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A Bio-Inspired, Small Molecule Electron-Coupled-Proton Buffer for Decoupling the Half-Reactions of Electrolytic Water Splitting

https://doi.org/10.1021/ja4071893
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Outgoing claims: the papers this work cites, builds on, or argues with.

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Electrochemical reactions with protonations at equilibrium
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Characterization of electrochemically pretreated glassy carbon electrodes
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Solar Fuels via Artificial Photosynthesis
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Semiconductor-based Photocatalytic Hydrogen Generation
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Artificial photosynthesis for solar fuels
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Resistance and polarization losses in aqueous buffer–membrane electrolytes for water-splitting photoelectrochemical cells
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Powering the planet: Chemical challenges in solar energy utilization
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Improving the efficiency of water splitting in dye-sensitized solar cells by using a biomimetic electron transfer mediator
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Mechanism of proton-coupled quinone reduction in Photosystem II
inferredcites →https://doi.org/10.1109/jproc.2011.2156750openalex-snapshot
Hydrogen Production From Water Electrolysis: Current Status and Future Trends
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Energy Converting NADH: Quinone Oxidoreductase (Complex I)
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CRC Handbook of Chemistry and Physics

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A General Strategy for Decoupled Hydrogen Production from Water Splitting by Integrating Oxidative Biomass Valorization
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Anion−π Complexes of Halides with p ‑Benzoquinones: Structures, Thermodynamics, and Criteria of Charge Transfer to Electron Transfer Transition
inferred← citeshttps://doi.org/10.1021/jacsau.4c00710openalex-snapshot
Decoupling Electrolytic Water Splitting by an Oxygen-Mediating Process
inferred← citeshttps://doi.org/10.1038/s41563-023-01767-yopenalex-snapshot
Electrochemical and chemical cycle for high-efficiency decoupled water splitting in a near-neutral electrolyte
inferred← citeshttps://doi.org/10.1038/s41570-016-0003openalex-snapshot
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
inferred← citeshttps://doi.org/10.1038/s41586-022-04874-zopenalex-snapshot
Electrocatalytic metal hydride generation using CPET mediators
inferred← citeshttps://doi.org/10.1038/s44359-025-00061-1openalex-snapshot
Technologies and prospects for decoupled and membraneless water electrolysis
inferred← citeshttps://doi.org/10.1039/c4dt03826fopenalex-snapshot
A silver-alkynyl cluster encapsulating a fluorescent polyoxometalate core: enhanced emission and fluorescence modulation
inferred← citeshttps://doi.org/10.1039/c5ee00161gopenalex-snapshot
Metal organic frameworks for photo-catalytic water splitting
inferred← citeshttps://doi.org/10.1039/c6dt00522eopenalex-snapshot
Electrochemical and chemical routes to hydride loss from an iridium dihydride
inferred← citeshttps://doi.org/10.1039/c6dt03658aopenalex-snapshot
Photochemical water splitting mediated by a C1 shuttle
inferred← citeshttps://doi.org/10.1039/c6ta03123dopenalex-snapshot
Quinone and its derivatives for energy harvesting and storage materials
inferred← citeshttps://doi.org/10.1039/c7cc09036fopenalex-snapshot
Selective hydrogenation of nitroarenes using an electrogenerated polyoxometalate redox mediator
inferred← citeshttps://doi.org/10.1039/c7sc05388fopenalex-snapshot
A practical, organic-mediated, hybrid electrolyser that decouples hydrogen production at high current densities
inferred← citeshttps://doi.org/10.1039/c8cc01830hopenalex-snapshot
Electrocatalytic and photocatalytic hydrogen evolution integrated with organic oxidation
inferred← citeshttps://doi.org/10.1039/c8ra07195kopenalex-snapshot
Highly efficient hydrogen evolution from water electrolysis using nanocrystalline transition metal phosphide catalysts
inferred← citeshttps://doi.org/10.1039/c9ob01323gopenalex-snapshot
Synthesis and electrochromic behavior of a multi-electron redox-active N-heteroheptacenequinone
inferred← citeshttps://doi.org/10.1039/c9ta03285aopenalex-snapshot
Decoupling half-reactions of electrolytic water splitting by integrating a polyaniline electrode
inferred← citeshttps://doi.org/10.1039/c9ta10213bopenalex-snapshot
Low electronegativity Mn bulk doping intensifies charge storage of Ni 2 P redox shuttle for membrane-free water electrolysis
inferred← citeshttps://doi.org/10.1039/d0cc05017bopenalex-snapshot
Ionicity-dependent proton-coupled electron transfer of supramolecular self-assembled electroactive heterocycles
inferred← citeshttps://doi.org/10.1039/d0cs00489hopenalex-snapshot
Redox mediators as charge agents for changing electrochemical reactions
inferred← citeshttps://doi.org/10.1039/d0sc02122aopenalex-snapshot
