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Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Hydrogen Dissociation by Gold Clusters
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Au/ZrO2 catalysts for low-temperature water gas shift reaction: Influence of particle sizes
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Surface chemistry of catalysis by gold
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Effect of the nature of the support on the catalytic performance of noble metal catalysts for the water–gas shift reaction
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On the origin of the catalytic activity of gold nanoparticles for low-temperature CO oxidation
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Evaluation of the Au size effect: CO oxidation catalyzed by Au/TiO2
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The effect of reaction conditions on the stability of Au/CeZrO4 catalysts in the low-temperature water–gas shift reaction
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Electron microscopy of catalysts: recent achievements and future prospects
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Active Sites for H2Adsorption and Activation in Au/TiO2and the Role of the Support
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Genesis of a Cerium Oxide Supported Gold Catalyst for CO Oxidation: Transformation of Mononuclear Gold Complexes into Clusters as Characterized by X-Ray Absorption Spectroscopy
inferredcites →https://doi.org/10.1021/jp9935992openalex-snapshot
When Gold Is Not Noble: Nanoscale Gold Catalysts
inferredcites →https://doi.org/10.1039/a606192copenalex-snapshot
Low-temperature water–gas shift reaction over gold deposited on TiO2
inferredcites →https://doi.org/10.1039/b607837kopenalex-snapshot
Gold catalysts for pure hydrogen production in the water–gas shift reaction: activity, structure and reaction mechanism
inferredcites →https://doi.org/10.1126/science.1085721openalex-snapshot
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
inferredcites →https://doi.org/10.1126/science.1159639openalex-snapshot
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
inferredcites →https://doi.org/10.1126/science.281.5383.1647openalex-snapshot
Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Promoted potassium salts based Ru/AC catalysts for water gas shift reaction
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Auδ−–Ov–Ti3+ Interfacial Site: Catalytic Active Center toward Low-Temperature Water Gas Shift Reaction
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Prospects of Nanoscience with Nanocrystals: 2025 Edition
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Construction of Functional Superhydrophobic Biochars as Hydrogen Transfer Catalysts for Dehydrogenation of N-Heterocycles
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Insights into Catalytic Oxidation at the Au/TiO2 Dual Perimeter Sites
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Catalysis by Supported Gold Nanoparticles: Beyond Aerobic Oxidative Processes
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Differences in Catalytic Sites for CO Oxidation and Propylene Epoxidation on Au Nanoparticles
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NaBr Poisoning of Au/TiO2 Catalysts: Effects on Kinetics, Poisoning Mechanism, and Estimation of the Number of Catalytic Active Sites
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General Method for Determination of the Surface Composition in Bimetallic Nanoparticle Catalysts from the L Edge X-ray Absorption Near-Edge Spectra
