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Spectroscopic and theoretical studies of an end-on peroxide-bridged coupled binuclear copper(II) model complex of relevance to the active sites in hemocyanin and tyrosinase

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Mechanism of Autoxidation of the Chromium(Ii) Porphyrins. in Situ Infrared Spectroscopic Detection of the Peroxo- Intermidiate
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Syntheses and Characterization of Copper(II) Complexes of the New LigandsN-[(2-Pyridyl)methyl]-2,2′-dipyridylamine andN-[Bis(2-pyridyl)methyl]-2-pyridylamine
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A Short Copper-Copper Distance in a (μ-1,2-Peroxo)dicopper(II) Complex Having a 1,8-Naphthyridine Unit as an Additional Bridge
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A Short Copper-Copper Distance in a (μ-1,2-Peroxo)dicopper(II) Complex Having a 1,8-Naphthyridine Unit as an Additional Bridge
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Electronic Structure and Magnetic Behavior in Polynuclear Transition‐Metal Compounds
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Bispidine Coordination Chemistry
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Chemical Reactivity of Copper Active‐Oxygen Complexes
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Electronic Structure and Magnetic Behavior in Polynuclear Transition‐Metal Compounds
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Bindung molekularen Sauerstoffs bei Raumtemperatur unter Bildung eines neuartigen Peroxokupfer(II)‐Komplexes mit einem makrocyclischen Azolliganden
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Spectroscopic Elucidation of a Peroxo Ni2(μ‐O2) Intermediate Derived from a Nickel( I ) Complex and Dioxygen
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Spectroscopic Elucidation of a New Heme/Copper Dioxygen Structure Type: Implications for O⋅⋅⋅O Bond Rupture in Cytochrome c Oxidase
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Observation of a Cu II 2 (μ‐1,2‐peroxo)/Cu III 2 (μ‐oxo) 2 Equilibrium and its Implications for Copper–Dioxygen Reactivity
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Dioxygen Binding at Ambient Temperature: Formation of a Novel Peroxodicopper( II ) Complex with an Azole Macrocyclic Ligand
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Spectroscopic Elucidation of a Peroxo Ni2(μ‐O2) Intermediate Derived from a Nickel( I ) Complex and Dioxygen
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Spectroscopic Elucidation of a New Heme/Copper Dioxygen Structure Type: Implications for O⋅⋅⋅O Bond Rupture in Cytochrome c Oxidase
inferred← citeshttps://doi.org/10.1002/anie.201402166openalex-snapshot
Observation of a Cu II 2 (μ‐1,2‐peroxo)/Cu III 2 (μ‐oxo) 2 Equilibrium and its Implications for Copper–Dioxygen Reactivity
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Activation of Molecular Oxygen by a Cobalt(II) Tetra‐NHC Complex**
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Study on the Crystal Structure of a Macrocycle and Tyrosinase Activity of Its Dinuclear Copper Complexes
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Thermal Stability and Absorption Spectroscopic Behavior of (μ‐Peroxo)dicopper Complexes Regulated with Intramolecular Hydrogen Bonding Interactions
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The Stability of Copper Oxo Species in Zeolite Frameworks
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How Ligand Geometry Affects the Reactivity of Co(II) Cyclam Complexes
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Gas‐phase complexes of amino acids with Cu(II) and diimine ligands. Part II. Amino acids with O, N and S functional groups in the side‐chain
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Activation of Hydrogen Peroxide for Oxidation by Copper(II) Complexes
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Copper-dioxygen complexes and their roles in biomimetic oxidation reactions
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Copper-Dioxygen and Copper-Oxo Species Relevant to Copper Oxygenases and Oxidases
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Dioxygen Reactivity in Copper Proteins and Complexes
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Dioxygen Reactivity Models for Cytochrome C Oxidase: Synthesis and Characterization of Oxo and Hydroxo-Bridged Porphyrin-Iron/Copper Dinuclear Complexes
