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Cs2K(UO)2Si4O12: A Mixed-Valence Uranium(IV,V) Silicate

https://doi.org/10.1021/ja9071805
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/anie.200803658openalex-snapshot
A3(U2O4)(Ge2O7) (A=Rb, Cs): Mixed‐Valence Uranium(V,VI) Germanates
inferredcites →https://doi.org/10.1007/978-3-642-50076-3openalex-snapshot
Structural Chemistry of Silicates
inferredcites →https://doi.org/10.1016/0022-3115(88)90019-0openalex-snapshot
Oxidation of UO2 fuel pellets in air at 503 and 543 K studied using X-ray photoelectron spectroscopy and X-ray diffraction
inferredcites →https://doi.org/10.1016/s0022-3115(97)00212-2openalex-snapshot
The crystal structure of ianthinite, [U24+(UO2)4O6(OH)4(H2O)4](H2O)5: a possible phase for Pu4+ incorporation during the oxidation of spent nuclear fuel
inferredcites →https://doi.org/10.1021/es048232bopenalex-snapshot
Bioreduction of Uranium: Environmental Implications of a Pentavalent Intermediate
inferredcites →https://doi.org/10.1021/ic0487880openalex-snapshot
K5(UO2)2[Si4O12(OH)]: A Uranyl Silicate Containing Chains of Four Silicate Tetrahedra Linked by SiO···HOSi Hydrogen Bonds
inferredcites →https://doi.org/10.1021/ic0500199openalex-snapshot
High-Temperature, High-Pressure Hydrothermal Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of Cs2(UO2)(Si2O6) and Variable-Temperature Powder X-ray Diffraction Study of the Hydrate Phase Cs2(UO2)(Si2O6)·0.5H2O
inferredcites →https://doi.org/10.1021/ic50039a012openalex-snapshot
Crystal Structure of the Rhombohedral MO3.3R2O3 Compounds (M = U, W, or Mo) and Their Relation to Ordered R7O12 Phases
inferredcites →https://doi.org/10.1021/ic800300vopenalex-snapshot
K3(U3O6)(Si2O7) and Rb3(U3O6)(Ge2O7): A Pentavalent-Uranium Silicate and Germanate
inferredcites →https://doi.org/10.1021/ic801534mopenalex-snapshot
Pentavalent Uranium Oxide via Reduction of [UO 2 ] 2+ Under Hydrothermal Reaction Conditions †
inferredcites →https://doi.org/10.1021/ja0288284openalex-snapshot
[(CH3)4N][(C5H5NH)0.8((CH3)3NH)0.2]U2Si9O23F4 (USH-8): An Organically Templated Open-Framework Uranium Silicate
inferredcites →https://doi.org/10.1021/ja0543853openalex-snapshot
K(UO)Si2O6: A Pentavalent−Uranium Silicate
inferredcites →https://doi.org/10.1021/ja8084143openalex-snapshot
Synthesis of Thermally Stable Extra-Large Pore Crystalline Materials: A Uranyl Germanate with 12-Ring Channels
inferredcites →https://doi.org/10.1039/b109878kopenalex-snapshot
The novel open-framework uranium silicates Na2(UO2)(Si4O10)·2.1H2O (USH-1) and RbNa(UO2)(Si2O6)·H2O (USH-3)
inferredcites →https://doi.org/10.1039/b208787copenalex-snapshot
Hydrothermal synthesis and structures of the new open-framework uranyl silicates Rb4(UO2)2(Si8O20) (USH-2Rb), Rb2(UO2)(Si2O6)·H2O (USH-4Rb) and A2(UO2)(Si2O6)·0.5H2O (USH-5A; A = Rb, Cs)
inferredcites →https://doi.org/10.1126/science.121.3147.608-aopenalex-snapshot
Preliminary Description of Coffinite-- a New Uranium Mineral
inferredcites →https://doi.org/10.1557/proc-333-625openalex-snapshot
Formation, Oxidation and Alteration of Ianthinite
inferredcites →https://doi.org/10.1557/proc-556-431openalex-snapshot
Oxidative Corrosion of Spent uo2 Fuel in Vapor and Dripping Groundwater at 90°C
inferredcites →https://doi.org/10.2138/am-1999-0926openalex-snapshot
Wyartite; crystallographic evidence for the first pentavalent-uranium mineral

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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[Na7UIVO2(UVO)2(UV/VIO2)2Si4O16]: A Mixed‐Valence Uranium Silicate
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Ca2PbGa8O15: Rational Design, Synthesis, and Structure Determination of a Purely Tetrahedra‐Based Intergrowth Oxide
inferred← citeshttps://doi.org/10.1002/anie.201001095openalex-snapshot
[Na7UIVO2(UVO)2(UV/VIO2)2Si4O16]: A Mixed‐Valence Uranium Silicate
inferred← citeshttps://doi.org/10.1002/anie.201901373openalex-snapshot
