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Highly Enantioselective Construction of Trifluoromethylated All-Carbon Quaternary Stereocenters via Nickel-Catalyzed Friedel–Crafts Alkylation Reaction

https://doi.org/10.1021/ja400650m
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Incoming claims: where this work appears in other papers’ reference lists and arguments.

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ChemInform Abstract: Highly Enantioselective Construction of Trifluoromethylated All‐Carbon Quaternary Stereocenters via Nickel‐Catalyzed Friedel—Crafts Alkylation Reaction.
inferred← citeshttps://doi.org/10.1002/cjoc.201800070openalex-snapshot
Copper(I)‐Catalyzed Asymmetric [3+2]‐Cycloaddition of α ‐Substituted Iminoesters with α ‐Trifluoromethyl α, β ‐Unsaturated Esters
inferred← citeshttps://doi.org/10.1002/cjoc.202100018openalex-snapshot
New Amines and Activation Modes in Asymmetric Aminocatalysis
inferred← citeshttps://doi.org/10.1002/ejoc.201402243openalex-snapshot
Highly Enantioselective Michael Addition of Malonates to β‐CF3‐β‐(3‐Indolyl)nitroalkenes: Construction of Trifluoromethylated All‐Carbon Quaternary Stereogenic Centres
inferred← citeshttps://doi.org/10.1002/ejoc.201403682openalex-snapshot
Remote Amide‐Controlled Gold‐Catalyzed Stereoselective Hydro‐heteroarylation of Acrylamides: Access to Pyrido[3,4‐b]indoles
inferred← citeshttps://doi.org/10.1002/ejoc.201601540openalex-snapshot
Nickel(II)‐Catalyzed Enantioselective 1,3‐Dipolar Cycloaddition of Nitrones with α,β‐Unsaturated Acylcarboxylates
inferred← citeshttps://doi.org/10.1002/ejoc.201700510openalex-snapshot
In Pursuit of β‐Amino‐α‐nitro‐β‐(trifluoromethyl) Ketones: Nitro‐Mannich versus Mannich‐Type Reactions
inferred← citeshttps://doi.org/10.1002/ejoc.202300428openalex-snapshot
Rh‐Catalyzed Hydroheteroarylation of Styrenes: Access to Alkylated Heteroarenes with All‐Carbon Quaternary Centers
inferred← citeshttps://doi.org/10.1002/ejoc.202401168openalex-snapshot
Modern Approaches for Asymmetric Construction of CF3‐All Carbon Quaternary Stereocenters from Prochiral Trifluoromethyl Alkenes
inferred← citeshttps://doi.org/10.1002/ejoc.202500500openalex-snapshot
Substrate Divergent 4π/6π Electrocyclization of CF3‐Quinolone Heterodendralenes
inferred← citeshttps://doi.org/10.1002/jcc.24877openalex-snapshot
Mechanistic investigation inspired “on water” reaction for hydrobromic acid‐catalyzed Friedel–Crafts–type reaction of β‐naphthol and formaldehyde
inferred← citeshttps://doi.org/10.1002/slct.201800113openalex-snapshot
Enantioselective Addition of Cyanide to CF 3 ‐Substituted Alkylidenemalonates: Construction of Trifluoromethylated All‐Carbon Quaternary Stereocenters
inferred← citeshttps://doi.org/10.1002/slct.202102134openalex-snapshot
A Highly Enantioselective Approach to Hydrocarbazole Derivatives Catalyzed by Diphenylmethylidene Bis(oxazoline)‐Ni(II) Complexes
inferred← citeshttps://doi.org/10.1007/s10562-014-1228-2openalex-snapshot
Chiral Bis(Oxazolinyl)thiophenes for Enantioselective Cu(II)-Catalyzed Friedel–Crafts Alkylation of Indole Derivatives with Nitroalkenes
inferred← citeshttps://doi.org/10.1007/s10593-016-1971-yopenalex-snapshot
3-Nitro-2-phenyl-2-(trifluoromethyl)-2H-chromenes: synthesis and reactions with nucleophiles
inferred← citeshttps://doi.org/10.1007/s40242-016-5482-2openalex-snapshot
Iron chloride hexahydrate-catalyzed Friedel-Crafts akylation of cyclic ketene dithioacetals with alcohols
