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Secondary Alkene Insertion and Precision Chain-Walking: A New Route to Semicrystalline “Polyethylene” from α-Olefins by Combining Two Rare Catalytic Events

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Olefin Polymerization by Late Transition Metal Complexes-A Root of Ziegler Catalysts Gains New Ground
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Syndiotactic Polymerization of Propylene: Single-Site Vanadium Catalysts in Comparison with Zirconium and Nickel
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Microstructure of Highly Syndiotactic “Living” Poly(propylene)s Produced from a Titanium Complex with Chelating Fluorine-Containing Phenoxyimine Ligands (an FI Catalyst)
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Pd‐Catalyzed Polymerization of Dienes that Involves Chain‐Walking Isomerization of the Growing Polymer End: Synthesis of Polymers Composed of Polymethylene and Five‐Membered‐Ring Units
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Synthesis and characterization of poly(higher‐α‐olefin)s with a nickel(α‐diimine)/methylaluminoxane catalyst system: Effect of chain running on the polymer properties
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Poly(1‐hexene) with long methylene sequences and controlled branches obtained by a thermostable α‐diimine nickel catalyst with bulky camphyl backbone
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Mechanism of stereospecific polymerization of α-olefins by late-transition metal and octahedral group 4 metal catalysts
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INSIGHTS
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CONFRONTING CHEMISTRY
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New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins
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Mechanism of Propylene Insertion Using Bis(phenoxyimine)-Based Titanium Catalysts: An Unusual Secondary Insertion of Propylene in a Group IV Catalyst System
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Living Polymerization of α-Olefins with an α-Diimine Ni(II) Catalyst: Formation of Well-Defined Ethylene−Propylene Copolymers through Controlled Chain-Walking
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Highly Selective Ruthenium Metathesis Catalysts for Ethenolysis
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Isomerization Polymerization of 4-Alkylcyclopentenes Catalyzed by Pd Complexes: Hydrocarbon Polymers with Isotactic-Type Stereochemistry and Liquid-Crystalline Properties
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Living Polymerization of α-Olefins Using NiII−α-Diimine Catalysts. Synthesis of New Block Polymers Based on α-Olefins
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Scope and Limitations of Auxiliary-Assisted, Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 C–H Bonds
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13C NMR Analysis of α-Olefin Enchainment in Poly(α-olefins) Produced with Nickel and Palladium α-Diimine Catalysts
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Rheological Behavior of Chain-Straightened Poly(α-olefin)s
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Chain-Walking Olefin Polymerizations with Donor-Substituted Half-Sandwich Chromium Complexes: Ethylene/Propylene Copolymer Look-Alikes by Polymerization of Propylene
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Molecular Organization in the Pseudo-hexagonal Crystalline Phase of Ethylene−Propylene Copolymers
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Polymerization of Propylene by a New Generation of Iron Catalysts: Mechanisms of Chain Initiation, Propagation, and Termination
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Synthesis of Highly Branched Polyethylene Using “Sandwich” (8- p -Tolyl naphthyl α-diimine)nickel(II) Catalysts