Ca2PbGa8O15: Rational Design, Synthesis, and Structure Determination of a Purely Tetrahedra‐Based Intergrowth Oxide
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Three‐Dimensional MOF‐Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8)
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A Mixed‐Valent Uranium Phosphonate Framework Containing UIV, UV, and UVI
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Building [UIV70(OH)36(O)64]4− Oxocluster Frameworks with Sulfate, Transition Metals, and UV
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The Role of Alkalis in Orchestrating Uranyl‐Peroxide Reactivity Leading to Direct Air Capture of Carbon Dioxide
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ChemInform Abstract: Cs2K(UO)2Si4O12: A Mixed‐Valence Uranium(IV,V) Silicate.
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Unprecedented Bidentate Coordination of the Uranyl Cation by the Chromate Anion in the Structure of [(CH3)2CHNH3]2[UO2(CrO4)2]
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Unusual Heterometallic Cation‐Cation Interactions in Uranyl Zinc Germanates
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MOFs of Uranium and the Actinides
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Environmental modeling of uranium interstitial compositions of non-stoichiometric oxides: experimental and theoretical analysis
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Erratum to: Environmental modeling of uranium interstitial compositions of non-stoichiometric oxides: experimental and theoretical analysis
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Single Crystal Growth and Structural Characterization of a Novel Mixed-Valent Ternary Uranium Oxide, K8U7O24
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Characteristic study for the uranium and cesium sorption on bentonite by using XPS and XANES
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Structural topology and dimensional reduction in uranyl oxysalts: eight novel phases in the methylamine–(UO2)(NO3)2–H2SeO4–H2O system
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Crystal Chemistry of Uranium Oxides and Minerals
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High temperature hydrothermal synthesis of inorganic compounds
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Synthesis, structural and emission studies of a bis (carbamoyl methyl) sulfone complex of uranyl nitrate
inferred← citeshttps://doi.org/10.1016/j.inoche.2011.07.009openalex-snapshot
Urothermal in situ ligand synthesis to fabricate a metal-organic framework with (3,4)-connected tfi topology
inferred← citeshttps://doi.org/10.1016/j.jhazmat.2016.10.015openalex-snapshot
Mechanical investigation of U(VI) on pyrrhotite by batch, EXAFS and modeling techniques
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Uranyl carboxyphosphonates that incorporate Cd(II)
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Barium uranyl diphosphonates
inferred← citeshttps://doi.org/10.1016/j.jssc.2012.07.048openalex-snapshot
High temperature synthesis of two open-framework uranyl silicates with ten-ring channels: Cs2(UO2)2Si8O19 and Rb2(UO2)2Si5O13
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Solid-state syntheses and single-crystal characterizations of three tetravalent thorium and uranium silicates
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High-temperature, high-pressure hydrothermal synthesis, characterization, and structural relationships of mixed-alkali metals uranyl silicates
inferred← citeshttps://doi.org/10.1016/j.molstruc.2026.145384openalex-snapshot
BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge
inferred← citeshttps://doi.org/10.1016/j.optmat.2023.114815openalex-snapshot
LiASi2O5 (A = K, Rb): Effects of cations on crystal structure and optical properties
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Synthetic, structural, extraction and theoretical studies of uranyl nitrate dithio-diglycolamide compounds
