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A Coordination Network That Catalyzes O2-Based Oxidations

https://doi.org/10.1021/ja069319v
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High Turnover Numbers for the Catalytic Selective Epoxidation of Alkenes with 1 atm of Molecular Oxygen We acknowledge T. Hayashi (The University of Tokyo), M. Wada (Nippon Shokubai Co., Ltd.), and Y. Sumita (Nippon Shokubai Co., Ltd.) for their help with experiments. This work was supported in…
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Cleavage of the Calkyl−Caryl Bond of [Pd−CH2CMe2Ph] Complexes This work was supported by the Dirección General de Enseñanza Superior e Investigación Científica (Project 1FD97-0919), the Ministerio de Educación y Ciencia (PFPI grant to D. del Rio), and the Junta de Andalucia. J. A. L. thanks the…
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Dresdner Chemische Gesellschaft
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Metal–Organic Frameworks with Tb 4 Clusters as Nodes: Luminescent Detection of Chromium(VI) and Chemical Fixation of CO 2
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b00366openalex-snapshot
Controllable Synthesis of Lindqvist Alkoxopolyoxovanadate Clusters as Heterogeneous Catalysts for Sulfoxidation of Sulfides
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.8b01528openalex-snapshot
Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster
inferred← citeshttps://doi.org/10.1021/acs.joc.7b01020openalex-snapshot
Regioselective Synthesis of 2-Vinylanilines Using O-aroyloxycarba-mates by Sequential Decarboxylation/Amination/Heck Reaction
inferred← citeshttps://doi.org/10.1021/acsami.0c09666openalex-snapshot
Sub-nanoscaled Metal Oxide Cluster-Integrated Polymer Network for Quasi-Homogeneous Catalysis
inferred← citeshttps://doi.org/10.1021/acsbiomaterials.3c00986openalex-snapshot
Effective Enrichment of Phosphopeptides Using Magnetic Polyoxometalate-Based Metal–Organic Frameworks
inferred← citeshttps://doi.org/10.1021/acscatal.6b01935openalex-snapshot
Lanthanide-Based Metal Organic Frameworks: Synthetic Strategies and Catalytic Applications
inferred← citeshttps://doi.org/10.1021/am900135gopenalex-snapshot
Interfacial Self-Assembly of Metal-Mediated Viologen-Like Coordination Polyelectrolyte Hybrids of the Bisterpyridine Ligand and Their Optical, Electrochemical, and Electrochromic Properties
inferred← citeshttps://doi.org/10.1021/cg100783wopenalex-snapshot
Polyoxometalate-Based Porous Framework with Perovskite Topology
inferred← citeshttps://doi.org/10.1021/cg101351bopenalex-snapshot
Construction of Coordination Polymers with a Bifurcating Ligand: Synthesis, Structure, Photoluminescence, and Magnetic Studies
inferred← citeshttps://doi.org/10.1021/cg101432kopenalex-snapshot
Coordination Polymers of Lanthanide(III): Toward Encapsulation of Well-Defined Assembly of Guest Molecules
inferred← citeshttps://doi.org/10.1021/cg201030uopenalex-snapshot
Solid Phase Morphological Diversity of a Rare Vanadium Cubane (V4O16) Based Metal Organic Framework
inferred← citeshttps://doi.org/10.1021/cg2013396openalex-snapshot
Significant Surface Modification of Polyoxometalate by Smart Silver-tetrazolate Units
inferred← citeshttps://doi.org/10.1021/cg300988aopenalex-snapshot
Coordination Polymers of Copper and Zinc Ions with a Linear Linker Having Imidazole at Each End and an Azo Moiety in the Middle: Pedal Motion, Gas Adsorption, and Emission Studies
inferred← citeshttps://doi.org/10.1021/cg301476popenalex-snapshot
pH-Dependent Interpenetrated, Polymorphic, Cd 2+ - and BTB-based Porous Coordination Polymers with Open Metal Sites
inferred← citeshttps://doi.org/10.1021/cg401935zopenalex-snapshot
Crystal Structures and Properties of Cd(II) Coordination Polymers Supported by a New Chiral Aromatic Polycarboxylate Ligand
inferred← citeshttps://doi.org/10.1021/cg8007393openalex-snapshot
