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Ruthenium-Vinylhelicenes: Remote Metal-Based Enhancement and Redox Switching of the Chiroptical Properties of a Helicene Core

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Syntheses of Functionalized and Aggregating Helical Conjugated Molecules

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A Redox Switch Based on Dihydro[5]helicene: Drastic Chiroptical Response Induced by Reversible C−C Bond Making/Breaking upon Electron Transfer

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Molecular Switches

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Aromatic Fluorine as a Versatile Control Element for the Construction of Molecules with Helical Chirality

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The Helicenes

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Recent Developments in the Synthesis of Helicene‐Like Molecules

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Efficient Phenanthrene, Helicene, and Azahelicene Syntheses

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Electrochemical Switching of the Cubic Nonlinear Optical Properties of an Aryldiethynyl‐Linked Heterobimetallic Complex between Three Distinct States

inferredcites →https://doi.org/10.1002/anie.200801991openalex-snapshot

Aromatic Fluorine as a Versatile Control Element for the Construction of Molecules with Helical Chirality

inferredcites →https://doi.org/10.1002/anie.200905099openalex-snapshot

Metallahelicenes: Easily Accessible Helicene Derivatives with Large and Tunable Chiroptical Properties

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Helquats: A Facile, Modular, Scalable Route to Novel Helical Dications

inferredcites →https://doi.org/10.1002/chem.200903583openalex-snapshot

Photochromic Organometallics with a Dithienylethene (DTE) Bridge, [YCCDTECCY] (Y={MCp*(dppe)}): Photoswitchable Molecular Wire (M=Fe) versus Dual Photo‐ and Electrochromism (M=Ru)

inferredcites →https://doi.org/10.1002/chem.201001655openalex-snapshot

Synthesis and Structures of Multifunctionalized Helicenes and Dehydrohelicenes: An Efficient Route to Construct Cyan Fluorescent Molecules

inferredcites →https://doi.org/10.1002/chem.201101866openalex-snapshot

Multifunctional and Reactive Enantiopure Organometallic Helicenes: Tuning Chiroptical Properties by Structural Variations of Mono‐ and Bis(platinahelicene)s

inferredcites →https://doi.org/10.1016/j.ccr.2010.02.020openalex-snapshot

Quantum chemical interpretation of redox properties of ruthenium complexes with vinyl and TCNX type non-innocent ligands

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Theoretical investigation on bridged triarylamine helicenes: UV/visible and circular dichroism spectra

inferredcites →https://doi.org/10.1021/cr200087ropenalex-snapshot

Helicenes: Synthesis and Applications

inferredcites →https://doi.org/10.1021/cr9003852openalex-snapshot

Electronic Communication through Unsaturated Hydrocarbon Bridges in Homobimetallic Organometallic Complexes

inferredcites →https://doi.org/10.1021/cr940053xopenalex-snapshot

Chemical Redox Agents for Organometallic Chemistry

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The electronic structure of helicene-bisquinone anion radicals

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Synthesis and properties of an optically active helical bis-cobaltocenium ion

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Optical and magnetic properties of anions of hexahelicene

inferredcites →https://doi.org/10.1021/ja01599a060openalex-snapshot

The Synthesis and Resolution of Hexahelicene 1

inferredcites →https://doi.org/10.1021/ja050190jopenalex-snapshot

Chiral Discrimination in Photochromic Helicenes

inferredcites →https://doi.org/10.1021/ja0526721openalex-snapshot

Dual Modulation of a Molecular Switch with Exceptional Chiroptical Properties

inferredcites →https://doi.org/10.1021/ja075547topenalex-snapshot

Ruthenium Complexes with Vinyl, Styryl, and Vinylpyrenyl Ligands: A Case of Non-innocence in Organometallic Chemistry

inferredcites →https://doi.org/10.1021/ja2023515openalex-snapshot

d−f Heterobimetallic Association between Ytterbium and Ruthenium Carbon-Rich Complexes: Redox Commutation of Near-IR Luminescence

inferredcites →https://doi.org/10.1021/ja300278eopenalex-snapshot

Rhodium-Catalyzed Enantioselective Synthesis, Crystal Structures, and Photophysical Properties of Helically Chiral 1,1′-Bitriphenylenes

