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Unveiling the “Booster Effect” of Fluorinated Alcohol Solvents: Aggregation-Induced Conformational Changes and Cooperatively Enhanced H-Bonding

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Role of Hexafluoro-2-propanol in Selective Oxidation of Sulfide to Sulfoxide: Efficient Preparation of Glycosyl Sulfoxides
inferredcites →https://doi.org/10.1002/1521-3749(200208)628:8<1821::aid-zaac1821>3.0.co;2-3openalex-snapshot
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inferredcites →https://doi.org/10.1002/1521-3773(20010518)40:10<1808::aid-anie1808>3.0.co;2-1openalex-snapshot
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inferredcites →https://doi.org/10.1021/ja00815a004openalex-snapshot
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inferredcites →https://doi.org/10.1021/ja00815a005openalex-snapshot
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inferredcites →https://doi.org/10.1021/ja01532a010openalex-snapshot
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inferredcites →https://doi.org/10.1021/ja028403hopenalex-snapshot
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inferredcites →https://doi.org/10.1021/ja0364524openalex-snapshot
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inferredcites →https://doi.org/10.1021/ja991829kopenalex-snapshot
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inferredcites →https://doi.org/10.1021/jo034087topenalex-snapshot
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inferredcites →https://doi.org/10.1021/jp012476qopenalex-snapshot
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inferredcites →https://doi.org/10.1021/jp0349334openalex-snapshot
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inferredcites →https://doi.org/10.1021/jp9928558openalex-snapshot
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inferredcites →https://doi.org/10.1063/1.474659openalex-snapshot
A new integral equation formalism for the polarizable continuum model: Theoretical background and applications to isotropic and anisotropic dielectrics

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/ange.202114048openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ange.202206681openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201206003openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201206566openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201409694openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201505167openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201510457openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201604321openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201612573openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201702511openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201702744openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201703757openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201705301openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201806847openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201809470openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201813881openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202010846openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202100115openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202114048openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202206681openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202208611openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202316037openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202318893openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202409388openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202416091openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202417889openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202425178openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202514539openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.202524449openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.3945602openalex-snapshot
