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Kinetics and thermodynamics of formation of copper-dioxygen adducts: oxygenation of mononuclear copper(I) complexes containing tripodal tetradentate ligands

https://doi.org/10.1021/ja00074a015
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Reversible Binding of Dioxygen by the Copper(I) Complex with Tris(2-dimethylaminoethyl)amine (Me6tren) Ligand
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Ligand Effect on Reversible Conversion between Copper(I) and Bis(μ-oxo)dicopper(III) Complex with a Sterically Hindered Tetradentate Tripodal Ligand and Monooxygenase Activity of Bis(μ-oxo)dicopper(III) Complex
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Mono-, Bi-, and Trinuclear CuII-Cl Containing Products Based on the Tris(2-pyridylmethyl)amine Chelate Derived from Copper(I) Complex Dechlorination Reactions of Chloroform
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Independent Synthesis and Structural Characterization of a Mononuclear Copper−Hydroxide Complex Previously Assigned as a Copper−Superoxide Species
inferred← citeshttps://doi.org/10.1021/ic960942yopenalex-snapshot
Synthesis and Cyclic Voltammetry Studies of Copper Complexes of Bromo- and Alkoxyphenyl-Substituted Derivatives of Tris(2-pyridylmethyl)amine: Influence of Cation−Alkoxy Interactions on Copper Redox Potentials
inferred← citeshttps://doi.org/10.1021/ic961267vopenalex-snapshot
Synthesis, Crystal Structures, and Catalytic Activity of Dicopper(II) Complexes with Dinucleating Tetraimidazole Ligands [Cu2(RO)(mbipl)](ClO4)2(R = Me, Et, 2-Pr; Hmbipl = 1,5-Bis[bis[(1-methyl-4-imidazolyl)methyl]amino]-3-pentanol) and [Cu2(MeO)(pbipl)](ClO4)2(Hpbipl =…
inferred← citeshttps://doi.org/10.1021/ic961371copenalex-snapshot
Kinetics and Equilibria of Dioxygen Binding to a Vacant Site in Cobalt(II) Complexes with Pentadentate Ligands
inferred← citeshttps://doi.org/10.1021/ic970396oopenalex-snapshot
Ligand Effects in the Models and Mimics of Oxyhemocyanin and Oxytyrosinase. A Density Functional Study of Reversible Dioxygen Binding and Reversible O−O Bond Cleavage
inferred← citeshttps://doi.org/10.1021/ic970639copenalex-snapshot
Binuclear Copper Complexes Based on the 6,6‘-Bis[[bis(2-pyridylmethyl)amino]methyl]-2,2‘-bipyridine Ligand
inferred← citeshttps://doi.org/10.1021/ic970718oopenalex-snapshot
Binucleating Ligand Structural Effects on (μ-Peroxo)- and Bis(μ-oxo)dicopper Complex Formation and Decay: Competition between Arene Hydroxylation and Aliphatic C−H Bond Activation
inferred← citeshttps://doi.org/10.1021/ic9707873openalex-snapshot
Synthesis, Molecular Structure, and Reactivity of Dinuclear Copper(II) Complexes with Carboxylate-Rich Coordination Environments
inferred← citeshttps://doi.org/10.1021/ic9709281openalex-snapshot
Studies of Copper Complexes Displaying N3S Coordination as Models for CuBCenter of Dopamine β-Hydroxylase and Peptidylglycine α-Hydroxylating Monooxygenase
inferred← citeshttps://doi.org/10.1021/ic981066mopenalex-snapshot
Intramolecular Ligand Hydroxylation: Mechanistic High-Pressure Studies on the Reaction of a Dinuclear Copper(I) Complex with Dioxygen
inferred← citeshttps://doi.org/10.1021/ic981431+openalex-snapshot
Oxo- and Hydroxo-Bridged Heme-Copper Assemblies Formed from Acid−Base or Metal−Dioxygen Chemistry
inferred← citeshttps://doi.org/10.1021/ic990334topenalex-snapshot
Influence of Coordination Geometry upon Copper(II/I) Redox Potentials. Physical Parameters for Twelve Copper Tripodal Ligand Complexes
inferred← citeshttps://doi.org/10.1021/ja012539iopenalex-snapshot
Targeted Strand Scission of DNA Substrates by a Tricopper(II) Coordination Complex
inferred← citeshttps://doi.org/10.1021/ja020039zopenalex-snapshot
Efficient and Specific Strand Scission of DNA by a Dinuclear Copper Complex: Comparative Reactivity of Complexes with Linked Tris(2-pyridylmethyl)amine Moieties
inferred← citeshttps://doi.org/10.1021/ja020969iopenalex-snapshot
