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Synthesis of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP), an atropisomeric chiral bis(triaryl)phosphine, and its use in the rhodium(I)-catalyzed asymmetric hydrogenation of .alpha.-(acylamino)acrylic acids
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(R)- & (S)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl
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( R )‐(+)‐ and ( S )‐(−)‐2,2′‐Bis(Diphenylphosphino)‐1,1′‐Binaphthyl (BINAP)
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(R)‐(+)‐ and (S)‐(−)‐2,2′‐Bis(Diphenylphosphino)‐1,1′‐Binaphthyl (BINAP)
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Discussion Addendum for: Resolution of 1,1′‐Bi‐2‐Naphthol; ( R )‐(+)‐ and ( S )‐(−)‐2,2′‐Bis(diphenylphosphino)‐1,1′‐binaphthyl ( BINAP )
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2,2′‐Bis(diphenylphosphine)‐1,1′‐binaphthyl ( BINAP ) 1
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Diols Activation by Cu/Borinic Acids Synergistic Catalysis in Atroposelective Ring‐Opening of Cyclic Diaryliodoniums
inferred← citeshttps://doi.org/10.1002/ange.202106880openalex-snapshot
Towards Data‐Driven Design of Asymmetric Hydrogenation of Olefins: Database and Hierarchical Learning
inferred← citeshttps://doi.org/10.1002/ange.202108630openalex-snapshot
Carbene‐Catalyzed Asymmetric Construction of Atropisomers
inferred← citeshttps://doi.org/10.1002/ange.202117340openalex-snapshot
Synthesis of Axially Chiral Aldehydes by N‐Heterocyclic‐Carbene‐Catalyzed Desymmetrization Followed by Kinetic Resolution
inferred← citeshttps://doi.org/10.1002/ange.202202467openalex-snapshot
Enantioselective Synthesis of Atropisomeric Biaryl Phosphorus Compounds by Chiral‐Phosphonium‐Salt‐Enabled Cascade Arene Formation
inferred← citeshttps://doi.org/10.1002/ange.202205037openalex-snapshot
Rhodium‐Catalyzed Atroposelective Click Cycloaddition of Azides and Alkynes
inferred← citeshttps://doi.org/10.1002/ange.202206631openalex-snapshot
Chemically Driven Rotatory Molecular Machines
inferred← citeshttps://doi.org/10.1002/ange.202209494openalex-snapshot
Synthesis of Axially Chiral CF3‐Substituted 2‐Arylpyrroles by Sequential Phosphine‐Catalyzed Asymmetric [3+2] Annulation and Oxidative Central‐to‐Axial Chirality Transfer
inferred← citeshttps://doi.org/10.1002/ange.202215820openalex-snapshot
Asymmetric Hydrophosphinylation of Alkynes: Facile Access to Axially Chiral Styrene‐Phosphines
inferred← citeshttps://doi.org/10.1002/ange.202309053openalex-snapshot
Atroposelective P III /P V =O Redox Catalysis for the Isoquinoline‐Forming Staudinger–aza‐Wittig Reaction
inferred← citeshttps://doi.org/10.1002/ange.202318712openalex-snapshot
2,2′‐Tethered Binaphthyl‐Embedded One‐Handed Helical Ladder Polymers: Impact of the Tether Length on Helical Geometry and Chiroptical Property
inferred← citeshttps://doi.org/10.1002/ange.202407034openalex-snapshot
BINOL‐Based Chiral Macrocycles and Cages
inferred← citeshttps://doi.org/10.1002/ange.202407767openalex-snapshot
Enantioselective Synthesis of Heteroatom‐Linked Non‐Biaryl Atropisomers
inferred← citeshttps://doi.org/10.1002/ange.202421060openalex-snapshot
Enantioselective Synthesis of Atropisomeric Tri‐Axis Naphthalenes via Diels–Alder Reaction and Dehydrative Aromatization of Isobenzofurans
inferred← citeshttps://doi.org/10.1002/ange.202421931openalex-snapshot
Atropisomerism in Triarylboranes: Lewis Base Assisted Rotation at C−B Stereogenic Axis in Asymmetrical Boron Lewis Acids
inferred← citeshttps://doi.org/10.1002/ange.202519122openalex-snapshot
Synthesis of Axially Chiral Phenanthryl–Aryl Phosphines via Nickel‐Catalyzed Atroposelective [4 + 2] Cycloaddition with Broad Ligand Applications
inferred← citeshttps://doi.org/10.1002/ange.202525455openalex-snapshot