Synthesis, X-ray Structures, and Fluorescent Properties of Coordination Networks Constructed from 2-(2-Pyridinyl-benzimidazolyl) Acetic Anion
inferred← citeshttps://doi.org/10.1021/cg9002516openalex-snapshot
Synthetic, Structural, Spectroscopic, Electrochemical Studies and Self-assembly of Nanoscale Polyoxometalate−Organic Hybrid Molecular Dumbbells
inferred← citeshttps://doi.org/10.1021/cg900520jopenalex-snapshot
Anion-Induced Assembly of Different Mercury Coordination Complexes and DFT Calculations To Evaluate Weak Interactions between Similar Double-Helical Chains
inferred← citeshttps://doi.org/10.1021/cg901453aopenalex-snapshot
Anion-Induced Assembly of Five-Coordinated Mercury(II) Complexes and Density Functional Theory Calculations to Study Bond Dissociation Energies of Long Hg−N Bonds
inferred← citeshttps://doi.org/10.1021/cm100503qopenalex-snapshot
A Family of Highly Stable Lanthanide Metal−Organic Frameworks: Structural Evolution and Catalytic Activity
inferred← citeshttps://doi.org/10.1021/cr1000578openalex-snapshot
Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications
inferred← citeshttps://doi.org/10.1021/cr500390vopenalex-snapshot
Recent Advances in Polyoxometalate-Catalyzed Reactions
inferred← citeshttps://doi.org/10.1021/cr800406uopenalex-snapshot
Self-Supported Catalysts
inferred← citeshttps://doi.org/10.1021/cr9003924openalex-snapshot
Engineering Metal Organic Frameworks for Heterogeneous Catalysis
inferred← citeshttps://doi.org/10.1021/ic1001495openalex-snapshot
Reaction Controlled Assemblies of Polyoxotungstates (-molybdates) and Coordination Polymers
inferred← citeshttps://doi.org/10.1021/ic102305vopenalex-snapshot
A Dynamic Open Framework Exhibiting Guest- and/or Temperature-Induced Bicycle-Pedal Motion in Single-Crystal to Single-Crystal Transformation
inferred← citeshttps://doi.org/10.1021/ic201298dopenalex-snapshot
New Hybrid Layered Molybdates Based on 2/∞[MonO3n+1]2– Units (n = 7, 9) with Systematic Organic–Inorganic Interfaces
inferred← citeshttps://doi.org/10.1021/ic202299dopenalex-snapshot
Tuning the Photochromic Properties of Molybdenum Bisphosphonate Polyoxometalates
inferred← citeshttps://doi.org/10.1021/ic202349uopenalex-snapshot
Sensitization of Lanthanoid Luminescence by Organic and Inorganic Ligands in Lanthanoid-Organic-Polyoxometalates
inferred← citeshttps://doi.org/10.1021/ic4005278openalex-snapshot
Organoimido-Derivatized Hexamolybdates with a Remote Carboxyl Group: Syntheses and Structural Characterizations
inferred← citeshttps://doi.org/10.1021/ic400598xopenalex-snapshot
Porous and Robust Lanthanide Metal-Organoboron Frameworks as Water Tolerant Lewis Acid Catalysts
inferred← citeshttps://doi.org/10.1021/ic502447bopenalex-snapshot
Four Alkoxohexavanadate-Based Pd-Polyoxovanadates as Robust Heterogeneous Catalysts for Oxidation of Benzyl-Alkanes
inferred← citeshttps://doi.org/10.1021/ic502730yopenalex-snapshot
Two Distinct Redox Intercalation Reactions of Hydroquinone with Porous Vanadium Benzenedicarboxylate MIL-47
inferred← citeshttps://doi.org/10.1021/ic900985wopenalex-snapshot
From 0D dimer to 2D Network—Supramolecular Assembly of Organic Derivatized Polyoxometalates with Remote Hydroxyl via Hydrogen Bonding
inferred← citeshttps://doi.org/10.1021/ic902241nopenalex-snapshot
Unique (3,12)-Connected Porous Lanthanide−Organic Frameworks Based on Ln4O4 Clusters: Synthesis, Crystal Structures, Luminescence, and Magnetism
inferred← citeshttps://doi.org/10.1021/ja201165copenalex-snapshot
Polyoxometalate-Based Metal Organic Frameworks (POMOFs): Structural Trends, Energetics, and High Electrocatalytic Efficiency for Hydrogen Evolution Reaction
inferred← citeshttps://doi.org/10.1021/ja203695hopenalex-snapshot
A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination
inferred← citeshttps://doi.org/10.1021/ja408228bopenalex-snapshot
Bottom-Up Construction of POM-Based Macrostructures: Coordination Assembled Paddle-Wheel Macroclusters and Their Vesicle-like Supramolecular Aggregation in Solution
