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Complexation Promoted Additions to N-Benzoyliminopyridinium Ylides. A Novel and Highly Regioselective Approach to Polysubstituted Piperidines

https://doi.org/10.1021/ja0348647
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Anionic Cyclizations of Chiral 2,3-Dihydro-4-pyridones: A Five-Step, Asymmetric Synthesis of Indolizidine 209D
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Diastereoselective Addition of Prochiral Metallo Enolates to Chiral 1-Acylpyridinium Salts
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Reaction of allylic tin reagents with nitrogen heteroaromatics activated by alkyl chloroformates: regioselective synthesis of .alpha.-allylated 1,2-dihydropyridines and change of the regioselectivity depending on methyl substituents at the allylic moiety
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New acetylenic alcohols from the sponge Cribrochalina vasculum
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Stereoselective synthesis of (.+-.)-cis-.alpha.-irone
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Correction. Reactions of Aryl Grignard Reagents with Pyridine 1-Oxide. The Structure of the Addition Products.
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Enediynes as Antitumor Compounds: Synthesis of Tetrahydropyridine Derivatives
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1-AMINOPYRIDINIUM IODIDE

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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N-(Benzoylimino)pyridinium Betaine (NAPBz)
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Synthesis of N ‐Acyl Pyridinium‐ N ‐Aminides and Their Conversion to 4‐Aminooxazoles via a Gold‐Catalyzed Formal (3+2)‐Dipolar Cycloaddition
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Grignard reagents
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Grignard Reagents
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Grignard Reagents
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Grignard reagents
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Grignard reagents
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Dearomatization Reactions of Electron‐Deficient Aromatic Rings
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Increasing the Reactivity of Amides towards Organometallic Reagents: An Overview
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N‐Imide Ylide‐Based Reactions: CH Functionalization, Nucleophilic Addition and Cycloaddition
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Efficient and Flexible Synthesis of Highly Functionalised 4‐Aminooxazoles by a Gold‐Catalysed Intermolecular Formal [3+2] Dipolar Cycloaddition
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[(5+1)−1] Cyclization of Nitroepoxides to Pyridinium 1,4‐Zwitterionic Thiolates for the Synthesis of Indolizine Derivatives
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Asymmetric Hydrogenation of Quinolines and Isoquinolines Activated by Chloroformates
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The Regio‐ and Stereoselective Synthesis of trans‐2,3‐Dihydropyridine N‐oxides and Piperidines
inferred← citeshttps://doi.org/10.1002/ange.200904981openalex-snapshot
Catalytic Enantioselective Addition of Dialkylzinc Reagents to N‐Acylpyridinium Salts
inferred← citeshttps://doi.org/10.1002/ange.201006017openalex-snapshot
Desaromatisierungsstrategien in der Synthese strukturell komplexer Naturstoffe
inferred← citeshttps://doi.org/10.1002/ange.201303994openalex-snapshot
Nickel‐Catalyzed Enantioselective Arylation of Pyridinium Ions: Harnessing an Iminium Ion Activation Mode
inferred← citeshttps://doi.org/10.1002/ange.202217328openalex-snapshot
Catalytic Access to Chiral δ‐Lactams via Nucleophilic Dearomatization of Pyridine Derivatives
inferred← citeshttps://doi.org/10.1002/ange.202406612openalex-snapshot
Regio‐ and Diastereoselective Synthesis of Polysubstituted Piperidines Enabled by Boronyl Radical‐Catalyzed (4+2) Cycloaddition
inferred← citeshttps://doi.org/10.1002/anie.200503073openalex-snapshot
Asymmetric Hydrogenation of Quinolines and Isoquinolines Activated by Chloroformates
inferred← citeshttps://doi.org/10.1002/anie.200900189openalex-snapshot
The Regio‐ and Stereoselective Synthesis of trans‐2,3‐Dihydropyridine N‐oxides and Piperidines
inferred← citeshttps://doi.org/10.1002/anie.200904981openalex-snapshot
Catalytic Enantioselective Addition of Dialkylzinc Reagents to N ‐Acylpyridinium Salts
inferred← citeshttps://doi.org/10.1002/anie.201006017openalex-snapshot
Dearomatization Strategies in the Synthesis of Complex Natural Products
inferred← citeshttps://doi.org/10.1002/anie.201303994openalex-snapshot
Nickel‐Catalyzed Enantioselective Arylation of Pyridinium Ions: Harnessing an Iminium Ion Activation Mode
inferred← citeshttps://doi.org/10.1002/anie.202217328openalex-snapshot
Catalytic Access to Chiral δ‐Lactams via Nucleophilic Dearomatization of Pyridine Derivatives
inferred← citeshttps://doi.org/10.1002/anie.202406612openalex-snapshot
Regio‐ and Diastereoselective Synthesis of Polysubstituted Piperidines Enabled by Boronyl Radical‐Catalyzed (4+2) Cycloaddition
inferred← citeshttps://doi.org/10.1002/chin.200338115openalex-snapshot
Complexation Promoted Additions to N‐Benzoyliminopyridinium Ylides. A Novel and Highly Regioselective Approach to Polysubstituted Piperidines.