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Recent progress in olefinpolymerization catalyzed by transition metal complexes: new catalysts and new reactions
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Chain Walking: A New Strategy to Control Polymer Topology
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Alpha Olefins Applications Handbook
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Organotransition metal chemistry: from bonding to catalysis

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Branching Regulation in Olefin Polymerization via Lewis Acid Triggered Isomerization of Monomers
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Chain-Walking Polymerization of α-Olefins by α-Diimine Ni(II) Complexes: Effect of Reducing the Steric Hindrance of Ortho- and Para-Aryl Substituents on the Catalytic Behavior, Monomer Enchainment, and Polymer Properties
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Bulky o-Phenylene-Bridged Bimetallic α-Diimine Ni(II) and Pd(II) Catalysts in Ethylene (Co)polymerization
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Nickel-Catalyzed Dimerization of Di- and Trisubstituted Olefins
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Chain-Straightening Polymerization of Olefins to Form Polar Functionalized Semicrystalline Polyethylene
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Ethylene Polymerization and Copolymerization by Palladium and Nickel Catalysts Containing Naphthalene-Bridged Phosphine–Sulfonate Ligands
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Synthesis of Branched Polyethylene with “Half-Sandwich” Pyridine-Imine Nickel Complexes
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Influence of Backbone Substituents on the Ethylene (Co)polymerization Properties of α-diimine Pd(II) and Ni(II) Catalysts
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Synthesis and Properties of “Sandwich” Diimine-Coinage Metal Ethylene Complexes
inferred← citeshttps://doi.org/10.1021/acs.organomet.6b00856openalex-snapshot
Alkene Isomerization by “Sandwich” Diimine-Palladium Catalysts
inferred← citeshttps://doi.org/10.1021/acs.organomet.6c00261openalex-snapshot
Luminescent Three-Coordinate Copper(I) Complexes Supported by an 8-Aryl-1-Naphthyl-Substituted “Sandwich” NacNac Ligand
inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00283openalex-snapshot
(α-Diimine)nickel Complexes That Contain Menthyl Substituents: Synthesis, Conformational Behavior, and Olefin Polymerization Catalysis
inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00294openalex-snapshot
Side-Arm Control in Phosphine-Sulfonate Palladium- and Nickel-Catalyzed Ethylene Polymerization and Copolymerization
inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00698openalex-snapshot
Ethylene Polymerization by Dinuclear Xanthene-Bridged Imino- and Aminopyridyl Nickel Complexes
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00042openalex-snapshot
Chain-Walking Polymerization of Linear Internal Octenes Catalyzed by α-Diimine Nickel Complexes
inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00492openalex-snapshot
C2-Symmetric Hindered “Sandwich” ChiralN-Heterocyclic Carbene Precursors and Their Transition Metal Complexes: Expedient Syntheses, Structural Authentication, and Catalytic Properties
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00106openalex-snapshot
Pentiptycenyl Substituents in Insertion Polymerization with α-Diimine Nickel and Palladium Species
inferred← citeshttps://doi.org/10.1021/acs.organomet.9b00649openalex-snapshot
Ethylene Polymerization with Ni(II) Diimine Complexes Generated from 8-Halo-1-naphthylamines: The Role of Equilibrating Syn / Anti Diastereomers in Determining Polymer Properties
inferred← citeshttps://doi.org/10.1021/acscatal.0c04567openalex-snapshot
Double-Linear Insertion Mode of α,ω-Dienes Enabled by Thio-imino-quinoline Iron Catalyst