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Revealing Structure–Function Relationships Involving Substituent Position for Isoquinoline Photobases
inferred← citeshttps://doi.org/10.1002/pola.24712openalex-snapshot
Main‐chain chiral poly(2‐oxazoline)s: Influence of alkyl side‐chain on secondary structure formation in solution
inferred← citeshttps://doi.org/10.1002/slct.201600027openalex-snapshot
Rhodamine‐Immobilised Electrospun Chitosan Nanofibrous Material as a Fluorescence Turn‐On Hg 2+ Sensor
inferred← citeshttps://doi.org/10.1002/slct.201700404openalex-snapshot
Synthesis and Characterization of First Row Metal Complexes Derived from a Pyridinophane Ligand Functionalized by Fluoroalcohol
inferred← citeshttps://doi.org/10.1002/smll.201805294openalex-snapshot
Recombinant Silk Fiber Properties Correlate to Prefibrillar Self‐Assembly
inferred← citeshttps://doi.org/10.1002/tcr.201500299openalex-snapshot
From QCA (Quantum Cellular Automata) to Organocatalytic Reactions with Stabilized Carbenium Ions
inferred← citeshttps://doi.org/10.1002/tcr.201900020openalex-snapshot
Fluorinated Alcohols: Magic Reaction Medium and Promoters for Organic Synthesis
inferred← citeshttps://doi.org/10.1002/zaac.201700050openalex-snapshot
In situ Crystallization Technique - an Approach to Circumvent Crystal Structures with high Z′-Crystallization Behavior of (CF3)2C-OH
inferred← citeshttps://doi.org/10.1007/128_2011_125openalex-snapshot
Boron-Doped Diamond Electrodes for Electroorganic Chemistry
inferred← citeshttps://doi.org/10.1007/2789_2008_080openalex-snapshot
Organocatalysis by Hydrogen Bonding Networks
inferred← citeshttps://doi.org/10.1007/978-3-642-02815-1_3openalex-snapshot
Noncovalent Organocatalysis Based on Hydrogen Bonding: Elucidation of Reaction Paths by Computational Methods
inferred← citeshttps://doi.org/10.1007/s00706-012-0883-5openalex-snapshot
Photophysics and hydrolytic stability of betalains in aqueous trifluoroethanol
inferred← citeshttps://doi.org/10.1007/s41981-020-00121-6openalex-snapshot
Electrosynthesis of 3,3′,5,5’-Tetramethyl-2,2′-biphenol in Flow
inferred← citeshttps://doi.org/10.1016/b978-0-12-820141-1.00004-2openalex-snapshot
Advances in peptide synthesis
inferred← citeshttps://doi.org/10.1016/b978-0-443-44921-5.00014-6openalex-snapshot
Recent advances in the condensed phase structure of the “magic solvent” hexafluoroisopropanol and its effects on chemical reactions
inferred← citeshttps://doi.org/10.1016/b978-008044992-0.00103-6openalex-snapshot
Oxiranes and Oxirenes: Monocyclic
inferred← citeshttps://doi.org/10.1016/j.actbio.2010.02.039openalex-snapshot
Synergistic effects of electrospun PLLA fiber dimension and pattern on neonatal mouse cerebellum C17.2 stem cells
inferred← citeshttps://doi.org/10.1016/j.bmc.2019.02.008openalex-snapshot
Catalyst-free cycloaddition of 1,3-diene-1-carbamates with azodicarboxylates: A rapid click reaction
inferred← citeshttps://doi.org/10.1016/j.cattod.2012.05.005openalex-snapshot
Evaluation of several catalytic systems for the epoxidation of methyl oleate using H2O2 as oxidant
inferred← citeshttps://doi.org/10.1016/j.chempr.2020.12.002openalex-snapshot
Electrochemical Aziridination of Internal Alkenes with Primary Amines
inferred← citeshttps://doi.org/10.1016/j.chempr.2022.08.017openalex-snapshot
Selective and quantitative functionalization of unprotected α-amino acids using a recyclable homogeneous catalyst
inferred← citeshttps://doi.org/10.1016/j.chroma.2019.01.030openalex-snapshot
Hexafluoroisopropanol/Brij-35 based supramolecular solvent for liquid-phase microextraction of parabens in different matrix samples
