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Rh-Catalyzed Intramolecular Olefin Hydroacylation: Enantioselective Synthesis of Seven- and Eight-Membered Heterocycles
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1002/adsc.200600583openalex-snapshot
An Unprecedented Rhodium‐Catalyzed Asymmetric Intermolecular Hydroacylation Reaction with Salicylaldehydes
inferredcites →https://doi.org/10.1016/s0040-4020(01)80954-6openalex-snapshot
Asymmetric cyclization reactions. Cyclization of substituted 4-pentenals into cyclopentanone derivatives by rhodium(I) with chiral ligands
inferredcites →https://doi.org/10.1016/s0040-4039(02)01552-6openalex-snapshot
Chelation-assisted intramolecular hydroacylation: synthesis of medium ring sulfur heterocycles
inferredcites →https://doi.org/10.1021/ar00064a001openalex-snapshot
Ring closure reactions of bifunctional chain molecules
inferredcites →https://doi.org/10.1021/cr0406108openalex-snapshot
Convergent Strategies for Syntheses of trans -Fused Polycyclic Ethers
inferredcites →https://doi.org/10.1021/cr050045oopenalex-snapshot
Total Synthesis of Natural 8- and 9-Membered Lactones: Recent Advancements in Medium-Sized Ring Formation
inferredcites →https://doi.org/10.1021/cr990372uopenalex-snapshot
Recent Developments in the Synthesis and Utilization of Chiral Sulfoxides
inferredcites →https://doi.org/10.1021/cr990407qopenalex-snapshot
Metal-Mediated Synthesis of Medium-Sized Rings
inferredcites →https://doi.org/10.1021/ja00084a025openalex-snapshot
Asymmetric Catalysis. Asymmetric Catalytic Intramolecular Hydroacylation of 4-Pentenals Using Chiral Rhodium Diphosphine Catalysts
inferredcites →https://doi.org/10.1021/ja00538a021openalex-snapshot
A mechanistic study of the rhodium-catalyzed cyclization of 4-hexenals. Reactions of deuterio-4-hexenals
inferredcites →https://doi.org/10.1021/ja0055920openalex-snapshot
Synthesis of Cyclooctenones Using Intramolecular Hydroacylation
inferredcites →https://doi.org/10.1021/ja0564416openalex-snapshot
Hydroacylation of 2-Vinyl Benzaldehyde Systems: An Efficient Method for the Synthesis of Chiral 3-Substituted Indanones
inferredcites →https://doi.org/10.1021/ja066509xopenalex-snapshot
Scope and Mechanism of the Intermolecular Addition of Aromatic Aldehydes to Olefins Catalyzed by Rh(I) Olefin Complexes
inferredcites →https://doi.org/10.1021/ja806758mopenalex-snapshot
Mechanistic Insights into the Rhodium-Catalyzed Intramolecular Ketone Hydroacylation
inferredcites →https://doi.org/10.1021/ja8069133openalex-snapshot
Catalytic Enantioselective Intermolecular Hydroacylation: Rhodium-Catalyzed Combination of β-S-Aldehydes and 1,3-Disubstituted Allenes
inferredcites →https://doi.org/10.1021/ja8085005openalex-snapshot
Asymmetric Synthesis of Medium-Sized Rings by Intramolecular Au(I)-Catalyzed Cyclopropanation
inferredcites →https://doi.org/10.1021/ja980610nopenalex-snapshot
Mechanistic and Synthetic Studies of the Addition of Alkyl Aldehydes to Vinylsilanes Catalyzed by Co(I) Complexes
inferredcites →https://doi.org/10.1021/om00009a043openalex-snapshot
Homogeneous Catalysis. Mechanism of Diastereoselective Hydroacylation of 3-Substituted-4-pentenals using Chiral Rhodium Catalysts
inferredcites →https://doi.org/10.1021/om00094a026openalex-snapshot
Homogeneous catalysis. Mechanism of catalytic hydroacylation: the conversion of 4-pentenals to cyclopentanones
inferredcites →https://doi.org/10.1021/om700842dopenalex-snapshot
Mechanism of Rhodium-Catalyzed Intramolecular Hydroacylation: A Computational Study
inferredcites →https://doi.org/10.1039/a700076fopenalex-snapshot
Asymmetric catalytic intramolecular hydroacylation of 4-substituted pent-4-enals to β-substituted cyclopentanones
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
inferred← citeshttps://doi.org/10.1002/047084289x.rn02159openalex-snapshot
Bis(norbornadiene)rhodium(I) Tetrafluoroborate
inferred← citeshttps://doi.org/10.1002/0471264180.or096.02openalex-snapshot
Transition‐Metal‐Catalyzed Hydroacylation
inferred← citeshttps://doi.org/10.1002/9781118788981.ch6openalex-snapshot
Homogeneous Transition‐Metal‐Catalyzed C–H Bond Functionalization
inferred← citeshttps://doi.org/10.1002/9783527346028.ch8openalex-snapshot