inferred← citeshttps://doi.org/10.1021/acscatal.1c03646openalex-snapshot
Redox Potential as a Predictor of Polyethylene Branching Using Nickel α-Diimine Catalysts
inferred← citeshttps://doi.org/10.1021/acscatal.2c04272openalex-snapshot
Advances on Controlled Chain Walking and Suppression of Chain Transfer in Catalytic Olefin Polymerization
inferred← citeshttps://doi.org/10.1021/acscatal.3c02702openalex-snapshot
Norbornene Monomer Effects and Mechanistic Insights in Binuclear Nickel-Catalyzed Olefin Chain Walking Copolymerizations
inferred← citeshttps://doi.org/10.1021/acscatal.4c01248openalex-snapshot
π–π Interactions-Driven Ethylene Polymerization Using “Sandwich” Bis(imino)pyridyl Iron Catalysts
inferred← citeshttps://doi.org/10.1021/acscatal.5b01490openalex-snapshot
Ethylene Polymerization and Copolymerization with Polar Monomers by Cationic Phosphine Phosphonic Amide Palladium Complexes
inferred← citeshttps://doi.org/10.1021/acscatal.5b02216openalex-snapshot
A Career in Catalysis: Maurice Brookhart
inferred← citeshttps://doi.org/10.1021/acscatal.5b02426openalex-snapshot
Palladium and Nickel Catalyzed Chain Walking Olefin Polymerization and Copolymerization
inferred← citeshttps://doi.org/10.1021/acscatal.7b02564openalex-snapshot
Accessing Multiple Catalytically Active States in Redox-Controlled Olefin Polymerization
inferred← citeshttps://doi.org/10.1021/acscatal.7b03282openalex-snapshot
Synthesis of Polyethylenes with Controlled Branching with α-Diimine Nickel Catalysts and Revisiting Formation of Long-Chain Branching
inferred← citeshttps://doi.org/10.1021/acscatal.7b03974openalex-snapshot
Spin-Switching Transmetalation at Ni Diimine Catalysts
inferred← citeshttps://doi.org/10.1021/acscatal.9b02951openalex-snapshot
Alkene Synthesis by Photocatalytic Chemoenzymatically Compatible Dehydrodecarboxylation of Carboxylic Acids and Biomass
inferred← citeshttps://doi.org/10.1021/cs501081aopenalex-snapshot
Ligand-Directed Regioselectivity in Amine–Imine Nickel-Catalyzed 1-Hexene Polymerization
inferred← citeshttps://doi.org/10.1021/cs5016029openalex-snapshot
Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using “Sandwich” Diimine Palladium Catalysts
inferred← citeshttps://doi.org/10.1021/cs501948dopenalex-snapshot
Synthesis of Branched Ultrahigh-Molecular-Weight Polyethylene Using Highly Active Neutral, Single-Component Ni(II) Catalysts
inferred← citeshttps://doi.org/10.1021/ja505579fopenalex-snapshot
Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes
inferred← citeshttps://doi.org/10.1021/jacs.0c02045openalex-snapshot
New Neutral Nickel and Palladium Sandwich Catalysts: Synthesis of Ultra-High Molecular Weight Polyethylene (UHMWPE) via Highly Controlled Polymerization and Mechanistic Studies of Chain Propagation
inferred← citeshttps://doi.org/10.1021/jacs.0c06644openalex-snapshot
Unsaturated Alcohols as Chain-Transfer Agents in Olefin Polymerization: Synthesis of Aldehyde End-Capped Oligomers and Polymers
inferred← citeshttps://doi.org/10.1021/jacs.4c01322openalex-snapshot
Ethylene Polymerizations Catalyzed by Fluorinated “Sandwich” Diimine-Nickel and Palladium Complexes
inferred← citeshttps://doi.org/10.1021/jacs.8b03223openalex-snapshot
Controlled Polymerization in Polar Solvents to Ultrahigh Molecular Weight Polyethylene
inferred← citeshttps://doi.org/10.1021/ma502427uopenalex-snapshot
Ni(II) α-Diimine-Catalyzed α-Olefins Polymerization: Thermoplastic Elastomers of Block Copolymers
inferred← citeshttps://doi.org/10.1038/s41467-019-14211-0openalex-snapshot
A simple and versatile nickel platform for the generation of branched high molecular weight polyolefins
inferred← citeshttps://doi.org/10.1038/s44160-023-00239-0openalex-snapshot
Nickel-catalysed hydrodimerization of unactivated terminal alkenes
inferred← citeshttps://doi.org/10.1039/c5py01743bopenalex-snapshot