Spectroscopic and Electronic Structure Studies of the Diamagnetic Side-On CuII-Superoxo Complex Cu(O2)[HB(3-R-5-iPrpz)3]: Antiferromagnetic Coupling versus Covalent Delocalization
inferred← citeshttps://doi.org/10.1021/ja027164vopenalex-snapshot
Snapshots of Dioxygen Activation by Copper: The Structure of a 1:1 Cu/O2 Adduct and Its Use in Syntheses of Asymmetric Bis(μ-oxo) Complexes
inferred← citeshttps://doi.org/10.1021/ja045678jopenalex-snapshot
Dioxygen Activation at a Single Copper Site: Structure, Bonding, and Mechanism of Formation of 1:1 Cu−O2 Adducts
inferred← citeshttps://doi.org/10.1021/ja056741nopenalex-snapshot
Evidence for Cu−O2Intermediates in Superoxide Oxidations by Biomimetic Copper(II) Complexes
inferred← citeshttps://doi.org/10.1021/ja067411lopenalex-snapshot
A 1:1 Copper−Dioxygen Adduct is an End-on Bound Superoxo Copper(II) Complex which Undergoes Oxygenation Reactions with Phenols
inferred← citeshttps://doi.org/10.1021/ja100714popenalex-snapshot
Development of Highly Sensitive Fluorescent Probes for Detection of Intracellular Copper(I) in Living Systems
inferred← citeshttps://doi.org/10.1021/ja312523uopenalex-snapshot
Temperature-Independent Catalytic Two-Electron Reduction of Dioxygen by Ferrocenes with a Copper(II) Tris[2-(2-pyridyl)ethyl]amine Catalyst in the Presence of Perchloric Acid
inferred← citeshttps://doi.org/10.1021/ja807081dopenalex-snapshot
Toluene and Ethylbenzene Aliphatic C−H Bond Oxidations Initiated by a Dicopper(II)-μ-1,2-Peroxo Complex
inferred← citeshttps://doi.org/10.1021/ja902327sopenalex-snapshot
Aliphatic C−H Bond Oxidation of Toluene Using Copper Peroxo Complexes That Are Stable at Room Temperature
inferred← citeshttps://doi.org/10.1021/ja902716dopenalex-snapshot
Imino-oxy Acetic Acid Dealkylation as Evidence for an Inner-Sphere Alcohol Intermediate in the Reaction Catalyzed by Peptidylglycine α-Hydroxylating Monooxygenase
inferred← citeshttps://doi.org/10.1021/ja954157gopenalex-snapshot
Formation and Interconversion of End-on and Side-on μ-Peroxo−Dicopper(II) Complexes
inferred← citeshttps://doi.org/10.1021/ja962814eopenalex-snapshot
Kinetic Studies of Reactions of Dioxygen with Carboxylate-Bridged Diiron(II) Complexes Leading to the Formation of (μ-Oxo)diiron(III) Complexes
inferred← citeshttps://doi.org/10.1021/ja972809qopenalex-snapshot
Mechanistic Studies of Aliphatic Ligand Hydroxylation of a Copper Complex by Dioxygen: A Model Reaction for Copper Monooxygenases
inferred← citeshttps://doi.org/10.1021/ja992296iopenalex-snapshot
Formation and Characterization of a High-Spin Heme-Copper Dioxygen (Peroxo) Complex
inferred← citeshttps://doi.org/10.1021/jacs.1c10252openalex-snapshot
End-On Copper(I) Superoxo and Cu(II) Peroxo and Hydroperoxo Complexes Generated by Cryoreduction/Annealing and Characterized by EPR/ENDOR Spectroscopy
inferred← citeshttps://doi.org/10.1021/ma020279zopenalex-snapshot
Measurement of Initial Degree of Polymerization without Reactivation as a New Method To Estimate Rate Constants of Deactivation in ATRP
inferred← citeshttps://doi.org/10.1021/om300833mopenalex-snapshot
Selective Redox Activation of H2 or O2 in a [NiRu] Complex by Aromatic Ligand Effects
inferred← citeshttps://doi.org/10.1021/tx010046lopenalex-snapshot
Molecular Mechanism of Hydrogen Peroxide Conversion and Activation by Cu(II)-Amikacin Complexes
inferred← citeshttps://doi.org/10.1023/a:1009549506565openalex-snapshot
Copper, a chemical Janus: two copper(II) complexes with different ligand in one single crystal
inferred← citeshttps://doi.org/10.1023/b:ruco.0000003432.39025.ccopenalex-snapshot
Complexes of Copper in Unstable Oxidation States
inferred← citeshttps://doi.org/10.1039/a607862aopenalex-snapshot
Copper dioxygen complexes stable at ambient temperature: optimization of ligand design and solvent
inferred← citeshttps://doi.org/10.1039/b107927copenalex-snapshot
Low temperature stopped-flow studies in inorganic chemistryBased on the presentation given at Dalton Discussion No. 4, 10–13th January 2002, Kloster Banz, Germany.