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Modeling of Structures and Molecular Properties of Transition Metal Compounds — Toward Metalloprotein Modeling
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Electronic Structures of Active Sites in Copper Proteins: Coupled Binuclear and Trinuclear Cluster Sites
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Functional Models for Hemocyanin and Copper Monooxygenases
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Diagrammatic valence bond studies on hemocyanin
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Copper(I)-phenolate complexes as models of the reduced active site of galactose oxidase: synthesis, characterization, and O2 reactivity
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Heme-copper/dioxygen adduct formation relevant to cytochrome c oxidase: spectroscopic characterization of [(6L)FeIII-(O22?)-CuII]+
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Catecholase activity of a μ-hydroxodicopper(II) macrocyclic complex: structures, intermediates and reaction mechanism
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A personal perspective on the discovery of dioxygen adducts of copper and iron by Nobumasa Kitajima
inferred← citeshttps://doi.org/10.1007/s10593-010-0630-yopenalex-snapshot
New organic ligands of the terpyridine series: modification of gold nanoparticles, preparation of coordination compounds with Cu(I), catalysis of oxidation reactions
inferred← citeshttps://doi.org/10.1016/0003-9861(92)90569-iopenalex-snapshot
Theoretical study of oxyhemocyanin active site: A possible insight on the first step of phenol oxidation by tyrosinase
inferred← citeshttps://doi.org/10.1016/0020-1693(94)03968-2openalex-snapshot
Hemocyanin model compounds; a quantum mechanical calculation of geometry-dependent exchange interaction
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New developments in Raman spectroscopy of biological systems
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Catalytic oxidation and photo-oxidation of nitrophenols by strong oxidants generated in situ via CuO-aerogel
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Dicopper Enzymes
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Quantum chemical studies of molecules incorporating a Cu2O22+ core
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Coupled binuclear copper sites in biology: An experimentally-calibrated computational perspective
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Spectroscopic characterization of a Ni-organic radical intermediate in the aerobic oxidation of methanol catalyzed by a Ni(II)(polyoximate) complex
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Mechanism of autoxidation of the chromium(II) porphyrins. In situ infrared spectroscopic detection of the peroxo- intermediate
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Cu-ZSM-5: A biomimetic inorganic model for methane oxidation
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Using a monocopper-superoxo complex to prepare multicopper-peroxo species relevant to proposed enzyme intermediates
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Probing metal-mediated O2 activation in chemical and biological systems
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Bimetallic dioxygen complexes derived from ‘end-off’ compartmental ligands
inferred← citeshttps://doi.org/10.1016/s0010-8545(00)00336-2openalex-snapshot
Understanding the dioxygen reaction chemistry of diiron proteins through synthetic modeling studies
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Heme–Cu complexes as oxygen-activating functional models for the active site of cytochrome c oxidase
inferred← citeshttps://doi.org/10.1016/s0898-8838(05)58004-8openalex-snapshot
Ligand Influences in Copper-Dioxygen Complex-Formation and Substrate Oxidations
inferred← citeshttps://doi.org/10.1021/acs.chemrev.6b00636openalex-snapshot
Copper–Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity
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Dimeric Copper(I) Complex with a Disulfonamide-Bridged Core
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Dioxygen Binding, Activation, and Reduction to H2O by Cu Enzymes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6b01136openalex-snapshot
Classical Characterization Techniques to Reveal the Structural Model of Nanocomposites with Bimetallic Monolayers of Porphyrins
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Formation of [Cu 2 O 2 ] 2+ and [Cu 2 O] 2+ toward C–H Bond Activation in Cu-SSZ-13 and Cu-SSZ-39