inferred← citeshttps://doi.org/10.1002/slct.202102580openalex-snapshot
Gold‐Catalyzed Synthesis of Pyrazolo[1,5‐ a ]pyridines Regioselectively via 6‐ endo‐dig Cyclization
inferred← citeshttps://doi.org/10.1016/j.tet.2005.08.052openalex-snapshot
The first synthesis of pyridinium N-benzoylguanidines by bismuth- and mercury-promoted guanylation of N-iminopyridinium ylide with thioureas
inferred← citeshttps://doi.org/10.1016/j.tet.2010.10.041openalex-snapshot
l-Proline-catalyzed five-component domino reaction leading to multifunctionalized 1,2,3,4-tetrahydropyridines
inferred← citeshttps://doi.org/10.1016/j.tet.2016.02.037openalex-snapshot
Achievement of regioselectivity in transition metal-catalyzed direct C–H (hetero)arylation reactions of heteroarenes with one heteroatom through the use of removable protecting/blocking substituents or traceless directing groups
inferred← citeshttps://doi.org/10.1016/j.tet.2024.133891openalex-snapshot
Aminopyridinium ylides from pyrano[3,4-c]pyran-7-ium salts: Synthesis and structure
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Synthesis of 3,4-disubstituted piperidines by ene cyclisation of 4-aza-1,7-dienes
inferred← citeshttps://doi.org/10.1016/j.tetlet.2008.09.104openalex-snapshot
Selective synthesis of 2-substituted pyridine N-oxides via directed ortho-metallation using Grignard reagents
inferred← citeshttps://doi.org/10.1016/j.tetlet.2012.09.136openalex-snapshot
Synthesis of 7-trifluoromethylpyrazolo[1,5-a]pyridinedicarboxylate
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b00028openalex-snapshot
Rhodium(III)-Catalyzed Vinylic C–H Activation: A Direct Route toward Pyridinium Salts
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b00279openalex-snapshot
Redox Cycloisomerization Approach to 1,2-Dihydropyridines
inferred← citeshttps://doi.org/10.1021/acscatal.1c01544openalex-snapshot
Enantioselective Catalytic Dearomative Addition of Grignard Reagents to 4-Methoxypyridinium Ions
inferred← citeshttps://doi.org/10.1021/acscatal.4c03520openalex-snapshot
Grignard Reagent Addition to Pyridinium Salts: A Catalytic Approach to Chiral 1,4-Dihydropyridines
inferred← citeshttps://doi.org/10.1021/ar300185zopenalex-snapshot
Direct Functionalization Processes: A Journey from Palladium to Copper to Iron to Nickel to Metal-Free Coupling Reactions
inferred← citeshttps://doi.org/10.1021/cr200251dopenalex-snapshot
Synthesis of Pyridine and Dihydropyridine Derivatives by Regio- and Stereoselective Addition to N -Activated Pyridines
inferred← citeshttps://doi.org/10.1021/cr300176gopenalex-snapshot
Arylglyoxals in Synthesis of Heterocyclic Compounds
inferred← citeshttps://doi.org/10.1021/ja0525298openalex-snapshot
Catalytic Asymmetric Hydrogenation of N-Iminopyridinium Ylides: Expedient Approach to Enantioenriched Substituted Piperidine Derivatives
inferred← citeshttps://doi.org/10.1021/ja0734849openalex-snapshot
Enantioselective Addition of Activated Terminal Alkynes to 1-Acylpyridinium Salts Catalyzed by Cu−Bis(oxazoline) Complexes
inferred← citeshttps://doi.org/10.1021/ja111540gopenalex-snapshot
Rhodium-Catalyzed Enantioselective Addition of Boronic Acids to N -Benzylnicotinate Salts
inferred← citeshttps://doi.org/10.1021/ja2119833openalex-snapshot
Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade
inferred← citeshttps://doi.org/10.1021/ja401146vopenalex-snapshot