inferred← citeshttps://doi.org/10.1016/b978-0-08-100017-5.00006-6openalex-snapshot
Five-Membered Ring Systems
inferred← citeshttps://doi.org/10.1016/b978-0-12-409547-2.14853-xopenalex-snapshot
Prroles and Their Benzo Derivatives: Reactivity
inferred← citeshttps://doi.org/10.1016/b978-0-32-390644-9.00056-1openalex-snapshot
Olefins Hydrofunctionnalization; Hydroarylation (Vinylation, Alkynylation) of Electron Deficient Olefins
inferred← citeshttps://doi.org/10.1016/b978-0-443-18939-5.00006-8openalex-snapshot
Five-membered ring systems: pyrroles and benzo analogs
inferred← citeshttps://doi.org/10.1016/j.catcom.2014.04.013openalex-snapshot
Synthesis of chiral benzene-based tetraoxazolines and their application in asymmetric Friedel–Crafts alkylation of indole derivatives with nitroalkenes
inferred← citeshttps://doi.org/10.1016/j.cclet.2021.10.062openalex-snapshot
Highly enantioselective construction of CF3-bearing all-carbon quaternary stereocenters: Chiral spiro-fused bisoxazoline ligands with 1,1′-binaphthyl sidearm for asymmetric Michael-type Friedel-Crafts reaction
inferred← citeshttps://doi.org/10.1016/j.inoche.2013.11.021openalex-snapshot
A trinuclear Cu2Eu complex catalyzed asymmetric Friedel–Crafts alkylations of indoles with nitroalkenes
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2014.10.002openalex-snapshot
Palladium-catalyzed allylation of trifluoromethylated ketene aminoacetals
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2015.01.015openalex-snapshot
A practical synthesis of trifluoromethyl alkyl ketones
inferred← citeshttps://doi.org/10.1016/j.jfluchem.2015.05.011openalex-snapshot
Organocatalytic enantioselective Diels–Alder reaction of 4,4,4-trifluorocrotonaldehyde
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2018.10.011openalex-snapshot
Organometal-catalyzed asymmetric Friedel-Crafts reactions
inferred← citeshttps://doi.org/10.1016/j.jorganchem.2024.123377openalex-snapshot
Enantioselective Friedel-Crafts alkylation of 1,3,5-trimethoxybenzene with trans-β-nitrostyrenes catalysed by [Cp*Rh{(R)-Prophos}(H2O)][SbF6]2 (Prophos = propane-1,2-diyl-bis(diphenylphosphane)
inferred← citeshttps://doi.org/10.1016/j.tet.2014.05.017openalex-snapshot
Highly selective trifluoroacetic ester/ketone metathesis: an efficient approach to trifluoromethyl ketones and esters
inferred← citeshttps://doi.org/10.1016/j.tet.2014.12.020openalex-snapshot
Heteroarylidene-tethered bis(oxazoline) copper complexes catalyzed cascade reaction involving asymmetric Friedel–Crafts alkylation/N-hemiacetalization of indoles with β,γ-unsaturated α-ketoester
inferred← citeshttps://doi.org/10.1016/j.tet.2016.09.002openalex-snapshot
All-carbon quaternary centers in natural products and medicinal chemistry: recent advances
inferred← citeshttps://doi.org/10.1016/j.tet.2018.07.011openalex-snapshot
Critical view on the recent enantioselective synthesis of alcohols, amines and related molecules having tertiary benzylic stereocenter
inferred← citeshttps://doi.org/10.1016/j.tet.2020.131897openalex-snapshot
Mg/BOX complexes as efficient catalysts for the enantioselective Michael addition of malonates to β-trifluoromethyl-α,β-unsaturated ketones and their N-tosyl imines
inferred← citeshttps://doi.org/10.1016/j.tetasy.2014.05.005openalex-snapshot
Enantioselective aldol reactions of α,β-unsaturated ketones with trifluoroacetophenone catalyzed by a chiral primary amine