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Synthesis of Na-Stabilized Nonporous t-ZrO2 Supports and Pt/t-ZrO2 Catalysts and Application to Water-Gas-Shift Reaction
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Effects of Pd on Catalysis by Au: CO Adsorption, CO Oxidation, and Cyclohexene Hydrogenation by Supported Au and Pd–Au Catalysts
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Remote Activation of Chemical Bonds in Heterogeneous Catalysis
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Mechanistic Aspects of the Water–Gas Shift Reaction on Isolated and Clustered Au Atoms on CeO2(110): A Density Functional Theory Study
inferred← citeshttps://doi.org/10.1021/cs500071copenalex-snapshot
Efficient and Durable Au Alloyed Pd Single-Atom Catalyst for the Ullmann Reaction of Aryl Chlorides in Water
inferred← citeshttps://doi.org/10.1021/cs5009283openalex-snapshot
Cu Nanoparticles Inlaid Mesoporous Al2O3 As a High-Performance Bifunctional Catalyst for Ethanol Synthesis via Dimethyl Oxalate Hydrogenation
inferred← citeshttps://doi.org/10.1021/cs5009706openalex-snapshot
Water–Gas Shift Catalysis at Corner Atoms of Pt Clusters in Contact with a TiO2(110) Support Surface
inferred← citeshttps://doi.org/10.1021/cs5020755openalex-snapshot
Toward Understanding Metal-Catalyzed Ethanol Reforming
inferred← citeshttps://doi.org/10.1021/ic3002674openalex-snapshot
Trends in the Electronic Structure of Extended Gold Compounds: Implications for Use of Gold in Heterogeneous Catalysis
inferred← citeshttps://doi.org/10.1021/ja207510vopenalex-snapshot
CO Oxidation Mechanism on CeO 2 -Supported Au Nanoparticles
inferred← citeshttps://doi.org/10.1021/ja210083dopenalex-snapshot
Size and Support Effects for the Water–Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al2O3 and TiO2
inferred← citeshttps://doi.org/10.1021/ja304426bopenalex-snapshot
Inhibition at Perimeter Sites of Au/TiO2 Oxidation Catalyst by Reactant Oxygen
inferred← citeshttps://doi.org/10.1021/ja312646dopenalex-snapshot
Atomically Dispersed Au–(OH)x Species Bound on Titania Catalyze the Low-Temperature Water-Gas Shift Reaction
inferred← citeshttps://doi.org/10.1021/ja401967yopenalex-snapshot
WGS Catalysis and In Situ Studies of CoO1–x, PtCon/Co3O4, and PtmCom′/CoO1–x Nanorod Catalysts
inferred← citeshttps://doi.org/10.1021/ja410292sopenalex-snapshot
CO Oxidation on TiO 2 (110) Supported Subnanometer Gold Clusters: Size and Shape Effects
inferred← citeshttps://doi.org/10.1021/ja508666aopenalex-snapshot
Direct Simulation Evidence of Generation of Oxygen Vacancies at the Golden Cage Au16 and TiO2 (110) Interface for CO Oxidation
inferred← citeshttps://doi.org/10.1021/jacs.4c02692openalex-snapshot
Metal–Sulfur Interfaces as the Primary Active Sites for Catalytic Hydrogenations
inferred← citeshttps://doi.org/10.1021/jacs.5b05945openalex-snapshot
Reverse Water–Gas Shift on Interfacial Sites Formed by Deposition of Oxidized Molybdenum Moieties onto Gold Nanoparticles
inferred← citeshttps://doi.org/10.1021/jacs.5c22700openalex-snapshot
Gas–Solid van der Waals Interaction Driving the Dynamic Evolution of Surface Nanostructures
inferred← citeshttps://doi.org/10.1021/jacs.6b08697openalex-snapshot
Increased Back-Bonding Explains Step-Edge Reactivity and Particle Size Effect for CO Activation on Ru Nanoparticles
inferred← citeshttps://doi.org/10.1021/jacs.7b05476openalex-snapshot
Catalytic Activity Control via Crossover between Two Different Microstructures
inferred← citeshttps://doi.org/10.1021/jp304106fopenalex-snapshot
Influence of Step Defects on the H2S Splitting on Copper Surfaces from First-Principles Microkinetic Modeling
inferred← citeshttps://doi.org/10.1021/jp3089325openalex-snapshot