Theoretical Study of Rh ‐Catalysis
inferred← citeshttps://doi.org/10.1002/9783527635207.ch2openalex-snapshot
Bisphosphacycles–From DuPhos and BPE to a Diverse Set of Broadly Applied Ligands
inferred← citeshttps://doi.org/10.1002/9783527804801.ch9openalex-snapshot
Carbonyl Compounds from Alkynes and Alkenes
inferred← citeshttps://doi.org/10.1002/9783527810857.ch8openalex-snapshot
Non‐stereoselective C(sp 2 )– H Activation Followed by Selective Functionalization of Metallacyclic Intermediate
inferred← citeshttps://doi.org/10.1002/9783527811908.ch4openalex-snapshot
Rhodium(I)‐Catalyzed Hydroacylation
inferred← citeshttps://doi.org/10.1002/9783527834242.chf0111openalex-snapshot
Rhodium‐Catalyzed Heterocycle Synthesis by CH Functionalization
inferred← citeshttps://doi.org/10.1002/adsc.201600112openalex-snapshot
Rhodium‐Catalyzed Tandem Annulation Reactions of 7‐Azaindoles with Electron‐Deficient Olefins via Double CH Activation
inferred← citeshttps://doi.org/10.1002/adsc.202100466openalex-snapshot
tert ‐Butyl Hydroperoxide‐Initiated Radical Cyclization of 1‐(Allyloxy)‐2‐(1‐Arylvinyl)Benzenes with Sulfinic Acids to Access Sulfonated Benzoxepines
inferred← citeshttps://doi.org/10.1002/adsc.202101423openalex-snapshot
Sterically and Temperature Controlled Divergent Cycloadditions of α,β‐Unsaturated Imines with Vinylethylene Carbonates: Insights from Experimental and DFT Studies
inferred← citeshttps://doi.org/10.1002/adsc.202200147openalex-snapshot
Rhodium‐Catalyzed Decarboxylative Hydroacylation of Vinylethylene Carbonates for Regioselective Ester Synthesis
inferred← citeshttps://doi.org/10.1002/adsc.202300206openalex-snapshot
Enantioselective Intramolecular Hydroacylation of Alkynes by Rhodium Catalysis through Dynamic Kinetic Resolution
inferred← citeshttps://doi.org/10.1002/adsc.70375openalex-snapshot
Transition‐Metal‐Free or Visible‐Light Catalyzed Selective C–C Bond Cleavage of Cyclobutanone Oxime Derivatives
inferred← citeshttps://doi.org/10.1002/ajoc.70265openalex-snapshot
Metal‐Free Electrophilic Selenocyclization of 1,7‐Dienes: Synthesis of Selenium‐Containing Benzoxepines
inferred← citeshttps://doi.org/10.1002/ange.200904527openalex-snapshot
Combined Rhodium‐Catalyzed Carbon–Hydrogen Activation and β‐Carbon Elimination to access Eight‐Membered Rings
inferred← citeshttps://doi.org/10.1002/ange.201002108openalex-snapshot
Enantioselective Oxidative Cross‐Coupling Reaction of 3‐Indolylmethyl CH Bonds with 1,3‐Dicarbonyls Using a Chiral Lewis Acid‐Bonded Nucleophile to Control Stereochemistry
inferred← citeshttps://doi.org/10.1002/ange.201005215openalex-snapshot
Enantioselective Rhodium‐Catalyzed Allylic CH Activation for the Addition to Conjugated Dienes
inferred← citeshttps://doi.org/10.1002/ange.201100956openalex-snapshot
Rhodium‐Catalyzed Branched‐Selective Alkyne Hydroacylation: A Ligand‐Controlled Regioselectivity Switch
inferred← citeshttps://doi.org/10.1002/ange.201103568openalex-snapshot
Computationally Guided Stereocontrol of the Combined CH Functionalization/Cope Rearrangement
inferred← citeshttps://doi.org/10.1002/ange.201202125openalex-snapshot
Rhodium‐Catalyzed Cascade Reactions of Dienynes Leading to Substituted Dihydronaphthalenes and Naphthalenes
inferred← citeshttps://doi.org/10.1002/ange.201308824openalex-snapshot
Rhodium(I)‐Catalyzed Cyclization of Allenynes with a Carbonyl Group through Unusual Insertion of a CO Bond into a Rhodacycle Intermediate
inferred← citeshttps://doi.org/10.1002/ange.201310354openalex-snapshot
Rhodium‐Catalyzed Sequential Allylic Amination and Olefin Hydroacylation Reactions: Enantioselective Synthesis of Seven‐Membered Nitrogen Heterocycles
inferred← citeshttps://doi.org/10.1002/ange.201509235openalex-snapshot
Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes
inferred← citeshttps://doi.org/10.1002/ange.201601540openalex-snapshot
Sulfoxid‐gelenkte C‐H‐Kupplungsreaktionen: Eine alte funktionelle Gruppe lernt neue Tricks
inferred← citeshttps://doi.org/10.1002/ange.201611518openalex-snapshot
Cobalt‐Catalyzed Enantio‐ and Diastereoselective Intramolecular Hydroacylation of Trisubstituted Alkenes
inferred← citeshttps://doi.org/10.1002/ange.202006716openalex-snapshot
