapshot
Quantitative Descriptions of Dewar‐Chatt‐Duncanson Bonding Model: A Case Study of Zeise and Its Family Ions
inferred← citeshttps://doi.org/10.1002/cphc.202300720openalex-snapshot
Pressure Induced Alteration and Stabilization of Intermolecular Stacking in Square‐planar Osmium tetracarbonyl
inferred← citeshttps://doi.org/10.1002/cphc.202400582openalex-snapshot
Quantification of the Donor‐Acceptor Character of Ligands by the Effective Fragment Orbitals
inferred← citeshttps://doi.org/10.1002/ejic.200300303openalex-snapshot
Group 10 Metal Complexes of SPS‐Based Pincer Ligands: Syntheses, X‐ray Structures, and DFT Calculations
inferred← citeshttps://doi.org/10.1002/ejic.200390095openalex-snapshot
Synthesis and Reactivity of the First η6‐Rhodium( I ) and η6‐Iridium( I ) Complexes of 2,6‐Bis(trimethylsilyl)phosphinines
inferred← citeshttps://doi.org/10.1002/ejic.200390140openalex-snapshot
Chelate Complexes of Functionalized Cycloheptatrienyl Ligands: Molybdenum Complexes with Linked Cycloheptatrienyl‐Phosphane Ligands and Their Use in Catalytic Carbon−Carbon Bond Formation
inferred← citeshttps://doi.org/10.1002/ejic.200400353openalex-snapshot
The Nature of the M≡E Bond: Theoretical Investigation of the Molecules [(RO)3M≡E] (M = Mo, W; E = N, P, As, Sb, Bi; R = H, Me) and [(Me3CO)3Mo≡P]
inferred← citeshttps://doi.org/10.1002/ejic.200500661openalex-snapshot
Theoretical Study of the Effects of Phosphane Substituents on the Bonding Properties of Acetylene with Ni(PR3)2 (R = H, CH3, F, CF3, C6H5)
inferred← citeshttps://doi.org/10.1002/ejic.200600592openalex-snapshot
Testing Phosphanes in the Palladium Catalysed Allylation of Secondary and Primary Amines
inferred← citeshttps://doi.org/10.1002/ejic.200600670openalex-snapshot
W(CO)4(diimine) Structure Revised – Correlating Structure to π* Back‐Bonding
inferred← citeshttps://doi.org/10.1002/ejic.200700198openalex-snapshot
Reactivity of InCp* Towards Transition Metal Carbonyl Clusters: Synthesis and Structural Characterization of the Rh6(CO)16–x(InCp*)x Mixed‐Metal Cluster Compounds, x = 1–2
inferred← citeshttps://doi.org/10.1002/ejic.200700573openalex-snapshot
Olefin Complexes of Low‐Valent Rhenium
inferred← citeshttps://doi.org/10.1002/ejic.200701055openalex-snapshot
Structurally Characterized Coinage‐Metal–Ethylene Complexes
inferred← citeshttps://doi.org/10.1002/ejic.200800008openalex-snapshot
Cationic Triple‐Decker Complexes with a Bridging 4‐Borataborepine Ligand: Synthesis, Structure, and Bonding
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