Effect of Ceria on Gold–Titania Catalysts for the Water–Gas Shift Reaction: Fundamental Studies for Au/CeOx/TiO2(110) and Au/CeOx/TiO2 Powders
inferred← citeshttps://doi.org/10.1021/jp503922xopenalex-snapshot
Role of Oxygen Vacancies in Water Gas Shift Reaction: Activity Study on BaCe0.98–xYxPt0.02O3−δ Perovskites
inferred← citeshttps://doi.org/10.1021/jp5124376openalex-snapshot
Density Functional Theory (DFT) Studies of CO Oxidation over Nanoporous Gold: Effects of Residual Ag and CO Self-Promoting Oxidation
inferred← citeshttps://doi.org/10.1038/s41467-025-61895-8openalex-snapshot
Quantifying electronic and geometric effects on the activity of platinum catalysts for water-gas shift
inferred← citeshttps://doi.org/10.1038/s41929-019-0343-2openalex-snapshot
Carboxyl intermediate formation via an in situ-generated metastable active site during water-gas shift catalysis
inferred← citeshttps://doi.org/10.1039/9781782621645-00111openalex-snapshot
Twenty Years of Golden Future in the Water Gas Shift Reaction
inferred← citeshttps://doi.org/10.1039/c1fd00030fopenalex-snapshot
Exploring the structure and chemical activity of 2-D gold islands on graphene moiré/Ru(0001)
inferred← citeshttps://doi.org/10.1039/c3cp51326bopenalex-snapshot
Water–gas shift on gold catalysts: catalyst systems and fundamental studies
inferred← citeshttps://doi.org/10.1039/c3cy00243hopenalex-snapshot
Au–metal oxide support interface as catalytic active sites
inferred← citeshttps://doi.org/10.1039/c3fd00002hopenalex-snapshot
Mechanistic insights into the partial oxidation of acetic acid by O2 at the dual perimeter sites of a Au/TiO2 catalyst
inferred← citeshttps://doi.org/10.1039/c4cy01183jopenalex-snapshot
Plasmon-enhanced reverse water gas shift reaction over oxide supported Au catalysts
inferred← citeshttps://doi.org/10.1039/c5cc01316jopenalex-snapshot
Structure transition of Au 18 from pyramidal to a hollow-cage during soft-landing onto a TiO 2 (110) surface
inferred← citeshttps://doi.org/10.1039/c5nj02608copenalex-snapshot
Perspectives on zeolite-encapsulated metal nanoparticles and their applications in catalysis
inferred← citeshttps://doi.org/10.1039/c5ra13962gopenalex-snapshot
Activity of faujasite supported gold monomer towards water gas shift reaction: hybrid density functional theory/molecular mechanics approach
inferred← citeshttps://doi.org/10.1039/c6nr00486eopenalex-snapshot
Relative edge energy in the stability of transition metal nanoclusters of different motifs
inferred← citeshttps://doi.org/10.1039/c6nr02166bopenalex-snapshot
Size-dependent adhesion energy of shape-selected Pd and Pt nanoparticles
inferred← citeshttps://doi.org/10.1039/c6ra27207jopenalex-snapshot
Theoretical insights into ω-alkynylfuran cycloisomerisation catalyzed by Au/CeO 2 (111): the role of the CeO 2 (111) support
inferred← citeshttps://doi.org/10.1039/c6ra27454dopenalex-snapshot
Sterical ligand stabilization of nanocrystals versus electrostatic shielding by ionic compounds: a principle model study with TEM and XPS
inferred← citeshttps://doi.org/10.1039/c7cy01020fopenalex-snapshot
Participation of interfacial hydroxyl groups in the water-gas shift reaction over Au/MgO catalysts
inferred← citeshttps://doi.org/10.1039/c8cc02966kopenalex-snapshot
Engineering nanoporous organic frameworks to stabilize naked Au clusters: a charge modulation approach
inferred← citeshttps://doi.org/10.1039/c9cp03943kopenalex-snapshot
Identification of active sites in CO oxidation over a Pd/Al 2 O 3 catalyst
inferred← citeshttps://doi.org/10.1039/c9cy00410fopenalex-snapshot
On the nature of active sites for formic acid decomposition on gold catalysts
inferred← citeshttps://doi.org/10.1039/c9cy02077bopenalex-snapshot
