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Structure−Property Correlations in Polypropylene from Metallocene Catalysts: Stereodefective, Regioregular Isotactic Polypropylene

https://doi.org/10.1021/ja045684f
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Outgoing claims: the papers this work cites, builds on, or argues with.

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The influence of regio‐ and stereoirregularities on the crystallization behaviour of isotactic poly(propylene)s prepared with homogeneous group IVa metallocene/methylaluminoxane Ziegler‐Natta catalysts
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X‐ray analysis on unoriented and oriented samples of the quenched form of isotactic polypropylene
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Structure and properties of isotactic polypropylene
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Unperturbed dimensions of isotactic and atactic polypropylene at various temperatures
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Influence of stereoirregularities on the formation of the γ-phase in isotactic polypropene
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Selectivity in Propene Polymerization with Metallocene Catalysts
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Highly Regiospecific Zirconocene Catalysts for the Isospecific Polymerization of Propene
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Morphological Partitioning of Ethylene Defects in Random Propylene−Ethylene Copolymers
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The Oriented γ Form of Isotactic Polypropylene
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Crystallization of the α and γ Forms of Isotactic Polypropylene as a Tool To Test the Degree of Segregation of Defects in the Polymer Chains
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Crystallization of Metallocene-Made Isotactic Polypropylene: Disordered Modifications Intermediate between the α and γ Forms
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Stereoblock Polypropylene from a Metallocene Catalyst with a Hapto-Flexible Naphthyl−Indenyl Ligand
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Formation of the α and γ Polymorphs in Random Metallocene−Propylene Copolymers. Effect of Concentration and Type of Comonomer
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Comparison between Polymorphic Behaviors of Ziegler−Natta and Metallocene-Made Isotactic Polypropylene: The Role of the Distribution of Defects in the Polymer Chains
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On the γ-Phase of Isotactic Polypropylene
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Structural and Kinetic Factors Governing the Formation of the γ Polymorph of Isotactic Polypropylene
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Observation of Resonances Associated with Stereo and Regio Defects in the Crystalline Regions of Isotactic Polypropylene: Toward a Determination of Morphological Partitioning
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The Influence of Aromatic Substituents on the Polymerization Behavior of Bridged Zirconocene Catalysts
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rac-[Methylene(3-tert-butyl-1-indenyl)2]ZrCl2: A Simple, High-Performance Zirconocene Catalyst for Isotactic Polypropene
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Oscillating Stereocontrol: A Strategy for the Synthesis of Thermoplastic Elastomeric Polypropylene

What points at this work

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Structure and physical properties of syndiotactic polypropylene: A highly crystalline thermoplastic elastomer
inferred← citeshttps://doi.org/10.1016/j.progpolymsci.2020.101342openalex-snapshot