Visible light-driven simultaneous water oxidation and quinone reduction by a nano-structured conjugated polymer without co-catalysts
inferred← citeshttps://doi.org/10.1039/d1ee01226fopenalex-snapshot
Decoupled electrochemical water-splitting systems: a review and perspective
inferred← citeshttps://doi.org/10.1039/d1ee03982bopenalex-snapshot
Membrane-less amphoteric decoupled water electrolysis using WO 3 and Ni(OH) 2 auxiliary electrodes
inferred← citeshttps://doi.org/10.1039/d1ta04981jopenalex-snapshot
Recent advances in the electrocatalytic synthesis of 2,5-furandicarboxylic acid from 5-(hydroxymethyl)furfural
inferred← citeshttps://doi.org/10.1039/d2ma00185copenalex-snapshot
Low-temperature water electrolysis: fundamentals, progress, and new strategies
inferred← citeshttps://doi.org/10.1039/d2ta01869aopenalex-snapshot
Multifunctional materials for photo-electrochemical water splitting
inferred← citeshttps://doi.org/10.1039/d2ta02374aopenalex-snapshot
Rational design of integrated electrodes for advancing high-rate alkaline electrolytic hydrogen production
inferred← citeshttps://doi.org/10.1039/d2ta06297fopenalex-snapshot
Doped MXene combinations as highly efficient bifunctional and multifunctional catalysts for water splitting and metal–air batteries
inferred← citeshttps://doi.org/10.1039/d3lf00193hopenalex-snapshot
Cobalt–benzimidazole swapped metal–organic macrocycle with reduced graphene oxide as a hybrid electrocatalyst for highly efficient oxygen evolution reaction
inferred← citeshttps://doi.org/10.1039/d3ta07059jopenalex-snapshot
Breaking boundaries: advancements in solid-state redox mediators for decoupled water electrolysis
inferred← citeshttps://doi.org/10.1039/d4ee03084bopenalex-snapshot
Recent advances in innovative systems for electrocatalytic hydrogen production
inferred← citeshttps://doi.org/10.1039/d4gc00227jopenalex-snapshot
Recent progress in transition metal based catalysts and mechanism analysis for alcohol electrooxidation reactions
inferred← citeshttps://doi.org/10.1039/d4sc01613kopenalex-snapshot
Photovoltaic-driven Ni( ii )/Ni( iii ) redox mediator for the valorization of PET plastic waste with hydrogen production
inferred← citeshttps://doi.org/10.1039/d5ta03829dopenalex-snapshot
Redox-mediated bipolar hydrogen production and furoic acid electrosynthesis
inferred← citeshttps://doi.org/10.1039/d5ta08516kopenalex-snapshot
Decoupled water splitting technologies: from redox mediators to renewable energy integration
inferred← citeshttps://doi.org/10.1039/d6sc02664hopenalex-snapshot
Machine learning-accelerated screening of hydroquinone analogs for proton-coupled electron transfer
inferred← citeshttps://doi.org/10.1080/01496395.2026.2632053openalex-snapshot
Amalgamation of electro-catalysts using manganese, iron, and nickel oxide Embedded in g-C 3 N 4 and rGO for efficient water splitting
inferred← citeshttps://doi.org/10.1080/02603594.2021.2013827openalex-snapshot
A Review on Electrochemical and Photochemical Processes for Hydrogen Production
inferred← citeshttps://doi.org/10.1088/2399-1984/ac1db9openalex-snapshot
Recent decoupling and coupling strategies for water splitting
inferred← citeshttps://doi.org/10.1126/sciadv.adi3180openalex-snapshot
Decoupled supercapacitive electrolyzer for membrane-free water splitting
inferred← citeshttps://doi.org/10.1126/science.1257443openalex-snapshot
Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting
inferred← citeshttps://doi.org/10.1515/revic-2024-0057openalex-snapshot
Cutting-edge techniques in low-temperature electrochemical water splitting: advancements in hydrogen production
inferred← citeshttps://doi.org/10.1557/s43581-026-00167-4openalex-snapshot
Bio-derived carbons dramatically enhance decoupled water electrolysis in acidic electrolytes
inferred← citeshttps://doi.org/10.26599/nre.2025.9120201openalex-snapshot
Decoupled water splitting for hydrogen generation
inferred← citeshttps://doi.org/10.33774/chemrxiv-2021-18tthopenalex-snapshot
Electrocatalytic metal hydride generation using concerted proton electron transfer mediators
inferred← citeshttps://doi.org/10.33915/etd.7798openalex-snapshot
Modulation of Semiconductor Photoconversion with Surface Modification and Plasmon
inferred← citeshttps://doi.org/10.37256/ujcs.1220232208openalex-snapshot
H2 as Clean Energy for Sustainable Future
inferred← citeshttps://doi.org/10.3740/mrsk.2016.26.5.241openalex-snapshot
Electrode Properties for Water Electrolysis of Hydrophilic Carbon Paper with Thermal Anneal
inferred← citeshttps://doi.org/10.48550/arxiv.2007.13345openalex-snapshot
Decoupled Water Splitting: From Basic Science to Application
inferred← citeshttps://doi.org/10.5012/bkcs.2014.35.11.3143openalex-snapshot
The Electrochemical Reaction Mechanism and Applications of Quinones
inferred← citeshttps://doi.org/10.5772/intechopen.92854openalex-snapshot
Recent Progress of Electrocatalysts and Photocatalysts Bearing First Row Transition Metal for Hydrogen Evolution Reaction (HER)
inferred← citeshttps://doi.org/10.5796/electrochemistry.20-64070openalex-snapshot
Electrocatalytic Activity of Heteroatom-Doped Graphene for Oxidation of Hydroquinones
inferred← citeshttps://doi.org/10.7454/mss.v20i4.6702openalex-snapshot
The Artificial Leaf: Recent Progress and Remaining Challenges
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