The catalytic mechanism of the Au@TiO 2−x /ZnO catalyst towards a low-temperature water-gas shift reaction
inferred← citeshttps://doi.org/10.1039/c9ta01734hopenalex-snapshot
Influence of the gas atmosphere during the synthesis of g-C 3 N 4 for enhanced photocatalytic H 2 production from water on Au/g-C 3 N 4 composites
inferred← citeshttps://doi.org/10.1039/d1cp05789hopenalex-snapshot
Rational design of highly efficient MXene-based catalysts for the water-gas-shift reaction
inferred← citeshttps://doi.org/10.1039/d1dt01345aopenalex-snapshot
Reconstruction and catalytic activity of hybrid Pd(100)/(111) monolayer on γ-Al 2 O 3 (100) in CH 4 , H 2 O, and O 2 dissociation
inferred← citeshttps://doi.org/10.1039/d4cc05165copenalex-snapshot
Dynamic restructuring of electrocatalysts in the activation of small molecules: challenges and opportunities
inferred← citeshttps://doi.org/10.1039/d4cy01550aopenalex-snapshot
Boosting visible light photocatalytic oxidation of CO using Au nanocatalysts through synergistic preparation of an Fe-doped TiO 2 support and cold plasma treatment
inferred← citeshttps://doi.org/10.1063/1.5128735openalex-snapshot
Water-gas shift activity on Pt-Re surfaces and the role of the support
inferred← citeshttps://doi.org/10.1063/5.0049582openalex-snapshot
Manipulation of CO adsorption over Me1/CeO2 by heterocation doping: Key roles of single-atom adsorption energy
inferred← citeshttps://doi.org/10.1073/pnas.2002342117openalex-snapshot
Revealing the structure of a catalytic combustion active-site ensemble combining uniform nanocrystal catalysts and theory insights
inferred← citeshttps://doi.org/10.1080/00986445.2019.1692002openalex-snapshot
New perspectives on the nature and imaging of active site in small metallic particles: I. Geometric effects
inferred← citeshttps://doi.org/10.1080/00986445.2020.1719078openalex-snapshot
New perspectives on the nature and imaging of active site in small metallic particles: II. Electronic effects
inferred← citeshttps://doi.org/10.1103/physrevlett.111.115501openalex-snapshot
Stacking Principle and Magic Sizes of Transition Metal Nanoclusters Based on Generalized Wulff Construction
inferred← citeshttps://doi.org/10.1126/science.1240148openalex-snapshot
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts
inferred← citeshttps://doi.org/10.1146/annurev-chembioeng-062011-080939openalex-snapshot
Atomically Dispersed Supported Metal Catalysts
inferred← citeshttps://doi.org/10.1246/cl.200856openalex-snapshot
Selective Hydrogenation of C=C bond in Cinnamaldehyde on Pd Step Sites of Pd/Al2O3
inferred← citeshttps://doi.org/10.18130/v36g34openalex-snapshot
Reactivity and Properties of Au/TiO2 Nanocatalysts
inferred← citeshttps://doi.org/10.21203/rs.3.rs-2614327/v1openalex-snapshot
Size-dependent active site and its catalytic mechanism for CO2 hydrogenation reactivity and selectivity over Re/TiO2
inferred← citeshttps://doi.org/10.3390/catal10040442openalex-snapshot
Advances in Designing Au Nanoparticles for Catalytic Epoxidation of Propylene with H2 and O2
inferred← citeshttps://doi.org/10.3390/catal13111444openalex-snapshot
Plasmonic-Assisted Water–Gas Shift Reaction of Gold Particles on TiO2
inferred← citeshttps://doi.org/10.3390/inorganics13060186openalex-snapshot
Size-Activity Relationship of TiO2-Supported Pt Nanoparticles in Hydrogenation Reactions
inferred← citeshttps://doi.org/10.3390/molecules17021716openalex-snapshot
Chemisorption and Reactions of Small Molecules on Small Gold Particles
inferred← citeshttps://doi.org/10.3390/s22166277openalex-snapshot
Study on Sensing Mechanism of Volatile Organic Compounds Using Pt-Loaded ZnO Nanocrystals
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