Asymmetric Synthesis of Fluorinated Cyclobutenes Containing Quaternary Carbon Stereocenters by Rh‐Catalyzed Defluoroarylation
inferred← citeshttps://doi.org/10.1002/ange.3486845openalex-snapshot
Enantioselective Synthesis of Axially Chiral Diaryl Ethers via Rhodium‐Catalyzed [2 + 2 + 2] Cycloaddition
inferred← citeshttps://doi.org/10.1002/anie.198408471openalex-snapshot
Prostaglandin Syntheses by Three‐Component Coupling. New Synthetic Methods (49)
inferred← citeshttps://doi.org/10.1002/anie.198500013openalex-snapshot
Double Asymmetric Synthesis and a New Strategy for Stereochemical Control in Organic Synthesis
inferred← citeshttps://doi.org/10.1002/anie.199522871openalex-snapshot
Asymmetrization of meso 1,4‐Enediol Ethers by Isomerization with a Chiral binap–Rh I Catalyst
inferred← citeshttps://doi.org/10.1002/anie.199600721openalex-snapshot
Chiral Recognition of α‐Amino Acid Derivatives with a Homooxacalix[3]arene: Construction of a Pseudo‐C2‐Symmetrical Compound from a C3‐Symmetrical Macrocycle
inferred← citeshttps://doi.org/10.1002/anie.199606621openalex-snapshot
Enantioselective Cycloisomerization of 1,6‐Enynes Catalyzed by Chiral Diphosphane–Palladium Complexes
inferred← citeshttps://doi.org/10.1002/anie.200290024openalex-snapshot
New Ferrocenyl Ligands with Broad Applications in Asymmetric Catalysis
inferred← citeshttps://doi.org/10.1002/anie.200351978openalex-snapshot
Structurally Defined Catalysts for Enantioselective Oxidative Coupling Reactions
inferred← citeshttps://doi.org/10.1002/anie.200462072openalex-snapshot
Highly Rigid Diphosphane Ligands with a Large Dihedral Angle Based on a Chiral Spirobifluorene Backbone
inferred← citeshttps://doi.org/10.1002/anie.200462661openalex-snapshot
Atroposelective Synthesis of Axially Chiral Biaryl Compounds
inferred← citeshttps://doi.org/10.1002/anie.200501798openalex-snapshot
Supramolecular Approaches to Generate Libraries of Chelating Bidentate Ligands for Homogeneous Catalysis
inferred← citeshttps://doi.org/10.1002/anie.200502703openalex-snapshot
Synthesis of Chiral α‐Fluoroketones through Catalytic Enantioselective Decarboxylation
inferred← citeshttps://doi.org/10.1002/anie.200604553openalex-snapshot
Palladium‐Catalyzed Synthesis of Substituted Cycloheptane‐1,4‐diones by an Asymmetric Ring‐Expanding Allylation (AREA)
inferred← citeshttps://doi.org/10.1002/anie.200700990openalex-snapshot
Propylene Carbonate as a Solvent for Asymmetric Hydrogenations
inferred← citeshttps://doi.org/10.1002/anie.200701040openalex-snapshot
N‐Phosphino Sulfinamide Ligands: An Efficient Manner To Combine Sulfur Chirality and Phosphorus Coordination Behavior
inferred← citeshttps://doi.org/10.1002/anie.200701631openalex-snapshot
Divergent Reactions for Racemates: Catalytic, Enantioselective, and Regiodivergent Nitroso Diels–Alder Reactions
inferred← citeshttps://doi.org/10.1002/anie.200704327openalex-snapshot
Combinatorial Transition‐Metal Catalysis: Mixing Monodentate Ligands to Control Enantio‐, Diastereo‐, and Regioselectivity
inferred← citeshttps://doi.org/10.1002/anie.201002990openalex-snapshot
Electron‐Donating and Rigid P‐Stereogenic Bisphospholane Ligands for Highly Enantioselective Rhodium‐Catalyzed Asymmetric Hydrogenations
inferred← citeshttps://doi.org/10.1002/anie.201105515openalex-snapshot
Formation of Isoxazolidines by Enantioselective Copper‐Catalyzed Annulation of 2‐Nitrosopyridine with Allylstannanes
inferred← citeshttps://doi.org/10.1002/anie.201107937openalex-snapshot
A Mechanochemical Approach to Deracemization
inferred← citeshttps://doi.org/10.1002/anie.201205537openalex-snapshot
Facts are the Enemy of Truth—Reflections on Serendipitous Discovery and Unforeseen Developments in Asymmetric Catalysis
inferred← citeshttps://doi.org/10.1002/anie.201705471openalex-snapshot
