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Steric Effects in the Ground and Excited States of Cu(NN) 2 + Systems
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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CONCENTRATION‐DEPENDENT LIFETIMES OF Cu(NN)+2 SYSTEMS: EXCIPLEX QUENCHING FROM THE ION PAIR STATE
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inferred← citeshttps://doi.org/10.1021/acs.inorgchem.1c01435openalex-snapshot
6,6′-Ditriphenylamine-2,2′-bipyridine: Coordination Chemistry and Electrochemical and Photophysical Properties
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.1c03901openalex-snapshot
Bulky and Stable Copper(I)-Phenanthroline Complex: Impact of Steric Strain and Symmetry on the Excited-State Properties
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c01145openalex-snapshot
So Close, Yet so Different: How One Donor Atom Changes Significantly the Photophysical Properties of Mononuclear Cu(I) Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c01791openalex-snapshot
Functionalizing Carbon Nanotubes with Bis(2,9-dialkyl-1,10-phenanthroline)copper(II) Complexes for the Oxygen Reduction Reaction
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c04315openalex-snapshot
Employing Long-Range Inductive Effects to Modulate Metal-to-Ligand Charge Transfer Photoluminescence in Homoleptic Cu(I) Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c02042openalex-snapshot
Sterically Encumbered Heteroleptic Copper(I) β-Diketiminate Complexes with Extended Excited-State Lifetimes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c02043openalex-snapshot
Changing Directions: Influence of Ligand Electronics on the Directionality and Kinetics of Photoinduced Charge Transfer in Cu(I)Diimine Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c04024openalex-snapshot
Enhanced Visible Light Absorption in Heteroleptic Cuprous Phenanthrolines
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b00907openalex-snapshot
Efficient Visible to Near-UV Photochemical Upconversion Sensitized by a Long Lifetime Cu(I) MLCT Complex
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6b01646openalex-snapshot
Cu(I) Complexes of Pincer Pyridine-Based N-Heterocyclic Carbenes with Small Wingtip Substituents: Synthesis and Structural and Spectroscopic Studies
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6b01880openalex-snapshot
Cuprous Phenanthroline MLCT Chromophore Featuring Synthetically Tailored Photophysics
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b03169openalex-snapshot
Enhancing the Visible-Light Absorption and Excited-State Properties of Cu(I) MLCT Excited States
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.8b01732openalex-snapshot
Photoluminescent Phosphinine Cu(I) Halide Complexes: Temperature Dependence of the Photophysical Properties and Applications as a Molecular Thermometer
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.8b03500openalex-snapshot
Influence of Sulfur Oxidation State and Substituents on Sulfur-Bridged Luminescent Copper(I) Complexes Showing Thermally Activated Delayed Fluorescence
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.9b00042openalex-snapshot
Intriguing Effects of Halogen Substitution on the Photophysical Properties of 2,9-(Bis)halo-Substituted Phenanthrolinecopper(I) Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.9b01487openalex-snapshot
Exploring the Optical and Electrochemical Properties of Homoleptic versus Heteroleptic Diimine Copper(I) Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.9b02976openalex-snapshot
Quantifying Entatic States in Photophysical Processes: Applications to Copper Photosensitizers
inferred← citeshttps://doi.org/10.1021/acs.jpca.5b00901openalex-snapshot
Transient Absorption Dynamics of Sterically Congested Cu(I) MLCT Excited States