Enantioselective Cobalt‐Catalyzed Intermolecular Hydroacylation of 1,6‐Enynes
inferred← citeshttps://doi.org/10.1002/anie.200904527openalex-snapshot
Combined Rhodium‐Catalyzed Carbon–Hydrogen Activation and β‐Carbon Elimination to access Eight‐Membered Rings
inferred← citeshttps://doi.org/10.1002/anie.201002108openalex-snapshot
Enantioselective Oxidative Cross‐Coupling Reaction of 3‐Indolylmethyl CH Bonds with 1,3‐Dicarbonyls Using a Chiral Lewis Acid‐Bonded Nucleophile to Control Stereochemistry
inferred← citeshttps://doi.org/10.1002/anie.201005215openalex-snapshot
Enantioselective Rhodium‐Catalyzed Allylic CH Activation for the Addition to Conjugated Dienes
inferred← citeshttps://doi.org/10.1002/anie.201100956openalex-snapshot
Rhodium‐Catalyzed Branched‐Selective Alkyne Hydroacylation: A Ligand‐Controlled Regioselectivity Switch
inferred← citeshttps://doi.org/10.1002/anie.201103568openalex-snapshot
Computationally Guided Stereocontrol of the Combined CH Functionalization/Cope Rearrangement
inferred← citeshttps://doi.org/10.1002/anie.201202125openalex-snapshot
Rhodium‐Catalyzed Cascade Reactions of Dienynes Leading to Substituted Dihydronaphthalenes and Naphthalenes
inferred← citeshttps://doi.org/10.1002/anie.201308824openalex-snapshot
Rhodium(I)‐Catalyzed Cyclization of Allenynes with a Carbonyl Group through Unusual Insertion of a CO Bond into a Rhodacycle Intermediate
inferred← citeshttps://doi.org/10.1002/anie.201310354openalex-snapshot
Rhodium‐Catalyzed Sequential Allylic Amination and Olefin Hydroacylation Reactions: Enantioselective Synthesis of Seven‐Membered Nitrogen Heterocycles
inferred← citeshttps://doi.org/10.1002/anie.201509235openalex-snapshot
Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes
inferred← citeshttps://doi.org/10.1002/anie.201601540openalex-snapshot
C−H Coupling Reactions Directed by Sulfoxides: Teaching an Old Functional Group New Tricks
inferred← citeshttps://doi.org/10.1002/anie.201611518openalex-snapshot
Cobalt‐Catalyzed Enantio‐ and Diastereoselective Intramolecular Hydroacylation of Trisubstituted Alkenes
inferred← citeshttps://doi.org/10.1002/anie.202006716openalex-snapshot
Enantioselective Cobalt‐Catalyzed Intermolecular Hydroacylation of 1,6‐Enynes
inferred← citeshttps://doi.org/10.1002/aoc.6555openalex-snapshot
Exciting progress in the transition metal‐catalyzed synthesis of oxepines, benzoxepines, dibenzoxepines, and other derivatives
inferred← citeshttps://doi.org/10.1002/asia.201100271openalex-snapshot
Internal Chelation‐Guided Regio‐ and Stereoselective Pauson–Khand‐Type Reaction by Chiral Rhodium(I) Catalysis
inferred← citeshttps://doi.org/10.1002/asia.201301264openalex-snapshot
Reactions of Aromatic S‐ and O‐Enynes with Two Methyl Substituents on the Olefinic Unit Assisted by a Ruthenium Complex: Tandem Cyclization and Product Selectivity
inferred← citeshttps://doi.org/10.1002/cctc.201300228openalex-snapshot
Addition of Sulfonic Acids to Terminal Alkynes Catalyzed by a Rhodium Complex: Ligand Concentration‐Controlled Reaction Selectivity
inferred← citeshttps://doi.org/10.1002/cctc.201600428openalex-snapshot
Cyclization of 2‐Ethynylphenyl Vinyl Ether Catalyzed by a Ruthenium Complex: Mechanism of Catalytic Cyclization and Stoichiometric Cycloisomerization
inferred← citeshttps://doi.org/10.1002/chem.201001748openalex-snapshot
Rhodium‐Catalysed Intermolecular Alkyne Hydroacylation: The Enantioselective Synthesis of α‐ and β‐Substituted Ketones by Kinetic Resolution
inferred← citeshttps://doi.org/10.1002/chem.201301168openalex-snapshot
Rhodium‐Catalyzed Synthesis of Amides from Aldehydes and Azides by Chelation‐Assisted CH Bond Activation
inferred← citeshttps://doi.org/10.1002/chem.201600425openalex-snapshot
Diastereoselective Radical Hydroacylation of Alkylidenemalonates with Aliphatic Aldehydes Initiated by Photolysis of Hypervalent Iodine(III) Reagents
inferred← citeshttps://doi.org/10.1002/chem.201603880openalex-snapshot
Rhodium‐Catalyzed Enantioselective Intramolecular Hydroacylation of Trisubstituted Alkenes
inferred← citeshttps://doi.org/10.1002/chin.200942174openalex-snapshot
ChemInform Abstract: Rh‐Catalyzed Intramolecular Olefin Hydroacylation: Enantioselective Synthesis of Seven‐ and Eight‐Membered Heterocycles.