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Steric effects in complexes of diphenyl(2-pyridyl)phosphine oxide with the uranyl ion. Synthetic, structural and theoretical studies
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Urothermal synthesis and distinct thermal behavior of isostructural transition metal-based MIL-53 analogs
inferred← citeshttps://doi.org/10.1021/acs.cgd.5b01408openalex-snapshot
Flux Growth of [NaK6F][(UO2)3(Si2O7)2] and [KK6Cl][(UO2)3(Si2O7)2]: The Effect of Surface Area to Volume Ratios on Reaction Products
inferred← citeshttps://doi.org/10.1021/acs.cgd.6b00817openalex-snapshot
Tubular Chains, Single Layers, and Multiple Chains in Uranyl Silicates: A2[(UO2)Si4O10] (A = Na, K, Rb, Cs)
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[U(H2O)2]{[(UO2)10O10(OH)2][(UO4)(H2O)2]}: A Mixed-Valence Uranium Oxide Hydrate Framework
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Exploring the Valence Diversity of Uranium by Flux Growth of Uranium Silicate under Inert Atmosphere
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Insight into γ-Irradiation-Induced Structure Evolution of Uranium(IV) Germanates as Crystalline Nuclear Waste Forms
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b00364openalex-snapshot
Flux Crystal Growth and Optical Properties of Two Uranium-Containing Silicates: A2USiO6 (A = Cs, Rb)
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b00556openalex-snapshot
Flux Synthesis, Structure, Properties, and Theoretical Magnetic Study of Uranium(IV)-Containing A2USi6O15 (A = K, Rb) with an Intriguing Green-to-Purple, Crystal-to-Crystal Structural Transition in the K Analogue
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b01004openalex-snapshot
A2MnU3O11 (A = K, Rb) and Li3.2Mn1.8U6O22: Three New Alkali-Metal Manganese Uranium(VI) Oxides Related to Natrotantite
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5b01390openalex-snapshot
K2Ca4[(UO2)(Si2O7)2]: A Uranyl Silicate with a One-Dimensional Chain Structure
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6b02010openalex-snapshot
Th(H2O)(IVO3)2[IVII0.6V1.76O7(OH)]: A Mixed-Valent Iodine Compound Containing Periodate Stabilized by Crystallographically Compatible Lattice Sites
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Flux versus Hydrothermal Growth: Polymorphism of A2(UO2)Si2O6 (A = Rb, Cs)
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.7b00480openalex-snapshot
Systematic Investigation of the in Situ Reduction Process from U(VI) to U(IV) in a Phosphonate System under Mild Solvothermal Conditions
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Hydrothermal Synthesis, Study, and Classification of Microporous Uranium Silicates and Germanates
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.8b00487openalex-snapshot
Na2(UO2)(BO3): An All-Uranium(V) Borate Synthesized under Mild Hydrothermal Conditions
inferred← citeshttps://doi.org/10.1021/cr300212fopenalex-snapshot
Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products
inferred← citeshttps://doi.org/10.1021/ic1006132openalex-snapshot
Comparison of Thorium(IV) and Uranium(VI) Carboxyphosphonates
inferred← citeshttps://doi.org/10.1021/ic100728sopenalex-snapshot
Crystal Chemistry of the Potassium and Rubidium Uranyl Borate Families Derived from Boric Acid Fluxes
inferred← citeshttps://doi.org/10.1021/ic200508vopenalex-snapshot
Cs8UIV(UVIO2)3(Ge3O9)3·3H2O: A Mixed-Valence Uranium Germanate with 9-Ring Channels
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Cs2USi6O15: A Tetravalent Uranium Silicate
inferred← citeshttps://doi.org/10.1021/ic201789fopenalex-snapshot
Cs4UGe8O20: A Tetravalent Uranium Germanate Containing Four- and Five-Coordinate Germanium
inferred← citeshttps://doi.org/10.1021/ic201857eopenalex-snapshot
High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of an Open-Framework Uranyl Silicate with Nine-Ring Channels: Cs2UO2Si10O22