inferred← citeshttps://doi.org/10.1021/acs.jpca.5b03842openalex-snapshot
Theoretical Rationalization of the Emission Properties of Prototypical Cu(I)–Phenanthroline Complexes
inferred← citeshttps://doi.org/10.1021/acs.jpca.5c08355openalex-snapshot
Encumbering the Copper(I)-Diimine Coordination Sphere with a Benzyl Group: Impact on the Stability and Photoredox Properties
inferred← citeshttps://doi.org/10.1021/acs.jpcc.4c01994openalex-snapshot
Intra- and Intermolecular Charge-Transfer Dynamics of Carbene–Metal–Amide Photosensitizers
inferred← citeshttps://doi.org/10.1021/acs.jpclett.8b00468openalex-snapshot
Ligand Mediation of Vectorial Charge Transfer in Cu(I)diimine Chromophore–Acceptor Dyads
inferred← citeshttps://doi.org/10.1021/acs.organomet.6c00261openalex-snapshot
Luminescent Three-Coordinate Copper(I) Complexes Supported by an 8-Aryl-1-Naphthyl-Substituted “Sandwich” NacNac Ligand
inferred← citeshttps://doi.org/10.1021/acsami.8b15897openalex-snapshot
Bluish-Green Cu(I) Dimers Chelated with Thiophene Ring-Introduced Diphosphine Ligands for Both Singlet and Triplet Harvesting in OLEDs
inferred← citeshttps://doi.org/10.1021/acscatal.5b01071openalex-snapshot
[Copper(phenanthroline)(bisisonitrile)] + -Complexes for the Visible-Light-Mediated Atom Transfer Radical Addition and Allylation Reactions
inferred← citeshttps://doi.org/10.1021/acsmacrolett.7b00465openalex-snapshot
Restricted Photoinduced Conformational Change in the Cu(I) Complex for Sensing Mechanical Properties
inferred← citeshttps://doi.org/10.1021/acsomega.1c05279openalex-snapshot
Design of Bis(1,10-phenanthroline) Copper(I)-Based Mechanochromic Indicators
inferred← citeshttps://doi.org/10.1021/acsomega.2c00531openalex-snapshot
Copper(I) Bis(diimine) Complexes with High Photooxidation Power: Reductive Quenching of the Excited State with a Benzimidazoline Sacrificial Donor
inferred← citeshttps://doi.org/10.1021/cg101018bopenalex-snapshot
Diversity of Architecture of Copper(I) Coordination Polymers Constructed of Copper(I) Halides and 4-Methyl-1,2,4-Triazole-3-Thiol (Hmptrz) Ligand: Syntheses, Structures, and Luminescent Properties
inferred← citeshttps://doi.org/10.1021/cm500511dopenalex-snapshot
Versatile Approach to Formation of Light-Harvesting Complexes on Nanostructured Metal Oxide Surfaces via “On-Surface” Assembly
inferred← citeshttps://doi.org/10.1021/cm901109nopenalex-snapshot
Void Space Containing Crystalline Cu(I) Phenanthroline Complexes As Molecular Oxygen Sensors
inferred← citeshttps://doi.org/10.1021/ic0000606openalex-snapshot
Evaluation of Diimine Ligand Exchange on Cu(I)
inferred← citeshttps://doi.org/10.1021/ic010044oopenalex-snapshot
Novel Boxlike Dinuclear or Chain Polymeric Silver(I) Complexes with Polypyridyl Bridging Ligands: Syntheses, Crystal Structures, and Spectroscopic and Electrochemical Properties
inferred← citeshttps://doi.org/10.1021/ic010297hopenalex-snapshot
Crowded Cu(I) Complexes Involving Benzo[h]quinoline: π-Stacking Effects and Long-Lived Excited States
inferred← citeshttps://doi.org/10.1021/ic0201809openalex-snapshot
Synthesis and Structural Characterization of Cu(I) and Ni(II) Complexes that Contain the Bis[2-(diphenylphosphino)phenyl]ether Ligand. Novel Emission Properties for the Cu(I) Species
inferred← citeshttps://doi.org/10.1021/ic0300417openalex-snapshot
Cu(I) Complexes of 3,3‘-Polymethylene Bridged Derivatives of 2,2‘-Bi-1,10-Phenanthroline
inferred← citeshttps://doi.org/10.1021/ic034412vopenalex-snapshot
Structure-Dependent Photophysical Properties of Singlet and Triplet Metal-to-Ligand Charge Transfer States in Copper(I) Bis(diimine) Compounds
inferred← citeshttps://doi.org/10.1021/ic034529jopenalex-snapshot
X-ray Structures, Photophysical Characterization, and Computational Analysis of Geometrically Constrained Copper(I)−Phenanthroline Complexes
inferred← citeshttps://doi.org/10.1021/ic0353108openalex-snapshot