inferred← citeshttps://doi.org/10.1016/j.tetlet.2016.05.062openalex-snapshot
DBSA-catalyzed Friedel–Crafts alkylation of cyclic ketene dithioacetals with alcohols in water
inferred← citeshttps://doi.org/10.1016/j.tetlet.2018.01.090openalex-snapshot
Base-catalyzed cascade 1,6-sulfur-Michael/Henry reaction of trifluoromethyl-substituted styrylisoxazoles: Diastereoselective synthesis of tetrahydrothiophenes with a trifluoromethylated quaternary center
inferred← citeshttps://doi.org/10.1016/j.tetlet.2020.152443openalex-snapshot
Organocatalytic enantioselective conjugate addition of nitroalkanes to trifluoromethylated 3-methyleneoxindoles
inferred← citeshttps://doi.org/10.1016/j.tetlet.2026.156254openalex-snapshot
Beyond traditional Pictet–Spengler cyclization: aromatic amines as emerging cyclization partners
inferred← citeshttps://doi.org/10.1021/acs.chemrev.0c00844openalex-snapshot
Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis
inferred← citeshttps://doi.org/10.1021/acs.chemrev.7b00385openalex-snapshot
Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis
inferred← citeshttps://doi.org/10.1021/acs.joc.0c00336openalex-snapshot
Synthesis of Chiral Bis(3-indolyl)methanes Bearing a Trifluoromethylated All-Carbon Quaternary Stereocenter via Nickel-Catalyzed Asymmetric Friedel–Crafts Alkylation Reaction
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02412openalex-snapshot
HFIP as Protonation Reagent and Solvent for Regioselective Alkylation of Indoles with All-Carbon Centers
inferred← citeshttps://doi.org/10.1021/acs.joc.4c02519openalex-snapshot
Visible-Light-Induced Markovnikov Hydroalkoxylation of α-Trifluoromethyl Alkenes with ortho-Diketones
inferred← citeshttps://doi.org/10.1021/acs.joc.5b02848openalex-snapshot
Organocatalytic Asymmetric Synthesis of Dihydrobenzoxazinones Bearing Trifluoromethylated Quaternary Stereocenters
inferred← citeshttps://doi.org/10.1021/acs.joc.5c01670openalex-snapshot
Catalyst-Free Synthesis of Trifluoromethylated Five- and Seven-Membered Nitrogen-Containing Heterocycles via Aza-Michael Addition and Lactamization of Trifluoroethylene Oxindoles
inferred← citeshttps://doi.org/10.1021/acs.joc.6b00123openalex-snapshot
Enantioselective Friedel–Crafts Alkylation Reactions of 3-Substituted Indoles with Electron-Deficient Alkenes
inferred← citeshttps://doi.org/10.1021/acs.joc.6b00358openalex-snapshot
Lewis Acid Catalyzed Friedel–Crafts Alkylation of Alkenes with Trifluoropyruvates
inferred← citeshttps://doi.org/10.1021/acs.joc.6b00855openalex-snapshot
Synthesis of (Z)-α-Trifluoromethyl Alkenyl Triflate: A Scaffold for Diverse Trifluoromethylated Species
inferred← citeshttps://doi.org/10.1021/acs.joc.6b00930openalex-snapshot
Visible Light-Induced Photoredox Construction of Trifluoromethylated Quaternary Carbon Centers from Trifluoromethylated Tertiary Bromides
inferred← citeshttps://doi.org/10.1021/acs.joc.6b01950openalex-snapshot
Construction of Furan Derivatives with a Trifluoromethyl Stereogenic Center: Enantioselective Friedel–Crafts Alkylations via Formal Trienamine Catalysis
inferred← citeshttps://doi.org/10.1021/acs.joc.7b01014openalex-snapshot
Enantioselective Conjugate Addition of 2-Acetyl Azaarenes to β,β-Disubstituted Nitroalkene for the Construction of All-Carbon Quaternary Stereocenters
inferred← citeshttps://doi.org/10.1021/acs.joc.8b00387openalex-snapshot
Mechanism and Origins of Stereoinduction in an Asymmetric Friedel–Crafts Alkylation Reaction of Chalcone Catalyzed by Chiral N,N′-Dioxide–Sc(III) Complex
