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Are Glycosyl Triflates Intermediates in the Sulfoxide Glycosylation Method? A Chemical and 1H, 13C, and 19F NMR Spectroscopic Investigation
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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Interfacial effects for transient heat conduction in the non‐continuum regime
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The methanolysis of some derivatives of 2,3,4-tri-O-benzyl-α-D-glucopyranosyl bromide in the presence and absence of silver salts
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Synthesis of glycosyl halides and glycosides via 1-O-sulfonyl derivatives
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A new synthesis of glycosides. Reactions of trifluoromethanesulfonic anhydride at the anomeric centre
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A synthesis of β-d-mannopyranosides by glycosidation at C-1
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Chemistry of the glycosidic linkage. An efficient synthesis of 1,2-trans-di-saccharides
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2,3,4,6-Tetra-O-benzyl-β-d-galactopyranosyl phenyl sulfoxide as a glycosyl donor. Synthesis of some oligosaccharides containing and α-d-galactopyranosyl group
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Preparation and reactions of some cyclic orthoester derivatives
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Regioselective manipulation of hydroxyl groups via organotin derivatives
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Ferric chloride, an anomerization catalyst for the preparation of alkyl α-glycopyranosides
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PhenylsulfenylD-ribofuranosides as efficient ribosyl donors: Application to the synthesis of [1′,-13C]-(deoxy)nucleosides
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vic-Disulfoxides and OS-sulfenyl sulfinates
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Total synthesis of (-)-hikizimycin employing the strategy of two-directional chain synthesis
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Glycosylation of unreactive substrates
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NMR chemical shift and NMR isotope shift evidence for the influence of nonbonded interactions on charge distribution in .alpha.,.beta.-unsaturated methoxycarbenium ions
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Photochemical rearrangements of o- and m-dichlorobenzene cations to p-dichlorobenzene cation in solid argon
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Stereoselective α-Sialylation with Sialyl Xanthate and Phenylsulfenyl Triflate as a Promotor
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A Solvation-Assisted Model for Estimating Anomeric Reactivity. Predicted versus Observed Trends in Hydrolysis of n-Pentenyl Glycosides1
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Simple and Efficient Method for the Oxidation of Sulfides to Sulfoxides: Application to the Preparation of Glycosyl Sulfoxides
inferredcites →https://doi.org/10.1126/science.274.5292.1520openalex-snapshot
Parallel Synthesis and Screening of a Solid Phase Carbohydrate Library
inferredcites →https://doi.org/10.1139/v81-069openalex-snapshot
Mécanisme de la réaction de glycosylation par réversion acide en présence d'anhydride trifluorométhane sulfonique comme agent de condensation
inferredcites →https://doi.org/10.1515/znb-1995-0431openalex-snapshot
Block Synthesis of Oligosaccharides under Mild Conditions
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Trifluoromethanesulfonic Anhydride
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Trifluoromethanesulfonic Anhydride
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Iterative Glycosylation of 2‐Deoxy‐2‐aminothioglycosides and Its Application to the Combinatorial Synthesis of Linear Oligoglucosamines
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Dual Stereoselectivity of 1‐(2′‐Carboxy)benzyl 2‐Deoxyglycosides as Glycosyl Donors in the Direct Construction of 2‐Deoxyglycosyl Linkages
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Mechanism of 4,6‐O‐Benzylidene‐Directed β‐Mannosylation as Determined by α‐Deuterium Kinetic Isotope Effects