Polyolefin thermoplastic elastomers from polymerization catalysis: Advantages, pitfalls and future challenges
inferred← citeshttps://doi.org/10.1016/j.tca.2019.03.007openalex-snapshot
The influence of crystallization conditions on the macromolecular structure and strength of γ-polypropylene
inferred← citeshttps://doi.org/10.1016/s0167-2991(07)00002-xopenalex-snapshot
Chapter 2 Single-Center and Multi-Center Polymerization Catalysis
inferred← citeshttps://doi.org/10.1016/s0167-2991(07)00003-1openalex-snapshot
Chapter 3 Chemistry and Stereochemistry of Polymerization and Copolymerization Reactions with Transition Metal Catalysts
inferred← citeshttps://doi.org/10.1016/s0167-2991(07)00004-3openalex-snapshot
Chapter 4 Synthesis, Chemical Composition, and Structure of Transition Metal Components and Cocatalysts in Catalyst Systems for Alkene Polymerization
inferred← citeshttps://doi.org/10.1021/acs.chemrev.9b00757openalex-snapshot
Metal–Organic Framework-Based Catalysts with Single Metal Sites
inferred← citeshttps://doi.org/10.1021/acs.jpcc.9b06842openalex-snapshot
Thermally Stable Polypropylene Superhydrophobic Surface Due to the Formation of a Surface Crystalline Layer of Microsized Particles
inferred← citeshttps://doi.org/10.1021/acs.langmuir.1c02382openalex-snapshot
pH-Controlled Stereoregular Polymerization of Poly(methyl methacrylate) in Vesicle Membranes
inferred← citeshttps://doi.org/10.1021/acs.macromol.0c00842openalex-snapshot
Propylene–Butene Copolymers: Tailoring Mechanical Properties from Isotactic Polypropylene to Polybutene
inferred← citeshttps://doi.org/10.1021/acs.macromol.0c01771openalex-snapshot
A Systematic Study of the Temperature-Induced Performance Decline of ansa-Metallocenes for iPP
inferred← citeshttps://doi.org/10.1021/acs.macromol.1c01877openalex-snapshot
Crystallization of Propene–Pentene Isotactic Copolymers as an Indicator of the General View of the Crystallization Behavior of Isotactic Polypropylene
inferred← citeshttps://doi.org/10.1021/acs.macromol.2c02232openalex-snapshot
Crystallization Behavior and Properties of Propylene/4-Methyl-1-pentene Copolymers from a Metallocene Catalyst
inferred← citeshttps://doi.org/10.1021/acs.macromol.3c02353openalex-snapshot
Self-Nucleation in Stereodefective Isotactic Polypropylene: The Impact of Stereodefects on the Melt Memory
inferred← citeshttps://doi.org/10.1021/acs.macromol.4c01333openalex-snapshot
Impact of Chain Orientation on the Melting of the α-Form of Isotactic Polypropylene
inferred← citeshttps://doi.org/10.1021/acs.macromol.4c01402openalex-snapshot
Crystallization Kinetics of Crystalline–Crystalline and Crystalline–Amorphous Block Copolymers of Linear Polyethylene and Isotactic Polypropylene
inferred← citeshttps://doi.org/10.1021/acs.macromol.4c01627openalex-snapshot
Random and Block Copolymers of Isotactic Polypropylene with Higher α-Olefins: The Role of the Chain Topology on the Side-Chains Confined Crystallization
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c00636openalex-snapshot
Propylene–Ethylene Copolymers from Supported Metallocene Catalysts: A Route to Span Properties from Polypropylene to Polyethylene
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c01784openalex-snapshot
Stereochemical Structure-Controlled Crystallization and Physical Property in Stereoisomeric Polymers
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c02612openalex-snapshot
Oxidative Extrusion of Polypropylene Melts: Impact of Chain-End and In-Chain Functionalization on Thermal Properties, Crystal Structure, and Crystallization Kinetics
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c03102openalex-snapshot
Unexpected Ductility Enhancement in Crystalline–Crystalline Polyolefin Diblock Copolymers without Introducing Soft Segments
inferred← citeshttps://doi.org/10.1021/acs.macromol.5c03636openalex-snapshot