inferred← citeshttps://doi.org/10.1021/acs.joc.8b00612openalex-snapshot
Enantioselective Synthesis of 2-Amino-1,1-diarylalkanes Bearing a Carbocyclic Ring Substituted Indole through Asymmetric Catalytic Reaction of Hydroxyindoles with Nitroalkenes
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02405openalex-snapshot
Visible Light-Induced Radical Cyclization of Tertiary Bromides with Isonitriles To Construct Trifluoromethylated Quaternary Carbon Center
inferred← citeshttps://doi.org/10.1021/acs.joc.8b02601openalex-snapshot
Asymmetric Michael Addition of 2-Acetyl Azaarenes to β-CF3-β-(3-indolyl)nitroalkenes Catalyzed by a Cobalt(II)/(imidazoline-oxazoline) Complex
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c00465openalex-snapshot
Nickel-Catalyzed Asymmetric Friedel–Crafts Propargylation of 3-Substituted Indoles with Propargylic Carbonates Bearing an Internal Alkyne Group
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c00612openalex-snapshot
Activation of Chiral (Salen)TiCl2 Complex by Phosphorane for the Highly Enantioselective Cyanation of Nitroolefins
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c03100openalex-snapshot
Iridium-Catalyzed Asymmetric Cascade Allylation/Lactonization of Indole Esters: Access to Chiral Tricyclic Oxazinoindolones
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c00656openalex-snapshot
Phosphine-Catalyzed Domino Annulation of γ-Vinyl Allenoates: Synthesis of Tetrahydrofuro[3,2-c]quinoline Derivatives
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b00077openalex-snapshot
Enantioselective Direct Functionalization of Indoles by Pd/Sulfoxide-Phosphine-Catalyzed N-Allylic Alkylation
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b01799openalex-snapshot
Highly Enantioselective Cascade Reaction Catalyzed by Squaramides: the Synthesis of CF3-Containing Chromanes
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c01864openalex-snapshot
Chiral Phosphoric Acid-Catalyzed Enantioselective Pictet–Spengler Reaction for Concise Synthesis of CF3-Substituted Tetrahydro-β-Carbolines
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b00781openalex-snapshot
Friedel–Crafts Alkylation of Indoles with p-Quinols: The Role of Hydrogen Bonding of Water for the Desymmetrization of the Cyclohexadienone System
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b01317openalex-snapshot
Cu(I)-Catalyzed Enantioselective Friedel–Crafts Alkylation of Indoles with 2-Aryl-N-sulfonylaziridines as Alkylating Agents
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b01494openalex-snapshot
Catalytic Enantioselective Conjugate Alkynylation of β-Aryl-β-trifluoromethyl Enones Constructing Propargylic All-Carbon Quaternary Stereogenic Centers
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b01498openalex-snapshot
Asymmetric Synthesis of CF3- and Indole-Containing Thiochromanes via a Squaramide-Catalyzed Michael–Aldol Reaction
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b02540openalex-snapshot
Enantioselective Synthesis of Quaternary Stereocenters via Chromium Catalysis
inferred← citeshttps://doi.org/10.1021/acs.orglett.6b03584openalex-snapshot
Catalytic Asymmetric Synthesis of Chiral 2-Vinylindole Scaffolds by Friedel–Crafts Reaction
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b03941openalex-snapshot
Rhodium-Catalyzed Asymmetric Arylative Ring-Opening Reactions of Heterobicyclic Alkenes with Anilines