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Ligand Effects on Dioxygen Activation by Copper and Nickel Complexes: Reactivity and Intermediates
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O2 and N2O Activation by Bi-, Tri-, and Tetranuclear Cu Clusters in Biology
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Heme–Copper/Dioxygen Adduct Formation, Properties, and Reactivity
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Tris(2-pyridylmethyl)amine Based Ligands in Copper Catalyzed Atom Transfer Radical Addition (ATRA) and Polymerization (ATRP)
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Synthetic Models for Heme−Copper Oxidases
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Structure and Spectroscopy of Copper−Dioxygen Complexes
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Synthesis, Structure, and H2O2-Dependent Catalytic Functions of Disulfide-Bridged Dicopper(I) and Related Thioether−Copper(I) and Thioether−Copper(II) Complexes
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Structural and Spectroscopic Studies of the Versatile Coordination Chemistry of the Chiral Ligand N,N-Bis(1-propan-2-onyl oxime)- l -methionine N‘-Methylamide with NiII and ZnII
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Copper−Bispidine Coordination Chemistry: Syntheses, Structures, Solution Properties, and Oxygenation Reactivity
inferred← citeshttps://doi.org/10.1021/ic020496gopenalex-snapshot
Electronic Structure and Reactivity of High-Spin Iron−Alkyl- and −Pterinperoxo Complexes
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Steric and Hydrogen-Bonding Effects on the Stability of Copper Complexes with Small Molecules
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Effect of Constrained Donor Atom Orientations on the Stabilities, Complexation Kinetics, Redox Potentials, and Structures of Macrocyclic Polythiaether Complexes. Copper(II) Complexes with Cyclopentanediyl Derivatives of [14]aneS4 in 80% Methanol
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Sulfur Donor Atom Effects on Copper(I)/O2 Chemistry with Thioanisole Containing Tetradentate N3S Ligand Leading to μ-1,2-Peroxo-Dicopper(II) Species
inferred← citeshttps://doi.org/10.1021/ic1016142openalex-snapshot
Structural Comparison of Copper(I) and Copper(II) Complexes with Tris(2-pyridylmethyl)amine Ligand
inferred← citeshttps://doi.org/10.1021/ic2019296openalex-snapshot
Dioxygen Reactivity of New Bispidine-Copper Complexes
inferred← citeshttps://doi.org/10.1021/ic3004917openalex-snapshot
Structure, Bonding, and Catecholase Mechanism of Copper Bispidine Complexes
inferred← citeshttps://doi.org/10.1021/ic502484sopenalex-snapshot
Properties and ATRP Activity of Copper Complexes with Substituted Tris(2-pyridylmethyl)amine-Based Ligands
inferred← citeshttps://doi.org/10.1021/ic702437copenalex-snapshot
Copper Dioxygen Adducts: Formation of Bis(μ-oxo)dicopper(III) versus (μ-1,2)Peroxodicopper(II) Complexes with Small Changes in One Pyridyl-Ligand Substituent
inferred← citeshttps://doi.org/10.1021/ic900975yopenalex-snapshot
Molecular Oxygen and Sulfur Reactivity of a Cyclotriveratrylene Derived Trinuclear Copper(I) Complex
inferred← citeshttps://doi.org/10.1021/ic9017695openalex-snapshot
Copper(I)/O2 Chemistry with Imidazole Containing Tripodal Tetradentate Ligands Leading to μ-1,2-Peroxo−Dicopper(II) Species
inferred← citeshttps://doi.org/10.1021/ic901814fopenalex-snapshot
Transition-Metal Ions in Zeolites: Coordination and Activation of Oxygen
inferred← citeshttps://doi.org/10.1021/ic961317wopenalex-snapshot
Modeling of End-On (μ-Peroxo)dicopper(II) Complexes
inferred← citeshttps://doi.org/10.1021/ic9707117openalex-snapshot
Ring Size, Substituent, and Anion Effects on the Kinetic and Equilibrium Properties of Copper(II) Complexes with Water-Soluble Macrocyclic Tetrathia Ethers
inferred← citeshttps://doi.org/10.1021/ic9907213openalex-snapshot
Unusually High Selectivity of Polythiaethers for Copper(II) over Nickel(II)
inferred← citeshttps://doi.org/10.1021/ja0016755openalex-snapshot
Spectroscopic and Theoretical Studies of Mononuclear Copper(II) Alkyl- and Hydroperoxo Complexes: Electronic Structure Contributions to Reactivity
inferred← citeshttps://doi.org/10.1021/ja010165nopenalex-snapshot
Spectroscopic Properties and Electronic Structure of Low-Spin Fe(III)−Alkylperoxo Complexes: Homolytic Cleavage of the O−O Bond
inferred← citeshttps://doi.org/10.1021/ja011450+openalex-snapshot