Transition-Metal-Free BF 3 -Mediated Regioselective Direct Alkylation and Arylation of Functionalized Pyridines Using Grignard or Organozinc Reagents
inferred← citeshttps://doi.org/10.1021/ja710073nopenalex-snapshot
Palladium-Catalyzed Direct C−H Arylation of N-Iminopyridinium Ylides: Application to the Synthesis of (±)-Anabasine
inferred← citeshttps://doi.org/10.1021/jacs.3c03048openalex-snapshot
Catalyst-Controlled Enantioselective and Regiodivergent Addition of Aryl Boron Nucleophiles to N-Alkyl Nicotinate Salts
inferred← citeshttps://doi.org/10.1021/jacsau.6c00022openalex-snapshot
N -Iminopyridinium Ylides as Chemically Stable Pharmacophores Enabling Targeted Degradation of SMARCA Proteins
inferred← citeshttps://doi.org/10.1021/jo034456lopenalex-snapshot
Highly Efficient Synthesis of O-(2,4-Dinitrophenyl)hydroxylamine. Application to the Synthesis of Substituted N-Benzoyliminopyridinium Ylides
inferred← citeshttps://doi.org/10.1021/jo0357418openalex-snapshot
Synthesis of 3-Substituted 4-Piperidinones via a One-Pot Tandem Oxidation−Cyclization−Oxidation Process: Stereodivergent Reduction to 3,4-Disubstituted Piperidines
inferred← citeshttps://doi.org/10.1021/jo052532+openalex-snapshot
Synthesis of 3,4-Disubstituted Piperidines by Carbonyl Ene and Prins Cyclizations: Switching between Kinetic and Thermodynamic Control with Brønsted and Lewis Acid Catalysts
inferred← citeshttps://doi.org/10.1021/jo060495wopenalex-snapshot
Synthesis of 2,4-Disubstituted Piperidines via Radical Cyclization: Unexpected Enhancement in Diastereoselectivity with Tris(trimethylsilyl)silane
inferred← citeshttps://doi.org/10.1021/jo201303xopenalex-snapshot
Synthesis of 2- and 2,3-Substituted Pyrazolo[1,5-a]pyridines: Scope and Mechanistic Considerations of a Domino Direct Alkynylation and Cyclization of N-Iminopyridinium Ylides Using Alkenyl Bromides, Alkenyl Iodides, and Alkynes
inferred← citeshttps://doi.org/10.1021/jo501746uopenalex-snapshot
Synthesis and Direct C2 Functionalization of Imidazolium and 1,2,4-Triazolium N-Imides
inferred← citeshttps://doi.org/10.1021/jo800800yopenalex-snapshot
Mechanistic Studies on the Catalytic Asymmetric Mannich-Type Reaction with Dihydroisoquinolines and Development of Oxidative Mannich-Type Reactions Starting from Tetrahydroisoquinolines
inferred← citeshttps://doi.org/10.1021/jo902527sopenalex-snapshot
Stereoselective Syntheses of l -Pipecolic Acid and (2S,3S)-3-Hydroxypipecolic Acid from a Chiral N-Imino-2-phenyl-1,2-dihydropyridine Intermediate
inferred← citeshttps://doi.org/10.1021/jp049958xopenalex-snapshot
Solid-State 17O NMR of Amino Acids
inferred← citeshttps://doi.org/10.1021/ol051022zopenalex-snapshot
Stereoselective Synthesis of 2,6-Disubstituted 3-Piperidinols: Application to the Expedient Synthesis of (+)-Julifloridine
inferred← citeshttps://doi.org/10.1021/ol061415dopenalex-snapshot
New Methodology Toward Chiral, Non-Racemic 2,5-cis-Substituted Piperidines via Suzuki Cross-Coupling
inferred← citeshttps://doi.org/10.1021/ol200478popenalex-snapshot
Intramolecular Hydride Addition to Pyridinium Salts: New Routes to Enantiopure Dihydropyridones
inferred← citeshttps://doi.org/10.1021/ol300541uopenalex-snapshot
Synthesis of Highly Oxidized Quinolizidine via Reduction of Acylpyridinium Cations, and Total Syntheses of Quinolizidines 207I and 1-epi-207I
inferred← citeshttps://doi.org/10.1021/ol303085qopenalex-snapshot