inferred← citeshttps://doi.org/10.1021/acs.orglett.7b04039openalex-snapshot
Asymmetric Construction of Fluoroalkyl Tertiary Alcohols through a Three-Component Reaction of (Bpin)2, 1,3-Enynes, and Fluoroalkyl Ketones Catalyzed by a Copper(I) Complex
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b00925openalex-snapshot
Direct Asymmetric Formal [3 + 2] Cycloaddition Reaction of Isocyanoesters with β-Trifluoromethyl β,β -Disubstituted Enones Leading to Optically Active Dihydropyrroles
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b00963openalex-snapshot
Asymmetric Synthesis of β-Indolyl Cyclopentanones and Cyclopentylamides with an All-Carbon Quaternary Stereocenter via Chiral Phosphoric Acid Catalyzed Friedel–Crafts Alkylation Reactions
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b03758openalex-snapshot
One-Pot Enantioselective Synthesis of 2-Pyrrolidinone Derivatives Bearing a Trifluoromethylated All-Carbon Quaternary Stereocenter
inferred← citeshttps://doi.org/10.1021/acscatal.2c03330openalex-snapshot
Leveraging the Hydroarylation of α-(Trifluoromethyl)styrenes to Access Trifluoromethylated All-Carbon Quaternary Centers
inferred← citeshttps://doi.org/10.1021/acscatal.6b02080openalex-snapshot
Restricted Conformation of a Hydrogen Bond Mediated Catalyst Enables the Highly Efficient Enantioselective Construction of an All-Carbon Quaternary Stereocenter
inferred← citeshttps://doi.org/10.1021/acscatal.6b03015openalex-snapshot
Copper(I)/Ming-Phos-Catalyzed Asymmetric Intermolecular [3 + 2] Cycloaddition of Azomethine Ylides with α-Trifluoromethyl α, β-Unsaturated Esters
inferred← citeshttps://doi.org/10.1021/acscatal.9b01502openalex-snapshot
Chiral Spiro Phosphoric Acid-Catalyzed Friedel–Crafts Conjugate Addition/Enantioselective Protonation Reactions
inferred← citeshttps://doi.org/10.1021/acscatal.9b01811openalex-snapshot
Enantioselective Friedel–Crafts Alkylation Reaction of Indoles with α-Trifluoromethylated β-Nitrostyrenes Catalyzed by Chiral BINOL Metal Phosphate
inferred← citeshttps://doi.org/10.1021/acsomega.0c03485openalex-snapshot
Catalytic Enantioselective Alkylation of Indoles with trans -4-Methylthio-β-Nitrostyrene
inferred← citeshttps://doi.org/10.1021/acsorginorgau.5c00039openalex-snapshot
Transfer Hydrogenation of β-Trifluoromethylated Nitroalkenes Catalyzed by Chiral Calcium Phosphate
inferred← citeshttps://doi.org/10.1021/cr400676vopenalex-snapshot
Synthetic Approaches to 3-(2-Nitroalkyl) Indoles and Their Use to Access Tryptamines and Related Bioactive Compounds
inferred← citeshttps://doi.org/10.1021/ja403852eopenalex-snapshot
Practical Selective Hydrogenation of α-Fluorinated Esters with Bifunctional Pincer-Type Ruthenium(II) Catalysts Leading to Fluorinated Alcohols or Fluoral Hemiacetals
inferred← citeshttps://doi.org/10.1021/ja507788ropenalex-snapshot
Gold-Catalyzed Hydroarylation of Alkenes with Dialkylanilines
inferred← citeshttps://doi.org/10.1021/jacs.1c12040openalex-snapshot
A New Organocatalytic Desymmetrization Reaction Enables the Enantioselective Total Synthesis of Madangamine E
inferred← citeshttps://doi.org/10.1021/jacs.7b04374openalex-snapshot
Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C–H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation
inferred← citeshttps://doi.org/10.1021/jacs.7b12137openalex-snapshot
Enantioselective Regiodivergent Synthesis of Chiral Pyrrolidines with Two Quaternary Stereocenters via Ligand-Controlled Copper(I)-Catalyzed Asymmetric 1,3-Dipolar Cycloadditions
