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Supramolecular Gold(I) Thiobarbiturate Chemistry: Combining Aurophilicity and Hydrogen Bonding to Make Polymers, Sheets, and Networks

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The Molecular Structure of Some Transition-Metal Complexes with 1,2,3,4-Tetrazole-5-thiolate Anions
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Synthesis and Structural Characterization of Gold(I) and Silver(I) Complexes of the Multidonor Ligand 2-(Phenacylthio)pyridine − Crystal Structures of [(AuPPh3){py{SCH2C(O)Ph}-2}](ClO4) and [(AgPPh3)(OClO3){py{SCH2C(O)Ph}-2}]
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Hydrogen Bonding Networks in Bis(amine)gold(I) Complexes with Disulfonylamide Anions
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Molecular Gold—Multinuclear Gold(I) Complexes
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A Novel Polynuclear Gold-Sulfur Cube with an Unusually Large Stokes Shift
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New Motifs in Aurophilic Self‐Assembly: Synthesis and Structures of [Au(NHCMe2)2]CF3SO3 and [Au(CCSiMe3)(CNtBu)]
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Functional Organic Analogues of Zeolites Based on Metal–Organic Coordination Frameworks
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Complexes with S‐Donor Ligands, 4. Mono‐ and Di‐Homo‐ and ‐Hetero‐Nuclear Gold(I), Silver(I), and Palladium(II) Complexes with 2‐(Methylthio)pyridine, Pyridine‐2(1H)‐thione, and Benzoxazole‐2(3H)‐thione. Some Examples of the Use of Complexes as Ligands
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Polynuclear Gold(I) Complexes of Functionalized Thiols and Dithiols
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Photophysical and Photochemical Properties of Gold(l) Complexes
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Gold(I) complexes of thioamides
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Complexes of heterocyclic thionates. Part 1. Complexes of monodentate and chelating ligands
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4-Amino-3-methyl-1,2,4-Δ2-triazoline-5-thione: an example of thione-thiol tautomerism and stabilization of Cu(I) and Au(I) complexes
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Comprehensive Coordination Chemistry
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Molecular design of luminescent dinuclear gold(I) thiolate complexes: from fundamentals to chemosensing
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Organometallic crystal engineering: prospects for a systematic design1This review article is largely based on conferences given by the authors in 1997: INDABA-II (Skukuza, South Africa); ECM17 (Lisbon, Portugal); Annual SCI Inorganic Chemistry Congress (Alessandria, Italy).1
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The characterization of 2-thiouracilato(triphenylphosphine)gold(I)
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Synthesis and characterization of complexes of trialkyl- and triarylphosphine gold(I) with thiolated purines and pyrimidines: a class of bifunctional compounds with potential antitumor activity
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Studies on the interaction of gold(I) phosphines with 2-thiouracil. Related studies with silver(I) phosphines
inferredcites →https://doi.org/10.1016/s0020-1693(00)87122-4openalex-snapshot
Gold(I) derivatives of heterocycles
inferredcites →https://doi.org/10.1016/s0020-1693(99)00459-4openalex-snapshot
Gold(I) complexes with P=O and P–OH functionalised phosphorus ligands
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The preparation and coordination chemistry of substituted benzenethiols. Triphenylphosphine gold(I)complexes of sterically demanding and nondemandingarenethiols. The absence of gold(I)–gold(I) interactions
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New hydrogen-bonded dimeric and polymeric gold(I) complexes of the heterodifunctional ligand Ph2PNHP(O)Ph2
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Spectral and thermal studies of thiobarbituric acid complexes