Enantioselective Synthesis of Substituted Piperidines by Addition of Aryl Grignard Reagents to Pyridine N-Oxides
inferred← citeshttps://doi.org/10.1021/ol702414eopenalex-snapshot
Cycloadditions of Aromatic Azomethine Imines with 1,1-Cyclopropane Diesters
inferred← citeshttps://doi.org/10.1021/ol800396vopenalex-snapshot
Palladium-Catalyzed Benzylic C−H Insertion of 2-Substituted N-Iminopyridinium Ylides
inferred← citeshttps://doi.org/10.1021/ol802383fopenalex-snapshot
Direct Transfer of the Sulfonylimino Group of Imino-λ3-Bromane to N-Heterocycles and Trialkylamines: Synthesis of N-Iminoammonium Ylides under Metal-Free Conditions
inferred← citeshttps://doi.org/10.1021/ol901264fopenalex-snapshot
Intramolecular Pyridine Activation−Dearomatization Reaction: Highly Stereoselective Synthesis of Polysubstituted Indolizidines and Quinolizidines
inferred← citeshttps://doi.org/10.1021/ol902619hopenalex-snapshot
Complete Regioselective Addition of Grignard Reagents to Pyrazine N-Oxides, Toward an Efficient Enantioselective Synthesis of Substituted Piperazines
inferred← citeshttps://doi.org/10.1021/ol902710fopenalex-snapshot
Synthesis of 2-Substituted Pyrazolo[1,5-a]pyridines through Cascade Direct Alkenylation/Cyclization Reactions
inferred← citeshttps://doi.org/10.1021/om060629wopenalex-snapshot
Donor-Stabilized Silyl Cations. 11. Bis-Zwitterionic Penta- and Hexacoordinate Silicon Dichelate Complexes Derived from (ClCH2)2SiCl2 through Double Internal Displacement of Chloride1
inferred← citeshttps://doi.org/10.1039/b506232bopenalex-snapshot
Structure and reactivity of a new anionic N-heterocyclic carbene silver(i) complex
inferred← citeshttps://doi.org/10.1039/b512139fopenalex-snapshot
Asymmetric hydrogenation of aromatic compounds
inferred← citeshttps://doi.org/10.1039/b708139aopenalex-snapshot
Stereoselective synthesis of 3,4-disubstituted and 3,4,5-trisubstituted piperidines by Lewis acid-catalysed ene cyclisation of 4-aza-1,7-dienes
inferred← citeshttps://doi.org/10.1039/c0ob00336kopenalex-snapshot
Reactions between Grignard reagents and heterocyclic N-oxides: Stereoselective synthesis of substituted pyridines, piperidines, and piperazines
inferred← citeshttps://doi.org/10.1039/c4cc02220copenalex-snapshot
Directed functionalization of 1,2-dihydropyridines: stereoselective synthesis of 2,6-disubstituted piperidines
inferred← citeshttps://doi.org/10.1039/c6sc00702copenalex-snapshot
Nickel-catalyzed enantioselective arylation of pyridine
inferred← citeshttps://doi.org/10.1039/d4sc03739aopenalex-snapshot
Unified ionic and radical C-4 alkylation and arylation of pyridines
inferred← citeshttps://doi.org/10.1039/d5tb00857copenalex-snapshot
Discovery of asymmetric pyridinium-based fluorescent probes with large Stokes shifts for live neural stem/progenitor cells
inferred← citeshttps://doi.org/10.1055/sos-sd-245-00201openalex-snapshot
5.1 Dearomatization of Activated Pyridines
inferred← citeshttps://doi.org/10.3987/com-08-s(n)93openalex-snapshot
Iridium Catalyzed Enantioselective Hydrogenation of N-Iminopyridinium Ylides: Mechanistic Insights
inferred← citeshttps://doi.org/10.3987/rev-12-sr(n)4openalex-snapshot
Asymmetric Reactions of a Series of Aromatic Azines with Nucleophiles
inferred← citeshttps://doi.org/10.6023/a25110372openalex-snapshot
Photocatalytic N-Radical-Mediated Addition/Cyclization Reaction of Vinylcyclopropanes for Tetrahydropyridine Synthesis ★
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