Isomerization Dynamics in Homo- and Heterochiral Atropoisomer Copper(I) Diimine Complexes: A 2D EXSY NMR Study
inferred← citeshttps://doi.org/10.1021/ic048346oopenalex-snapshot
Unsupported Gold(I)−Copper(I) Interactions through η1Au-[Au(C6F5)2]- Coordination to Cu+ Lewis Acid Sites
inferred← citeshttps://doi.org/10.1021/ic051412hopenalex-snapshot
Phosphorescent Cu(I) Complexes of 2-(2‘-pyridylbenzimidazolyl)benzene: Impact of Phosphine Ancillary Ligands on Electronic and Photophysical Properties of the Cu(I) Complexes
inferred← citeshttps://doi.org/10.1021/ic102550zopenalex-snapshot
Influence of the Electronic Characteristics of N-Donor Ligands in the Excited State of Heteronuclear Gold(I)–Copper(I) Systems
inferred← citeshttps://doi.org/10.1021/ic2006343openalex-snapshot
New Heteroleptic Bis-Phenanthroline Copper(I) Complexes with Dipyridophenazine or Imidazole Fused Phenanthroline Ligands: Spectral, Electrochemical, and Quantum Chemical Studies
inferred← citeshttps://doi.org/10.1021/ic401213popenalex-snapshot
Design of a Long-Lifetime, Earth-Abundant, Aqueous Compatible Cu(I) Photosensitizer Using Cooperative Steric Effects
inferred← citeshttps://doi.org/10.1021/ic5012204openalex-snapshot
Luminescent Dinuclear Cu(I) Complexes Containing Rigid Tetraphosphine Ligands
inferred← citeshttps://doi.org/10.1021/ic7014786openalex-snapshot
Halogen Exchange and Scrambling between C−X and M−X‘ Bonds in Copper, Nickel, and Cobalt Complexes of 6,6‘-bis(bromo/ chloromethyl)-2,2‘-bipyridine. Structural, Electrochemical, and Photochemical Studies
inferred← citeshttps://doi.org/10.1021/ic802361qopenalex-snapshot
Photophysical Characteristics and Reactivity of Bis(2,9-di-tert-butyl-1,10-phenanthroline)copper(I)
inferred← citeshttps://doi.org/10.1021/ic902236nopenalex-snapshot
Tetranuclear Copper(I) Iodide Complexes of Chelating Bis(1-benzyl-1H-1,2,3-triazole) Ligands: Structural Characterization and Solid State Photoluminescence
inferred← citeshttps://doi.org/10.1021/ic970135eopenalex-snapshot
A Twist on the Copper Center in the Crystal Structure of [Cu(dnpp)2]PF6 and the Charge-Transfer Excited State? (dnpp = 2,9-Dineopentyl-1,10-phenanthroline)
inferred← citeshttps://doi.org/10.1021/ic971267aopenalex-snapshot
Diastereoselective Formation and Photophysical Behavior of a Chiral Copper(I) Phenanthroline Complex
inferred← citeshttps://doi.org/10.1021/ja0043439openalex-snapshot
Highly Luminescent Cu(I)−Phenanthroline Complexes in Rigid Matrix and Temperature Dependence of the Photophysical Properties
inferred← citeshttps://doi.org/10.1021/ja072335nopenalex-snapshot
Equilibration between Three Different Excited States in a Bichromophoric Copper(I) Polypyridine Complex
inferred← citeshttps://doi.org/10.1021/ja1004575openalex-snapshot
E-Type Delayed Fluorescence of a Phosphine-Supported Cu 2 (μ-NAr 2 ) 2 Diamond Core: Harvesting Singlet and Triplet Excitons in OLEDs
inferred← citeshttps://doi.org/10.1021/ja302807sopenalex-snapshot
Exceptionally Long-Lived Luminescence from [Cu(I)(isocyanide)2(phen)]+Complexes in Nanoporous Crystals Enables Remarkable Oxygen Gas Sensing
inferred← citeshttps://doi.org/10.1021/ja3085093openalex-snapshot
Photoinduced Multistep Charge Separation in a Heteroleptic Cu(I) Bis(phenanthroline)-Based Donor–Chromophore–Acceptor Triad
inferred← citeshttps://doi.org/10.1021/ja990036vopenalex-snapshot
Synthesis, X-ray Structure, and Electrochemical and Excited-State Properties of Multicomponent Complexes Made of a [Ru(Tpy)2]2+ Unit Covalently Linked to a [2]-Catenate Moiety. Controlling the Energy-Transfer Direction by Changing the Catenate Metal Ion
inferred← citeshttps://doi.org/10.1021/jacs.3c02825openalex-snapshot
Two-Coordinate Coinage Metal Complexes as Solar Photosensitizers
inferred← citeshttps://doi.org/10.1021/jacs.6c02560openalex-snapshot