inferred← citeshttps://doi.org/10.1039/b208740eopenalex-snapshot
Syntheses and characterization of copper complexes of the ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) and derivatives
inferred← citeshttps://doi.org/10.1039/b302037aopenalex-snapshot
Coordination chemistry of copper-( i ) and -( ii ) with 2-pyridylmethyl substituted triazacyclohexanes
inferred← citeshttps://doi.org/10.1039/b307265gopenalex-snapshot
Formation and dissociation kinetics of dinuclear metal complexes with pyrazole and triazole bridged bis-macrocycles
inferred← citeshttps://doi.org/10.1039/b308966popenalex-snapshot
Synthesis and complexation properties of ditopic ligands built from a macrocyclic and an open chain chelator moiety
inferred← citeshttps://doi.org/10.1039/b310262aopenalex-snapshot
Syntheses, structural properties and catecholase activity of copper( ii ) complexes with reduced Schiff base N-(2-hydroxybenzyl)-amino acids
inferred← citeshttps://doi.org/10.1039/b503385nopenalex-snapshot
Kinetics and mechanism of the stepwise complex formation of Cu(ii) with tren-centered tris-macrocycles
inferred← citeshttps://doi.org/10.1039/b506288hopenalex-snapshot
Oxygen binding and activation by the complexes of PY2- and TPA-appended diphenylglycoluril receptors with copper and other metals
inferred← citeshttps://doi.org/10.1039/b709422aopenalex-snapshot
Homo- and heteropolynuclear Ni2+ and Cu2+ complexes of polytopic ligands, consisting of a tren unit substituted with three 12-membered tetraazamacrocycles
inferred← citeshttps://doi.org/10.1039/c2cp41207aopenalex-snapshot
Improvement of durability of an organic photocatalyst in p-xylene oxygenation by addition of a Cu(ii) complex
inferred← citeshttps://doi.org/10.1039/c39950000499openalex-snapshot
Copper–dioxygen reactivity involved in the formation of µ-oxo [(por)Fe III –O–Cu II L] + heterodinuclear complexes (por = porphyrinate, L = tetradentate ligand), and novel synthesis of square-planar Fe II (por) species
inferred← citeshttps://doi.org/10.1039/c3dt52829dopenalex-snapshot
Influence of inductive effects and steric encumbrance on the catecholase activities of copper(ii) complexes of reduced Schiff base ligands
inferred← citeshttps://doi.org/10.1039/c3nj00974bopenalex-snapshot
Synergistic enzyme inhibition effect of cefuroxime by conjugation with gold and silver
inferred← citeshttps://doi.org/10.1039/c4dt00606bopenalex-snapshot
Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: the relationship between activity and redox potential
inferred← citeshttps://doi.org/10.1039/c5nj01571eopenalex-snapshot
Moxifloxacin-capped noble metal nanoparticles as potential urease inhibitors
inferred← citeshttps://doi.org/10.1039/c7cc08619aopenalex-snapshot
Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes
inferred← citeshttps://doi.org/10.1039/c8dt03183eopenalex-snapshot
Tuning the reactivity of copper complexes supported by tridentate ligands leading to two-electron reduction of dioxygen
inferred← citeshttps://doi.org/10.1039/c9dt01726gopenalex-snapshot
Ascorbyl and hydroxyl radical generation mediated by a copper complex adsorbed on gold
inferred← citeshttps://doi.org/10.1039/d0sc02393kopenalex-snapshot
Switchable foldamer ion channels with antibacterial activity
inferred← citeshttps://doi.org/10.1039/d4qi00701hopenalex-snapshot
How do quantum chemical descriptors shape hydrogen atom abstraction reactivity in cupric-superoxo species? A combined DFT and machine learning perspective
inferred← citeshttps://doi.org/10.1039/dt9940002005openalex-snapshot