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The C−H···O Hydrogen Bond: Structural Implications and Supramolecular Design
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Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids
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Strong Closed-Shell Interactions in Inorganic Chemistry
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Three- and Four-Coordinate Gold(I) Complexes
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New Self-Assembled Structural Motifs in Coordination Chemistry
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Gold(I) phosphine complexes: mercaptooxopurine base interactions. Molecular and crystal structure of (8-mercaptotheophyllinato-S)(triphenylphosphine)gold(I)
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A Gold(I) Mononuclear Complex and Its Association into Binuclear and Cluster Compounds by Hydrogen Bonding or Metal Ion Coordination
inferredcites →https://doi.org/10.1021/ic990308vopenalex-snapshot
Crystal Engineering of Gold(I) Thiolate Based Compounds via Cooperative Aurophilic and Hydrogen-Bonding Interactions
inferredcites →https://doi.org/10.1021/ic990662topenalex-snapshot
Novel Luminescent Au(I) Pyrimidinethiolate Dimer Having an Unusual π-Stacking Structure
inferredcites →https://doi.org/10.1021/ic991085bopenalex-snapshot
Gold Complexes of Trithiocyanuric Acid: A Two-Dimensional Polymer Assembled through Gold(I)···Gold(I) Interactions
inferredcites →https://doi.org/10.1021/ic991497kopenalex-snapshot
Self-Association in Gold Chemistry: A Tetragold(I) Complex Linked by Both Aurophilic and Hydrogen Bonding
inferredcites →https://doi.org/10.1021/ja00089a019openalex-snapshot
Steric Control of secondary, solid-state architecture in 1:1 complexes of melamines and barbiturates that crystallize as crinkled tapes
inferredcites →https://doi.org/10.1021/ja00262a047openalex-snapshot
Synthesis and structure of [Au6(o-CH3C6H4CS2)6], a novel gold cluster compound
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The Structural and Functional Equivalence of Aurophilic and Hydrogen Bonding: Evidence for the First Examples of Rotator Phases Induced by Aurophilic Bonding
inferredcites →https://doi.org/10.1021/jm00048a018openalex-snapshot
Synthesis and Antimicrobial Activity of Novel [(3-Aminopyrimidiniumyl)thio]methyl Cephalosporins
inferredcites →https://doi.org/10.1021/om960682sopenalex-snapshot
(Isocyanide)gold(I) Thiosalicylates: Supramolecular Assembly Based on both Auriophilic and Hydrogen Bonding
inferredcites →https://doi.org/10.1039/a606494iopenalex-snapshot
Dramatic solvent effect on the luminescence of a dinuclear gold(i) complex of quinoline-8-thiolate
inferredcites →https://doi.org/10.1039/a701434aopenalex-snapshot
Self-assembly of a chiral phosphinegold(I) building block into a two-dimensional netsheet based on a hydrogen bond between one Cl− anion and three hydroxy groups, co-ordination and aurophilicity interactions†
inferredcites →https://doi.org/10.1039/a707650iopenalex-snapshot
X-Ray crystallographic and extended X-ray absorption fine structure studies of gold(I) complexes containing weak intermolecular interactions
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Weak hydrogen bonds: theoretical studies
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Deprotonated ethylenethiourea as a ligand in an unusual tetrameric gold(I) complex†
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Synthesis and crystal structure of a hexanuclear silver(I) cluster [Ag(Hmna)]6·4H2O (H2mna = 2-mercaptonicotinic acid) and a supramolecular gold(I) complex H[Au(Hmna)2] in the solid state, and their antimicrobial activities
inferredcites →https://doi.org/10.1039/b005251popenalex-snapshot
Luminescent gold(I) macrocycles with diphosphine and 4,4′-bipyridyl ligands
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Solid-state luminescence and crystal structures of novel gold(I) benzenethiolate complexes
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Self-assembly in synthetic macromolecular systems via multiple hydrogen bonding interactions
