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Highly Enantioselective Insertion of Carbenoids into N−H Bonds Catalyzed by Copper Complexes of Chiral Spiro Bisoxazolines
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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α-Trialkylsilyl-Substitutedα-Amino Acids
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Iridium‐Catalyzed Enantioselective Hydrogenation of Olefins
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Une nouvelle synthese asymetrique de l'alanine par insertion d'un carbene sur une liaison N-H.
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Cu( i )-carbenoid- and Ag( i )-Lewis acid-catalyzed asymmetric intermolecular insertion of α-diazo compounds into N–H bonds
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Asymmetric catalysis of intramolecular N–H insertion reactions of α-diazocarbonyls
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Chiral Auxiliaries and Catalysts
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Chiral Auxiliaries and Catalysts
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inferred← citeshttps://doi.org/10.1016/j.tetlet.2011.06.120openalex-snapshot
Catalytic carbene insertion into an aminoporphyrin and formation of a new chiral supramolecular porphyrin system
inferred← citeshttps://doi.org/10.1016/j.tetlet.2011.11.005openalex-snapshot
InBr3 catalyzed three-component reactions of an aryldiazoacetate, an alcohol, and a carbonyl compound
inferred← citeshttps://doi.org/10.1016/j.tetlet.2011.12.019openalex-snapshot
Catalytic enantioselective synthesis of azacycloalkenes via intermolecular rhodium carbenoid C–H insertion/ring-closing metathesis sequence
inferred← citeshttps://doi.org/10.1016/j.tetlet.2012.09.087openalex-snapshot
Cinchona alkaloids induce asymmetry in the insertion reaction of thermally generated carbenes into N−H bonds
inferred← citeshttps://doi.org/10.1016/j.tetlet.2013.03.046openalex-snapshot
Copper-catalyzed enantioselective allylic oxidation of acyclic olefins
inferred← citeshttps://doi.org/10.1016/j.tetlet.2022.154135openalex-snapshot
Diazo compounds: Recent applications in synthetic organic chemistry and beyond
inferred← citeshttps://doi.org/10.1016/j.tetlet.2023.154496openalex-snapshot
Visible-light-mediated catalytic asymmetric synthesis of α-amino esters via free carbene insertion into N H bond
inferred← citeshttps://doi.org/10.1016/j.tetlet.2024.154942openalex-snapshot
Highly effective one pot reaction from α-hydrazonoesters to give anilinoesters via α-diazoesters
inferred← citeshttps://doi.org/10.1016/j.tetlet.2025.155588openalex-snapshot
Copper(II) NHC pincer complexes containing 1,2,3-triazole units: Synthesis, structure and catalysis for C N bond forming reactions
inferred← citeshttps://doi.org/10.1016/s1872-2067(20)63751-2openalex-snapshot
Palladium-catalyzed enantioselective linear allylic alkylation of vinyl benzoxazinanones: An inner-sphere mechanism
inferred← citeshttps://doi.org/10.1021/acs.chemrev.0c00903openalex-snapshot
Divergent Gold Catalysis: Unlocking Molecular Diversity through Catalyst Control
inferred← citeshttps://doi.org/10.1021/acs.chemrev.5b00121openalex-snapshot
Modern Organic Synthesis with α-Diazocarbonyl Compounds
inferred← citeshttps://doi.org/10.1021/acs.chemrev.5b00381openalex-snapshot
Homologation Reaction of Ketones with Diazo Compounds
inferred← citeshttps://doi.org/10.1021/acs.joc.0c02588openalex-snapshot
TfOH-Catalyzed N–H Insertion of α-Substituted-α-Diazoesters with Anilines Provides Access to Unnatural α-Amino Esters