inferred← citeshttps://doi.org/10.1021/ja905009eopenalex-snapshot
Zeolitic Polyoxometalate-Based Metal−Organic Frameworks (Z-POMOFs): Computational Evaluation of Hypothetical Polymorphs and the Successful Targeted Synthesis of the Redox-Active Z-POMOF1
inferred← citeshttps://doi.org/10.1021/jacs.6b00972openalex-snapshot
Hierarchical Self-Assembly of Polyoxometalate-Based Hybrids Driven by Metal Coordination and Electrostatic Interactions: From Discrete Supramolecular Species to Dense Monodisperse Nanoparticles
inferred← citeshttps://doi.org/10.1021/jacs.8b07577openalex-snapshot
Temperature-Stable Compelled Composite Superhydrophobic Porous Coordination Polymers Achieved via an Unattainable de Novo Synthetic Method
inferred← citeshttps://doi.org/10.1021/jp2010937openalex-snapshot
Structural Study of D2 within the Trimodal Pore System of a Metal Organic Framework
inferred← citeshttps://doi.org/10.1021/nl4002475openalex-snapshot
Binary Superlattices from Colloidal Nanocrystals and Giant Polyoxometalate Clusters
inferred← citeshttps://doi.org/10.1038/s41596-025-01212-1openalex-snapshot
Modular assembly of polyoxometalate clusters at the sub-1 nm scale
inferred← citeshttps://doi.org/10.1038/s41598-017-12633-8openalex-snapshot
Tosylation of alcohols: an effective strategy for the functional group transformation of organic derivatives of polyoxometalates
inferred← citeshttps://doi.org/10.1039/b719766gopenalex-snapshot
Design, synthesis and characterization of a Pt–Gd metal–organic framework containing potentially catalytically active sites
inferred← citeshttps://doi.org/10.1039/b802583popenalex-snapshot
Polymerization reactions in porous coordination polymers
inferred← citeshttps://doi.org/10.1039/b807080fopenalex-snapshot
Metal–organic framework materials as catalysts
inferred← citeshttps://doi.org/10.1039/b808180hopenalex-snapshot
Unprecedented NaI–CuII–LnIII heterometallic coordination polymers based on 3,5-pyrazoledicarboxylate with both infinite cationic and anionic chains
inferred← citeshttps://doi.org/10.1039/b816205kopenalex-snapshot
Novel dense organic–lanthanide hybrid architectures: syntheses, structures and magnetic properties
inferred← citeshttps://doi.org/10.1039/b821750eopenalex-snapshot
Synthesis and crystal structure of pseudo-sandwich-type heteropolytungstates functionalized by organometallic ruthenium(ii)
inferred← citeshttps://doi.org/10.1039/b822104aopenalex-snapshot
Metal–organic gels as functionalisable supports for catalysis
inferred← citeshttps://doi.org/10.1039/b906313gopenalex-snapshot
Steric hindrance-dependent rational design and synthesis of three new Keggin-based supramolecular networks
inferred← citeshttps://doi.org/10.1039/b911606kopenalex-snapshot
pH-dependent assembly of 0D to 3D Keggin-based coordination polymers: Structures and catalytic properties
inferred← citeshttps://doi.org/10.1039/b916462fopenalex-snapshot
The first polyoxometalate-templated four-fold interpenetrated coordination polymer with new topology and ferroelectricity
inferred← citeshttps://doi.org/10.1039/b919503copenalex-snapshot
Hydrothermal syntheses and characterizations of two novel frameworks constructed from polyoxometalates, metals and organic units
inferred← citeshttps://doi.org/10.1039/b919819aopenalex-snapshot
Recent advances in crystal engineering
inferred← citeshttps://doi.org/10.1039/b925822aopenalex-snapshot
New tetra(organotin)-decorated boat-like polyoxometalate
inferred← citeshttps://doi.org/10.1039/c004214eopenalex-snapshot
Fluorescent octahedron and rounded-octahedron coordination polymer particles (CPPs)
inferred← citeshttps://doi.org/10.1039/c004543hopenalex-snapshot
Honeycomb nanoscale-porous material constructed from copper complexes and mixed-addenda Lindqvist-type polyoxoanions
inferred← citeshttps://doi.org/10.1039/c0ce00216jopenalex-snapshot
Mechanochemical synthesis of homo- and hetero-rare-earth(iii) metal–organic frameworks by ball milling