Amine–imine palladium catalysts for living polymerization of ethylene and copolymerization of ethylene with methyl acrylate: incorporation of acrylate units into the main chain and branch end
inferred← citeshttps://doi.org/10.1039/c5sc03361fopenalex-snapshot
Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide–palladium catalysts
inferred← citeshttps://doi.org/10.1039/c6cc00457aopenalex-snapshot
Synthesis of high molecular weight polyethylene using iminopyridyl nickel catalysts
inferred← citeshttps://doi.org/10.1039/c6nj03834dopenalex-snapshot
Ethylene polymerization with a nickel diimine catalyst covalently anchored on spherical ZSM-5
inferred← citeshttps://doi.org/10.1039/c6py00750copenalex-snapshot
Influence of ligand second coordination sphere effects on the olefin (co)polymerization properties of α-diimine Pd( ii ) catalysts
inferred← citeshttps://doi.org/10.1039/c6qi00562dopenalex-snapshot
Redox control in palladium catalyzed norbornene and alkyne polymerization
inferred← citeshttps://doi.org/10.1039/c6qm00235hopenalex-snapshot
Unsymmetrical α-diimine palladium catalysts and their properties in olefin (co)polymerization
inferred← citeshttps://doi.org/10.1039/c7qm00321hopenalex-snapshot
Late transition metal catalyzed α-olefin polymerization and copolymerization with polar monomers
inferred← citeshttps://doi.org/10.1039/c7ra11783copenalex-snapshot
Ligand steric effects on α-diimine nickel catalyzed ethylene and 1-hexene polymerization
inferred← citeshttps://doi.org/10.1039/c8dt04413aopenalex-snapshot
Synthesis of nickel and palladium complexes with diarylamido-based unsymmetrical pincer ligands and application for norbornene polymerization
inferred← citeshttps://doi.org/10.1039/c9cc03154eopenalex-snapshot
Switchable living nickel( ii ) α-diimine catalyst for ethylene polymerisation
inferred← citeshttps://doi.org/10.1039/c9py00226jopenalex-snapshot
A continuing legend: the Brookhart-type α-diimine nickel and palladium catalysts
inferred← citeshttps://doi.org/10.1039/c9py00857hopenalex-snapshot
Bulky yet flexible substituents in insertion polymerization with α-diimine nickel and palladium systems
inferred← citeshttps://doi.org/10.1039/d0cy01617aopenalex-snapshot
Combining hydrogen bonding interactions with steric and electronic modifications for thermally robust α-diimine palladium catalysts toward ethylene (co)polymerization
inferred← citeshttps://doi.org/10.1039/d0py01152eopenalex-snapshot
α-Diimine nickel complexes bearing axially bulky terphenyl and equatorially bulky dibenzobarrelene groups: synthesis, characterization and olefin polymerization studies
inferred← citeshttps://doi.org/10.1039/d1nj02437jopenalex-snapshot
Influence of intramolecular π–π and H-bonding interactions on pyrazolylimine nickel-catalyzed ethylene polymerization and co-polymerization
inferred← citeshttps://doi.org/10.1039/d3dt03146bopenalex-snapshot
Experimental and theoretical insights into palladium-mediated polymerization of para-N , N -disubstituted aminostyrene
inferred← citeshttps://doi.org/10.1039/d3py00028aopenalex-snapshot
Recent developments in catalyst systems for selective oligomerization and polymerization of higher α-olefins
inferred← citeshttps://doi.org/10.1039/d3py00118kopenalex-snapshot
Ethylene polymerization using heterogeneous multinuclear nickel catalysts supported by a crosslinked alpha diimine ligand network
inferred← citeshttps://doi.org/10.1039/d3py01266bopenalex-snapshot
Lewis acid-induced homo- and heterogeneous nickel catalysts for ethylene polymerization and copolymerization with polar monomers
inferred← citeshttps://doi.org/10.1039/d4py00863dopenalex-snapshot
Benzosuberyl installed “sandwich” type unsymmetrical α-diimine nickel precatalysts for synthesizing plastomeric to elastomeric polyethylene
inferred← citeshttps://doi.org/10.1039/d4qi00005fopenalex-snapshot
Dearomatized diimines for nickel( ii ) and palladium( ii ) catalyzed ethylene polymerization and copolymerization
inferred← citeshttps://doi.org/10.1039/d5dt00571jopenalex-snapshot