Photoluminescent Cu(I) HETPHENs Featuring Bulky Alkyl-Substituted Phenanthrolines
inferred← citeshttps://doi.org/10.1021/jacs.6c11305openalex-snapshot
Visible Light Harvesting Cr(III) Photocatalysts
inferred← citeshttps://doi.org/10.1021/jacs.8b12397openalex-snapshot
Highly Efficient Photo- and Electroluminescence from Two-Coordinate Cu(I) Complexes Featuring Nonconventional N-Heterocyclic Carbenes
inferred← citeshttps://doi.org/10.1021/jacs.9b03775openalex-snapshot
Intermolecular 2 + 2 Carbonyl–Olefin Photocycloadditions Enabled by Cu(I)–Norbornene MLCT
inferred← citeshttps://doi.org/10.1021/jacsau.6c01216openalex-snapshot
Air-Stable Nickel(0) Complexes with Room-Temperature Photoluminescence
inferred← citeshttps://doi.org/10.1021/jp036857aopenalex-snapshot
The Effect of Ligand Constraints on the Metal-to-Ligand Charge-Tranfer Relaxation Dynamics of Copper(I)−Phenanthroline Complexes: A Comparative Study by Femtosecond Time-Resolved Spectroscopy
inferred← citeshttps://doi.org/10.1021/jp102278uopenalex-snapshot
Influence of Ligand Substitution on Excited State Structural Dynamics in Cu(I) Bisphenanthroline Complexes
inferred← citeshttps://doi.org/10.1021/jp202008jopenalex-snapshot
Photoexcited State Properties of H2-Porphyrin/C60-Based Rotaxanes as Studied by Time-Resolved Electron Paramagnetic Resonance Spectroscopy
inferred← citeshttps://doi.org/10.1021/jp300313sopenalex-snapshot
Restricted Photochemistry in the Molecular Solid State: Structural Changes on Photoexcitation of Cu(I) Phenanthroline Metal-to-Ligand Charge Transfer (MLCT) Complexes by Time-Resolved Diffraction
inferred← citeshttps://doi.org/10.1021/jp403751mopenalex-snapshot
Solvent-Induced Luminescence Quenching: Static and Time-Resolved X-Ray Absorption Spectroscopy of a Copper(I) Phenanthroline Complex
inferred← citeshttps://doi.org/10.1021/jp509728mopenalex-snapshot
A Quantum Dynamics Study of the Ultrafast Relaxation in a Prototypical Cu(I)–Phenanthroline
inferred← citeshttps://doi.org/10.1021/jp903774gopenalex-snapshot
Realization of High-Energy Emission from [Cu(N−N)(P−P)]+ Complexes for Organic Light-Emitting Diode Applications
inferred← citeshttps://doi.org/10.1021/la803822sopenalex-snapshot
Phosphorescence Enhancement Triggered by Π Stacking in Solid-State [Cu(N−N)(P−P)]BF4 Complexes
inferred← citeshttps://doi.org/10.1021/om060181zopenalex-snapshot
Photophysical and Theoretical Studies on Luminescent Tetranuclear Coinage Metal Building Blocks
inferred← citeshttps://doi.org/10.1023/a:1019891325387openalex-snapshot
Synthesis, spectroscopic, photophysical and electrochemical behaviour of ruthenium(II) and copper(I) isocyano-bridged complexes with polypyridine ligands: 2,2′-bipyridine and 1,10-phenanthroline
inferred← citeshttps://doi.org/10.1038/ncomms15390openalex-snapshot
11% efficiency solid-state dye-sensitized solar cells with copper(II/I) hole transport materials
inferred← citeshttps://doi.org/10.1038/s41557-026-02233-3openalex-snapshot
Modulating endergonic triplet photosensitization for cycloadditions between bicyclo[1.1.0]butanes and alkenes
inferred← citeshttps://doi.org/10.1039/a804389bopenalex-snapshot
Evidence for the localisation of electronic charge in electrochemically reduced copper(I) complexes with electron deficient ligands: a structural and spectroelectrochemical study ‡
inferred← citeshttps://doi.org/10.1039/a909121aopenalex-snapshot
Metal-to-ligand charge-transfer excited-states in binuclear copper(I) complexes. Tuning MLCT excited-states through structural modification of bridging ligands. A resonance Raman study
inferred← citeshttps://doi.org/10.1039/a909224bopenalex-snapshot
New photoluminescent CuIN4 chromophores. Stabilisation of copper(I) by unconjugated diimines
inferred← citeshttps://doi.org/10.1039/b000703jopenalex-snapshot
Photoactive mono- and polynuclear Cu(i)–phenanthrolines. A viable alternative to Ru(ii)–polypyridines?