inferred← citeshttps://doi.org/10.1016/j.chroma.2025.466407openalex-snapshot
Liquid chromatography - high resolution mass spectrometry analysis of intact ribonucleic acid through hydrogen bonding of alkylamines
inferred← citeshttps://doi.org/10.1016/j.coelec.2026.101860openalex-snapshot
Electrochemical conversion of phenylpropanoids
inferred← citeshttps://doi.org/10.1016/j.colsurfa.2023.132781openalex-snapshot
Impact of 2,2,2-trifluoroethanol (TFE) on hydrophobicity enhancement in the aggregation of sodium N-dodecanoyl sarcosinate (SDDS) with nonionic hydroxyethyl cellulose
inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2016.07.013openalex-snapshot
Polyhydroxyurethane hydrogels: Synthesis and characterizations
inferred← citeshttps://doi.org/10.1016/j.gce.2023.12.003openalex-snapshot
Elucidating solvent effects on the stability of phenoxyl radicals in monohydric alcohols via electron paramagnetic resonance
inferred← citeshttps://doi.org/10.1016/j.jcou.2024.102739openalex-snapshot
Fast and sustainable CO2 conversion to propylene carbonate using fluoroalcohol-based bifunctional ionic liquids: Insights from experiments and theoretical simulations
inferred← citeshttps://doi.org/10.1016/j.jece.2022.107486openalex-snapshot
Electrochemically driven one-pot oxidative conversion of arylhydrazines into aromatic iodides
inferred← citeshttps://doi.org/10.1016/j.jelechem.2013.03.024openalex-snapshot
The electro-oxidation of water and alcohols at BDD in hexafluoroisopropanol
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2007.03.014openalex-snapshot
A crystalline H-bond cluster of hexafluoroisopropanol (HFIP) and piperidine
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2011.02.018openalex-snapshot
Synthesis and evaluation of fluorinated analogues of monoamine reuptake inhibitors
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2012.12.006openalex-snapshot
Straightforward synthesis of 2-propylquinolines under multicomponent conditions in fluorinated alcohols
inferred← citeshttps://doi.org/10.1016/j.jms.2020.111408openalex-snapshot
Hydrogen bonding interactions in the 1,1,1,3,3,3-hexafluoro-2-propanol∙∙∙1,4-dioxane complex: Rotational spectroscopy and density functional theory calculations
inferred← citeshttps://doi.org/10.1016/j.jms.2022.111687openalex-snapshot
Rotation-tunneling spectra and barriers of isotopologues of 2,2,2-trifluoroethanol and 2,2,3,3,3-pentafluoropropanol
inferred← citeshttps://doi.org/10.1016/j.jqsrt.2017.04.031openalex-snapshot
Conformational analysis and global warming potentials of 1,1,1,3,3,3-hexafluoro-2-propanol from absorption spectroscopy
inferred← citeshttps://doi.org/10.1016/j.mcat.2020.111244openalex-snapshot
Highly efficient transformation of ethylbenzene into acetophenone catalyzed by NHPI/Co(II) using molecular oxygen in hexafluoropropan-2-ol
inferred← citeshttps://doi.org/10.1016/j.mencom.2011.07.019openalex-snapshot
The Hosomi–Sakurai allylation in hexafluoroisopropanol: solvent promotion effect
inferred← citeshttps://doi.org/10.1016/j.molcata.2010.10.027openalex-snapshot
Epoxidation of cyclooctene and cyclohexene with hydrogen peroxide catalyzed by bis[3,5-bis(trifluoromethyl)-diphenyl] diselenide: Recyclable catalyst-containing phases through the use of glycerol-derived solvents
inferred← citeshttps://doi.org/10.1016/j.molcata.2012.06.015openalex-snapshot
Catalytic olefin epoxidation with a fluorinated organomolybdenum complex
inferred← citeshttps://doi.org/10.1016/j.molstruc.2007.11.062openalex-snapshot
Structure of hexafluoroisopropanol–water mixture studied by FTIR-ATR spectra and selected chemometric methods
inferred← citeshttps://doi.org/10.1016/j.molstruc.2020.128359openalex-snapshot
Conformational landscape and intricate conformational relaxation paths of 4,4,4-trifluoro-1-butanol: Rotational spectroscopy and quantum chemical calculations
