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Building Blocks for N-Type Molecular and Polymeric Electronics. Perfluoroalkyl- versus Alkyl-Functionalized Oligothiophenes (nTs; n = 2−6). Systematic Synthesis, Spectroscopy, Electrochemistry, and Solid-State Organization

https://doi.org/10.1021/ja048988a
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The Synthesis od Alpha-thiophene Oligomers by Oxidative Coupling of 2-Lithiothiophenes
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inferredcites →https://doi.org/10.3987/r-1987-07-1793openalex-snapshot
Preparation of a-Quater-, a-Sexi-, and a-Octithiophenes

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/chem.200901003openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/chem.201501811openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/chem.201504899openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/cphc.201100736openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/cphc.201402323openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ejoc.200700566openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ejoc.200700779openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ejoc.201001103openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ejoc.201100111openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ejoc.202200770openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ijch.201400010openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ijch.201400014openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/macp.200900180openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/pat.6220openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/pi.4765openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/polb.23167openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/pssa.200723407openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/128_2011_267openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/7081_2011_65openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/978-3-319-04346-3_6openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/978-3-662-45780-1_5openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/978-981-10-0724-8_5openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/s00214-008-0454-3openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/s10853-026-13597-9openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/b978-0-12-803479-8.00007-3openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.comptc.2012.11.005openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.comptc.2015.01.019openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.cplett.2006.12.106openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.cplett.2016.08.073openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.dyepig.2009.10.003openalex-snapshot
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inferred← citeshttps://doi.org/10.1016/j.jphotochem.2011.12.008openalex-snapshot
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Ambipolar field-effect transistor based on α,ω-dihexylquaterthiophene and α,ω-diperfluoroquaterthiophene vertical heterojunction
inferred← citeshttps://doi.org/10.1016/j.molstruc.2013.06.023openalex-snapshot
Structural, electronic and charge transfer studies of dianthra[2,3-b:2′,3′-f]thieno[3,2-b]thiophene and its analogues: Quantum chemical investigations
inferred← citeshttps://doi.org/10.1016/j.molstruc.2018.03.052openalex-snapshot
Theoretical investigation of the photophysical properties of donor-acceptor dyes containing coumarin and naphthoquinone moieties linked by an aminomethylene bridge
inferred← citeshttps://doi.org/10.1016/j.molstruc.2020.128019openalex-snapshot
Effect of fluorine on optoelectronic properties in DI-A-DII-A-DI type organic molecules: A combined experimental and DFT study
inferred← citeshttps://doi.org/10.1016/j.msec.2005.09.064openalex-snapshot
Oligo- and polymeric FET devices: Thiophene-based active materials and their interaction with different gate dielectrics
inferred← citeshttps://doi.org/10.1016/j.mtchem.2025.103149openalex-snapshot
