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Evidence of Significant Covalent Bonding in Au(CN) 2 −

https://doi.org/10.1021/ja908106e
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Vibrational spectra and structures of some dicyanoaurate(I) complexes
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Electrospray ionization photoelectron spectroscopy: Probing the electronic structure of inorganic metal complexes in the gas-phase
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Assignment of photoelectron spectra of AuX2 (X=Cl, Br, and I) clusters
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Hydrothermal synthesis, structural, Raman, and luminescence studies of Am[M(CN)2]3·3H2O and Nd[M(CN)2]3·3H2O (M=Ag, Au): Bimetallic coordination polymers containing both trans-plutonium and transition metal elements
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Relativistic effects in gold chemistry. 3. Gold(I) complexes
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Molecular Structures, Bond Energies, and Bonding Analysis of Group 11 Cyanides TM(CN) and Isocyanides TM(NC) (TM = Cu, Ag, Au)
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Structure of AuCN Determined from Total Neutron Diffraction
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Crystal Structures of AuCN and AgCN and Vibrational Spectroscopic Studies of AuCN, AgCN, and CuCN
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Bis(carbonyl)gold(I) undecafluorodiantimonate(V), [Au(CO)2][Sb2F11]: synthesis, vibrational, and carbon-13 NMR study and the molecular structure of bis(acetonitrile)gold(I) hexafluoroantimonate(V), [Au(NCCH3)2][SbF6]
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Probing the Electronic Structure and Chemical Bonding of Gold Oxides and Sulfides in AuOn− and AuSn− (n = 1, 2)
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Detection of Free Monomeric Silver(I) and Gold(I) Cyanides, AgCN and AuCN: Microwave Spectra and Molecular Structure
inferredcites →https://doi.org/10.1021/jp0736645openalex-snapshot
Theoretical Calculation of the Photodetachment Spectra of XAuY- (X, Y = Cl, Br, and I)
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Relativistic effects in homogeneous gold catalysis
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Photodetachment photoelectron spectroscopy of multiply charged anions using electrospray ionization
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Vibrational Spectrum and Structure of Metal-Cyanide Complexes in the Solid State. II. KAu(CN)2
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Structure and bonding of the MCN molecules, M=Cu,Ag,Au,Rg
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Photoelectron spectroscopy of anions at 118.2nm: Observation of high electron binding energies in superhalogens MCl4− (M=Sc, Y, La)
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Development of a low-temperature photoelectron spectroscopy instrument using an electrospray ion source and a cryogenically controlled ion trap
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A simple measure of electron localization in atomic and molecular systems
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Vibrationally resolved photoelectron spectra of CuCN− and AgCN− and ab initio studies of the structure and bonding in CuCN
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Spin-orbit matrix elements for internally contracted multireference configuration interaction wavefunctions
inferredcites →https://doi.org/10.1107/s0365110x59002109openalex-snapshot
The crystal structure of KAu(CN)2

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inferred← citeshttps://doi.org/10.1038/ncomms3223openalex-snapshot
Probing the nature of gold–carbon bonding in gold–alkynyl complexes
inferred← citeshttps://doi.org/10.1038/ncomms5861openalex-snapshot
Pressure-stabilized lithium caesides with caesium anions beyond the −1 state
inferred← citeshttps://doi.org/10.1038/s42004-024-01257-5openalex-snapshot
Photodetachment photoelectron spectroscopy shows isomer-specific proton-coupled electron transfer reactions in phenolic nitrate complexes
inferred← citeshttps://doi.org/10.1038/s44160-022-00225-yopenalex-snapshot
Synthesis and reactivity of copper carbyne anion complexes
inferred← citeshttps://doi.org/10.1038/srep28900openalex-snapshot