Melt Memory in Propene–Butene Isotactic Copolymers: The Case of Defects Hosted in the Crystals and of Isodimorphism in Olefin Copolymers
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b00045openalex-snapshot
Deformation of Stereoirregular Isotactic Polypropylene across Length Scales. Influence of Temperature
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b02345openalex-snapshot
Tuning Morphology and Melting Temperature in Polyethylene Films by MAPLE
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b00181openalex-snapshot
Catalyst Nuclearity Effects on Stereo- and Regioinduction in Pyridylamidohafnium-Catalyzed Propylene and 1-Octene Polymerizations
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b00362openalex-snapshot
Mechanical Properties and Morphology of Propene–Pentene Isotactic Copolymers
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b02600openalex-snapshot
Phase Transition from Tetragonal Form II to Hexagonal Form I of Butene-1/4-Methyl-1-pentene Random Copolymers: Molecular Factor versus Stretching Stimuli
inferred← citeshttps://doi.org/10.1021/acs.macromol.9b01570openalex-snapshot
Crystallization Behavior of Copolymers of Isotactic Poly(1-butene) with Ethylene from Ziegler–Natta Catalyst: Evidence of the Blocky Molecular Structure
inferred← citeshttps://doi.org/10.1021/acsapm.1c00742openalex-snapshot
Non-Negligible Effect of Additives in the Application of Successive Self-Nucleation and Annealing Fractionation for Microstructure Characterization of Matrix Resin in Additive-Containing Samples
inferred← citeshttps://doi.org/10.1021/acsapm.4c02161openalex-snapshot
Crystallization Behavior of Block Copolymers of Isotactic Polypropylene and Linear Low-Density Polyethylene
inferred← citeshttps://doi.org/10.1021/acscatal.1c00633openalex-snapshot
Optical Purity as a Programmable Variable for Controlling Polyolefin Tacticity in Living Coordinative Chain Transfer Polymerization: Application to the Stereomodulated LCCTP of α,ω-Nonconjugated Dienes
inferred← citeshttps://doi.org/10.1021/acscatal.5c00558openalex-snapshot
Monomer Discrimination in the Enantioselective Living Coordinative Chain Transfer Polymerization of α,ω-Nonconjugated Dienes vs α-Olefins
inferred← citeshttps://doi.org/10.1021/acsmacrolett.4c00066openalex-snapshot
Combining Cyclic Units and Unsaturated Pendant Groups by Propene/1,5-Hexadiene Copolymerization Toward Functional Isotactic Polypropylene
inferred← citeshttps://doi.org/10.1021/acsmacrolett.6c00423openalex-snapshot
Stereodefect Strategy Enables Thermally Resilient, Rapidly Crystallizable, High-Performance Aliphatic Polyester Thermoplastic Elastomers
inferred← citeshttps://doi.org/10.1021/acsomega.7b01269openalex-snapshot
Counits Content and Stretching Temperature-Dependent Critical Stress for Destruction of γ Crystals in Propylene–Ethylene Random Copolymers
inferred← citeshttps://doi.org/10.1021/ar040288nopenalex-snapshot
Crystals and Crystallinity in Polymeric Materials
inferred← citeshttps://doi.org/10.1021/cg800102fopenalex-snapshot
Stress-Induced Polymorphic Transformations and Mechanical Properties of Isotactic Propylene-Hexene Copolymers
inferred← citeshttps://doi.org/10.1021/cm071502fopenalex-snapshot
Tailoring the Physical Properties of Isotactic Polypropylene through Incorporation of Comonomers and the Precise Control of Stereo- and Regioregularity by Metallocene Catalysts
inferred← citeshttps://doi.org/10.1021/ja063464ropenalex-snapshot
Structural−Mechanical Phase Diagram of Isotactic Polypropylene
inferred← citeshttps://doi.org/10.1021/ja312463fopenalex-snapshot
Dinuclear Bis-Propagators for the Stereoselective Living Coordinative Chain Transfer Polymerization of Propene
inferred← citeshttps://doi.org/10.1021/jacs.0c08254openalex-snapshot
Mechanistic Insight into the Stereoselective Cationic Polymerization of Vinyl Ethers
inferred← citeshttps://doi.org/10.1021/ma051004xopenalex-snapshot