Effect of functionalization on axially substituted 2,7-pyrene covalent triazine frameworks for dual sensing applications
inferred← citeshttps://doi.org/10.1016/j.orgel.2008.10.020openalex-snapshot
Thin-film transistors based on liquid-crystalline tetrafluorophenylter thiophene derivatives: thin-film structure and carrier transport
inferred← citeshttps://doi.org/10.1016/j.orgel.2009.04.018openalex-snapshot
Structurally tailored thiophene-based hybrid materials for thin-film and single-crystal transistors: Synthesis, photophysics and carrier-transport properties
inferred← citeshttps://doi.org/10.1016/j.orgel.2010.01.022openalex-snapshot
Functionalized dithieno[2,3-b:3′,2′-d]thiophenes (DTTs) for organic thin-film transistors
inferred← citeshttps://doi.org/10.1016/j.orgel.2010.07.014openalex-snapshot
Solution-processed n-type organic field-effect transistors based on electronegative oligothiophenes having fully oxo-substituted terthiophenes
inferred← citeshttps://doi.org/10.1016/j.orgel.2013.12.011openalex-snapshot
Theoretical studies on the hole transport property of tetrathienoarene derivatives: The influence of the position of sulfur atom, substituent and π-conjugated core
inferred← citeshttps://doi.org/10.1016/j.orgel.2014.02.018openalex-snapshot
Synthesis, characterization and semiconducting properties of oligo(2,6-naphthalene)s
inferred← citeshttps://doi.org/10.1016/j.orgel.2018.06.048openalex-snapshot
Benzothiadiazole, hexylthiophen and alkoxy benzene based solution processable copolymer: Effect of the electron withdrawing substituents (fluorine atoms) on electrochemical, optical and electrochromic properties
inferred← citeshttps://doi.org/10.1016/j.saa.2014.06.074openalex-snapshot
Synthesis, molecular structure and photoluminescence properties of 1,2-diphenyl-4-(3-methoxyphenyl)-1,3-cyclopentadiene
inferred← citeshttps://doi.org/10.1016/j.snb.2007.10.028openalex-snapshot
The effect of humidity on the electrical conductivity of mesoporous polythiophene
inferred← citeshttps://doi.org/10.1016/j.solmat.2012.07.005openalex-snapshot
Solution-processable oligothiophenes with solubilizing β-alkyl groups for organic photovoltaic cells
inferred← citeshttps://doi.org/10.1016/j.solmat.2014.11.037openalex-snapshot
Copolymerisation as a way to enhance the electrochromic properties of an alkylthiophene oligomer and a pyrrole derivative: copolymer of 3,3′″ dihexyl-2,2′:5′,2″:5″,2′″-quaterthiophene with (R)-(-)-3-(1-pyrrolyl)propyl-N-(3,5-dinitrobenzoyl)-α-phenylglycinate
inferred← citeshttps://doi.org/10.1016/j.susc.2017.11.014openalex-snapshot
Influence of molecular distortion on the exciton quenching for quaterthiophene-terminated self-assembled monolayers on Au(111)
inferred← citeshttps://doi.org/10.1016/j.synthmet.2005.10.009openalex-snapshot
Synthesis and properties of novel fluorinated ester substituted polythiophenes
inferred← citeshttps://doi.org/10.1016/j.synthmet.2007.04.016openalex-snapshot
Soluble terthiophene-labeled cruciform molecule as a semiconductor for organic field-effect transistor
inferred← citeshttps://doi.org/10.1016/j.synthmet.2009.03.018openalex-snapshot
Conformational analysis of the conducting copolymer poly(3,4-ethylenedioxythiophene-co-pyrrole)
inferred← citeshttps://doi.org/10.1016/j.synthmet.2009.04.022openalex-snapshot
Synthesis and characterization of a series of bis(dimethyl-n-octylsilyl)oligothiophenes for organic thin film transistor applications
inferred← citeshttps://doi.org/10.1016/j.synthmet.2009.09.011openalex-snapshot
Oliogothiophenes end-capped with arylacetylenes for organic thin film transistors
inferred← citeshttps://doi.org/10.1016/j.synthmet.2011.05.020openalex-snapshot
The effect of chain length on the dielectric and optical properties of oligothiophenes
inferred← citeshttps://doi.org/10.1016/j.synthmet.2014.10.003openalex-snapshot
Alkyl chain engineering in the hybrid bithiophene-3,4-ethylenedioxythiophene: Synthesis, electronic properties, and electropolymerization
inferred← citeshttps://doi.org/10.1016/j.synthmet.2016.05.010openalex-snapshot