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Mössbauer and nuclear magnetic resonance spectroscopic studies on ‘Myocrisin’, ‘Solganol’, ‘Auranofin’, and related gold( I ) thiolates
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Triorganophosphinegold(I) complexes of pyridine-2-thionate and pyrimidine-2-thionate
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Database analysis of Au ? Au interactions
inferredcites →https://doi.org/10.1039/dt9950000319openalex-snapshot
Synthesis of [Au(NH3)2]+ salts and the crystal structure of [Au(NH3)2]Br
inferredcites →https://doi.org/10.1039/dt9960001769openalex-snapshot
Photophysical properties, electronic and crystal structure of a luminescent pentanuclear gold(I) complex
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Molecular Design of a New Fluorescent Barbiturate Receptor. Sensitive Detection of Barbiturates through Solvent Extraction
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Synthesis and Structural Characterization of Silver(I) and Gold(I) Complexes with 2-Mercaptonicotinic Acid (H2mna) and Triphenylphosphine Ligands, and Their Antimicrobial Activities. Crystal Structures of Monomeric, 3- and 4-Coordinate Silver(I) Complexes [Ag(Hmna)(PPh3)2] and [Ag(Hmna)(PPh3)3] in…
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Molecular design of luminescent metal-based materials
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An introduction to hydrogen bonding

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Coordination of a monomeric diphosphido platinum complex as a bridging ligand
inferred← citeshttps://doi.org/10.1039/b708622aopenalex-snapshot
Macrocycles, catenanes, oligomers and polymers in gold chemistry
inferred← citeshttps://doi.org/10.1039/b717198fopenalex-snapshot
Electronic and steric control over Au⋯Au, C–H⋯O and C–H⋯π interactions in the crystal structures of mononuclear triarylphosphinegold(i) carbonimidothioates: R3PAu[SC(OMe)=NR′] for R = Ph, o-tol, m-tol or p-tol, and R′ = Ph, o-tol, m-tol, p-tol or C6H4NO2-4
inferred← citeshttps://doi.org/10.1039/b901576kopenalex-snapshot
Gold⋯π aryl interactions as supramolecular synthons
inferred← citeshttps://doi.org/10.1039/b918615hopenalex-snapshot
Dynamic ring-opening polymerization of silver(i) complexes with bis(amidopyridine) ligands
inferred← citeshttps://doi.org/10.1039/c1dt10437copenalex-snapshot
Synthesis, structural characterization, photophysical properties and theoretical analysis of gold(i) thiolate-phosphine complexes
inferred← citeshttps://doi.org/10.1039/c1sc00487eopenalex-snapshot
The mixed cyanide halide Au(i) complexes, [XAuCN]− (X = F, Cl, Br, and I): evolution from ionic to covalent bonding
inferred← citeshttps://doi.org/10.1039/c4dt04031gopenalex-snapshot
On the gold–ligand covalency in linear [AuX 2 ] − complexes
inferred← citeshttps://doi.org/10.1039/c5nj02860dopenalex-snapshot
Weaving an infinite 3-D supramolecular network via Au I ⋯Au III aurophilicity and C–H⋯Cl hydrogen bonding
inferred← citeshttps://doi.org/10.1039/c7nj04354fopenalex-snapshot
Aurophilicity vs. thiophilicity: directing the crystalline supramolecular arrangement in luminescent gold compounds
inferred← citeshttps://doi.org/10.1039/c7tc03605aopenalex-snapshot
An intrinsic dual-emitting gold thiolate coordination polymer, [Au(+I)(p-SPhCO 2 H)] n , for ratiometric temperature sensing
inferred← citeshttps://doi.org/10.1039/d0ce00416bopenalex-snapshot
Supramolecular association of M 2+ ⋯π induced by different electrostatic properties using naphthyl substituted β-diketonate complexes (metal = Cu, Pd, Pt)
inferred← citeshttps://doi.org/10.1039/d0cs00438copenalex-snapshot
Dinuclear gold( i ) complexes: from bonding to applications
inferred← citeshttps://doi.org/10.1039/d2ra00368fopenalex-snapshot
Spontaneous in situ generation of photoemissive aurophilic oligomers in water solution based on the 2-thiocytosine ligand
inferred← citeshttps://doi.org/10.1063/1.4868553openalex-snapshot
Photoelectron imaging and theoretical study on the structure and chemical binding of the mixed-ligand M(I) complexes, [HMSH]− (M = Cu, Ag, and Au)