Crystallization Behavior and Mechanical Properties of Regiodefective, Highly Stereoregular Isotactic Polypropylene: Effect of Regiodefects versus Stereodefects and Influence of the Molecular Mass
inferred← citeshttps://doi.org/10.1021/ma0510845openalex-snapshot
Influence of Chain Microstructure on the Crystallization Kinetics of Metallocene-Made Isotactic Polypropylene
inferred← citeshttps://doi.org/10.1021/ma0606354openalex-snapshot
Crystal Structure of Isotactic Propylene−Hexene Copolymers: The Trigonal Form of Isotactic Polypropylene
inferred← citeshttps://doi.org/10.1021/ma0609127openalex-snapshot
Stretching Isotactic Polypropylene: From “cross-β” to Crosshatches, from γ Form to α Form
inferred← citeshttps://doi.org/10.1021/ma061749iopenalex-snapshot
Phase Diagram of Syndiotactic Polypropylene: Influence of Stereoregularity and Temperature on the Polymorphic Behavior
inferred← citeshttps://doi.org/10.1021/ma070060qopenalex-snapshot
Intrinsic Branching Effects in Syndiotactic Copolymers of Propylene and Higher α-Olefins
inferred← citeshttps://doi.org/10.1021/ma070377qopenalex-snapshot
Microstructural Analysis of Insoluble Polyolefins by Melt-State 13C NMR at Very High Temperatures
inferred← citeshttps://doi.org/10.1021/ma070409+openalex-snapshot
Crystallization Behavior of Isotactic Propylene−Ethylene and Propylene−Butene Copolymers: Effect of ComonomersversusStereodefects on Crystallization Properties of Isotactic Polypropylene
inferred← citeshttps://doi.org/10.1021/ma070771oopenalex-snapshot
Synthesis and Characterization of Dichlorotitanium Alkoxide Complex and Its Activity in the Polymerization of α-Olefins
inferred← citeshttps://doi.org/10.1021/ma071753+openalex-snapshot
The Double Role of Comonomers on the Crystallization Behavior of Isotactic Polypropylene: Propylene−Hexene Copolymers
inferred← citeshttps://doi.org/10.1021/ma101543dopenalex-snapshot
A New Mesophase of Isotactic Polypropylene in Copolymers of Propylene with Long Branched Comonomers
inferred← citeshttps://doi.org/10.1021/ma102007eopenalex-snapshot
Theoretical Investigation of Nano-Scale Organization in Blends of Semicrystalline/Semicrystalline Polymers by Small Angle X-ray Scattering
inferred← citeshttps://doi.org/10.1021/ma102134yopenalex-snapshot
Synthesis, Characterization, and Electrospinning of Architecturally-Discrete Isotactic−Atactic−Isotactic Triblock Stereoblock Polypropene Elastomers
inferred← citeshttps://doi.org/10.1021/ma102534fopenalex-snapshot
Crystallization Behavior of Propylene−Butene Copolymers: The Trigonal Form of Isotactic Polypropylene and Form I of Isotactic Poly(1-butene)
inferred← citeshttps://doi.org/10.1021/ma200231aopenalex-snapshot
Isotactic Polypropylene with (3,1) Chain-Walking Defects: Characterization, Crystallization, and Melting Behaviors
inferred← citeshttps://doi.org/10.1021/ma201420fopenalex-snapshot
Tailoring the Mechanical Properties of Isotactic Polypropylene by Blending Samples with Different Stereoregularity
inferred← citeshttps://doi.org/10.1021/ma2026513openalex-snapshot
Stretch-Induced Crystal–Crystal Transition of Polybutene-1: An in Situ Synchrotron Radiation Wide-Angle X-ray Scattering Study
inferred← citeshttps://doi.org/10.1021/ma400570kopenalex-snapshot
Morphology and Mechanical Properties of the Mesomorphic Form of Isotactic Polypropylene in Stereodefective Polypropylene
inferred← citeshttps://doi.org/10.1021/ma401032zopenalex-snapshot
Solid-State NMR Characterization of the Chemical Defects and Physical Disorders in α Form of Isotactic Poly(propylene) Synthesized by Ziegler–Natta Catalysts
inferred← citeshttps://doi.org/10.1021/ma402239kopenalex-snapshot
Mechanical Properties and Stress-Induced Phase Transformations of Metallocene Isotactic Poly(1-butene): The Influence of Stereodefects
inferred← citeshttps://doi.org/10.1021/ma5009868openalex-snapshot