inferred← citeshttps://doi.org/10.1016/j.polymer.2013.05.027openalex-snapshot
Polyfluorinated mercaptoalcohol as a H-bond modifier of poly(2,3,4,5,6-pentafluorostyrene) (PPFS) enhancing miscibility of hydroxylated-PPFS with various acceptor polymers
inferred← citeshttps://doi.org/10.1016/j.saa.2010.08.032openalex-snapshot
FTIR study of H-bonds cooperativity in complexes of 1,2-dihydroxybenzene with proton acceptors in aprotic solvents: Influence of the intramolecular hydrogen bond
inferred← citeshttps://doi.org/10.1016/j.talanta.2020.120839openalex-snapshot
Aqueous biphasic systems formed by hydrophilic and hydrophobic deep eutectic solvents for the partitioning of dyes
inferred← citeshttps://doi.org/10.1016/j.tet.2008.09.005openalex-snapshot
Synthesis of 2,3-unsaturated glycosides via metal-free Ferrier reaction
inferred← citeshttps://doi.org/10.1016/j.tet.2014.04.096openalex-snapshot
One-pot reactions of nitroenamines with anilines and ethyl glyoxylate
inferred← citeshttps://doi.org/10.1016/j.tet.2017.03.094openalex-snapshot
Iron-catalyzed selective oxidative arylation of phenols and biphenols
inferred← citeshttps://doi.org/10.1016/j.tet.2019.01.041openalex-snapshot
Mn(III)-promoted synthesis of spiroannular tricyclic scaffolds via sulfonylation/dearomatization of biaryl ynones
inferred← citeshttps://doi.org/10.1016/j.tet.2019.02.021openalex-snapshot
Oxidative phenol-arene and phenol-phenol cross-coupling using periodic acid
inferred← citeshttps://doi.org/10.1016/j.tet.2024.133943openalex-snapshot
HFIP-promoted synthesis of imidazo [1,2-a]pyridines containing CF3-substituted tertiary alcohols at room temperature
inferred← citeshttps://doi.org/10.1016/j.tet.2024.133948openalex-snapshot
HFIP promoted cyclization of o-hydroxyaryl enaminones with chlorohydrocarbon for synthesis of chromone-containing triarylmethanes
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.01.003openalex-snapshot
Rapid aerobic iodination of arenes mediated by hypervalent iodine in fluorinated solvents
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.04.004openalex-snapshot
Harnessing the catalytic behaviour of 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP): An expeditious synthesis of thioesters
inferred← citeshttps://doi.org/10.1016/j.tgchem.2025.100071openalex-snapshot
Research progress of homogeneous catalytic reactions of hexafluoroisopropanol (HFIP)
inferred← citeshttps://doi.org/10.1016/j.trechm.2025.04.001openalex-snapshot
The rise and future of hexafluoroisopropanol as a solvent
inferred← citeshttps://doi.org/10.1016/j.vibspec.2008.01.016openalex-snapshot
Molecular and electronic structures, infrared spectra, and vibrational assignment for ap and sc conformers of hexafluoro-iso-propanol
inferred← citeshttps://doi.org/10.1016/s0066-4103(08)00002-1openalex-snapshot
Chapter 2 NOE Studies of Solvent–Solute Interactions
inferred← citeshttps://doi.org/10.1021/ac200755copenalex-snapshot
Pyrene-Modified Quartz Crystal Microbalance for the Detection of Polynitroaromatic Compounds
inferred← citeshttps://doi.org/10.1021/acs.chemrev.1c00749openalex-snapshot
HFIP in Organic Synthesis
inferred← citeshttps://doi.org/10.1021/acs.chemrev.5c01044openalex-snapshot
Transition Metal-Catalyzed Direct C(sp 3 )–H Functionalization Reactions of Aliphatic Carboxylic Acids
inferred← citeshttps://doi.org/10.1021/acs.iecr.2c02927openalex-snapshot
Activation of a Palladium-Based Catalyst by Hexafluoroisopropanol for Polyketone Synthesis via Homogeneous Solution Polymerization
inferred← citeshttps://doi.org/10.1021/acs.joc.0c00087openalex-snapshot
Visible-Light-Mediated [2+2+1] Carbocyclization Reactions of 1,7-Enynes with Bromofluoroacetate to Form Fused Monofluorinated Cyclopenta[c]quinolin-4-ones
inferred← citeshttps://doi.org/10.1021/acs.joc.0c00218openalex-snapshot
Oxidation of Electron-Rich Arenes Using HFIP-UHP System