inferred← citeshttps://doi.org/10.1021/acs.joc.3c02652openalex-snapshot
Rhodium(I)-Catalyzed O–H Insertions onO-Protected α-Diazo-β-Hydroxyesters
inferred← citeshttps://doi.org/10.1021/acs.joc.5b01954openalex-snapshot
General Approach to Nitrogen-Bridged Bicyclic Frameworks by Rh-Catalyzed Formal Carbenoid Insertion into an Amide C–N Bond
inferred← citeshttps://doi.org/10.1021/acs.joc.6b00233openalex-snapshot
Amination of Diazocarbonyl Compounds: N–H Insertion under Metal-Free Conditions
inferred← citeshttps://doi.org/10.1021/acs.joc.7b01274openalex-snapshot
In Situ-Generated Glycinyl Chloroaminals for a One-Pot Synthesis of Non-proteinogenic α-Amino Esters
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c00787openalex-snapshot
Visible Light Induced Cyclization to Spirobi[indene] Skeletons from Functionalized Alkylidienecyclopropanes
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c04376openalex-snapshot
Iridium-Catalyzed Amidation of In Situ Prepared Silyl Ketene Acetals to Access α-Amino Esters
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c04017openalex-snapshot
Palladium-Catalyzed Asymmetric C–C Bond Activation/Carbonylation of Cyclobutanones
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c04161openalex-snapshot
Cu-Catalyzed Cross-Electrophilic Coupling of α-Diazoesters with O-Benzoyl Hydroxylamines for the Synthesis of Unnatural N-Alkyl α-Amino Acid Derivatives
inferred← citeshttps://doi.org/10.1021/acs.orglett.3c01736openalex-snapshot
Single-Flask Enantioselective Synthesis of α-Amino Acid Esters by Organocatalysis
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c00409openalex-snapshot
Spiro-Josiphos Ligands for the Ir-Catalyzed Asymmetric Synthesis of Chiral Amines under Hydrogenation Conditions
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c02135openalex-snapshot
Enantioselective N–H Bond Insertion Reaction of Anilines Enabled by Ruthenium and Chiral Phosphoric Acid Cooperative Catalysis
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b00934openalex-snapshot
Copper(I)-Catalyzed Asymmetric Pinacolboryl Addition of N -Boc-imines Using a Chiral Sulfoxide–Phosphine Ligand
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b01776openalex-snapshot
Chemoselective Carbene insertion into the N–H Bond over O–H Bond Using a Well-Defined Single Site (P–P)Cu(I) Catalyst
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c03534openalex-snapshot
Enantioselective N–H Insertion of Sulfonamides: Access to Chiral α-Aminoesters
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c03859openalex-snapshot
Enantioselective Copper-Catalyzed N–H Insertion Reaction of Pyrazoles and α-Diazo Phosphates
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c04827openalex-snapshot
Construction of Chiral 1,2-Azaborines via Rhodium-Catalyzed Enantioselective Carbene N–H Bond Insertion
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b00564openalex-snapshot
Correction to Catalytic Enantioselective Desymmetrization of 1,3-Diazido-2-propanol via Intramolecular Interception of Alkyl Azides with Diazo(aryl)acetates
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b03256openalex-snapshot
C2-Symmetric Chiral Bisoxazolines as Hydrogen-Bond-Acceptor Catalysts in Enantioselective Aldol Reaction of β-Carbonyl Acids with Trifluoroacetaldehyde Hemiacetals
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b00687openalex-snapshot
Preparation of Axially Chiral 2,2′-Biimidazole Ligands through Remote Chirality Delivery and Their Application in Asymmetric Carbene Insertion into N–H of Carbazoles