A New ε Crystal Modification Found in Stereodefective Isotactic Polypropylene Samples
inferred← citeshttps://doi.org/10.1021/ma801229uopenalex-snapshot
Stress-Induced Phase Transitions in Syndiotactic Propene−Butene Copolymers
inferred← citeshttps://doi.org/10.1021/ma900760zopenalex-snapshot
A Direct Function Relationship between Isotacticity and Melting Temperature of Multiblock Stereocopolymer Poly(rac-lactide)
inferred← citeshttps://doi.org/10.1021/ma902626eopenalex-snapshot
Same Ligand, Different Metals: Diiodo−Salan Complexes of the Group 4 Triad in Isospecific Polymerization of 1-Hexene and Propylene
inferred← citeshttps://doi.org/10.1021/mz3000978openalex-snapshot
Oriented Gamma Phase in Isotactic Polypropylene Homopolymer
inferred← citeshttps://doi.org/10.1021/om300160vopenalex-snapshot
5-Methoxy-Substituted Zirconium Bis-indenyl ansa-Complexes: Synthesis, Structure, and Catalytic Activity in the Polymerization and Copolymerization of Alkenes
inferred← citeshttps://doi.org/10.1021/om301026eopenalex-snapshot
Achiral Cs-Symmetric Half-Sandwich Scandium(III) Complexes with Imine–Cyclopentadienyl Ligands Catalyze Isotactic Polymerization of 1-Hexene
inferred← citeshttps://doi.org/10.1021/om500992vopenalex-snapshot
Synthesis of Heterocyclic-Fused Cyclopentadienyl Scandium Complexes and the Catalysis for Copolymerization of Ethylene and Dicyclopentadiene
inferred← citeshttps://doi.org/10.1021/om900853qopenalex-snapshot
Titanium Complexes of Silicon-Bridged Cyclopentadienyl−Phenoxy Ligands Modified with Fused-Thiophene: Synthesis, Characterization, and Their Catalytic Performance in Copolymerization of Ethylene and 1-Hexene
inferred← citeshttps://doi.org/10.1038/s41428-019-0284-2openalex-snapshot
X-ray scattering study on the changes in the morphology of low-modulus polypropylene under cyclic uniaxial elongation
inferred← citeshttps://doi.org/10.1039/c0dt00637hopenalex-snapshot
Preparation of half-metallocenes of thiophene-fused and tetrahydroquinoline-linked cyclopentadienyl ligands for ethylene/α-olefin copolymerization
inferred← citeshttps://doi.org/10.1039/c1py00129aopenalex-snapshot
Single site metallorganic polymerization catalysis as a method to probe the properties of polyolefins
inferred← citeshttps://doi.org/10.1039/c2py20452eopenalex-snapshot
Study on the sequence length distribution of polypropylene by the successive self-nucleation and annealing (SSA) calorimetric technique
inferred← citeshttps://doi.org/10.1039/c4sc01686fopenalex-snapshot
Copolymerization of CO 2 and meso epoxides using enantioselective β-diiminate catalysts: a route to highly isotactic polycarbonates
inferred← citeshttps://doi.org/10.1039/c8cc06415fopenalex-snapshot
Controlled polymerizations using metal–organic frameworks
inferred← citeshttps://doi.org/10.1039/c8py00318aopenalex-snapshot
New effort to synthesize star isotactic polypropylene
inferred← citeshttps://doi.org/10.1039/c9ra04587bopenalex-snapshot
The structural diversity of heterocycle-fused potassium cyclopentadienides
inferred← citeshttps://doi.org/10.1039/d1ce01228bopenalex-snapshot
Toughening of polybutene-1 with form I′ induced by rapid pressurization
inferred← citeshttps://doi.org/10.1039/d2py00197gopenalex-snapshot
Structure and morphology of isotactic polypropylene–polyethylene block copolymers prepared with living and stereoselective catalyst
inferred← citeshttps://doi.org/10.1073/pnas.0603071103openalex-snapshot
Kinetic resolution of racemic α-olefins with ansa -zirconocene polymerization catalysts: Enantiomorphic site vs. chain end control
inferred← citeshttps://doi.org/10.1080/00222341003648904openalex-snapshot
Effect of Temperature and Comonomer Content on Thermal Behavior and Crystallization Property of the Propylene–Ethylene Random Copolymers
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