Protein-directed synthesis of highly monodispersed, spherical gold nanoparticles and their applications in multidimensional sensing
inferred← citeshttps://doi.org/10.1039/c003886eopenalex-snapshot
Covalent gold
inferred← citeshttps://doi.org/10.1039/c0cc04591hopenalex-snapshot
Colorimetric assay for cyanide and cyanogenic glycoside using polysorbate 40-stabilized gold nanoparticles
inferred← citeshttps://doi.org/10.1039/c1cc13149dopenalex-snapshot
Dual-functional Au–Fe3O4 dumbbell nanoparticles for sensitive and selective turn-on fluorescent detection of cyanide based on the inner filter effect
inferred← citeshttps://doi.org/10.1039/c1sc00487eopenalex-snapshot
The mixed cyanide halide Au(i) complexes, [XAuCN]− (X = F, Cl, Br, and I): evolution from ionic to covalent bonding
inferred← citeshttps://doi.org/10.1039/c2ay25291kopenalex-snapshot
Using polysorbate 40-stabilized gold nanoparticles in colorimetric assays of hydrogen cyanide in cyanogenic glycoside-containing plants
inferred← citeshttps://doi.org/10.1039/c2cp23490dopenalex-snapshot
Probing the electronic structure and chemical bonding of the “staple” motifs of thiolate gold nanoparticles: Au(SCH3)2− and Au2(SCH3)3−
inferred← citeshttps://doi.org/10.1039/c2cp41164dopenalex-snapshot
Photoelectron imaging and theoretical calculations of gold–silver hydrides: comparing the characteristics of Au, Ag and H in small clusters
inferred← citeshttps://doi.org/10.1039/c2cs15325dopenalex-snapshot
Sub-nanometre sized metal clusters: from synthetic challenges to the unique property discoveries
inferred← citeshttps://doi.org/10.1039/c2jm15516hopenalex-snapshot
Functionalized polyacetylenes with strong luminescence: “turn-on” fluorescent detection of cyanide based on the dissolution of gold nanoparticles and its application in real samples
inferred← citeshttps://doi.org/10.1039/c2nr33202gopenalex-snapshot
Disassembly mediated fluorescence recovery of gold nanodots for selective sulfide sensing
inferred← citeshttps://doi.org/10.1039/c2sc01052fopenalex-snapshot
Observation and investigation of the uranyl tetrafluoride dianion (UO2F42−) and its solvation complexes with water and acetonitrile
inferred← citeshttps://doi.org/10.1039/c2sc20984eopenalex-snapshot
The electronic structure and chemical bonding in gold dihydride: AuH2− and AuH2
inferred← citeshttps://doi.org/10.1039/c3cp55362kopenalex-snapshot
Photoelectron spectroscopy of lithium and gold alloyed boron oxide clusters: charge transfer complexes, covalent gold, hyperhalogen, and dual three-center four-electron hyperbonds
inferred← citeshttps://doi.org/10.1039/c4dt04031gopenalex-snapshot
On the gold–ligand covalency in linear [AuX 2 ] − complexes
inferred← citeshttps://doi.org/10.1039/c4ra14806aopenalex-snapshot
A simple cyanide sensing probe based on Ag/Fe 3 O 4 nanoparticles
inferred← citeshttps://doi.org/10.1039/c5dt00942aopenalex-snapshot
Copper mediated decyano decarboxylative coupling of cyanoacetate ligands: Pesci versus Lewis acid mechanism
inferred← citeshttps://doi.org/10.1039/c5nr03033aopenalex-snapshot
Highly selective and sensitive nanoprobes for cyanide based on gold nanoclusters with red fluorescence emission
inferred← citeshttps://doi.org/10.1039/c5ob01617gopenalex-snapshot
A catalytic chemodosimetric approach for detection of nanomolar cyanide ions in water, blood serum and live cell imaging
inferred← citeshttps://doi.org/10.1039/c5sc03568fopenalex-snapshot
Bond-bending isomerism of Au 2 I 3 − : competition between covalent bonding and aurophilicity
inferred← citeshttps://doi.org/10.1039/c6an02112copenalex-snapshot
The mechanism and application of the protein-stabilized gold nanocluster sensing system
inferred← citeshttps://doi.org/10.1039/c6cp01542eopenalex-snapshot
Examining the structural evolution of bicarbonate–water clusters: insights from photoelectron spectroscopy, basin-hopping structural search, and comparison with available IR spectral studies
inferred← citeshttps://doi.org/10.1039/c7cp05637kopenalex-snapshot
Density functional theory modeling of C–Au chemical bond formation in gold implanted polyethylene
inferred← citeshttps://doi.org/10.1039/c8cp01548aopenalex-snapshot
Photoelectron spectroscopic and computational studies of [EDTA·M( iii )] − complexes (M = H 3 , Al, Sc, V–Co)
inferred← citeshttps://doi.org/10.1039/c8cp05154bopenalex-snapshot
Understanding gold nanoparticle dissolution in cyanide-containing solution via impact-chemistry
inferred← citeshttps://doi.org/10.1039/c8fd00175hopenalex-snapshot