inferred← citeshttps://doi.org/10.1039/b307065bopenalex-snapshot
Copper( i ) complexes of 1,10-phenanthroline–oligophenylenevinylene conjugates
inferred← citeshttps://doi.org/10.1039/b515540aopenalex-snapshot
Chiral spiro Cu(i) complexes. Supramolecular stereocontrol and isomerisation dynamics by the use of TRISPHAT anions
inferred← citeshttps://doi.org/10.1039/b608641aopenalex-snapshot
A series of luminescent Cu(i) mixed-ligand complexes containing 2,9-dimethyl-1,10-phenanthroline and simple diphosphine ligands
inferred← citeshttps://doi.org/10.1039/b801019fopenalex-snapshot
The aryl–phen and phen–phen embraces—new supramolecular motifs
inferred← citeshttps://doi.org/10.1039/b900768gopenalex-snapshot
Unsupported Au(i)⋯Cu(i) interactions: influence of nitrile ligands and aurophilicity on the structure and luminescence
inferred← citeshttps://doi.org/10.1039/c0cc01864copenalex-snapshot
Synthesis and characterization of phosphorescent three-coordinate Cu(i)–NHC complexes
inferred← citeshttps://doi.org/10.1039/c3cc44595jopenalex-snapshot
Copper(i) dye-sensitized solar cells with [Co(bpy)3]2+/3+ electrolyte
inferred← citeshttps://doi.org/10.1039/c3cp54322fopenalex-snapshot
Substituent effect on the photoinduced structural change of Cu(i) complexes observed by femtosecond emission spectroscopy
inferred← citeshttps://doi.org/10.1039/c3dt50258aopenalex-snapshot
A single- and double-flash flash photolysis study of the sequential biphotonic photoprocesses of Cu(i) phenanthrolines. Comparison of the helicate complex, [Cu2(1,3-bis(9-methyl-1,10-phenanthrolin-2-yl)propane)2]2+, and [Cu(2,9-dimethyl-1,10-phenanthroline)2]+ photoprocesses
inferred← citeshttps://doi.org/10.1039/c3dt51006aopenalex-snapshot
Highly efficient thermally activated fluorescence of a new rigid Cu(i) complex [Cu(dmp)(phanephos)]+
inferred← citeshttps://doi.org/10.1039/c3dt51416aopenalex-snapshot
Improving the photoresponse of copper(i) dyes in dye-sensitized solar cells by tuning ancillary and anchoring ligand modules
inferred← citeshttps://doi.org/10.1039/c4dt02046dopenalex-snapshot
A strong steric hindrance effect on ground state, excited state, and charge separated state properties of a Cu I -diimine complex captured by X-ray transient absorption spectroscopy
inferred← citeshttps://doi.org/10.1039/c4ra03700fopenalex-snapshot
Factors controlling the photoresponse of copper( i ) diimine dyes containing hole-transporting dendrons in dye-sensitized solar cells: substituent and solvent effects
inferred← citeshttps://doi.org/10.1039/c5ce02533hopenalex-snapshot
A series of dinuclear cuprous iodide complexes chelated with 1,2-bis(diphenylphosphino)benzene derivatives: structural, photophysical and thermal properties
inferred← citeshttps://doi.org/10.1039/c5cp06861dopenalex-snapshot
Ultrafast structural flattening motion in photoinduced excited state dynamics of a bis(diimine) copper( i ) complex
inferred← citeshttps://doi.org/10.1039/c5dt03451eopenalex-snapshot
Luminescent dinuclear copper( i ) complexes bearing 1,4-bis(diphenylphosphino)butane and functionalized 3-(2′-pyridyl)pyrazole mixed ligands
inferred← citeshttps://doi.org/10.1039/c5nj03529eopenalex-snapshot
Luminescent monometallic Cu( i ) triphenylphosphine complexes based on methylated 5-trifluoromethyl-3-(2′-pyridyl)-1,2,4-triazole ligands
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