inferred← citeshttps://doi.org/10.1002/cjoc.202000019openalex-snapshot
Expedient Synthesis of Ketones via N‐Heterocyclic Carbene/ Nickel‐Catalyzed Redox‐Economical Coupling of Alcohols and Alkynes†
inferred← citeshttps://doi.org/10.1002/cplu.202300728openalex-snapshot
Aryl Sulfoxides: A Traceless Directing Group for Catalytic C−H Activation of Arenes
inferred← citeshttps://doi.org/10.1002/ejoc.201300096openalex-snapshot
Diastereoselective Synthesis of Isoindole‐Fused Diazacyclooctaindenones from Spirochromenes through Domino Reactions with Aliphatic 1,2‐Diamines
inferred← citeshttps://doi.org/10.1002/ejoc.201500374openalex-snapshot
Silver Triflate Catalyzed Cyclopropyl Carbinol Rearrangement for Benzo[b]oxepine and 2H‐Chromene Synthesis
inferred← citeshttps://doi.org/10.1002/ejoc.201701532openalex-snapshot
Enantioselective Synthesis of Sulfur‐Containing Medium‐Ring Heterocycles with Axial Chiralities by Catalytic Intramolecular [2+2+2] Cycloaddition
inferred← citeshttps://doi.org/10.1002/ejoc.201901513openalex-snapshot
Thioether‐Facilitated Iridium‐Catalyzed Hydrosilylation of Steric 1,1‐Disubstituted Olefins
inferred← citeshttps://doi.org/10.1002/jhet.2357openalex-snapshot
Regioselective and Stereoselective Synthesis of Pyridine‐Fused Benzoxepine Derivatives by Intramolecular Reductive Heck Cyclization[1]
inferred← citeshttps://doi.org/10.1002/slct.202403892openalex-snapshot
Ligand‐Controlled Regioselective Hydroacylation Reactions of Methylenecyclobutanes under Rhodium Catalysis
inferred← citeshttps://doi.org/10.1007/978-3-642-41470-1_2openalex-snapshot
Synthesis of Eight- to Ten-Membered Ring Ethers
inferred← citeshttps://doi.org/10.1016/b978-0-08-097742-3.00423-7openalex-snapshot
4.17 Hydroacylation of Alkenes, Alkynes, and Allenes
inferred← citeshttps://doi.org/10.1016/b978-0-323-89812-6.00016-xopenalex-snapshot
Seven-membered rings
inferred← citeshttps://doi.org/10.1016/b978-0-323-95652-9.00004-1openalex-snapshot
Synthesis of thiocines
inferred← citeshttps://doi.org/10.1016/j.checat.2022.07.021openalex-snapshot
Recent advances for the catalytic asymmetric construction of medium-sized rings
inferred← citeshttps://doi.org/10.1016/j.gresc.2024.01.002openalex-snapshot
Controlled generation of ortho-quinone methides and (4+3) cyclization with 2-indolylalcohols by dual photoredox/Brønsted acid relay catalysis
inferred← citeshttps://doi.org/10.1016/j.gresc.2025.10.002openalex-snapshot
TBADT/nickel co-catalyzed three-component radical acylarylation of alkenes with aldehydes and aryl iodides
inferred← citeshttps://doi.org/10.1016/j.tet.2011.02.023openalex-snapshot
Synthesis of C3- and C2-symmetric tris- and bis-sulfoxide ligands by asymmetric oxidation
inferred← citeshttps://doi.org/10.1016/j.tet.2012.05.081openalex-snapshot
Recent progress in the synthesis of oxepanes and medium ring ethers
inferred← citeshttps://doi.org/10.1016/j.tet.2015.01.066openalex-snapshot
Palladium-catalyzed formal hydroacylation of allenes employing carboxylic anhydrides and hydrosilanes
inferred← citeshttps://doi.org/10.1016/j.tet.2017.08.018openalex-snapshot
Hypervalent iodine(III) catalyzed radical hydroacylation of chiral alkylidenemalonates with aliphatic aldehydes under photolysis
inferred← citeshttps://doi.org/10.1016/j.tet.2018.11.057openalex-snapshot
Rhodium-catalyzed intramolecular hydroacylation of 1,2-disubstituted alkenes for the synthesis of 2-substituted indanones
inferred← citeshttps://doi.org/10.1016/j.tetlet.2011.12.125openalex-snapshot
Amine-directed intramolecular hydroacylation of alkenes and alkynes
inferred← citeshttps://doi.org/10.1016/j.tetlet.2013.06.070openalex-snapshot
A reductive Mizoroki–Heck approach to dibenzo[b,e]oxepine
inferred← citeshttps://doi.org/10.1021/acs.accounts.0c00771openalex-snapshot
Teaching Aldehydes New Tricks Using Rhodium- and Cobalt-Hydride Catalysis
inferred← citeshttps://doi.org/10.1021/acs.chemrev.3c00149openalex-snapshot
Rhodium-Catalyzed Asymmetric C–H Functionalization Reactions
inferred← citeshttps://doi.org/10.1021/acs.chemrev.6b00692openalex-snapshot
Catalytic Enantioselective Transformations Involving C–H Bond Cleavage by Transition-Metal Complexes
inferred← citeshttps://doi.org/10.1021/acs.joc.2c00361openalex-snapshot
Propargyl Chalcones’ Radical Annulation/Sulfonation Reaction: Efficient Synthesis of Benzo[ b ]oxepin-5(2 H )-one and Chromane Derivatives
inferred← citeshttps://doi.org/10.1021/acs.joc.2c00446openalex-snapshot
Regio- and Diastereoselective Construction of Functionalized Benzo[b]oxepines and Benzo[b]azepines via Recyclable Gold(I)-Catalyzed Cyclizations