A π–π interaction strategy for targeting highly thermostable bis(arylimino)pyridyliron precatalysts in ethylene polymerization
inferred← citeshttps://doi.org/10.1039/d5ra05407aopenalex-snapshot
High molecular weight polyethylene via the spatial proximity of benzosuberyl in iminopyridine nickel catalysts
inferred← citeshttps://doi.org/10.1055/sos-sd-148-00006openalex-snapshot
48.5.5 Hydrocarbon Polymers (Update 2020)
inferred← citeshttps://doi.org/10.1088/1757-899x/770/1/012019openalex-snapshot
Steric hindrance effects of phenoxyimine nickel catalysts in ethylene/propylene polymerization
inferred← citeshttps://doi.org/10.1134/s0036024420050295openalex-snapshot
Synthesis and Сharacterization of Soft-Bridged Iminopyridyl Iron and Cobalt Complexes and Their Catalytic Behavior toward Ethylene Oligomerization
inferred← citeshttps://doi.org/10.1155/adv/7837370openalex-snapshot
Oxo‐Nitrogenated Dinuclear Co(II) Catalyst for Polymerization of Methyl Methacrylate
inferred← citeshttps://doi.org/10.1246/cl.200793openalex-snapshot
Synthesis of Polymers with Regulated Repeating Structures by Utilizing Chain Walking Strategy
inferred← citeshttps://doi.org/10.12794/metadc1833439openalex-snapshot
Theoretical Thermochemistry of Tungsten Including σ and π Bond Components
inferred← citeshttps://doi.org/10.1515/ncrs-2020-0038openalex-snapshot
Crystal structure of 4′-amino-3′,5′-diisopropyl-(1,1′-biphenyl)-4-carbonitrile, C19H22N2
inferred← citeshttps://doi.org/10.19080/ajop.2019.02.555585openalex-snapshot
Nickel and Palladium Catalyzed Olefin Polymerization
inferred← citeshttps://doi.org/10.2174/1385272825666210126100641openalex-snapshot
Advances in the Synthesis of Polyolefin Elastomers with “Chain-walking” Catalysts and Electron Spin Resonance Research of Related Catalytic Systems
inferred← citeshttps://doi.org/10.3390/catal11030407openalex-snapshot
Investigations on the Ethylene Polymerization with Bisarylimine Pyridine Iron (BIP) Catalysts
inferred← citeshttps://doi.org/10.3390/catal15020127openalex-snapshot
A Comprehensive Review on Barrelene-Derived α-Diimine Nickel and Palladium Olefin Polymerization Catalysts
inferred← citeshttps://doi.org/10.3390/inorganics12110277openalex-snapshot
Late Transition Metal Olefin Polymerization Catalysts Derived from 8-Arylnaphthylamines
inferred← citeshttps://doi.org/10.3390/molecules27248942openalex-snapshot
Unsymmetrical Strategy on α-Diimine Nickel and Palladium Mediated Ethylene (Co)Polymerizations
inferred← citeshttps://doi.org/10.3390/polym12091988openalex-snapshot
Living Chain-Walking (Co)Polymerization of Propylene and 1-Decene by Nickel α-Diimine Catalysts
inferred← citeshttps://doi.org/10.3390/polym18080961openalex-snapshot
Investigations of the α-Olefin Polymerization Process Using the Classic α-Diimine Nickel Catalyst
inferred← citeshttps://doi.org/10.3390/polym8020037openalex-snapshot
Investigations of the Ligand Electronic Effects on α-Diimine Nickel(II) Catalyzed Ethylene Polymerization
inferred← citeshttps://doi.org/10.3390/polym8040160openalex-snapshot
Synthesis of Highly Branched Polyolefins Using Phenyl Substituted α-Diimine Ni(II) Catalysts
inferred← citeshttps://doi.org/10.3390/polym8110389openalex-snapshot
Influences of Alkyl and Aryl Substituents on Iminopyridine Fe(II)- and Co(II)-Catalyzed Isoprene Polymerization
inferred← citeshttps://doi.org/10.3390/polym9040122openalex-snapshot
Direct Synthesis of Branched Carboxylic Acid Functionalized Poly(1-octene) by α-Diimine Palladium Catalysts
inferred← citeshttps://doi.org/10.4028/www.scientific.net/amr.1120-1121.564openalex-snapshot
Synthesis, Characterization and Applications of Late-Transition Metal Branched Polyethylene
inferred← citeshttps://doi.org/10.6023/a23040162openalex-snapshot
Catalytic Synthesis of Polyolefin Elastomer Using Unsymmetrical α-Diimine Nickel Catalyst★
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