Reversible Dioxygen Binding and Aromatic Hydroxylation in O2-Reactions with Substituted Xylyl Dinuclear Copper(I) Complexes: Syntheses and Low-Temperature Kinetic/Thermodynamic and Spectroscopic Investigations of a Copper Monooxygenase Model System
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New copper(II) µ-Alkoxo-µ-Carboxylato Double Bridged Complexes As Models for Active Site of Catechol Oxidase: Synthesis, Spectral Characterization and DFT Calculations
Syntheses, Structures and Properties of Copper(I) and Copper(II) Complexes of the Ligand N,N′-Bis[2′-(dimethylamino)ethyl]-N,N′-dimethylethane1,2-diamine (Me6trien)
Copper: Hemocyanin/Tyrosinase ModelsBased in part on the article Copper: Hemocyanin/Tyrosinase Models by Nobumasa Kitajima which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .
Effects of a Side Chain Aromatic Ring on the Reactivity of Copper(I) Complexes with Dioxygen This work was supported by the Grants-in-Aid for Scientific Research (No. 09304062 to O.Y. and No. 07CE2004 (COE) to A.O.) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan,…
Copper: Hemocyanin/Tyrosinase ModelsBased in part on the article Copper: Hemocyanin/Tyrosinase Models by Nobumasa Kitajima which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .
Copper( II ) Complexes of Schiff‐Base and Reduced Schiff‐Base Ligands: Influence of Weakly Coordinating Sulfonate Groups on the Structure and Oxidation of 3,5‐DTBC
New copper(II) μ-alkoxo-μ-carboxylato double-bridged complexes as models for the active site of catechol oxidase: synthesis, spectral characterization and DFT calculations
Thiol-copper(I) and disulfide–dicopper(I) complex O2-reactivity leading to sulfonate–copper(II) complex or the formation of a cross-linked thioether–phenol product with phenol addition
Synthesis, characterization and reactivity of a series of dinuclear copper complexes bearing the ligand bis[3-(2-hydroxybenzylideneamino)phenyl] sulfone and derivatives
Synthesis of new copper(II) complexes of polydentate ligands containing pyridyl pendant arms. Crystal structure of [N, N, N′, N′-tetrakis(2-pyrid-2-yl-ethyl)1, 2-ethylenediaminecopper(II)]-bis(hexafluorophosphate) · 1.5 acetone
Highly Stabilized Low-Spin Iron(III) and Cobalt(III) Complexes of a Tridentate Bis-Amide Ligand 2,6-Bis(N-phenylcarbamoyl)pyridine. Novel Nonmacrocyclic Tetraamido-N Coordination and Two Unusually Short Metal−Pyridine Bonds
Synthesis, Crystal Structures, and Catalytic Activity of Dicopper(II) Complexes with Dinucleating Tetraimidazole Ligands [Cu2(RO)(mbipl)](ClO4)2(R = Me, Et, 2-Pr; Hmbipl = 1,5-Bis[bis[(1-methyl-4-imidazolyl)methyl]amino]-3-pentanol) and [Cu2(MeO)(pbipl)](ClO4)2(Hpbipl =…
Modeling Tyrosinase Monooxygenase Activity. Spectroscopic and Magnetic Investigations of Products Due to Reactions between Copper(I) Complexes of Xylyl-Based Dinucleating Ligands and Dioxygen: Aromatic Ring Hydroxylation and Irreversible Oxidation Products
Modeling Tyrosinase Monooxygenase Activity. Spectroscopic and Magnetic Investigations of Products Due to Reactions between Copper(I) Complexes of Xylyl-Based Dinucleating Ligands and Dioxygen: Aromatic Ring Hydroxylations and Irreversible Oxidation Products
L-Edge X-ray Absorption Spectroscopy and DFT Calculations on Cu2O2 Species: Direct Electrophilic Aromatic Attack by Side-on Peroxo Bridged Dicopper(II) Complexes
Crystal Structure and Reversible O2-Binding of a Room Temperature Stable μ-η2:η2-Peroxodicopper(II) Complex of a Sterically Hindered Hexapyridine Dinucleating Ligand
Coordination Variations within Binuclear Copper Dioxygen-Derived (Hydro)Peroxo and Superoxo Species; Influences upon Thermodynamic and Electronic Properties
Low temperature stopped-flow studies in inorganic chemistryBased on the presentation given at Dalton Discussion No. 4, 10–13th January 2002, Kloster Banz, Germany.
The phenol ortho-oxygenation by mononuclear copper(i) complexes requires a dinuclear µ-η2∶η2-peroxodicopper(ii) complex rather than mononuclear CuO2 species
Dinuclear complexes of copper and zinc with m-xylene/cyclohexane-linked bis-aspartic acids: Synthesis, characterization, dioxygen activation, and catalytic oxidation of nitrobenzene in pure aqueous solution
Copper-(I) and -(II) complexes of a macrocycle derived from 2:2 condensation of pyridine-2,6-dicarbaldehyde and 4-azaheptane-1,7-diamine; oxygenation of the copper(I) complex
Tetrameric Self-Assembly of a Cu(II) Complex Containing Schiff-Base Ligand and Its Unusually High Catecholase-like Activity
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