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Direct and Stereoselective Synthesis of 2‐Acetamido‐2‐deoxy‐β‐ D ‐glycopyranosides by Using the Phosphite Method
inferred← citeshttps://doi.org/10.1002/anie.200462439openalex-snapshot
Total Synthesis of Caprazol, a Core Structure of the Caprazamycin Antituberculosis Antibiotics
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A Highly Reactive and Stereoselective β‐Mannopyranosylation System: Mannosyl 4‐Pentenoate/PhSeOTf
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inferred← citeshttps://doi.org/10.1007/978-3-642-56874-9_37openalex-snapshot
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inferred← citeshttps://doi.org/10.1007/978-3-662-11893-1_13openalex-snapshot
Stereoselective Synthesis of β-manno Glycosides
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Pre-activation based stereoselective glycosylations: Stereochemical control by additives and solvent
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Alkyl Chalcogenides: Sulfur-based Functional Groups
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6.01 Synthesis of Glycosides
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Synthesis of 2-Deoxyglycosides
inferred← citeshttps://doi.org/10.1016/b978-0-12-819475-1.00016-xopenalex-snapshot
1,2-cis O-Glycosylation Methods
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Photochemical Glycosylation
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Formation of the Glycosidic Linkage
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Synthesis of Glycosides
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The Stereoselective Synthesis of β-Mannosides
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The Formation of the Glycosidic Linkage
inferred← citeshttps://doi.org/10.1016/b978-044451967-2/00008-8openalex-snapshot
O-Glycosidation Methods
inferred← citeshttps://doi.org/10.1016/j.carres.2005.06.016openalex-snapshot
Glycosylation of allyl 2-acetamido-4,6-O-benzylidene-2-deoxy-α-d-glucopyranoside with bulky substituted glycosyl donors
inferred← citeshttps://doi.org/10.1016/j.carres.2006.03.014openalex-snapshot
2′-Carboxybenzyl glycosides: glycosyl donors for C-glycosylation and conversion into other glycosyl donors
inferred← citeshttps://doi.org/10.1016/j.carres.2006.03.036openalex-snapshot
On the nitrile effect in l-rhamnopyranosylation
inferred← citeshttps://doi.org/10.1016/j.carres.2006.09.002openalex-snapshot
The use of cyclic bifunctional protecting groups in oligosaccharide synthesis—an overview
inferred← citeshttps://doi.org/10.1016/j.carres.2009.07.013openalex-snapshot
Recent advances in the synthesis of 2-deoxy-glycosides
inferred← citeshttps://doi.org/10.1016/j.carres.2009.10.011openalex-snapshot
Development of new glycosylation methodologies for the synthesis of archaeal-derived glycolipid adjuvants
inferred← citeshttps://doi.org/10.1016/j.carres.2010.02.027openalex-snapshot
The impact of oxacarbenium ion conformers on the stereochemical outcome of glycosylations
inferred← citeshttps://doi.org/10.1016/j.carres.2010.06.004openalex-snapshot
Computational study of the influence of cyclic protecting groups in stereoselectivity of glycosylation reactions
inferred← citeshttps://doi.org/10.1016/j.carres.2011.06.026openalex-snapshot
Solvent-induced anomeric diastereoselectivity switching using a single glycosyl donor
inferred← citeshttps://doi.org/10.1016/j.carres.2011.08.015openalex-snapshot
Study of the stereoselectivity of 2-azido-2-deoxygalactosyl donors: relationship to the steric factors of glycosyl acceptors
inferred← citeshttps://doi.org/10.1016/j.carres.2012.09.023openalex-snapshot
Synthetic carbohydrate research based on organic electrochemistry
inferred← citeshttps://doi.org/10.1016/j.carres.2012.09.025openalex-snapshot
Revisit of the phenol O-glycosylation with glycosyl imidates, BF3·OEt2 is a better catalyst than TMSOTf
inferred← citeshttps://doi.org/10.1016/j.carres.2013.08.010openalex-snapshot
Synthesis and antiviral evaluation of 6′-acylamido-6′-deoxy-α-d-mannoglycerolipids
inferred← citeshttps://doi.org/10.1016/j.carres.2013.11.016openalex-snapshot
Is an acyl group at O-3 in glucosyl donors able to control α-stereoselectivity of glycosylation? The role of conformational mobility and the protecting group at O-6