inferred← citeshttps://doi.org/10.1021/acscatal.0c02794openalex-snapshot
Enantioselective Synthesis of Chiral Amines via Biocatalytic Carbene N–H Insertion
inferred← citeshttps://doi.org/10.1021/acscatal.2c03777openalex-snapshot
Rhodium/Amine Dual Catalytic System for Reassembling C≡C Bonds of Conjugated Alkynes with Cyclopropenes via Cutting/Insertion Cascade
inferred← citeshttps://doi.org/10.1021/acscatal.3c05040openalex-snapshot
Iron-Carbene Initiated O–H Insertion/Aldol Cascade for the Stereoselective Synthesis of Functionalized Tetrahydrofurans
inferred← citeshttps://doi.org/10.1021/acscentsci.6c00925openalex-snapshot
Fischer Indole Synthesis Inspired De Novo and Modular Assembly of Indolines
inferred← citeshttps://doi.org/10.1021/ar300051uopenalex-snapshot
Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions
inferred← citeshttps://doi.org/10.1021/ar300340kopenalex-snapshot
Novel Multicomponent Reactions via Trapping of Protic Onium Ylides with Electrophiles
inferred← citeshttps://doi.org/10.1021/ar500437hopenalex-snapshot
Ring-Strain-Enabled Reaction Discovery: New Heterocycles from Bicyclo[1.1.0]butanes
inferred← citeshttps://doi.org/10.1021/cr800400zopenalex-snapshot
Recent Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis
inferred← citeshttps://doi.org/10.1021/ja074729kopenalex-snapshot
Highly Enantioselective Insertion of Carbenoids into O−H Bonds of Phenols: An Efficient Approach to Chiral α-Aryloxycarboxylic Esters
inferred← citeshttps://doi.org/10.1021/ja1078464openalex-snapshot
Enantioselective Copper-Catalyzed Intramolecular O−H Insertion: An Efficient Approach to Chiral 2-Carboxy Cyclic Ethers
inferred← citeshttps://doi.org/10.1021/ja201589kopenalex-snapshot
Diastereoselectively Switchable Enantioselective Trapping of Carbamate Ammonium Ylides with Imines
inferred← citeshttps://doi.org/10.1021/ja2084493openalex-snapshot
Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N–H Insertion
inferred← citeshttps://doi.org/10.1021/ja3031054openalex-snapshot
Urea Activation of α-Nitrodiazoesters: An Organocatalytic Approach to N–H Insertion Reactions
inferred← citeshttps://doi.org/10.1021/ja408306aopenalex-snapshot
Copper-Catalyzed B–H Bond Insertion Reaction: A Highly Efficient and Enantioselective C–B Bond-Forming Reaction with Amine–Borane and Phosphine–Borane Adducts
inferred← citeshttps://doi.org/10.1021/ja503163kopenalex-snapshot
Highly Site-Selective Direct C–H Bond Functionalization of Phenols with α-Aryl-α-diazoacetates and Diazooxindoles via Gold Catalysis
inferred← citeshttps://doi.org/10.1021/ja508586topenalex-snapshot
Enantioselective Intramolecular C–H Insertion Reactions of Donor–Donor Metal Carbenoids
inferred← citeshttps://doi.org/10.1021/ja9075293openalex-snapshot
Enantioselective C−C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement between Donor/Acceptor Carbenoids and Allylic Alcohols
inferred← citeshttps://doi.org/10.1021/ja9077254openalex-snapshot
A Water-Soluble Ruthenium Glycosylated Porphyrin Catalyst for Carbenoid Transfer Reactions in Aqueous Media with Applications in Bioconjugation Reactions
inferred← citeshttps://doi.org/10.1021/ja9086566openalex-snapshot
Why Is Copper(I) Complex More Competent Than Dirhodium(II) Complex in Catalytic Asymmetric O−H Insertion Reactions? A Computational Study of the Metal Carbenoid O−H Insertion into Water
inferred← citeshttps://doi.org/10.1021/jacs.0c01918openalex-snapshot