Novel monomeric and dimeric copper( II ) pyridone complexes containing the 2,2′-bipyridyl ligand
inferred← citeshttps://doi.org/10.1039/dt9940002471openalex-snapshot
Stabilization of copper(I) by phosphinoamines
inferred← citeshttps://doi.org/10.1039/dt9950000031openalex-snapshot
Comparative study of the catalytic oxidation of catechols by copper(II) complexes of tripodal ligands
inferred← citeshttps://doi.org/10.1039/ic9939000207openalex-snapshot
Chapter 15. Copper
inferred← citeshttps://doi.org/10.1039/ic9959200481openalex-snapshot
Chapter 26. Inorganic mechanisms
inferred← citeshttps://doi.org/10.1071/ch09263openalex-snapshot
Diphenoxo-Bridged Copper(ii) Complexes of Reduced Schiff Base Ligands as Functional Models for Catechol Oxidase
inferred← citeshttps://doi.org/10.1080/00958972.2018.1493581openalex-snapshot
From mononuclear to polynuclear: copper and zinc complexes obtained from polypyridylamine ligands related to tris(2-pyridylmethyl)-amine (tmpa)
inferred← citeshttps://doi.org/10.1080/00958972.2022.2107429openalex-snapshot
Oxygenation of copper(I) complexes containing fluorine tagged tripodal tetradentate chelates: significant ligand electronic effects
inferred← citeshttps://doi.org/10.1080/07391102.2021.1924263openalex-snapshot
Effect of structural variation on enzymatic activity in tetranuclear (Cu 4 ) clusters with defective cubane core
inferred← citeshttps://doi.org/10.1126/science.271.5254.1397openalex-snapshot
Reversible Cleavage and Formation of the Dioxygen O-O Bond Within a Dicopper Complex
inferred← citeshttps://doi.org/10.1134/s1023193507100059openalex-snapshot
Electrochemical synthesis of Cu-containing polyheteroarylenes and study of their catalytic properties
inferred← citeshttps://doi.org/10.1135/cccc20021647openalex-snapshot
Syntheses and Characterization of Copper(II) and Cobalt(II) Complexes with Tris[2-(benzylamino)ethyl]amine
inferred← citeshttps://doi.org/10.1201/9780203908457.ch14openalex-snapshot
Formation, Structure, and Reactivity of Copper Dioxygen Complexes
inferred← citeshttps://doi.org/10.1246/bcsj.71.1031openalex-snapshot
Preparations, Structures, and Properties of Copper(II) Complexes with a New Tripodal Tetradentate Ligand, N-(2-Pyridylmethyl)bis(6-pivalamido-2-pyridylmethyl)amine, and Reactivities of the Cu(I) Complex with Dioxygen
inferred← citeshttps://doi.org/10.1246/bcsj.71.637openalex-snapshot
Preparations, Structures, and Properties of Cu(II) Complexes with Tripodal Tetradentate Ligand, Tris(6-pivaloylamino-2-pyridylmethyl)amine (Htppa), and Reaction of Its Cu(I) Complex with Dioxygen
inferred← citeshttps://doi.org/10.1246/bcsj.77.59openalex-snapshot
Dioxygen Reactivity of Copper(I) Complexes with Tetradentate Tripodal Ligands Having Aliphatic Nitrogen Donors: Synthesis, Structures, and Properties of Peroxo and Superoxo Complexes
inferred← citeshttps://doi.org/10.1246/bcsj.79.1729openalex-snapshot
Syntheses, Structures, and O2-Reactivities of Copper(I) Complexes with Bis(2-pyridylmethyl)amine and Bis(2-quinolylmethyl)amine Tridentate Ligands
inferred← citeshttps://doi.org/10.1366/0003702953965902openalex-snapshot
ATR-IR Spectroscopy for the Investigation of Solution Reaction Kinetics: Hydrolysis of Trimethyl Phosphate
inferred← citeshttps://doi.org/10.1515/irm-2003-0105openalex-snapshot
Simulation of Complex Chemical Kinetics
inferred← citeshttps://doi.org/10.1515/irm.2003.5.1.39openalex-snapshot
Simulation of Complex Chemical Kinetics
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