Manganese(I)‐Catalyzed Enantioselective Hydrogenation of Ketones Using a Defined Chiral PNP Pincer Ligand
inferred← citeshttps://doi.org/10.1002/anie.201801048openalex-snapshot
Inducing Axial Chirality in a Supramolecular Catalyst
inferred← citeshttps://doi.org/10.1002/anie.201806294openalex-snapshot
Atropselective Dibrominations of a 1,1′‐Disubstituted 2,2′‐Biindolyl with Diverging Point‐to‐Axial Asymmetric Inductions. Deriving 2,2′‐Biindolyl‐3,3′‐diphosphane Ligands for Asymmetric Catalysis
inferred← citeshttps://doi.org/10.1002/anie.201809310openalex-snapshot
A General Amino Acid Synthesis Enabled by Innate Radical Cross‐Coupling
inferred← citeshttps://doi.org/10.1002/anie.201814470openalex-snapshot
The Prins Reaction in the Fragrance Industry: 100th Anniversary (1919–2019)
inferred← citeshttps://doi.org/10.1002/anie.201915386openalex-snapshot
Tailored Palladium Catalysts for Selective Synthesis of Conjugated Enynes by Monocarbonylation of 1,3‐Diynes
inferred← citeshttps://doi.org/10.1002/anie.202001561openalex-snapshot
Diastereoselective Synthesis of P‐Chirogenic and Atropisomeric 2,2′‐Bisphosphino‐1,1′‐binaphthyls Enabled by Internal Phosphine Oxide Directing Groups
inferred← citeshttps://doi.org/10.1002/anie.202014127openalex-snapshot
Diols Activation by Cu/Borinic Acids Synergistic Catalysis in Atroposelective Ring‐Opening of Cyclic Diaryliodoniums
inferred← citeshttps://doi.org/10.1002/anie.202106880openalex-snapshot
Towards Data‐Driven Design of Asymmetric Hydrogenation of Olefins: Database and Hierarchical Learning
inferred← citeshttps://doi.org/10.1002/anie.202108630openalex-snapshot
Carbene‐Catalyzed Asymmetric Construction of Atropisomers
inferred← citeshttps://doi.org/10.1002/anie.202117340openalex-snapshot
Synthesis of Axially Chiral Aldehydes by N‐Heterocyclic‐Carbene‐Catalyzed Desymmetrization Followed by Kinetic Resolution
inferred← citeshttps://doi.org/10.1002/anie.202202467openalex-snapshot
Enantioselective Synthesis of Atropisomeric Biaryl Phosphorus Compounds by Chiral‐Phosphonium‐Salt‐Enabled Cascade Arene Formation
inferred← citeshttps://doi.org/10.1002/anie.202205037openalex-snapshot
Rhodium‐Catalyzed Atroposelective Click Cycloaddition of Azides and Alkynes
inferred← citeshttps://doi.org/10.1002/anie.202206631openalex-snapshot
Chemically Driven Rotatory Molecular Machines
inferred← citeshttps://doi.org/10.1002/anie.202209494openalex-snapshot
Synthesis of Axially Chiral CF 3 ‐Substituted 2‐Arylpyrroles by Sequential Phosphine‐Catalyzed Asymmetric [3+2] Annulation and Oxidative Central‐to‐Axial Chirality Transfer
inferred← citeshttps://doi.org/10.1002/anie.202215820openalex-snapshot
Asymmetric Hydrophosphinylation of Alkynes: Facile Access to Axially Chiral Styrene‐Phosphines
inferred← citeshttps://doi.org/10.1002/anie.202309053openalex-snapshot
Atroposelective P III /P V =O Redox Catalysis for the Isoquinoline‐Forming Staudinger–aza‐Wittig Reaction
inferred← citeshttps://doi.org/10.1002/anie.202318712openalex-snapshot
2,2′‐Tethered Binaphthyl‐Embedded One‐Handed Helical Ladder Polymers: Impact of the Tether Length on Helical Geometry and Chiroptical Property
inferred← citeshttps://doi.org/10.1002/anie.202407034openalex-snapshot
BINOL‐Based Chiral Macrocycles and Cages
inferred← citeshttps://doi.org/10.1002/anie.202407767openalex-snapshot
Enantioselective Synthesis of Heteroatom‐Linked Non‐Biaryl Atropisomers
inferred← citeshttps://doi.org/10.1002/anie.202421060openalex-snapshot
Enantioselective Synthesis of Atropisomeric Tri‐Axis Naphthalenes via Diels–Alder Reaction and Dehydrative Aromatization of Isobenzofurans
inferred← citeshttps://doi.org/10.1002/anie.202421931openalex-snapshot
Atropisomerism in Triarylboranes: Lewis Base Assisted Rotation at C−B Stereogenic Axis in Asymmetrical Boron Lewis Acids
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