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Radical Cation of Helical, Cross-Conjugated β-Oligothiophene

inferredcites →https://doi.org/10.1021/ja991960sopenalex-snapshot

Circular Dichroism of Helicenes Investigated by Time-Dependent Density Functional Theory

inferredcites →https://doi.org/10.1021/jo026883popenalex-snapshot

Bridged Triarylamines: A New Class of Heterohelicenes

inferredcites →https://doi.org/10.1021/jo972101uopenalex-snapshot

Synthesis of Conjugated Helical Acetylene-Bridged Polymers and Cyclophanes

inferredcites →https://doi.org/10.1021/ol1003466openalex-snapshot

Synthesis, Resolution, and Stabilities of a Cationic Chromenoxanthene [4]helicene

inferredcites →https://doi.org/10.1021/om00142a019openalex-snapshot

Insertion reactions of the 16-electron complexes MHCl(CO)[P(CHMe2)3]2 (M = Ru, Os) with alkynes. The x-ray crystal structure of [(E)-PhCH:CHOs(Cl)(CO)[P(CHMe2)3]2

inferredcites →https://doi.org/10.1021/om0602660openalex-snapshot

Divinylphenylene-Bridged Diruthenium Complexes Bearing Ru(CO)Cl(PiPr3)2Entities

inferredcites →https://doi.org/10.1021/om1007133openalex-snapshot

Fully Delocalized (Ethynyl)(vinyl)phenylene-Bridged Diruthenium Radical Complexes

inferredcites →https://doi.org/10.1021/om200571aopenalex-snapshot

Tetrathia[7]helicene-Based Complexes of Ferrocene and (η5-Cyclohexadienyl)tricarbonylmanganese: Synthesis and Electrochemical Studies

inferredcites →https://doi.org/10.1039/b800412aopenalex-snapshot

Redox-triggered chiroptical molecular switches

inferredcites →https://doi.org/10.1039/b815899aopenalex-snapshot

A multifunctional organometallic switch with carbon-rich ruthenium and diarylethene units

inferredcites →https://doi.org/10.1039/b819270gopenalex-snapshot

Electrically-controlled near-infrared chiroptical switching of enantiomeric dinuclear ruthenium complexes

inferredcites →https://doi.org/10.1039/b905670jopenalex-snapshot

First expeditious synthesis of 6,11-diamino-[6]carbohelicenes

inferredcites →https://doi.org/10.1039/c0dt01388aopenalex-snapshot

Polynuclear carbon-rich organometallic complexes: clarification of the role of the bridging ligand in the redox properties

inferredcites →https://doi.org/10.1073/pnas.0902612106openalex-snapshot

An organometallic route to long helicenes

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1021/acs.orglett.3c00424openalex-snapshot

Divergent Synthesis of Helical Ketone Enabled by Rearrangement of Spiro Carbocation

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c00398openalex-snapshot

Azacoronene in Helicenes and Conjugated Polymers

inferred← citeshttps://doi.org/10.1021/acs.orglett.6b01708openalex-snapshot

Synthesis and Properties of [7]Helicene-like Compounds Fused with a Fluorene Unit

inferred← citeshttps://doi.org/10.1021/cr500671popenalex-snapshot

Supramolecular Chirality in Self-Assembled Systems

inferred← citeshttps://doi.org/10.1021/ic503075eopenalex-snapshot

Vinyl Ruthenium-Modified Biphenyl and 2,2′-Bipyridines

inferred← citeshttps://doi.org/10.1021/ja500220jopenalex-snapshot

Intense Chiroptical Switching in a Dicationic Helicene-Like Derivative: Exploration of a Viologen-Type Redox Manifold of a Non-Racemic Helquat

inferred← citeshttps://doi.org/10.1021/ja5069323openalex-snapshot

Helicene Quinones: Redox-Triggered Chiroptical Switching and Chiral Recognition of the Semiquinone Radical Anion Lithium Salt by Electron Nuclear Double Resonance Spectroscopy

inferred← citeshttps://doi.org/10.1021/jacs.2c00556openalex-snapshot

Mutual Monomer Orientation To Bias the Supramolecular Polymerization of [6]Helicenes and the Resulting Circularly Polarized Light and Spin Filtering Properties

inferred← citeshttps://doi.org/10.1021/jacs.2c03681openalex-snapshot

Localized Antiaromaticity Hotspot Drives Reductive Dehydrogenative Cyclizations in Bis- and Mono-Helicenes