inferred← citeshttps://doi.org/10.1021/acs.joc.2c02870openalex-snapshot
Base-Promoted Decarboxylative Annulation of Methyl 2-(2-Bromophenyl)acetates and Ynones to Access Benzoxepines
inferred← citeshttps://doi.org/10.1021/acs.joc.3c02184openalex-snapshot
Visible-Light-Induced Regioselective Cascade Radical Cyclization of α-Bromocarbonyls: Access to Benzazepine Derivatives
inferred← citeshttps://doi.org/10.1021/acs.joc.5b02487openalex-snapshot
Base-Promoted Formal [4 + 3] Annulation between 2-Fluorophenylacetylenes and Ketones: A Route to Benzoxepines
inferred← citeshttps://doi.org/10.1021/acs.joc.5c01739openalex-snapshot
Radical Cascade Nitro-Cyclization Reaction of Oxygen-Linked 1,7-Dienes for the Synthesis of NO 2 -Substituted Benzoxepines
inferred← citeshttps://doi.org/10.1021/acs.joc.6b00203openalex-snapshot
Nickel-Catalyzed Regioselective Cleavage of C sp 2 –S Bonds: Method for the Synthesis of Tri- and Tetrasubstituted Alkenes
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c01751openalex-snapshot
Rhodium-Catalyzed Ring-Opening Hydroacylation of Alkylidenecyclopropanes with Chelating Aldehydes for the Synthesis of γ,δ-Unsaturated Ketones
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c02340openalex-snapshot
Direct Synthesis of Mono-α-arylated Ketones from Alcohols and Olefins via Ni-Catalyzed Oxidative Cross-Coupling
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c00391openalex-snapshot
Construction of Highly Functionalized Xanthones via Rh-Catalyzed Cascade C–H Activation/O-Annulation
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c02153openalex-snapshot
Rhodium-Catalyzed Regioselective Formal Hydroacylation of Vinyl Epoxides toward Esters Involving β-Carbon Cleavage
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c02314openalex-snapshot
Visible-Light-Induced Difluoroalkylation of 1-(Allyloxy)-2-(1-arylvinyl)benzenes and 1-(1-Arylvinyl)-2-(vinyloxy)benzenes: Synthesis of Bis-Difluoroalkylated Benzoxepines and 2 H -Chromenes
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b00027openalex-snapshot
Iridium- and Rhodium-Catalyzed C–H Activation and Formyl Alkynylation of Benzaldehydes under Chelation-Assistance
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b01447openalex-snapshot
Tandem Alkyne Hydroacylation and Oxo-Michael Addition: Diastereoselective Synthesis of 2,3-Disubstituted Chroman-4-ones and Fluorinated Derivatives
inferred← citeshttps://doi.org/10.1021/acs.orglett.5b02559openalex-snapshot
Rhodium-Catalyzed, Enantioselective Hydroacylation of ortho -Allylbenzaldehydes
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c00579openalex-snapshot
Ni–Al Bimetal-Catalyzed Dual C–H Annulation of Formamides with Alkynes for Synthesis of Seven-Membered Lactams
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b00131openalex-snapshot
Visible-Light-Induced External Radical-Triggered Annulation To Access CF 2 -Containing Benzoxepine Derivatives
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b02037openalex-snapshot
A Rh-Catalyzed Air and Moisture Tolerable Aldehyde (Ketone)-Directed Fluorosulfonylvinylation of Aryl C(sp2)–H Bonds
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b03709openalex-snapshot
Lewis Base-Catalyzed [4 + 3] Annulation of ortho-Quinone Methides and MBH Carbonates: Synthesis of Functionalized Benzo[b]oxepines Bearing Oxindole Scaffolds
inferred← citeshttps://doi.org/10.1021/acs.orglett.8b03973openalex-snapshot
Synthesis of 2-(2-Oxo-2-phenylethyl)cyclopentanone by Rhodium-Catalyzed Tandem Alkynyl Cyclobutanols Hydroacylation and Semipinacol Rearrangement
inferred← citeshttps://doi.org/10.1021/acs.orglett.9b01700openalex-snapshot
Base-Controlled Divergent Synthesis of 5-Cyanobenzoxepines and Benzofuro[2,3-b]pyridines from 2-Bromophenylacetonitriles and Ynones
inferred← citeshttps://doi.org/10.1021/acscatal.2c05638openalex-snapshot
Temperature-Controlled Divergent Asymmetric Synthesis of Indole-Based Medium-Sized Heterocycles through Palladium Catalysis
inferred← citeshttps://doi.org/10.1021/acscatal.3c02562openalex-snapshot
Catalyst-Controlled Switchable (5 + 4)/(3 + 4) Cycloadditions for the Divergent Synthesis of Pyrazole-Fused Seven- and Nine-Membered Heterocycles
inferred← citeshttps://doi.org/10.1021/acscatal.3c05616openalex-snapshot
Regio- and Diastereoselective Highly Strained Alkylidenecyclobutane Isomerization/Hydroacylation: Synthesis of Multisubstituted Cyclobutanes with Consecutive Stereocenters