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Lanthanide-Thiophene-2,5-dicarboxylate Frameworks: Ionothermal Synthesis, Helical Structures, Photoluminescent Properties, and Single-Crystal-to-Single-Crystal Guest Exchange
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Ba8Hg3U3S18: A Complex Uranium(+4)/Uranium(+5) Sulfide
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Metal–Organic-Framework-Type 1D-Channel Open Network of a Tetravalent Uranium Trimesate
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Cs3UGe7O18: A Pentavalent Uranium Germanate Containing Four- and Six-Coordinate Germanium
inferred← citeshttps://doi.org/10.1021/ic300391popenalex-snapshot
Mixed-Valent Uranium(IV,VI) Diphosphonate: Synthesis, Structure, and Spectroscopy
inferred← citeshttps://doi.org/10.1021/ic300398aopenalex-snapshot
Steric Effects on Uranyl Complexation: Synthetic, Structural, and Theoretical Studies of Carbamoyl Pyrazole Compounds of the Uranyl(VI) Ion
inferred← citeshttps://doi.org/10.1021/ic301091fopenalex-snapshot
Mixed-Valence Uranium Germanate and Silicate: Csx(UVO)(UIV/VO)2(Ge2O7)2 (x = 3.18) and Cs4(UVO)(UIV/VO)2(Si2O7)2
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Flux Synthesis, Crystal Structure, and Photoluminescence of a Heterometallic Uranyl-Europium Germanate with U═O–Eu Linkage: K4[(UO2)Eu2(Ge2O7)2]
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High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a Salt-Inclusion Mixed-Valence Uranium(V,VI) Silicate: [Na9F2][(UVO2)(UVIO2)2(Si2O7)2]
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Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids
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Mixed-Valence Uranium(V,VI) and Uranyl Oxyhydroxides Synthesized under High-Temperature, High-Pressure Hydrothermal Conditions: Na5[U5O16(OH)2] and Na5[U5O17(OH)]
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Further Evidence for the Stabilization of U(V) within a Tetraoxo Core
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Straightforward Reductive Routes to Air-Stable Uranium(III) and Neptunium(III) Materials
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Unexpected Actinyl Cation-Directed Structural Variation in Neptunyl(VI) A-Type Tri-lacunary Heteropolyoxotungstate Complexes
inferred← citeshttps://doi.org/10.1021/ja4067207openalex-snapshot
Isolation of the Large {Actinide}38 Poly-oxo Cluster with Uranium
inferred← citeshttps://doi.org/10.1039/c0cc03507fopenalex-snapshot
Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials
inferred← citeshttps://doi.org/10.1039/c1dt11742dopenalex-snapshot
Stabilising pentavalent actinides—visible–near infrared and X-ray absorption spectroscopic studies of the utility of the [(Np 3 W 4 O 15 )(H 2 O) 3 (MW 9 O 33 ) 3 ] 18 − (M = Sb, Bi) structural type
inferred← citeshttps://doi.org/10.1039/c5ce00504copenalex-snapshot
Synthesis and structure of the new pentanary uranium( vi ) silicate, K 4 CaUSi 4 O 14 , a member of a structural family related to fresnoite
inferred← citeshttps://doi.org/10.1039/c7tc03000bopenalex-snapshot
A new phase-matchable nonlinear optical silicate: Rb 2 ZnSi 3 O 8
inferred← citeshttps://doi.org/10.1039/c8cc07789dopenalex-snapshot
Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates
inferred← citeshttps://doi.org/10.1039/c8dt04675aopenalex-snapshot
Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides
inferred← citeshttps://doi.org/10.1039/d0dt02944kopenalex-snapshot
Uranyl oxide hydrate frameworks with lanthanide ions
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Progress in solid state and coordination chemistry of actinides in China
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High Resolution Core- and Valence-Level XPS Studies of the Properties (Structural, Chemical and Bonding) of Silicate Minerals and Glasses
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Advances Of Synchrotron Radiation-Based Radiometallomics For The Study Of Uranium
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