Electrospray ionization photoelectron spectroscopy of cryogenic [EDTA·M( ii )] 2− complexes (M = Ca, V–Zn): electronic structures and intrinsic redox properties
inferred← citeshttps://doi.org/10.1039/c9cp03788hopenalex-snapshot
Exploring the structure, bonding and stability of noble gas compounds promoted by superhalogens. A case study on HNgMX 3 (Ng = Ar–Rn, M = Be–Ca, X = F–Br) via combined high-level ab initio and DFT calculations
inferred← citeshttps://doi.org/10.1039/d0nj05326kopenalex-snapshot
Dative versus electron-sharing bonding in the isoelectronic argon compounds ArR + (R = CH 3 , NH 2 , OH, and F)
inferred← citeshttps://doi.org/10.1039/d1ce00964hopenalex-snapshot
Crystal engineering of aurophilic supramolecular architectures and coordination polymers based on butterfly-like copper–dicyanoaurate complexes: vapochromism, P – T behaviour and multi-metallic cocrystal formation
inferred← citeshttps://doi.org/10.1039/d1sm01031jopenalex-snapshot
Au 3+ -Induced gel network formation of proteins
inferred← citeshttps://doi.org/10.1039/d2cp05544aopenalex-snapshot
The additional nitrogen atom breaks the uranyl structure: a combined photoelectron spectroscopy and theoretical study of NUO 2 −
inferred← citeshttps://doi.org/10.1039/d3gc03713dopenalex-snapshot
Complexation of heavy metal cations with imidazolium ionic liquids lowers their reduction energy: implications for electrochemical separations
inferred← citeshttps://doi.org/10.1039/d5cp03821aopenalex-snapshot
Gas-phase negative ion photoelectron spectroscopy and reactivity of phenylacetylide PhCC−
inferred← citeshttps://doi.org/10.1063/1.3658858openalex-snapshot
Photoelectron spectroscopy of higher bromine and iodine oxide anions: Electron affinities and electronic structures of BrO2,3 and IO2–4 radicals
inferred← citeshttps://doi.org/10.1063/1.3670415openalex-snapshot
Localization scheme for relativistic spinors
inferred← citeshttps://doi.org/10.1063/1.4716182openalex-snapshot
Photoelectron spectroscopy and theoretical studies of UF5− and UF6−
inferred← citeshttps://doi.org/10.1063/1.4742062openalex-snapshot
Photoelectron spectroscopy and the electronic structure of the uranyl tetrachloride dianion: UO2Cl42−
inferred← citeshttps://doi.org/10.1063/1.4792501openalex-snapshot
On the structures and bonding in boron-gold alloy clusters: B6Aun− and B6Aun (n = 1−3)
inferred← citeshttps://doi.org/10.1063/1.4868553openalex-snapshot
Photoelectron imaging and theoretical study on the structure and chemical binding of the mixed-ligand M(I) complexes, [HMSH]− (M = Cu, Ag, and Au)
inferred← citeshttps://doi.org/10.1063/1.4916399openalex-snapshot
Photoelectron spectroscopy and theoretical studies of gaseous uranium hexachlorides in different oxidation states: UCl6q− (q = 0–2)
inferred← citeshttps://doi.org/10.1063/1.4922958openalex-snapshot
Are superhalogens without halogen ligand capable of transcending traditional halogen-based superhalogens? Ab initio case study of binuclear anions based on pseudohalogen ligand
inferred← citeshttps://doi.org/10.1063/1.4934798openalex-snapshot
Intriguing structures and magic sizes of heavy noble metal nanoclusters around size 55 governed by relativistic effect and covalent bonding
inferred← citeshttps://doi.org/10.1063/1.5038191openalex-snapshot
Why do higher VDEs of superhalogen not ensure improved stabilities of the noble gas hydrides promoted by them? A high-level ab initio case study
inferred← citeshttps://doi.org/10.1063/1674-0068/cjcp2310102openalex-snapshot
Spin-orbit coupling in molecular complexes beyond van der Waals regime: Key factors for further splitting of 2P3/2 ground state
inferred← citeshttps://doi.org/10.1063/1674-0068/cjcp2507094openalex-snapshot
Structure and stabilization mechanism of [ATP4−·Mg2+]2−: A joint negative ion photoelectron spectroscopic and computational study
inferred← citeshttps://doi.org/10.1063/5.0099789openalex-snapshot
Significant π bonding in coinage metal complexes OCTMCCO− from infrared photodissociation spectroscopy and theoretical calculations
inferred← citeshttps://doi.org/10.1063/5.0159326openalex-snapshot
How generic is iodide-tagging photoelectron spectroscopy: An extended investigation on the Gly·X− (Gly = glycine, X = Cl or Br) complexes
inferred← citeshttps://doi.org/10.1063/5.0190757openalex-snapshot
Deprotonated sulfamic acid and its homodimers: Does sulfamic acid adopt zwitterion during cluster growth?