inferred← citeshttps://doi.org/10.1021/acscatal.5b00581openalex-snapshot
Cobalt-Catalyzed Intermolecular Hydroacylation of Olefins through Chelation-Assisted Imidoyl C–H Activation
inferred← citeshttps://doi.org/10.1021/acscatal.5c02922openalex-snapshot
Chiral Transient Directing Groups for Catalytic Asymmetric Intramolecular Alkene Hydroacylation
inferred← citeshttps://doi.org/10.1021/acscatal.6b00856openalex-snapshot
Intermolecular Markovnikov-Selective Hydroacylation of Olefins Catalyzed by a Cationic Ruthenium–Hydride Complex
inferred← citeshttps://doi.org/10.1021/acscatal.6b03661openalex-snapshot
Palladium-Catalyzed β-C–H Arylation of Alkyl Carboxamides with Sterically Hindered Aryl Iodides Using ortho-Sulfinyl Aniline Auxiliaries
inferred← citeshttps://doi.org/10.1021/acscatal.6c01939openalex-snapshot
Synthesis of α-(Hetero)aryl Ketones by Ni-Catalyzed Regio- and Enantioselective Hydroacylation of Alkenes with Acid Chlorides
inferred← citeshttps://doi.org/10.1021/acsomega.4c06569openalex-snapshot
Ni(0)-Catalyzed Efficient, Regioselective Synthesis of Dibenzo[b,e]oxepines and Dibenzo[c,f][1,2]oxathiepine 6,6-Dioxides: Mechanistic Study by DFT Calculation and Docking Interactions
inferred← citeshttps://doi.org/10.1021/cr900096xopenalex-snapshot
Transition Metal Catalyzed Alkene and Alkyne Hydroacylation
inferred← citeshttps://doi.org/10.1021/ja107198eopenalex-snapshot
Regio- and Enantioselective Intermolecular Hydroacylation: Substrate-Directed Addition of Salicylaldehydes to Homoallylic Sulfides
inferred← citeshttps://doi.org/10.1021/ja107738aopenalex-snapshot
Enantioselective Desymmetrization of Cyclopropenes by Hydroacylation
inferred← citeshttps://doi.org/10.1021/ja209679copenalex-snapshot
Iridium-Catalyzed Addition of Aroyl Chlorides and Aliphatic Acid Chlorides to Terminal Alkynes
inferred← citeshttps://doi.org/10.1021/ja306025dopenalex-snapshot
Ruthenium-Catalyzed Aldehyde Functionality Reshuffle: Selective Synthesis ofE-2-Arylcinnamaldehydes fromE-β-Bromostyrenes and Aryl Aldehydes
inferred← citeshttps://doi.org/10.1021/ja4026787openalex-snapshot
Ruthenium-Catalyzed Intramolecular Hydrocarbamoylation of Allylic Formamides: Convenient Access to Chiral Pyrrolidones
inferred← citeshttps://doi.org/10.1021/ja409824bopenalex-snapshot
Dynamic Kinetic Resolution of Allylic Sulfoxides by Rh-Catalyzed Hydrogenation: A Combined Theoretical and Experimental Mechanistic Study
inferred← citeshttps://doi.org/10.1021/ja411913eopenalex-snapshot
Regiodivergent Access to Five- and Six-Membered Benzo-Fused Lactams: Ru-Catalyzed Olefin Hydrocarbamoylation
inferred← citeshttps://doi.org/10.1021/ja500268wopenalex-snapshot
Regioselective Hydroacylation of 1,3-Dienes by Cobalt Catalysis
inferred← citeshttps://doi.org/10.1021/ja509919xopenalex-snapshot
Cobalt-Catalyzed Enantioselective Intramolecular Hydroacylation of Ketones and Olefins
inferred← citeshttps://doi.org/10.1021/ja9038449openalex-snapshot
Cationic Rhodium(I)−dppf Complex-Catalyzed Olefin Isomerization/Propargyl Claisen Rearrangement/Carbonyl Migration Cascade
inferred← citeshttps://doi.org/10.1021/ja905908zopenalex-snapshot
Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes
inferred← citeshttps://doi.org/10.1021/ja906361gopenalex-snapshot
N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds
inferred← citeshttps://doi.org/10.1021/ja9077705openalex-snapshot
Synthetic Applications of Pd(II)-Catalyzed C−H Carboxylation and Mechanistic Insights: Expedient Routes to Anthranilic Acids, Oxazolinones, and Quinazolinones
inferred← citeshttps://doi.org/10.1021/ja909571zopenalex-snapshot
Pd(II)-Catalyzed Enantioselective C−H Olefination of Diphenylacetic Acids
inferred← citeshttps://doi.org/10.1021/jacs.3c10609openalex-snapshot
Amide-Directed, Rhodium-Catalyzed Regio- and Enantioselective Hydroacylation of Internal Alkenes with Unfunctionalized Aldehydes
inferred← citeshttps://doi.org/10.1021/jacs.5c00053openalex-snapshot
Enantioselective Synthesis of 1-Dihydrobenzazepines through Rh2(II)-Catalyzed Cycloisomerization of 1,6-Enyne
inferred← citeshttps://doi.org/10.1021/jacs.6b00024openalex-snapshot
Nickel-Catalyzed Hydroacylation of Styrenes with Simple Aldehydes: Reaction Development and Mechanistic Insights
inferred← citeshttps://doi.org/10.1021/jacs.7b04937openalex-snapshot
Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates
inferred← citeshttps://doi.org/10.1021/jacs.7b05427openalex-snapshot
Expedient Synthesis of 1,5-Diketones by Rhodium-Catalyzed Hydroacylation Enabled by C–C Bond Cleavage
inferred← citeshttps://doi.org/10.1021/jo300779qopenalex-snapshot