inferred← citeshttps://doi.org/10.1039/c0ce00727gopenalex-snapshot
New extended poly(oxomolybdophosphates) based on strontium(ii) linkers
inferred← citeshttps://doi.org/10.1039/c0ce00761gopenalex-snapshot
Polyoxometalate charge directed coordination assemblies: Macrocycles and polymer chains
inferred← citeshttps://doi.org/10.1039/c0dt00325eopenalex-snapshot
Cations in control: crystal engineering polyoxometalate clusters using cation directed self-assembly
inferred← citeshttps://doi.org/10.1039/c0dt00426jopenalex-snapshot
Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na4(H2O)14}{Cu(gly)}2][TeMo6O24] and [{Cu(en)2}3{TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines
inferred← citeshttps://doi.org/10.1039/c0nj00275eopenalex-snapshot
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
inferred← citeshttps://doi.org/10.1039/c0nj00421aopenalex-snapshot
Synthesis, structural characterisation and bonding in an anionic hexavanadate bearing redox-active ferrocenyl groups at the periphery
inferred← citeshttps://doi.org/10.1039/c1cc10650copenalex-snapshot
DMAP-catalyzed esterification of pentaerythritol-derivatized POMs: a new route for the functionalization of polyoxometalates
inferred← citeshttps://doi.org/10.1039/c1ce05698kopenalex-snapshot
Lanthanide-pyridyl-2,5-dicarboxylate N-oxide frameworks with rutile topology
inferred← citeshttps://doi.org/10.1039/c1ce06015eopenalex-snapshot
In situ syntheses, crystal structures and magnetic properties of Cu II and Mn II coordination assemblies based on a novel heteroalicyclic dicarboxylate tecton and N-donor co-ligands
inferred← citeshttps://doi.org/10.1039/c1dt10168dopenalex-snapshot
Monosubstituted arylimido hexamolybdates containing pendant amino groups: synthesis and structural characterization
inferred← citeshttps://doi.org/10.1039/c1dt10241aopenalex-snapshot
Erbium-formate frameworks templated by diammonium cations: syntheses, structures, structural transition and magnetic properties
inferred← citeshttps://doi.org/10.1039/c1dt10866bopenalex-snapshot
The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres
inferred← citeshttps://doi.org/10.1039/c1jm10947bopenalex-snapshot
Effect of Keggin polyoxometalate on Cu(ii) speciation and its role in the assembly of Cu3(BTC)2 metal–organic framework
inferred← citeshttps://doi.org/10.1039/c1nj20736aopenalex-snapshot
Catalytic performance of lanthanide molecular solids containing well-modified metal–organic octahedra
inferred← citeshttps://doi.org/10.1039/c2cc31667fopenalex-snapshot
Functionalized polyoxometalates with covalently linked bisphosphonate, N-donor or carboxylate ligands: from electrocatalytic to optical properties
inferred← citeshttps://doi.org/10.1039/c2ce06151aopenalex-snapshot
A series of lanthanide–organic polymers incorporating ethyl-4,5-imidazole-dicarboxylato and formate coligand: structures, luminescent and magnetic properties
inferred← citeshttps://doi.org/10.1039/c2ce06481bopenalex-snapshot
Self assembly of a tren-derivative hydrogenated Schiff base with transition metal ions: syntheses, crystal structures and photoluminescent properties
inferred← citeshttps://doi.org/10.1039/c2cs35119fopenalex-snapshot
Functionalization and post-functionalization: a step towards polyoxometalate-based materials
inferred← citeshttps://doi.org/10.1039/c2cs35190kopenalex-snapshot
Engineering polyoxometalates with emergent properties
inferred← citeshttps://doi.org/10.1039/c2dt11153eopenalex-snapshot
Self-assembly of hybrid organic–inorganic polyoxovanadates: functionalised mixed-valent clusters and molecular cages
inferred← citeshttps://doi.org/10.1039/c2dt30393kopenalex-snapshot
Influence of pH and organic ligands on the supramolecular network based on molybdenum phosphate/strontium chemistry
inferred← citeshttps://doi.org/10.1039/c2dt30481copenalex-snapshot
Synthesis of diamondoid lanthanide–polyoxometalate solids as tunable photoluminescent materials
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