Electronic Structure of High-Spin Iron(III)−Alkylperoxo Complexes and Its Relation to Low-Spin Analogues: Reaction Coordinate of O−O Bond Homolysis
inferred← citeshttps://doi.org/10.1021/ja012621dopenalex-snapshot
Electronic Structure and Reactivity of Low-Spin Fe(III)−Hydroperoxo Complexes: Comparison to Activated Bleomycin
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Spectroscopy and Bonding in Side-On and End-On Cu2(S2) Cores: Comparison to Peroxide Analogues
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Resonance Raman Investigation of Equatorial Ligand Donor Effects on the Cu 2 O 2 2+ Core in End-On and Side-On μ-Peroxo-Dicopper(II) and Bis-μ-oxo-Dicopper(III) Complexes
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Synthesis, Structure, and Chemistry of New, Mixed Group 14 and 16 Heterocycles: Nucleophile-Induced Ring Contraction of Mesocyclic Dications
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An Anionic, Tetragonal Copper(II) Superoxide Complex
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Factors That Control Catalytic Two- versus Four-Electron Reduction of Dioxygen by Copper Complexes
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Geometric and Electronic Structure of [{Cu(MeAN)} 2 (μ-η 2 :η 2 (O 2 2– ))] 2+ with an Unusually Long O–O Bond: O–O Bond Weakening vs Activation for Reductive Cleavage
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Characterization of Metastable Intermediates Formed in the Reaction between a Mn(II) Complex and Dioxygen, Including a Crystallographic Structure of a Binuclear Mn(III)–Peroxo Species
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L-Edge X-ray Absorption Spectroscopy and DFT Calculations on Cu2O2 Species: Direct Electrophilic Aromatic Attack by Side-on Peroxo Bridged Dicopper(II) Complexes
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Weakly Coupled Biologically Relevant Cu II 2 (μ-η 1 :η 1 -O 2 ) cis -Peroxo Adduct that Binds Side-On to Additional Metal Ions
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Tuning of the Copper–Thioether Bond in Tetradentate N3S(thioether) Ligands; O–O Bond Reductive Cleavage via a [CuII2(μ-1,2-peroxo)]2+/[CuIII2(μ-oxo)2]2+ Equilibrium
inferred← citeshttps://doi.org/10.1021/ja807081dopenalex-snapshot
Toluene and Ethylbenzene Aliphatic C−H Bond Oxidations Initiated by a Dicopper(II)-μ-1,2-Peroxo Complex
inferred← citeshttps://doi.org/10.1021/ja902327sopenalex-snapshot
Aliphatic C−H Bond Oxidation of Toluene Using Copper Peroxo Complexes That Are Stable at Room Temperature
inferred← citeshttps://doi.org/10.1021/ja952598uopenalex-snapshot
Transition Metal Complexes with Sulfur Ligands. 117.1A Reaction Cycle for Nickel Mediated Thioester Formation from Alkyl, CO, and Thiolate Groups Modeling the Acetyl-Coenzyme A Synthase Function of CO Dehydrogenase
inferred← citeshttps://doi.org/10.1021/ja962455nopenalex-snapshot
Ab Initio Characterization of the Isomerism between the μ-η2:η2-Peroxo- and Bis(μ-oxo)dicopper Cores
inferred← citeshttps://doi.org/10.1021/ja970420xopenalex-snapshot
Activation of Diazene and the Nitrogenase Problem: An Investigation of Diazene-Bridged Fe(II) Centers with Sulfur Ligand Sphere. 2. Vibrational Properties
inferred← citeshttps://doi.org/10.1021/ja980129xopenalex-snapshot
Spectroscopic Study of [Fe2(O2)(OBz)2{HB(pz‘)3}2]: Nature of the μ-1,2 Peroxide−Fe(III) Bond and Its Possible Relevance to O2Activation by Non-Heme Iron Enzymes
inferred← citeshttps://doi.org/10.1021/ja992017ropenalex-snapshot
Re-engineering Enzyme-Model Active Sites: Reversible Binding of Dioxygen at Ambient Conditions by a Bioinspired Copper Complex
inferred← citeshttps://doi.org/10.1021/jacs.0c06270openalex-snapshot
Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH3-Mediated Selective Catalytic Reduction
inferred← citeshttps://doi.org/10.1021/jacs.1c02835openalex-snapshot
Spectroscopic Definition of a Highly Reactive Site in Cu-CHA for Selective Methane Oxidation: Tuning a Mono-μ-Oxo Dicopper(II) Active Site for Reactivity
inferred← citeshttps://doi.org/10.1021/jacs.1c08645openalex-snapshot
Modulation of a μ-1,2-Peroxo Dicopper(II) Intermediate by Strong Interaction with Alkali Metal Ions
inferred← citeshttps://doi.org/10.1021/jacs.1c10252openalex-snapshot
End-On Copper(I) Superoxo and Cu(II) Peroxo and Hydroperoxo Complexes Generated by Cryoreduction/Annealing and Characterized by EPR/ENDOR Spectroscopy
inferred← citeshttps://doi.org/10.1021/jacs.3c14422openalex-snapshot