inferred← citeshttps://doi.org/10.1016/j.carres.2014.06.020openalex-snapshot
A propos of glycosyl cations and the mechanism of chemical glycosylation; the current state of the art
inferred← citeshttps://doi.org/10.1016/j.carres.2014.10.013openalex-snapshot
Contact ion pairs and solvent-separated ion pairs from d-mannopyranosyl and d-glucopyranosyl triflates
inferred← citeshttps://doi.org/10.1016/j.carres.2015.02.007openalex-snapshot
Common side reactions of the glycosyl donor in chemical glycosylation
inferred← citeshttps://doi.org/10.1016/j.carres.2015.03.010openalex-snapshot
Theoretical study on the effects of a 4,6-O-diacetal protecting group on the stability of ion pairs from d-mannopyranosyl and d-glucopyranosyl triflates
inferred← citeshttps://doi.org/10.1016/j.carres.2016.09.019openalex-snapshot
Synthesis and intramolecular glycosylation of sialyl mono-esters of o-xylylene glycol. The importance of donor configuration and nitrogen protecting groups on cyclization yield and selectivity; isolation and characterization of a N-sialyl acetamide indicative of participation by acetonitrile
inferred← citeshttps://doi.org/10.1016/j.carres.2019.06.013openalex-snapshot
Synthesis of the hexasaccharide from Trypanosoma cruzi mucins with the Galp(1 → 2)Galf unit constructed with a superarmed thiogalactopyranosyl donor
inferred← citeshttps://doi.org/10.1016/j.carres.2021.108237openalex-snapshot
4,6-Di-O-Benzylidenyl group-directed preparation of 2-deoxy-2-azido-α-d-galactopyranosides promoted by 3-O-TBDPS
inferred← citeshttps://doi.org/10.1016/j.carres.2022.108556openalex-snapshot
A comprehensive review on natural occurrence, synthesis and biological activities of glycolipids
inferred← citeshttps://doi.org/10.1016/j.carres.2024.109227openalex-snapshot
Role of ion pairs in model glycosylation reactions of permethylated glucosyl and xylosyl triflates
inferred← citeshttps://doi.org/10.1016/j.carres.2025.109396openalex-snapshot
Named reaction in carbohydrate chemistry: A review
inferred← citeshttps://doi.org/10.1016/j.cclet.2017.09.034openalex-snapshot
Modulation of the stereoselectivity and reactivity of glycosylation via ( p -Tol) 2 SO/Tf 2 O preactivation strategy: From O -, C -sialylation to general O -, N -glycosylation
inferred← citeshttps://doi.org/10.1016/j.crci.2010.03.016openalex-snapshot
A propos of glycosyl cations and the mechanism of chemical glycosylation
inferred← citeshttps://doi.org/10.1016/j.crci.2010.05.010openalex-snapshot
Novel protecting groups in carbohydrate chemistry
inferred← citeshttps://doi.org/10.1016/j.gresc.2024.03.004openalex-snapshot
Unraveling chemical glycosylation: DFT insights into factors imparting stereoselectivity
inferred← citeshttps://doi.org/10.1016/j.tet.2004.08.076openalex-snapshot
A highly stereoselective construction of 1,2-trans-β-glycosidic linkages capitalizing on 2-azido-2-deoxy-d-glycosyl diphenyl phosphates as glycosyl donors
inferred← citeshttps://doi.org/10.1016/j.tet.2005.01.070openalex-snapshot
Use of O-glycosylation in total synthesis
inferred← citeshttps://doi.org/10.1016/j.tet.2005.08.090openalex-snapshot
Direct and stereoselective synthesis of β-d-mannosides using 4,6-O-benzylidene-protected mannosyl diethyl phosphite as a donor
inferred← citeshttps://doi.org/10.1016/j.tet.2007.03.128openalex-snapshot
β-Selective glucosylation in the absence of neighboring group participation: influence of the 3,4-O-bisacetal protecting system
inferred← citeshttps://doi.org/10.1016/j.tet.2008.05.051openalex-snapshot
Glycosulfoxides in carbohydrate chemistry
inferred← citeshttps://doi.org/10.1016/j.tet.2010.02.052openalex-snapshot
Convergent synthesis of the tetrasaccharide repeating unit related to the O-antigenic polysaccharide of Escherichia coli 78
inferred← citeshttps://doi.org/10.1016/j.tet.2010.06.007openalex-snapshot
The methylsulfonylethoxymethyl (Msem) as a hydroxyl protecting group in oligosaccharide synthesis
inferred← citeshttps://doi.org/10.1016/j.tet.2015.06.014openalex-snapshot
Directing effect by remote electron-withdrawing protecting groups at O-3 or O-4 position of donors in glucosylations and galactosylations
inferred← citeshttps://doi.org/10.1016/j.tet.2020.131800openalex-snapshot