inferred← citeshttps://doi.org/10.1021/acs.joc.0c01579openalex-snapshot
Direct Synthesis of N,N-Disubstituted Formamides by Oxidation of Imines Using an HFIP/UHP System
inferred← citeshttps://doi.org/10.1021/acs.joc.1c01928openalex-snapshot
Sensitivity of Isomerization Kinetics of 1,3,5-Triphenylformazan on Cosolvents Added to Toluene
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02197openalex-snapshot
Selective Acid-Catalyzed Hydroarylation of Nonactivated Alkenes with Aniline Assisted by Hexafluoroisopropanol
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02361openalex-snapshot
Studies on the Origin of the Stabilizing Effects of Fluorinated Alcohols and Weakly Coordinated Fluorine-Containing Anions on Cationic Reaction Intermediates
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02621openalex-snapshot
Leveraging the Domino Skeletal Expansion of Thia-/Selenazolidinones via Nitrogen-Atom Transfer in Hexafluoroisopropanol: Room Temperature Access to Six-Membered S/Se,N-Heterocycles
inferred← citeshttps://doi.org/10.1021/acs.joc.2c01180openalex-snapshot
Reactivity and Product Selectivity of Fluoroalkyl Carbonates in Substitution Reactions with Primary Alcohols and Amines
inferred← citeshttps://doi.org/10.1021/acs.joc.3c00911openalex-snapshot
Stereoselective Synthesis ofZ-Styryl Sulfides from Nucleophilic Addition of Arylacetylenes and Benzyl Thiols
inferred← citeshttps://doi.org/10.1021/acs.joc.3c01472openalex-snapshot
Metal-Free Selective Ortho-C–H Amidation of Hypervalent(III) Iodobezenes with N-Methoxy Amides under Mild Conditions
inferred← citeshttps://doi.org/10.1021/acs.joc.3c02331openalex-snapshot
Brønsted Acid-Catalyzed Dehydrative Nazarov-type Cyclization of CF3-Substituted 3-Indolylallyl Alcohols: Divergent Synthesis of 1-Trifluoromethylated Cyclopenta[b]indoles
inferred← citeshttps://doi.org/10.1021/acs.joc.3c02481openalex-snapshot
Total Synthesis of Alanense A through an Intramolecular Friedel–Crafts Alkylation
inferred← citeshttps://doi.org/10.1021/acs.joc.4c00205openalex-snapshot
Desulfurative Functionalization of β-Acyl Allylic Sulfides with N–H Free Indoles Highly Regioselective at C3 and N1 Positions: Rapid Access to α-Branched Enones
inferred← citeshttps://doi.org/10.1021/acs.joc.5b01756openalex-snapshot
Benefits of a Dual Chemical and Physical Activation: Direct aza-Michael Addition of Anilines Promoted by Solvent Effect under High Pressure
inferred← citeshttps://doi.org/10.1021/acs.joc.5c00137openalex-snapshot
Electrophilic (Hetero)Arene C–H Nitration by Ferric Nitrate Nonahydrate in Hexafluoroisopropanol
inferred← citeshttps://doi.org/10.1021/acs.joc.5c00326openalex-snapshot
HFIP-Promoted Friedel–Crafts Allenylation of Imidazopyridines with Propargyl Alcohols at Room Temperature
inferred← citeshttps://doi.org/10.1021/acs.joc.5c01455openalex-snapshot
Leveraging Environmental Control for Regiodivergent Epoxide Ring-Openings
inferred← citeshttps://doi.org/10.1021/acs.joc.6c00762openalex-snapshot
Iron-Catalyzed Friedel–Crafts Reactions of Unactivated 3-Aryl-Oxetanols Exploiting HFIP Stabilization of Carbocations
inferred← citeshttps://doi.org/10.1021/acs.joc.6c00788openalex-snapshot
How Hexafluoroisopropanol Catalyzes the Michael Addition of Anilines to Maleimides: Mechanistic Insights from Density Functional Theory and Classical Force-Field Molecular Dynamics
inferred← citeshttps://doi.org/10.1021/acs.joc.7b02920openalex-snapshot
Regioselective Halogenation of Arenes and Heterocycles in Hexafluoroisopropanol
inferred← citeshttps://doi.org/10.1021/acs.joc.8b01392openalex-snapshot
Tuning the Reactivity of Peroxo Anhydrides for Aromatic C–H Bond Oxidation
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02361openalex-snapshot
Bisulfate Salt-Catalyzed Friedel–Crafts Benzylation of Arenes with Benzylic Alcohols
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