inferred← citeshttps://doi.org/10.1063/5.0224002openalex-snapshot
Observation of halogen-like behavior of gold in fluorinated bimetallic CoAuF1-2− and CuAuF1-2− clusters: Anion photoelectron spectroscopy and density functional theory
inferred← citeshttps://doi.org/10.1080/00268976.2018.1431408openalex-snapshot
Metal–ligand bond directionality in the M2–NH3 complexes (M = Cu, Ag and Au)
inferred← citeshttps://doi.org/10.1080/00958970802020673openalex-snapshot
Synthesis, structure and nonlinear optical properties of three dimensional compounds
inferred← citeshttps://doi.org/10.1080/00958972.2012.660148openalex-snapshot
Structural characterization of polymeric potassium salts with 2-thiobarbituric acid: influence of organotin(IV) chlorides on potassium cation solvation
inferred← citeshttps://doi.org/10.1080/00958972.2013.860450openalex-snapshot
Calcium and strontium thiobarbiturates with discrete and polymeric structures
inferred← citeshttps://doi.org/10.1080/00958972.2015.1031119openalex-snapshot
Synthesis and thermal transformation of a neodymium(III) complex [Nd(HTBA)2(C2H3O2)(H2O)2]·2H2O to non-centrosymmetric oxosulfate Nd2O2SO4
inferred← citeshttps://doi.org/10.1080/00958972.2016.1149168openalex-snapshot
Influence of alkyl substituents in 1,3-diethyl-2-thiobarbituric acid on the coordination environment in M(H2O)2(1,3-diethyl-2-thiobarbiturate)2 M = Ca2+, Sr2+
inferred← citeshttps://doi.org/10.1088/1674-0068/20/06/796-800openalex-snapshot
Fluorescent Property of Gold Nanoparticles with Different Surface Structures
inferred← citeshttps://doi.org/10.1107/s0108270107045143openalex-snapshot
Poly[bis[aquaneodymium(III)]-μ2-oxalato-di-μ4-succinato]
inferred← citeshttps://doi.org/10.1107/s0108270113014078openalex-snapshot
Bridging behaviour of the 2-thiobarbiturate anion in its complexes with LiIand NaI
inferred← citeshttps://doi.org/10.1107/s2052520615001729openalex-snapshot
Hydrogen bonding patterns in salts of derivatives of aminopyrimidine and thiobarbituric acid
inferred← citeshttps://doi.org/10.1134/s0022476613030141openalex-snapshot
Crystal structure of potassium 2-thiobarbiturate
inferred← citeshttps://doi.org/10.1134/s0022476614050114openalex-snapshot
Crystal structures of two barium 2-thiobarbiturate complexes
inferred← citeshttps://doi.org/10.1134/s0036023613100094openalex-snapshot
Crystal structure of catena-Bis(2-thiobarbiturato-O,S)diaquacadmium
inferred← citeshttps://doi.org/10.1134/s0036023615050071openalex-snapshot
Crystal structure of catena-(μ4-1,3-diethyl-2-thiobarbiturato-O,O’,S,S)silver(I)
inferred← citeshttps://doi.org/10.1134/s1070328415050012openalex-snapshot
The crystal structure of lead(II) 1,3-diethyl-2-thiobarbiturate
inferred← citeshttps://doi.org/10.1135/cccc2009515openalex-snapshot
Adsorption of 2-thiobarbituric acid at the electrochemical interface: Contrasted behaviours on mercury and gold
inferred← citeshttps://doi.org/10.1139/cjc-2018-0435openalex-snapshot
Platinum(II) complexes of pyridine–amine ligands with phenol substituents: isotactic supramolecular polymers
inferred← citeshttps://doi.org/10.1155/2008/654137openalex-snapshot
Crystal Structure and Antitumor Activity of the Novel Zwitterionic Complex of tri‐n‐Butyltin(IV) with 2‐Thiobarbituric Acid
inferred← citeshttps://doi.org/10.1246/cl.2003.762openalex-snapshot
A Well Characterized Example of Conversion of Molecular Configuration Depending on the Existence of Intermolecular Interactions
inferred← citeshttps://doi.org/10.1515/znb-2024-0086openalex-snapshot
‘Schmidbaur gold chemistry’ and beyond
inferred← citeshttps://doi.org/10.3390/s91210447openalex-snapshot
Laser Spectroscopy for Atmospheric and Environmental Sensing
inferred← citeshttps://doi.org/10.70675/2f3d6c55z5be5z4cf2zaf1ez4871e9f13dfdopenalex-snapshot
Structural and photophysical studies of coordination polymers of coinage metals thiolates
inferred← citeshttps://doi.org/10.7150/thno.47243openalex-snapshot
A general-purpose Nanohybrid fabricated by Polymeric Au(I)-peptide precursor to wake the function of Peptide Therapeutics
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