A dehydrative glycosylation protocol mediated by nonafluorobutanesulfonyl fluoride (NfF)
inferred← citeshttps://doi.org/10.1016/j.tet.2021.132140openalex-snapshot
Recent advances in direct synthesis of 2-deoxy glycosides and thioglycosides
inferred← citeshttps://doi.org/10.1016/j.tetasy.2004.11.032openalex-snapshot
Disarming, non-participating 2-O-protecting groups in manno- and rhamnopyranosylation: scope and limitations of sulfonates, vinylogous esters, phosphates, cyanates, and nitrates
inferred← citeshttps://doi.org/10.1016/j.tetasy.2009.02.024openalex-snapshot
A unique approach to the synthesis of a dengue vaccine and the novel tetrasaccharide that results
inferred← citeshttps://doi.org/10.1016/j.tetlet.2003.08.063openalex-snapshot
Glycosylation with 2′-thio-S-acetyl participation
inferred← citeshttps://doi.org/10.1016/j.tetlet.2008.04.017openalex-snapshot
An efficient glycosylation protocol with glycosyl ortho-alkynylbenzoates as donors under the catalysis of Ph3PAuOTf
inferred← citeshttps://doi.org/10.1016/j.tetlet.2008.07.089openalex-snapshot
Synthesis of the repeating trisaccharide unit of the cell wall lipopolysaccharide of Escherichia coli type 8
inferred← citeshttps://doi.org/10.1016/j.tetlet.2011.04.060openalex-snapshot
A convenient synthesis of the core trisaccharide of the N-glycans
inferred← citeshttps://doi.org/10.1016/j.tetlet.2011.08.091openalex-snapshot
Development of a highly α-selective galactopyranosyl donor based on a rational design
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.04.049openalex-snapshot
Stereoselective β-mannosylation via anomeric O-alkylation: Formal synthesis of potent calcium signal modulator acremomannolipin A
inferred← citeshttps://doi.org/10.1016/j.tetlet.2017.12.077openalex-snapshot
Recent topics in β-stereoselective mannosylation
inferred← citeshttps://doi.org/10.1016/j.tetlet.2023.154391openalex-snapshot
Straightforward stereoselective synthesis of 1-thio-β-d-mannosides and 1-thio-β-l-rhamnosides
inferred← citeshttps://doi.org/10.1016/s0040-4020(00)00093-4openalex-snapshot
Chemical Transformations Induced by Triflic Anhydride
inferred← citeshttps://doi.org/10.1016/s0040-4020(01)01087-0openalex-snapshot
Synthesis of the mannosyl erythritol lipid MEL A; confirmation of the configuration of the meso-erythritol moiety
inferred← citeshttps://doi.org/10.1016/s0040-4020(98)00426-8openalex-snapshot
Direct chemical synthesis of β-mannopyranosides and other glycosides via glycosyl triflates
inferred← citeshttps://doi.org/10.1016/s0040-4020(98)01202-2openalex-snapshot
Direct synthesis of β-mannosides. Synthesis of β-D-xyl-(1→2)-β-D-man-(1→4)-α-D-Glc-OMe: A trisaccharide component of the Hyriopsis schlegelii glycosphingolipid. Formation of an orthoester from a xylopyranosyl sulfoxide
inferred← citeshttps://doi.org/10.1016/s0040-4039(00)00887-xopenalex-snapshot
Sulfur atom configuration of sulfinyl galactofuranosides determines different reactivities in glycosylation reactions
inferred← citeshttps://doi.org/10.1016/s0040-4039(00)00941-2openalex-snapshot
An unusual example of steric buttressing in glycosylation
inferred← citeshttps://doi.org/10.1016/s0040-4039(00)01497-0openalex-snapshot
Can preferential β-mannopyranoside formation with 4,6-O-benzylidene protected mannopyranosyl sulfoxides be reached with trichloroacetimidates?
inferred← citeshttps://doi.org/10.1016/s0040-4039(01)01133-9openalex-snapshot
Synthesis of arabinofuranosides via low-temperature activation of thioglycosides
inferred← citeshttps://doi.org/10.1016/s0040-4039(01)01880-9openalex-snapshot
A novel approach towards the stereoselective synthesis of 2-azido-2-deoxy-β-d-mannosides
inferred← citeshttps://doi.org/10.1016/s0040-4039(03)00102-3openalex-snapshot
A short synthesis of the trisaccharide building block of the N-linked glycans
inferred← citeshttps://doi.org/10.1016/s0040-4039(98)00124-5openalex-snapshot
Direct synthesis of β-d-Xyl-(1→2)-β-d-Man-(1→4)-α-d-Glc-OME: a trisaccharide component of the Hyriopsis schlegelii glycosphingolipid
inferred← citeshttps://doi.org/10.1016/s0040-4039(98)02159-5openalex-snapshot
Convergent, stereoselective synthesis of the caloporoside disaccharide
inferred← citeshttps://doi.org/10.1016/s0065-2318(09)00004-3openalex-snapshot