Cooperative Catalysis Approach to Intramolecular Hydroacylation
inferred← citeshttps://doi.org/10.1021/ol1029194openalex-snapshot
Electrophilic Carbocyclization of Aryl Propargylic Alcohols: A Facile Synthesis of Diiodinated Carbocycles and Heterocycles
inferred← citeshttps://doi.org/10.1021/ol1030662openalex-snapshot
O-Substituted Alkyl Aldehydes for Rhodium-Catalyzed Intermolecular Alkyne Hydroacylation: The Utility of Methylthiomethyl Ethers
inferred← citeshttps://doi.org/10.1021/ol201431copenalex-snapshot
Highly Regioselective Intermolecular Hydroacylations of Enamides with Salicylaldehydes
inferred← citeshttps://doi.org/10.1021/ol302252hopenalex-snapshot
Gold-Catalyzed Cyclizations of (o-Alkynyl)phenoxyacrylates with External Nucleophiles: Regio- and Stereoselective Synthesis of Functionalized Benzo[b]oxepines
inferred← citeshttps://doi.org/10.1021/ol400266gopenalex-snapshot
Multiple Rhodium-Catalyzed Cleavages of Single C–C bonds
inferred← citeshttps://doi.org/10.1021/ol400574sopenalex-snapshot
Rhodium-Catalyzed Olefin Isomerization/Allyl Claisen Rearrangement/Intramolecular Hydroacylation Cascade
inferred← citeshttps://doi.org/10.1021/ol400862kopenalex-snapshot
Palladium-Catalyzed Formal Hydroacylation of Allenes Employing Acid Chlorides and Hydrosilanes
inferred← citeshttps://doi.org/10.1021/ol400921ropenalex-snapshot
Rhodium(III)-Catalyzed Intermolecular Direct Amidation of Aldehyde C–H Bonds withN-Chloroamines at Room Temperature
inferred← citeshttps://doi.org/10.1021/ol501869sopenalex-snapshot
Enantioselective Synthesis of Polycyclic Nitrogen Heterocycles by Rh-Catalyzed Alkene Hydroacylation: Constructing Six-Membered Rings in the Absence of Chelation Assistance
inferred← citeshttps://doi.org/10.1021/om300647nopenalex-snapshot
Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination
inferred← citeshttps://doi.org/10.1021/om400742xopenalex-snapshot
Tandem Cyclization of Enynes Containing a Thioether or Ether Linkage via Ruthenium Allenylidene and Vinylidene Complexes
inferred← citeshttps://doi.org/10.1021/om9011104openalex-snapshot
Controlling Selectivity in Intermolecular Alkene or Aldehyde Hydroacylation Reactions Catalyzed by {Rh(L2)}+Fragments
inferred← citeshttps://doi.org/10.1038/s41467-021-23371-xopenalex-snapshot
Construction 7-membered ring via Ni–Al bimetal-enabled C–H cyclization for synthesis of tricyclic imidazoles
inferred← citeshttps://doi.org/10.1039/9781782621966-00358openalex-snapshot
Asymmetric Hydroacylation Reactions
inferred← citeshttps://doi.org/10.1039/c0sc00469copenalex-snapshot
Nitrogen-directed ketone hydroacylation: Enantioselective synthesis of benzoxazecinones
inferred← citeshttps://doi.org/10.1039/c1cc14626bopenalex-snapshot
Facile and chemoselective rhodium-catalysed intramolecular hydroacylation of α,α-disubstituted 4-alkylidenecyclopropanals
inferred← citeshttps://doi.org/10.1039/c2cc32713aopenalex-snapshot
Rhodium-catalysed linear-selective alkyne hydroacylation
inferred← citeshttps://doi.org/10.1039/c2cy20111aopenalex-snapshot
Asymmetric catalytic carbon–carbon coupling reactions via C–H bond activation
inferred← citeshttps://doi.org/10.1039/c2sc20542dopenalex-snapshot
Catalytic enantioselective carbon-carbon bond formation using cycloisomerization reactions
inferred← citeshttps://doi.org/10.1039/c3cc47397jopenalex-snapshot
Highly enantioselective synthesis of chiral 7-ring O- and N-heterocycles by a one-pot nitro-Michael–cyclization tandem reaction
inferred← citeshttps://doi.org/10.1039/c3ob41624kopenalex-snapshot
FeCl 3 -catalyzed synthesis of functionally diverse dibenzo[b,f]oxepines and benzo[b]oxepines via alkyne–aldehyde metathesis
inferred← citeshttps://doi.org/10.1039/c3sc50486gopenalex-snapshot
Carbocyclization of unsaturated thioesters under palladium catalysis
inferred← citeshttps://doi.org/10.1039/c4cc00210eopenalex-snapshot
Enantioselective hydroacylation of N-vinylindole-2-carboxaldehydes
inferred← citeshttps://doi.org/10.1039/c4cc02276aopenalex-snapshot
Enantioselective hydroacylation of olefins with rhodium catalysts
inferred← citeshttps://doi.org/10.1039/c4cs00524dopenalex-snapshot
The emergence of sulfoxides as efficient ligands in transition metal catalysis
inferred← citeshttps://doi.org/10.1039/c4qo00282bopenalex-snapshot
Direct amidation of the phenylalanine moiety in short peptides via Pd-catalyzed C–H activation/C–N formation
inferred← citeshttps://doi.org/10.1039/c4ra03384aopenalex-snapshot