inferred← citeshttps://doi.org/10.1021/jacs.3c10578openalex-snapshot

Near-Infrared, Organic Chiroptic Switch with High Dissymmetry Factors

inferred← citeshttps://doi.org/10.1021/jacs.5b02794openalex-snapshot

An Ultimate Stereocontrol in Asymmetric Synthesis of Optically Pure Fully Aromatic Helicenes

inferred← citeshttps://doi.org/10.1021/jacs.5c00524openalex-snapshot

Encoding and Expressing the Handedness of a Möbius π System in a Totemic Architecture

inferred← citeshttps://doi.org/10.1021/jacs.7b13512openalex-snapshot

Chiral Organic Cages with a Triple-Stranded Helical Structure Derived from Helicene

inferred← citeshttps://doi.org/10.1021/jacs.8b08969openalex-snapshot

Preparation of Carbodiimides with One-Handed Axial Chirality

inferred← citeshttps://doi.org/10.1021/jp3104084openalex-snapshot

Circular Dichroism of (Di)methyl- and Diaza[6]helicenes. A Combined Theoretical and Experimental Study

inferred← citeshttps://doi.org/10.1021/jp403426wopenalex-snapshot

Theoretical and Experimental Studies of Circular Dichroism of Mono- and Diazonia[6]helicenes

inferred← citeshttps://doi.org/10.1021/ol502180yopenalex-snapshot

Photophysical and Electrochemical Characterization of a Helical Viologen, N,N′-Dimethyl-5,10-diaza[5]helicene

inferred← citeshttps://doi.org/10.1039/c3cc47825dopenalex-snapshot

Helicene-grafted vinyl- and carbene-osmium complexes: an example of acid–base chiroptical switching

inferred← citeshttps://doi.org/10.1039/c3cp54338bopenalex-snapshot

Optical rotation calculations on large molecules using the approximate coupled cluster model CC2 and the resolution-of-the-identity approximation

inferred← citeshttps://doi.org/10.1039/c3dt52291aopenalex-snapshot

Cationic half-sandwich quinolinophaneoxazoline-based (η 6 -p-cymene)ruthenium( ii ) complexes exhibiting different chirality types: synthesis and structural determination by complementary spectroscopic methods

inferred← citeshttps://doi.org/10.1039/c3sc53442aopenalex-snapshot

Straightforward access to mono- and bis-cycloplatinated helicenes displaying circularly polarized phosphorescence by using crystallization resolution methods

inferred← citeshttps://doi.org/10.1039/c3tc00040kopenalex-snapshot

Photophysical properties of azaboradibenzo[6]helicene derivatives

inferred← citeshttps://doi.org/10.1039/c4cc08967gopenalex-snapshot

Functional helquats: helical cationic dyes with marked, switchable chiroptical properties in the visible region

inferred← citeshttps://doi.org/10.1039/c4py00692eopenalex-snapshot

Synthesis and chiral recognition ability of helical polyacetylenes bearing helicene pendants

inferred← citeshttps://doi.org/10.1039/c4sc01404aopenalex-snapshot

Helicene-based transition metal complexes: synthesis, properties and applications

inferred← citeshttps://doi.org/10.1039/c5nr01297jopenalex-snapshot

Mechanical tuning of conductance and thermopower in helicene molecular junctions

inferred← citeshttps://doi.org/10.1039/c6cc00995fopenalex-snapshot

Chiroptical switching caused by crystalline/liquid crystalline phase transition of a chiral bowl-shaped molecule

inferred← citeshttps://doi.org/10.1039/c6cc01748gopenalex-snapshot

Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn 2+ binding

inferred← citeshttps://doi.org/10.1039/c6cc03256gopenalex-snapshot

Controlled formation of chiral networks and their reversible chiroptical switching behaviour by UV/microwave irradiation

inferred← citeshttps://doi.org/10.1039/c6cc04257kopenalex-snapshot

Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

inferred← citeshttps://doi.org/10.1039/c6ob01102kopenalex-snapshot

Competing amination and C–H arylation pathways in Pd/xantphos-catalyzed transformations of binaphthyl triflates: switchable routes to chiral amines and helicene derivatives

inferred← citeshttps://doi.org/10.1039/c6sc00614kopenalex-snapshot

Functionalized cationic [4]helicenes with unique tuning of absorption, fluorescence and chiroptical properties up to the far-red range