Theoretical and experimental study of model oligothiophenes containing 1-methylene-2-(perfluorophenyl)hydrazine terminal unit
inferred← citeshttps://doi.org/10.1016/j.synthmet.2016.09.007openalex-snapshot
Studying saturation mobility, threshold voltage, and stability of PMMA-SiO2-TMSPM nano-hybrid as OFET gate dielectric
inferred← citeshttps://doi.org/10.1016/j.synthmet.2020.116347openalex-snapshot
Bilayer systems based on conjugated polymers for fluorescence development of latent fingerprints on stainless steel
inferred← citeshttps://doi.org/10.1016/j.tet.2006.11.029openalex-snapshot
Non-symmetrical oligothiophenes with ‘incompatible’ substituents
inferred← citeshttps://doi.org/10.1016/j.tet.2009.09.065openalex-snapshot
Synthesis and characterization of α,ω-disubstituted quaterthiophenes functionalized with polar groups for solution processed OTFTs
inferred← citeshttps://doi.org/10.1016/j.tet.2011.03.055openalex-snapshot
Novel 2,7-substituted pyrene derivatives: syntheses, solid-state structures, and properties
inferred← citeshttps://doi.org/10.1016/j.tet.2011.10.020openalex-snapshot
Quaterthiophene-based dimers containing an ethylene bridge: molecular design, synthesis, and optoelectronic properties
inferred← citeshttps://doi.org/10.1016/j.tet.2012.04.072openalex-snapshot
Bridged 3,3″′-didodecylquaterthiophene-based dimers: design, synthesis, and optoelectronic properties
inferred← citeshttps://doi.org/10.1016/j.tetlet.2006.11.165openalex-snapshot
Rapid synthesis and fluorous-phase purification of α-perfluorohexyloligothiophenes
inferred← citeshttps://doi.org/10.1016/j.tetlet.2008.11.061openalex-snapshot
Synthesis of thiophene–pyrrole mixed oligomers end-capped with hexyl group for field-effect transistors
inferred← citeshttps://doi.org/10.1016/j.tetlet.2009.01.126openalex-snapshot
Starburst substituted hexaazatriphenylene compounds: synthesis, photophysical and electrochemical properties
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.12.071openalex-snapshot
A new method of using supercritical carbon dioxide as a green solvent for synthesis and purification of 5,5‴-bis(tridecafluorohexyl)-2,2′:5′,2″:5″,2‴-quaterthiophene, which is one of n-type organic semiconducting materials
inferred← citeshttps://doi.org/10.1016/j.theochem.2005.10.009openalex-snapshot
Effect of substitution of electron-donating and -withdrawing groups on the stability of flavin–diaminepyridine complexes—a density functional theory study
inferred← citeshttps://doi.org/10.1016/j.theochem.2009.03.021openalex-snapshot
From linear quaterthiophene to sulflower: A comparative theoretical study
inferred← citeshttps://doi.org/10.1016/j.tsf.2007.02.081openalex-snapshot
Solid state properties of oligomers containing dithienothiophene or fluorene residues suitable for field effect transistor devices
inferred← citeshttps://doi.org/10.1016/j.tsf.2009.07.030openalex-snapshot
New semiconducting multi-branched conjugated molecules based on π-extended triphenylene and its application to organic field-effect transistor
inferred← citeshttps://doi.org/10.1016/j.tsf.2016.08.041openalex-snapshot
π-Conjugated donor-acceptor small molecule thin-films on gold electrodes for reducing the metal work-function
inferred← citeshttps://doi.org/10.1016/j.ultramic.2010.02.040openalex-snapshot
Patterning pentacene surfaces by local oxidation nanolithography
inferred← citeshttps://doi.org/10.1016/s1369-7021(07)70016-0openalex-snapshot
Organic single-crystal field-effect transistors
inferred← citeshttps://doi.org/10.1016/s1369-7021(07)70017-2openalex-snapshot
Semiconductors for organic transistors
inferred← citeshttps://doi.org/10.1021/acs.cgd.2c00783openalex-snapshot
Azulene End-Capped 1,3,4-Thiadiazole as an n-Type Organic Semiconductor with a Herringbone–Brickwork Cooperative 2D Layered Structure
inferred← citeshttps://doi.org/10.1021/acs.chemmater.4c00640openalex-snapshot
Design Rules to Optimize the Intermolecular and Long-Range Packing of Organic Semiconductor Crystals
inferred← citeshttps://doi.org/10.1021/acs.chemmater.9b01614openalex-snapshot