Facile cyclization in the synthesis of highly fused diaza cyclooctanoid compounds using retrievable nano magnetite-supported sulfonic acid catalyst
inferred← citeshttps://doi.org/10.1039/c4sc02026jopenalex-snapshot
Mechanistic insights into hydroacylation with non-chelating aldehydes
inferred← citeshttps://doi.org/10.1039/c5ob00083aopenalex-snapshot
Tandem rhodium catalysis: exploiting sulfoxides for asymmetric transition-metal catalysis
inferred← citeshttps://doi.org/10.1039/c5sc01553gopenalex-snapshot
Rh-catalyzed desymmetrization of α-quaternary centers by isomerization-hydroacylation
inferred← citeshttps://doi.org/10.1039/c6ob00835fopenalex-snapshot
Homogeneous rhodium( i )-catalysis in de novo heterocycle syntheses
inferred← citeshttps://doi.org/10.1039/c6ob02021fopenalex-snapshot
Recent advances in rhodium-catalyzed asymmetric synthesis of heterocycles
inferred← citeshttps://doi.org/10.1039/c8qo00337hopenalex-snapshot
Cobalt-catalyzed intermolecular hydroacylation of aldehydes: initiation of hydride transfer enables turnover
inferred← citeshttps://doi.org/10.1039/c8sc02101eopenalex-snapshot
Nickel(0)-catalyzed linear-selective hydroarylation of unactivated alkenes and styrenes with aryl boronic acids
inferred← citeshttps://doi.org/10.1039/c9cc07558eopenalex-snapshot
Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction
inferred← citeshttps://doi.org/10.1039/c9ob01146copenalex-snapshot
Visible light-mediated intermolecular [2 + 2] photocycloaddition of 1-aryl-2-nitroethenes and olefins
inferred← citeshttps://doi.org/10.1039/c9sc06377copenalex-snapshot
Regiodivergent construction of medium-sized heterocycles from vinylethylene carbonates and allylidenemalononitriles
inferred← citeshttps://doi.org/10.1039/d0sc05543copenalex-snapshot
Rh( i )-catalyzed stereoselective desymmetrization of prochiral cyclohexadienones via highly exo -selective Huisgen-type [3 + 2] cycloaddition
inferred← citeshttps://doi.org/10.1039/d1nj03437eopenalex-snapshot
Direct synthesis of 4-hydroxycoumarins and 4-hydroxy-6-methyl-2-pyrone containing chroman-4-ones via a silver catalyzed radical cascade cyclization reaction
inferred← citeshttps://doi.org/10.1039/d1qo00611hopenalex-snapshot
Visible-light-induced radical cascade cyclization of 1-(allyloxy)-2-(1-arylvinyl)benzenes with sulfonyl chlorides for the synthesis of sulfonated benzoxepines
inferred← citeshttps://doi.org/10.1039/d1qo01183aopenalex-snapshot
A photoredox- or metal-catalyzed three-component cyanoalkylsulfonylation reaction of 1-(allyloxy)-2-(1-arylvinyl)benzenes, potassium metabisulfite, and cycloketone oxime esters: synthesis of cyanoalkylsulfonylated benzoxepines
inferred← citeshttps://doi.org/10.1039/d1sc06900dopenalex-snapshot
Diverse saturated heterocycles from a hydroacylation/conjugate addition cascade
inferred← citeshttps://doi.org/10.1039/d4ra05495dopenalex-snapshot
Recent trends for chemoselectivity modulation in one-pot organic transformations
inferred← citeshttps://doi.org/10.1055/a-2862-0270openalex-snapshot
Earth-Abundant-Metal-Catalyzed Asymmetric Hydrofunctionalizations of Alkenes with Acid Derivatives
inferred← citeshttps://doi.org/10.1134/s1070428015050188openalex-snapshot
Synthesis of new seven-membered benzo-fused heterocyclic ortho-dicarbonitriles
inferred← citeshttps://doi.org/10.1246/cl.160862openalex-snapshot
Lewis Acid-assisted Dirhodium(II)-catalyzed Ketone Hydroacylation
inferred← citeshttps://doi.org/10.1351/pac-con-09-09-05openalex-snapshot
Cationic rhodium(I) complex-catalyzed σ- and π-bond activation cascade: Isomerization of allyl propargyl ethers to allenic aldehydes and dienals
inferred← citeshttps://doi.org/10.1360/ssc-2025-0250openalex-snapshot
Recent advances in cobalt-catalyzed asymmetric hydrocarbonation of alkenes
inferred← citeshttps://doi.org/10.3987/com-12-s(n)89openalex-snapshot
DIVERSITY ORIENTED APPROACH TO 9-ARYL-SUBSTITUTED NAPHTHOXEPINE DERIVATIVES VIA CLAISEN REARRANGEMENT, RING-CLOSING METATHESIS AND SUZUKI–MIYAURA CROSS-COUPLING AS KEY STEPS
inferred← citeshttps://doi.org/10.5059/yukigoseikyokaishi.69.236openalex-snapshot
Rh-catalyzed Hydroacylation Reaction: Development from Intramolecular Reaction into Intermolecular Reaction
inferred← citeshttps://doi.org/10.6023/cjoc202207036openalex-snapshot
Research Advance on Enantioselective Transition Metal-Catalyzed Hydroacylation Reactions
inferred← citeshttps://doi.org/10.70675/579e171azd6e6z4417zb0d3zf85caab98726openalex-snapshot
Ligands BiaxPhos à double chiralité axiale et leurs applications en catalyse asymétrique
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