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Charge Delocalization and Enhanced Acidity in Tricationic Superelectrophiles

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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The Chemistry of Heterocycles: Structure, Reactions, Syntheses, and Applications
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The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals
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Evaluation of dispersion-corrected density functional theory (B3LYP-DCP) for compounds of biochemical interest
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Reactions of O,O-diprotonated nitro olefins with benzenes. Formations of phenylacetones, 4H-1,2-benzoxazines and biarylacetone oximes
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Multiply charged carbocations and related species in solution
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Tris(2-thienyl)methyl cation; An unprecedent 13C NMR behavior
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Selective electrophilic activation of alkanes
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Aromatic substitution. XXVIII. Mechanism of electrophilic aromatic substitutions
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1,2-Dications in Organic Main Group Systems
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Ab Initio Calculation of Vibrational Absorption and Circular Dichroism Spectra Using Density Functional Force Fields
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Friedel-Crafts-type reactions involving di- and tricationic species. Onium-allyl dications and O,O-diprotonated aci-nitro species bearing a protonated carbonyl group
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1,3,5,7-Adamantanetetrakis(.alpha.,.alpha.-diphenylmethyl)tetrayl Tetracation: A Stable Tetrahedrally Arrayed Tetracation
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Acid-catalyzed reactions of N-arylhydroxylamines and related compounds with benzene. Iminium-benzenium ions
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Stable carbocations. 192. Acyclic carbodications
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Stable carbocations. 194. Patterns of carbon-13 chemical shift response to substituent effects in arylcarbenium ions. The phenyl, phenylethynyl, and naphthyl systems
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Electrophilic reactions at single bonds. XVIII. Indication of protosolvated de facto substituting agents in the reactions of alkanes with acetylium and nitronium ions in superacidic media
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Relative stabilities of dications in strong acids. Calorimetric study of dications formed from diesters, diketones, and diacid chlorides
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Stable carbonium ions. LIX. Protonated alkyl carbamates and their cleavage to protonated carbamic acids and alkylcarbonium ions
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Stable carbonium ions. LXVI. Protonation of diketones in FSO3H-SbF5-SO2 solution
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Distribution of Isomers in the Mononitration of t-Butylbenzene; Properties of the Pure Mononitro-t-butylbenzenes
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Formation of 4H-1,2-Benzoxazines by Intramolecular Cyclization of Nitroalkanes. Scope of Aromatic Oxygen-Functionalization Reaction Involving a Nitro Oxygen Atom and Mechanistic Insights
inferredcites →https://doi.org/10.1021/ja1001482openalex-snapshot
Superelectrophiles and the Effects of Trifluoromethyl Substituents
inferredcites →https://doi.org/10.1021/ja202557zopenalex-snapshot
Superacid-Promoted Additions Involving Vinyl-Substituted Pyrimidines, Quinoxalines, and Quinazolines: Mechanisms Correlated to Charge Distributions
inferredcites →https://doi.org/10.1021/ja908749uopenalex-snapshot
Cyclization of Arylacetoacetates to Indene and Dihydronaphthalene Derivatives in Strong Acids. Evidence for Involvement of Further Protonation of O,O-Diprotonated β-Ketoester, Leading to Enhancement of Cyclization
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Search for Long-Lived 1,3-Carbodications and Preparation of the Persistent 1,1,3,3-Tetracyclopropyl-1,3-propanediyl Dication1
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Prediction of substituent sensitivities (.rho.R+) for carbocations. Correlation with charges or HOMO-LUMO interactions
inferredcites →https://doi.org/10.1021/jo020753zopenalex-snapshot
13C NMR/DFT/GIAO Studies of Phenylene Bis(1,3-dioxolanium) Dications and 2,4,6-Triphenylene Tris(1,3-dioxolanium) Trication
inferredcites →https://doi.org/10.1021/jo035598iopenalex-snapshot
Synthesis and Isolation of Polytrityl Cations by Utilizing Hexaphenylbenzene and Tetraphenylmethane Scaffolds
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Superelectrophilic Activation of 4-Heterocyclohexanones. Implications for Polymer Synthesis. A Theoretical Study
inferredcites →https://doi.org/10.1021/jp806162topenalex-snapshot
Interactions in Large, Polyaromatic Hydrocarbon Dimers: Application of Density Functional Theory with Dispersion Corrections
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New Model for Calculation of Solvation Free Energies: Correction of Self-Consistent Reaction Field Continuum Dielectric Theory for Short-Range Hydrogen-Bonding Effects
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Superelectrophiles and Their Chemistry
inferredcites →https://doi.org/10.1063/1.456153openalex-snapshot
Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen
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Gaussian basis sets for use in correlated molecular calculations. III. The atoms aluminum through argon
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Synthesis, Properties, and Redox Behaviors of Di- and Trications Composed of Di(1-azulenyl)methylium Units Connected by p- and m-Phenylene and 1,3,5-Benzenetriyl Spacers

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Superelectrophiles Reactions Assisted by Hydrogen Bonds Synthesis of Multi-Diazafluorenes Units (Mdafs)
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Successive Protonation of an N‐Heterocyclic Imine Derived Carbonyl: Superelectrophilic Dication Versus Masked Acylium Ion
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Enantioenriched Methylene‐Bridged Benzazocanes Synthesis by Organocatalytic and Superacid Activations
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Unbiased C3‐Electrophilic Indoles: Triflic Acid Mediated C3‐Regioselective Hydroarylation of N−H Indoles**
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C−H Functionalisation for Hydrogen Isotope Exchange
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Successive Protonation of an N‐Heterocyclic Imine Derived Carbonyl: Superelectrophilic Dication Versus Masked Acylium Ion
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Enantioenriched Methylene‐Bridged Benzazocanes Synthesis by Organocatalytic and Superacid Activations
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Unbiased C3‐Electrophilic Indoles: Triflic Acid Mediated C3‐Regioselective Hydroarylation of N−H Indoles**
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Protonation Switching to the Least‐Basic Heteroatom of Carbamate through Cationic Hydrogen Bonding Promotes the Formation of Isocyanate Cations
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Use of Charge‐Charge Repulsion to Enhance π‐Electron Delocalization into Anti‐Aromatic and Aromatic Systems
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Incorporation of a p‐Phenylene Unit into the Azuliporphyrinogens Frame—Oxidation and Ruthenium Cluster Coordination
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Decoding Voltammograms at the Molecular Frontier: Integration of Voltammetry and Mass Spectrometry
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Insights into the Structure–Property Relationship of Difluoro Boron Dipyridomethene Derivatives
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Preparation of NH‐Pyrroles under Superelectrophilic Conditions by an Aza‐Nazarov Reaction Cascade with Indole as Neutral Leaving Group: Experiment and Theory
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A General Synthesis of Bis( o ‐azaheteroaryl)methane Derivatives from N ‐Oxides of Azines and Azoles
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Switch From Pauli‐Lowering to LUMO‐Lowering Catalysis in Brønsted Acid‐Catalyzed Aza‐Diels‐Alder Reactions
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Quantifying superacidity with density-based reactivity theory
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Superelectrophilic-initiated Friedel–Crafts reaction of diazafluorenols: Synthesis of multi-diazafluorene units (MDAFs)
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Denitrogenative Transformations of Pyridotriazoles and Related Compounds: Synthesis of N-Containing Heterocyclic Compounds and Beyond
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Friedel–Crafts Reactions with N-Heterocyclic Alcohols
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Friedel–Crafts Coupling of Electron-Deficient Benzoylacetones Tuned by Remote Electronic Effects
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Carbon Cationic Relay via Superelectrophiles: Synthesis of Spiro-diazafluorenes
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Diels–Alder Reactions with Ethylene and Superelectrophiles
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Aza-Nazarov Cyclization Reactions via Anion Exchange Catalysis
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Indium-Catalyzed Denitrogenative Transannulation of Pyridotriazoles: Synthesis of Pyrido[1,2-a]indoles
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Copper-Catalyzed Cascade Cyclization Reaction of Enamines and Electron-Deficient Terminal Alkynes: Synthesis of Polysubstituted Pyrido[1,2-a]indoles
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Stereoselective gridization and polygridization with centrosymmetric molecular packing
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Friedel–Crafts-type reactions with ureas and thioureas
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Reaction mechanisms: polar reactions
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Reaction mechanisms: polar reactions
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Recent advances in the synthesis of pyrido[1,2- a ]indoles
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One-pot formal [3 + 2] annulation of 2-pyridinyl-substituted p -quinone methides and arynes for the synthesis of 3-aryl pyrido[1,2- a ]indoles
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Pd-catalyzed efficient synthesis of benzo[4,5]imidazo[1,2- a ]indoles with diaziridinone
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15.1.4 Pyridines (Update 2016)
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Harnessing vinyl cations in nucleophilic substitutions and Lewis acidity enhancement of aluminum(III) salts in catalyzed cyclizations
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