inferred← citeshttps://doi.org/10.1063/5.0218918openalex-snapshot
A comprehensive study on three typical photoacid generators using photoelectron spectroscopy and ab initio calculations
inferred← citeshttps://doi.org/10.1063/5.0338285openalex-snapshot
Cryogenic photoelectron and photodetachment spectroscopy of complex anions
inferred← citeshttps://doi.org/10.1073/pnas.1820812116openalex-snapshot
Rational design of an argon-binding superelectrophilic anion
inferred← citeshttps://doi.org/10.1080/00958972.2014.971020openalex-snapshot
NMR and kinetic studies of the interactions of [Au(cis-DACH)Cl2]Cl and [Au(cis-DACH)2]Cl3 with potassium cyanide in aqueous solution
inferred← citeshttps://doi.org/10.1107/s0108270111051365openalex-snapshot
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloridogold(I)
inferred← citeshttps://doi.org/10.1134/s1070328424600979openalex-snapshot
Heterometallic Manganese(III) Coordination Polymers with Schiff Bases (H2SALPN) and Dicyanometallates
inferred← citeshttps://doi.org/10.1144/sp402.4openalex-snapshot
Gold speciation and transport in geological fluids: insights from experiments and physical-chemical modelling
inferred← citeshttps://doi.org/10.1149/1945-7111/ae0553openalex-snapshot
Gold Electrodeposition on Tungsten Single Crystals and Thin Wires
inferred← citeshttps://doi.org/10.12794/metadc499981openalex-snapshot
A Study of Silver: an Alternative Maldi Matrix for Low Weight Compounds and Mass Spectrometry Imaging
inferred← citeshttps://doi.org/10.21203/rs.3.rs-2793420/v1openalex-snapshot
Is pseudohalide CN - a real halide? An easy identification method
inferred← citeshttps://doi.org/10.2320/jinstmet.ja202104openalex-snapshot
Review of Recent Progress on Dissolution of Precious Metals and Speciation of Their Complexes in Aqueous Solutions
inferred← citeshttps://doi.org/10.3389/fchem.2022.909110openalex-snapshot
Metal Graphitic Nanocapsules for Theranostics in Harsh Conditions
inferred← citeshttps://doi.org/10.3390/bios12070511openalex-snapshot
An Overview on Coinage Metal Nanocluster-Based Luminescent Biosensors via Etching Chemistry
inferred← citeshttps://doi.org/10.3390/ijms24021682openalex-snapshot
Properties of Gaseous Deprotonated L-Cysteine S-Sulfate Anion [cysS-SO3]−: Intramolecular H-Bond Network, Electron Affinity, Chemically Active Site, and Vibrational Fingerprints
inferred← citeshttps://doi.org/10.3390/molecules26123484openalex-snapshot
Complexes with Atomic Gold Ions: Efficient Bis-Ligand Formation
inferred← citeshttps://doi.org/10.3390/s17081895openalex-snapshot
Ag Nanorods-Oxide Hybrid Array Substrates: Synthesis, Characterization, and Applications in Surface-Enhanced Raman Scattering
inferred← citeshttps://doi.org/10.3390/sym15071329openalex-snapshot
Is Pseudohalide CN− a Real Halide? A General Symmetry Consideration
inferred← citeshttps://doi.org/10.3390/targets4030029openalex-snapshot
Metal-Graphitic Nanocapsules for Molecular Spectroscopy-Based Chemical Analysis, Biosensing, and Targeted Diagnosis
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