inferred← citeshttps://doi.org/10.1039/c7cc04903jopenalex-snapshot

Intense redox-driven chiroptical switching with a 580 mV hysteresis actuated through reversible dimerization of an azoniahelicene

inferred← citeshttps://doi.org/10.1039/c7ob01742aopenalex-snapshot

Microwave-assisted synthesis of novel hetero[5]helicene-like molecules and coumarin derivatives

inferred← citeshttps://doi.org/10.1039/c7sc04312kopenalex-snapshot

Exciton coupling in diketopyrrolopyrrole–helicene derivatives leads to red and near-infrared circularly polarized luminescence

inferred← citeshttps://doi.org/10.1039/c8dt01493kopenalex-snapshot

Redox-driven porphyrin based systems for new luminescent molecular switches

inferred← citeshttps://doi.org/10.1039/c8sc02935kopenalex-snapshot

Combined reversible switching of ECD and quenching of CPL with chiral fluorescent macrocycles

inferred← citeshttps://doi.org/10.1039/c9sc05231copenalex-snapshot

Modulation of circularly polarized luminescence through excited-state symmetry breaking and interbranched exciton coupling in helical push–pull organic systems

inferred← citeshttps://doi.org/10.1039/d0cc06970aopenalex-snapshot

Furan-containing double tetraoxa[7]helicene and its radical cation

inferred← citeshttps://doi.org/10.1039/d0cs00191kopenalex-snapshot

Supramolecular chiroptical switches

inferred← citeshttps://doi.org/10.1039/d2dt02665aopenalex-snapshot

Inherently chiral helicene-substituted thioalkyl porphyrazine complexes: synthesis and electronic and chiroptical properties

inferred← citeshttps://doi.org/10.1039/d4sc03578jopenalex-snapshot

Fast photochromism of helicene-bridged imidazole dimers

inferred← citeshttps://doi.org/10.1039/d6sc00729eopenalex-snapshot

CPL-active supramolecular polymers

inferred← citeshttps://doi.org/10.1246/bcsj.20200181openalex-snapshot

Helical Pitch Dependent Optical Properties of π-Extended Aza[5]helicene Radical Cations

inferred← citeshttps://doi.org/10.3389/fchem.2020.00237openalex-snapshot

Chiral Diketopyrrolopyrrole-Helicene Polymer With Efficient Red Circularly Polarized Luminescence

inferred← citeshttps://doi.org/10.3389/fchem.2022.860398openalex-snapshot

Central-to-Folding Chirality Control: Asymmetric Synthesis of Multilayer 3D Targets With Electron-Deficient Bridges

inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.72.280openalex-snapshot

Helical Chirality Control of Oligopyrroles

inferred← citeshttps://doi.org/10.70675/10f13f92z1088z4b6czb380z47b47b74803bopenalex-snapshot

Helicene-porphyrin conjugates : exciton coupling and chiral-Induced spin selectivity

inferred← citeshttps://doi.org/10.70675/16c3d235z562dz4388z9b9bz58b1caa675bfopenalex-snapshot

Systèmes pi-conjugués hélicèniques émetteurs de lumière circulairement polarisée

inferred← citeshttps://doi.org/10.70675/1a27990eze4c1z4d0fz98d9z37895c44b657openalex-snapshot

Supramolecular assemblies with organophosphorated based derivatives for potential applications in optoelectronics

inferred← citeshttps://doi.org/10.70675/7751da7cz3eb1z46c5zaffez28bbca067b7bopenalex-snapshot

Chiral complexes based on helicenic N-heterocyclic carbenes : synthesis, structure, photophysical and chiroptical properties

inferred← citeshttps://doi.org/10.70675/e15431abzf627z4c13z86bazc00d5f0dc6a6openalex-snapshot

Distorted arenes by Scholl cyclizations, towards twisted carbon nanoribbons

inferred← citeshttps://doi.org/10.70675/ea0cdc3cze4f5z4a8fzad55zdf0afc0b46d2openalex-snapshot

Asymmetric C(sp2)–H activation for the synthesis of original materials

inferred← citeshttps://doi.org/10.70675/fd0fa139z0c11z4d34z9d1fz3d1d2a7e4031openalex-snapshot

Helicenes for chiral molecular switches, magnetic materials, and chiral fullerene derivatives

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