High Electron Mobility in [1]Benzothieno[3,2-b][1]benzothiophene-Based Field-Effect Transistors: Toward n-Type BTBTs
inferred← citeshttps://doi.org/10.1021/acs.chemrev.7b00084openalex-snapshot
Organic and Polymeric Semiconductors Enhanced by Noncovalent Conformational Locks
inferred← citeshttps://doi.org/10.1021/acs.jctc.6b00737openalex-snapshot
Intramolecular Singlet Fission in Quinoidal Bi- and Tetrathiophenes: A Comparative Study of Low-Lying Excited Electronic States and Potential Energy Surfaces
inferred← citeshttps://doi.org/10.1021/acs.joc.5b01626openalex-snapshot
Stereoselective Iterative Convergent Synthesis ofZ-Oligodiacetylenes from Propargylic Dithioacetals
inferred← citeshttps://doi.org/10.1021/acs.jpca.1c01569openalex-snapshot
Spontaneous Combustion of 2-Bromo-3-Methoxythiophene: A Study on Reaction Pathways and Energetics by Quantum Chemical Calculations
inferred← citeshttps://doi.org/10.1021/acs.jpca.7b09095openalex-snapshot
Photoinduced Electron Transfer in Naphthalene Diimide End-Capped Thiophene Oligomers
inferred← citeshttps://doi.org/10.1021/acs.jpcc.5b02105openalex-snapshot
Decay of the Exciton in Quaterthiophene-Terminated Alkanethiolate Self-Assembled Monolayers on Au(111)
inferred← citeshttps://doi.org/10.1021/acs.jpcc.5b07577openalex-snapshot
Coverage-Dependent Self-Assembly Regimes of Alkyl-Substituted Thiophene Oligomers on Au(111): Scanning Tunneling Microscopy and Spectroscopy
inferred← citeshttps://doi.org/10.1021/acs.jpcc.9b01801openalex-snapshot
Deviation from Point Dipole Analysis for Exciton Quenching in Quaterthiophene-Terminated Self-Assembled Monolayers on Au(111)
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b01169openalex-snapshot
Fluorinated Dithienylethene–Naphthalenediimide Copolymers for High-Mobility n-Channel Field-Effect Transistors
inferred← citeshttps://doi.org/10.1021/acs.macromol.7b01524openalex-snapshot
Modulation of Majority Charge Carrier from Hole to Electron by Incorporation of Cyano Groups in Diketopyrrolopyrrole-Based Polymers
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b00839openalex-snapshot
Tuning the Energy Levels of Aza-Heterocycle-Based Polymers for Long-Term n-Channel Bottom-Gate/Top-Contact Polymer Transistors
inferred← citeshttps://doi.org/10.1021/acs.macromol.8b01344openalex-snapshot
Monte Carlo Algorithm Based on Internal Bridging Moves for the Atomistic Simulation of Thiophene Oligomers and Polymers
inferred← citeshttps://doi.org/10.1021/acsaem.3c02371openalex-snapshot
Enhancing the Chemical Stability and Photovoltaic Properties of Highly Efficient Nonfullerene Acceptors by Chalcogen Substitution: Insights from Quantum Chemical Calculations
inferred← citeshttps://doi.org/10.1021/acsami.9b20544openalex-snapshot
Trifluoromethyl Group-Modified Non-Fullerene Acceptor toward Improved Power Conversion Efficiency over 13% in Polymer Solar Cells
inferred← citeshttps://doi.org/10.1021/am2000592openalex-snapshot
Photochemical Stabilization of Terthiophene and Its Utilization as a New Sensing Element in the Fabrication of Monolayer-Chemistry-Based Fluorescent Sensing Films
inferred← citeshttps://doi.org/10.1021/am301349gopenalex-snapshot
Long-Chain 3,4-Ethylenedioxythiophene/Thiophene Oligomers and Semiconducting Thin Films Prepared by Their Electropolymerization
inferred← citeshttps://doi.org/10.1021/am402066topenalex-snapshot
Hydrogen-Bonding-Facilitated Layer-by-Layer Growth of Ultrathin Organic Semiconducting Films
inferred← citeshttps://doi.org/10.1021/am4060468openalex-snapshot
Oligothiophene Semiconductors: Synthesis, Characterization, and Applications for Organic Devices
inferred← citeshttps://doi.org/10.1021/ar200006ropenalex-snapshot
n -Channel Semiconductor Materials Design for Organic Complementary Circuits
inferred← citeshttps://doi.org/10.1021/cg301151uopenalex-snapshot
Strengthening π–π Interactions While Suppressing Csp2–H···π (T-Shaped) Interactions via Perfluoroalkylation: A Crystallographic and Computational Study That Supports the Beneficial Formation of 1-D π–π Stacked Aromatic Materials
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