inferred← citeshttps://doi.org/10.1021/jo402212jopenalex-snapshot
Organocatalytic Reactions of α-Trifluoromethylated Esters with Terminal Alkenes at Room Temperature
inferred← citeshttps://doi.org/10.1021/ol403480vopenalex-snapshot
Asymmetric Friedel–Crafts Alkylation of α-Substituted β-Nitroacrylates: Access to β 2,2 -Amino Acids Bearing Indolic All-Carbon Quaternary Stereocenters
inferred← citeshttps://doi.org/10.1021/ol500157bopenalex-snapshot
Highly Enantioselective Organocatalyzed Vinylogous Michael-Type Reaction for the Construction of Trifluoromethylated All-Carbon Quaternary Stereocenters
inferred← citeshttps://doi.org/10.1021/ol502941dopenalex-snapshot
Efficient and Highly Enantioselective Construction of Trifluoromethylated Quaternary Stereogenic Centers via High-Pressure Mediated Organocatalytic Conjugate Addition of Nitromethane to β,β-Disubstituted Enones
inferred← citeshttps://doi.org/10.1021/ol503067gopenalex-snapshot
Amide Groups Switch Selectivity: C–H Trifluoromethylation of α,β-Unsaturated Amides and Subsequent Asymmetric Transformation
inferred← citeshttps://doi.org/10.1021/ol5035222openalex-snapshot
Chiral Phosphoric Acid Catalyzed Highly Enantioselective Friedel–Crafts Alkylation Reaction of C3-Substituted Indoles to β,γ-Unsaturated α-Ketimino Esters
inferred← citeshttps://doi.org/10.1021/om401125qopenalex-snapshot
Metal–Nitroalkene and aci -Nitro Intermediates in Catalytic Enantioselective Friedel–Crafts Reactions of Indoles with trans -β-Nitrostyrenes
inferred← citeshttps://doi.org/10.1038/s41598-023-41921-9openalex-snapshot
Catalytic asymmetric Friedel–Crafts alkylation of unprotected indoles with nitroalkenes using a novel chiral Yb(OTf)3–pybox complex
inferred← citeshttps://doi.org/10.1039/9781782621966-00214openalex-snapshot
Asymmetric Friedel–Crafts Alkylation Reactions
inferred← citeshttps://doi.org/10.1039/9781782626701-00310openalex-snapshot
Enantioselective Nickel-Catalysed Miscellaneous Reactions
inferred← citeshttps://doi.org/10.1039/c3ob42329hopenalex-snapshot
Enantioselective organocatalytic oxa-Michael addition of oximes to β-CF 3 -β-disubstituted nitroalkenes: efficient synthesis of β-amino-α-trifluoromethyl alcohols
inferred← citeshttps://doi.org/10.1039/c3sc52548aopenalex-snapshot
Effect of the trifluoromethyl group on torquoselectivity in the 4π ring-opening reaction of oxetenes: stereoselective synthesis of tetrasubstituted olefins
inferred← citeshttps://doi.org/10.1039/c3sc53542hopenalex-snapshot
Stereoselective construction of all-carbon quaternary center by means of chiral phosphoric acid: highly enantioselective Friedel–Crafts reaction of indoles with β,β-disubstituted nitroalkenes
inferred← citeshttps://doi.org/10.1039/c4cc07801bopenalex-snapshot
Catalytic highly enantioselective transfer hydrogenation of β-trifluoromethyl nitroalkenes. An easy and general entry to optically active β-trifluoromethyl amines
inferred← citeshttps://doi.org/10.1039/c4ob01144aopenalex-snapshot
Fluorous chiral bisoxazolines: application in copper-catalyzed asymmetric α-hydrophosphonylation
inferred← citeshttps://doi.org/10.1039/c4ob01920bopenalex-snapshot
1,4 Addition of unprotected pyrrole onto chiral acrylamides: toward synthesis of new polypeptidic architectures
inferred← citeshttps://doi.org/10.1039/c4qo00265bopenalex-snapshot
Enantioselective Friedel–Crafts reaction of 4,7-dihydroindoles with β-CF 3 -β-disubstituted nitroalkenes