Chapter 4 Computational Studies of the Role of Glycopyranosyl Oxacarbenium Ions in Glycobiology and Glycochemistry
inferred← citeshttps://doi.org/10.1016/s0065-2318(09)00006-7openalex-snapshot
Chapter 6 Stereocontrolled Synthesis of Mannans and Rhamnans
inferred← citeshttps://doi.org/10.1016/s0304-4165(01)00164-7openalex-snapshot
A novel disaccharide substrate having 1,2-oxazoline moiety for detection of transglycosylating activity of endoglycosidases
inferred← citeshttps://doi.org/10.1016/s0957-4166(01)00437-2openalex-snapshot
Unexpected fluorous solvent effect on oxidation of 1-thioglycosides
inferred← citeshttps://doi.org/10.1016/s1874-5296(00)80015-7openalex-snapshot
Iodine, a versatile reagent in carbohydrate chemistry
inferred← citeshttps://doi.org/10.1021/acs.accounts.1c00021openalex-snapshot
Glycosyl Oxocarbenium Ions: Structure, Conformation, Reactivity, and Interactions
inferred← citeshttps://doi.org/10.1021/acs.accounts.6b00164openalex-snapshot
Twenty Years of Mycobacterial Glycans: Furanosides and Beyond
inferred← citeshttps://doi.org/10.1021/acs.accounts.7b00573openalex-snapshot
Gold(I)-Catalyzed Glycosylation with Glycosyl o -Alkynylbenzoates as Donors
inferred← citeshttps://doi.org/10.1021/acs.chemrev.0c00243openalex-snapshot
Mechanisms of Stereodirecting Participation and Ester Migration from Near and Far in Glycosylation and Related Reactions
inferred← citeshttps://doi.org/10.1021/acs.chemrev.2c00029openalex-snapshot
Synthesis and Glycosidation of Anomeric Halides: Evolution from Early Studies to Modern Methods of the 21st Century
inferred← citeshttps://doi.org/10.1021/acs.chemrev.2c00892openalex-snapshot
Catalytic Approaches to Chemo- and Site-Selective Transformation of Carbohydrates
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00036openalex-snapshot
“One-Pot” Protection, Glycosylation, and Protection–Glycosylation Strategies of Carbohydrates
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00051openalex-snapshot
Automated Chemical Oligosaccharide Synthesis: Novel Approach to Traditional Challenges
inferred← citeshttps://doi.org/10.1021/acs.chemrev.8b00083openalex-snapshot
The Experimental Evidence in Support of Glycosylation Mechanisms at the SN1–SN2 Interface
inferred← citeshttps://doi.org/10.1021/acs.joc.0c02045openalex-snapshot
Conformationally Constrained Glycosyl Donors as Tools to Control Glycosylation Outcomes
inferred← citeshttps://doi.org/10.1021/acs.joc.0c02339openalex-snapshot
Red Algal Molecules - Synthesis of Methyl Neo-β-carrabioside and Its S-Linked Variant via Two Synthetic Routes: A Late Stage Ring Closure and Using a 3,6-Anhydro- d -galactosyl Donor
inferred← citeshttps://doi.org/10.1021/acs.joc.0c02370openalex-snapshot
Stereoselective Synthesis of 2-Azido-2-deoxy-β- d -mannosides via Cs2CO3-Mediated Anomeric O-Alkylation with Primary Triflates: Synthesis of a Tetrasaccharide Fragment of Micrococcus luteus Teichuronic Acid
inferred← citeshttps://doi.org/10.1021/acs.joc.1c01535openalex-snapshot
Influence of Configuration at the 4- and 6-Positions on the Conformation and Anomeric Reactivity and Selectivity of 7-Deoxyheptopyranosyl Donors: Discovery of a Highly Equatorially Selective l -glycero- d -gluco-Heptopyranosyl Donor
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02305openalex-snapshot
Sterically Strained Brønsted Pair Catalysis by Bulky Pyridinium Salts: Direct Stereoselective Synthesis of 2-Deoxy and 2,6-Dideoxy-β-thioglycosides from Glycals
inferred← citeshttps://doi.org/10.1021/acs.joc.1c02374openalex-snapshot
Side Chain Conformation and Its Influence on Glycosylation Selectivity in Hexo- and Higher Carbon Furanosides
inferred← citeshttps://doi.org/10.1021/acs.joc.3c02262openalex-snapshot
Anomeric Triflates versus Dioxanium Ions: Different Product-Forming Intermediates from 3-Acyl Benzylidene Mannosyl and Glucosyl Donors
inferred← citeshttps://doi.org/10.1021/acs.joc.4c02956openalex-snapshot
The Stereochemical Outcome of Galactosylations Is Influenced by Both the Position and Electron-Withdrawing Power of Distal Acyl Protecting Groups
inferred← citeshttps://doi.org/10.1021/acs.joc.5b00138openalex-snapshot
Glycosylation with 2-Acetamido-2-deoxyglycosyl Donors at a Low Temperature: Scope of the Non-Oxazoline Method
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