Copper-Catalyzed Asymmetric Reaction of Alkenyl Diynes with Styrenes by Formal [3 + 2] Cycloaddition via Cu-Containing All-Carbon 1,3-Dipoles: Access to Chiral Pyrrole-Fused Bridged [2.2.1] Skeletons
inferred← citeshttps://doi.org/10.1021/jacs.0c07210openalex-snapshot
Chiral Phosphoric Acid Catalyzed Enantioselective Synthesis of α-Tertiary Amino Ketones from Sulfonium Ylides
inferred← citeshttps://doi.org/10.1021/jacs.1c04367openalex-snapshot
Enantioselective Formal Vinylogous N–H Insertion of Secondary Aliphatic Amines Catalyzed by a High-Spin Cobalt(II) Complex
inferred← citeshttps://doi.org/10.1021/jacs.2c09176openalex-snapshot
One-Pot Chemoenzymatic Cascade for the Enantioselective C(1)-Allylation of Tetrahydroisoquinolines
inferred← citeshttps://doi.org/10.1021/jacs.3c06906openalex-snapshot
Catalytic Asymmetric P–H Insertion Reactions
inferred← citeshttps://doi.org/10.1021/jacs.3c10596openalex-snapshot
Silver(I)/Dirhodium(II) Catalytic Platform for Asymmetric N–H Insertion Reaction of Heteroaromatics
inferred← citeshttps://doi.org/10.1021/jacs.3c14386openalex-snapshot
Construction of Ge-Stereogenic Center by Desymmetric Carbene Insertion of Dihydrogermanes
inferred← citeshttps://doi.org/10.1021/jacs.4c02141openalex-snapshot
Copper-Catalyzed Enantioconvergent Radical N-Alkylation of Diverse (Hetero)aromatic Amines
inferred← citeshttps://doi.org/10.1021/jacs.4c04540openalex-snapshot
Enantioselective Construction of Quaternary Stereocenters via A Chiral Spiro Phosphoric Acid-Assisted Formal Gold Carbene gem-Dialkylation Reaction
inferred← citeshttps://doi.org/10.1021/jacs.5b00892openalex-snapshot
Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B–H Bonds: Highly Enantioselective Access to Functionalized Organoboranes
inferred← citeshttps://doi.org/10.1021/jacs.5c02996openalex-snapshot
Cu-Catalyzed Enantioselective Carbene Insertion into Ge–H and Si–H Bonds Enabled by SPSiBox with a Tunable Chiral Pocket
inferred← citeshttps://doi.org/10.1021/jacs.6c00508openalex-snapshot
Enantioselective Pyrazole Alkylation via Iridium and Squaramide Catalyzed N–H Insertion
inferred← citeshttps://doi.org/10.1021/jacs.7b03086openalex-snapshot
Highly Enantioselective Copper- and Iron-Catalyzed Intramolecular Cyclopropanation of Indoles
inferred← citeshttps://doi.org/10.1021/jacs.7b04756openalex-snapshot
Enantioselective Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds
inferred← citeshttps://doi.org/10.1021/jacsau.5c00807openalex-snapshot
Cu-Catalyzed Asymmetric Carbene Insertion into N–H, O–H, and S–H Bonds: Challenging the Existing Mechanistic Dogma
inferred← citeshttps://doi.org/10.1021/jo3001047openalex-snapshot
Enantioselective Synthesis of 3,4-Dihydropyran Derivatives via Organocatalytic Michael Reaction of α,β-Unsaturated Enones
inferred← citeshttps://doi.org/10.1021/jo501178kopenalex-snapshot
Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex
inferred← citeshttps://doi.org/10.1021/jo801781vopenalex-snapshot
Convenient Synthetic Route to an Enantiomerically Pure FMOC α-Amino Acid
inferred← citeshttps://doi.org/10.1021/jo9009968openalex-snapshot
Computational Study on the Selectivity of Donor/Acceptor-Substituted Rhodium Carbenoids
inferred← citeshttps://doi.org/10.1021/jo902089eopenalex-snapshot
Lewis Acid Catalyzed Indole Synthesis via Intramolecular Nucleophilic Attack of Phenyldiazoacetates to Iminium Ions
inferred← citeshttps://doi.org/10.1021/ol100604mopenalex-snapshot
Vinylogous Aldol Products from Chiral Crotylsilanes Obtained by Enantioselective Rh(II) and Cu(I) Carbenoid Si−H Insertion
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