inferred← citeshttps://doi.org/10.1039/c4ra00701hopenalex-snapshot
Enantioselective synthesis of N-allylindoles via palladium-catalyzed allylic amination/oxidation of indolines
inferred← citeshttps://doi.org/10.1039/c4ra03269aopenalex-snapshot
Bis(oxazoline)-copper catalyzed enantioselective hydrophosphonylation of aldehydes
inferred← citeshttps://doi.org/10.1039/c5cc08480fopenalex-snapshot
An efficient approach for the construction of trifluoromethylated all-carbon quaternary stereocenters: enantioselective Ni( ii )-catalyzed Michael addition of 2-acetyl azaarene to β,β-disubstituted nitroalkenes
inferred← citeshttps://doi.org/10.1039/c5nj01488copenalex-snapshot
A Ce(OTf) 3 /PyBox catalyzed enantioselective Hosomi–Sakurai reaction of aldehydes with allyltrimethylsilane
inferred← citeshttps://doi.org/10.1039/c6ob00119jopenalex-snapshot
The squaramide-catalyzed asymmetric Michael/cyclization tandem reaction for the synthesis of chiral trifluoromethylated hydroxyimino tetrahydrobenzofuranones
inferred← citeshttps://doi.org/10.1039/c6qo00273kopenalex-snapshot
Enantioselective β-alkylation of pyrroles with the formation of an all-carbon quaternary stereocenter
inferred← citeshttps://doi.org/10.1039/c6ra00093bopenalex-snapshot
Catalytic asymmetric synthesis of enantioenriched β-nitronitrile bearing a C-CF 3 stereogenic center
inferred← citeshttps://doi.org/10.1039/c7cc03015kopenalex-snapshot
Copper( i )-catalyzed asymmetric exo-selective [3+2] cycloaddition of azomethine ylides with β-trifluoromethyl β,β-disubstituted enones
inferred← citeshttps://doi.org/10.1039/c7ob00413copenalex-snapshot
Recent progress in transition-metal-catalyzed enantioselective indole functionalizations
inferred← citeshttps://doi.org/10.1039/c7ob00595dopenalex-snapshot
Copper-catalysed enantioselective Michael addition of malonic esters to β-trifluoromethyl-α,β-unsaturated imines
inferred← citeshttps://doi.org/10.1039/c7ob00970dopenalex-snapshot
Palladium-catalyzed geometrically selective hydrogenation of (Z)-trifluoromethyl alkenyl triflate: an efficient approach to (Z) or (E)-3,3,3-trifluoropropenyl derivatives
inferred← citeshttps://doi.org/10.1039/c7qo00229gopenalex-snapshot
Asymmetric synthesis of CF 3 - and indole-containing tetrahydro-β-carbolines via chiral spirocyclic phosphoric acid-catalyzed aza-Friedel–Crafts reaction
inferred← citeshttps://doi.org/10.1039/c7qo00291bopenalex-snapshot
Cu( i )-catalyzed Michael addition of ketiminoesters to β-trifluoromethyl β,β-disubstituted enones: rapid access to 1-pyrrolines bearing a quaternary all-carbon stereocenter
inferred← citeshttps://doi.org/10.1039/c8cc03447hopenalex-snapshot
Highly enantioselective Friedel–Crafts alkylation of N , N -dialkylanilines with trans -β-nitrostyrene catalyzed by a homochiral metal–organic framework
inferred← citeshttps://doi.org/10.1039/c8qo00932eopenalex-snapshot
Regioselective indole C2-alkylation using β-CF 3 -substituted enones under redox neutral Rh( iii ) catalysis
inferred← citeshttps://doi.org/10.1039/c9gc03345aopenalex-snapshot
Metal-free graphene oxide-catalyzed aza-semipinacol rearrangement to prepare 2-(indol-2-yl)phenols and benzofuro[3,2- b ]indolines containing quaternary carbon centers
inferred← citeshttps://doi.org/10.1039/c9qo01203fopenalex-snapshot
The enantioselective construction of trifluoromethylated quaternary stereocenters via the Rh-catalyzed asymmetric dehydrated arylation of unprotected hemiaminals