Coordination Variations within Binuclear Copper Dioxygen-Derived (Hydro)Peroxo and Superoxo Species; Influences upon Thermodynamic and Electronic Properties
inferred← citeshttps://doi.org/10.1021/jacs.5b10177openalex-snapshot
Laser-Induced Dynamics of Peroxodicopper(II) Complexes Vary with the Ligand Architecture. One-Photon Two-Electron O2 Ejection and Formation of Mixed-Valent CuICuII–Superoxide Intermediates
inferred← citeshttps://doi.org/10.1021/jacs.7b06472openalex-snapshot
Methane to Methanol: Structure–Activity Relationships for Cu-CHA
inferred← citeshttps://doi.org/10.1021/jp9813241openalex-snapshot
Theoretical Study of the Interconversion of O2-Binding Dicopper Complexes
inferred← citeshttps://doi.org/10.1039/9781837677955-00266openalex-snapshot
Molecular Mechanism of Phenolase Activity of Tyrosinase
inferred← citeshttps://doi.org/10.1039/a607862aopenalex-snapshot
Copper dioxygen complexes stable at ambient temperature: optimization of ligand design and solvent
inferred← citeshttps://doi.org/10.1039/b404640dopenalex-snapshot
Mixed metal bis(μ-oxo) complexes with [CuM(μ-O) 2 ] n+ (M = Ni( iii ) or Pd( ii )) cores
inferred← citeshttps://doi.org/10.1039/b712572kopenalex-snapshot
H-atom abstraction reaction for organic substrates via mononuclear copper(ii)-superoxo species as a model for DβM and PHM
inferred← citeshttps://doi.org/10.1039/c4cc09645bopenalex-snapshot
Conversion of methane to methanol on copper-containing small-pore zeolites and zeotypes
inferred← citeshttps://doi.org/10.1039/c7cs00709dopenalex-snapshot
Active sites and mechanisms in the direct conversion of methane to methanol using Cu in zeolitic hosts: a critical examination
inferred← citeshttps://doi.org/10.1039/c8dt03604gopenalex-snapshot
Photoexcited state chemistry of metal–oxygen complexes
inferred← citeshttps://doi.org/10.1039/c9dt02814eopenalex-snapshot
Theoretical study of aromatic hydroxylation of the [Cu 2 (H-XYL)O 2 ] 2+ complex mediated by a side-on peroxo dicopper core and Cu-ligand effects
inferred← citeshttps://doi.org/10.1039/ic093291openalex-snapshot
Chapter 19. The co-ordination chemistry of open-chain polydentate ligands
inferred← citeshttps://doi.org/10.1073/pnas.0402114101openalex-snapshot
O 2 activation by binuclear Cu sites: Noncoupled versus exchange coupled reaction mechanisms
inferred← citeshttps://doi.org/10.1073/pnas.0737180100openalex-snapshot
Superoxo, μ-peroxo, and μ-oxo complexes from heme/O 2 and heme-Cu/O 2 reactivity: Copper ligand influences in cytochrome c oxidase models
inferred← citeshttps://doi.org/10.1073/pnas.0910461106openalex-snapshot
A [Cu 2 O] 2+ core in Cu-ZSM-5, the active site in the oxidation of methane to methanol
inferred← citeshttps://doi.org/10.1073/pnas.2205619119openalex-snapshot
Elucidation of the tyrosinase/O 2 /monophenol ternary intermediate that dictates the monooxygenation mechanism in melanin biosynthesis
inferred← citeshttps://doi.org/10.1080/00958972.2022.2107429openalex-snapshot
Oxygenation of copper(I) complexes containing fluorine tagged tripodal tetradentate chelates: significant ligand electronic effects
inferred← citeshttps://doi.org/10.1080/02603599808032748openalex-snapshot
Oxy-hemocyanin: A Peroxo Copper(II) Complex? A Mixed-Valence Alternative View
inferred← citeshttps://doi.org/10.1126/science.8384374openalex-snapshot
Electronic structure contributions to function in bioinorganic chemistry
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Formation, Structure, and Reactivity of Copper Dioxygen Complexes
inferred← citeshttps://doi.org/10.1246/bcsj.77.59openalex-snapshot
Dioxygen Reactivity of Copper(I) Complexes with Tetradentate Tripodal Ligands Having Aliphatic Nitrogen Donors: Synthesis, Structures, and Properties of Peroxo and Superoxo Complexes
inferred← citeshttps://doi.org/10.1246/cl.1993.963openalex-snapshot
Reactivity of Copper(I) Complexes Containing Various Tetradentate Tripodal Ligands with Molecular Oxygen
inferred← citeshttps://doi.org/10.1246/cl.2002.416openalex-snapshot
Modulation of the Copper-Dioxygen Reactivity by Stereochemical Effect of Tetradentate Tripodal Ligands
inferred← citeshttps://doi.org/10.4019/bjscc.83.16openalex-snapshot
Synthetic Copper-(Di)oxygen Complex Generation and Reactivity Relevant to Copper Protein O2-Processing
inferred← citeshttps://doi.org/10.5958/2277-8934.2023.00030.9openalex-snapshot
Comparative Study on Antioxidant Capacity, Oxidative Changes and in vitro Digestibility of Spray Dried Camel, Goat and Cow Milk Powder during Accelerated Storage
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