inferred← citeshttps://doi.org/10.1039/c9sc01446bopenalex-snapshot
Nickel-catalyzed C–H alkylation of indoles with unactivated alkyl chlorides: evidence of a Ni( i )/Ni( iii ) pathway
inferred← citeshttps://doi.org/10.1039/c9sc04858hopenalex-snapshot
Chiral cis -iron( ii ) complexes with metal- and ligand-centered chirality for highly regio- and enantioselective alkylation of N-heteroaromatics
inferred← citeshttps://doi.org/10.1039/d0ob00004copenalex-snapshot
Enantioselective synthesis of trifluoromethyl substituted cyclohexanones via an organocatalytic cascade Michael/aldol reaction
inferred← citeshttps://doi.org/10.1039/d0ob00956copenalex-snapshot
Synthesis and practical applications of 2-(2-nitroalkyl)pyrroles
inferred← citeshttps://doi.org/10.1039/d1ob01238jopenalex-snapshot
Enantioselective Friedel–Crafts reaction of hydroxyarenes with nitroenynes to access chiral heterocycles via sequential catalysis
inferred← citeshttps://doi.org/10.1039/d2qo01982eopenalex-snapshot
Asymmetric synthesis of 7-membered-ring-bridged 3,4-fused tricyclic indoles via Friedel–Crafts alkylation/annulation
inferred← citeshttps://doi.org/10.1039/d4qo00555dopenalex-snapshot
Acid–solvent cluster-catalyzed general and regioselective Friedel–Crafts arylation of alcohols
inferred← citeshttps://doi.org/10.1039/d4qo01942copenalex-snapshot
Organocatalytic enantioselective [2 + 2] cycloadditions towards chiral fused α-trifluoromethyl azetidines
inferred← citeshttps://doi.org/10.1055/a-2921-6973openalex-snapshot
Enantioselective Construction of Trifluoromethylated Quaternary Centers via NHC-Catalyzed Cross-Annulation Reaction
inferred← citeshttps://doi.org/10.1055/s-0040-1719879openalex-snapshot
Chiral Calcium Phosphate Catalyzed Enantioselective Synthesis of All-Carbon Quaternary Center by Friedel–Crafts Alkylation Reaction of Pyrroles and Trifluoromethylated Nitrostyrenes
inferred← citeshttps://doi.org/10.1055/s-0040-1720139openalex-snapshot
Visible-Light-Induced Photoredox Construction of Trifluoromethylated Quaternary All-Carbon Centers and Tertiary Alcohols via C(sp3)–Si Bond Cleavage
inferred← citeshttps://doi.org/10.1093/nsr/nwx058openalex-snapshot
China's flourishing synthetic organofluorine chemistry: innovations in the new millennium
inferred← citeshttps://doi.org/10.1134/s1070428016100018openalex-snapshot
1-Bromo-3,3,3-trifluoro-1-nitropropene: Synthesis and reaction with phenyl azide
inferred← citeshttps://doi.org/10.3184/174751918x15240724383170openalex-snapshot
Michael Addition of Aryl Thiols to 3-(2,2,2-Trifluoroethylidene)Oxindoles under Catalyst-Free Conditions: The Rapid Synthesis of Sulfur-Containing Oxindole Derivatives
inferred← citeshttps://doi.org/10.3390/molecules21060699openalex-snapshot
The Chiral Pool in the Pictet–Spengler Reaction for the Synthesis of β-Carbolines
inferred← citeshttps://doi.org/10.3390/molecules21081000openalex-snapshot
A General Catalytic Enantioselective Transfer Hydrogenation Reaction of β,β-Disubstituted Nitroalkenes Promoted by a Simple Organocatalyst
inferred← citeshttps://doi.org/10.3390/molecules25020414openalex-snapshot
The Pictet-Spengler Reaction Updates Its Habits
inferred← citeshttps://doi.org/10.3390/molecules26237408openalex-snapshot
Exploiting the Chiral Ligands of Bis(imidazolinyl)- and Bis(oxazolinyl)thiophenes—Synthesis and Application in Cu-Catalyzed Friedel–Crafts Asymmetric Alkylation
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