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Synthesis and Characterization of Stable Stoichiometric Clathrates of Silicon and Germanium: Cs8Na16Si136 and Cs8Na16Ge136

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Hypothetical Carbon Modifications Derived from Zeolite Frameworks

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Ge: A Deltahedral Zintl Ion Now Made in the Solid‐State

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Strukturen mit Polyanionen als Defektvarianten allgemeiner Strukturtypen

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An ESR study on the thermal electron excitation of a sodium atom incorporated in a silicon clathrate compound

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Sur une nouvelle famille de clathrates minéraux isotypes des hydrates de gaz et de liquides. Interprétation des résultats obtenus

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Composition dependence of the superconducting transition temperature of silicon clathrate compound Na Ba6Si46

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The electronic structure of metallo-silicon clathrates Na Si136 (x = 0, 4, 8, 16 and 24)

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Superconductivity in silicon based barium-inclusion clathrates

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Zintl Phases in Alkali-Metal-Tin Systems: K8Sn25 with Condensed Pentagonal Dodecahedra of Tin. Two A8Sn44 Phases with a Defect Clathrate Structure

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Synthesis and Structure of Isolated Silicon Clusters of Nine Atoms

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Structural characterisations of the NaxSi136 and Na8Si46 silicon clathrates using the Rietveld method

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Silicon quantum wire array fabrication by electrochemical and chemical dissolution of wafers

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Semiconducting Ge clathrates: Promising candidates for thermoelectric applications

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The structural and luminescence properties of porous silicon

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The insulator-to-metal transition in Si-Na ‘clathrate’ compounds: A search for superconductivity

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Electronic structure of Si46 and Na2 Ba6 Si46

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Expanded-volume phases of silicon: Zeolites without oxygen

inferredcites →https://doi.org/10.1103/physrevb.54.3037openalex-snapshot

NMR studies of Na atoms in silicon clathrate compounds

inferredcites →https://doi.org/10.1103/physrevb.56.13898openalex-snapshot

Structural properties and vibrational modes of Si34 and Si46 clathrates

inferredcites →https://doi.org/10.1103/physrevb.57.4172openalex-snapshot

Temperature-dependent 23Na Knight shifts and sharply peaked structure in the electronic densities of states of Na-Si clathrates

inferredcites →https://doi.org/10.1103/physrevb.57.7686openalex-snapshot

Raman scattering from vibrational modes in Si46 clathrates

inferredcites →https://doi.org/10.1103/physrevb.57.r9475openalex-snapshot

Raman scattering of silicon clathrates

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Electronic signature of the pentagonal rings in silicon clathrate phases: Comparison with cluster-assembled films

inferredcites →https://doi.org/10.1103/physrevlett.68.2325openalex-snapshot

Predicted new low energy forms of carbon

inferredcites →https://doi.org/10.1103/physrevlett.74.1427openalex-snapshot

Superconductivity in the Silicon Clathrate Compound (Na,Ba) x S i46

inferredcites →https://doi.org/10.1126/science.150.3704.1713openalex-snapshot

Clathrate Structure of Silicon Na 8 Si 46 and Na x Si 136 ( x < 11)

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On the Problem of Polar Intermetallic Compounds: The Stimulation of E. Zintl's Work for the Modern Chemistry of Intermetallics

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Notizen: Eine Käfigstruktur als gemeinsames Bauprinzip der Verbindungen K8E46 (E = Si, Ge, Sn)

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Synthesis and Structure of Type -Ii Clathrates Cs8na16ga23.0(5)Ge113.0(5), Cs8na16si22.0(3)Ge114.0(3) and Rb8na16si13.7(4)Ge122.3(4)

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arachno-[Sn8]6− orcloso-[Li2Sn8]4−? Synthesis and Characterization of A4Li2Sn8 (A=Rb, K)

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Synthesis and Characterization of RbLi7Ge8 with Isolatedcloso-[Li4Ge12]8− Ions, Lithium-Capped Truncated Tetrahedra of Ge1212−

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arachno-[Sn8]6− orcloso-[Li2Sn8]4−? Synthesis and Characterization of A4Li2Sn8 (A=Rb, K)

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Synthesis and Characterization of RbLi(7)Ge(8) with Isolated closo-

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A Branch of Zintl Chemistry

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Germanium(cF136) – eine neue kristalline Modifikation des Germaniums mit poröser Clathrat‐II‐Struktur

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Ionische Flüssigkeiten – neue Perspektiven für die anorganische Synthesechemie?

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Germanium(cF136): A New Crystalline Modification of Germanium with the Porous Clathrate‐II Structure

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Ionic Liquids: New Perspectives for Inorganic Synthesis?

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Semiconducting Clathrates Meet Gas Hydrates: Xe 24 [Sn 136 ]

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ChemInform Abstract: Synthesis and Characterization of Stable Stoichiometric Clathrates of Silicon and Germanium: Cs8Na16Si136 and Cs8Na16Ge136.

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Synthesis of the Clathrate‐II K8.6(4)Ge136 by Oxidation of K4Ge9 in an Ionic Liquid

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Zintl Phases K4–xNaxSi4 (1 ≤ x ≤ 2.2) and K7NaSi8: Synthesis, Crystal Structures, and Solid‐State NMR Spectroscopic Investigations

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Gold nanoparticles for microfluidics‐based biosensing of PCR products by hybridization‐induced fluorescence quenching

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Rattling guest atoms in Si, Ge, and Sn‐based type‐II clathrate materials

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Cu and Zn Substituted Silicon Clathrates with the Cubic Type‐II Structure: Synthesis and Characterization of Cs8Na16Cu3.8Si132.2and Cs8Na16Zn6.9Si129.1

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Frameworks for Extended Solids: Geometrical Design Principles

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Clathrates of Group 14 with Alkali Metals: An Exploration

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Structure and Thermoelectric Properties of Ba6Ge25−, Ba6Ge23Sn2, and Ba6Ge22In3: Zintl Phases with a Chiral Clathrate Structure

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K7.62(1)Si46 and Rb6.15(2)Si46: Two Structure I Clathrates with Fully Occupied Framework Sites

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Zintl Clathrates

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Structural Relationships Between Intermetallic Clathrates, Porous Tectosilicates and Clathrate Hydrates

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Semiconductor Clathrates: In Situ Studies of Their High Pressure, Variable Temperature and Synthesis Behavior

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Density functional study of onion-skin-like [As@Ni12As20]3− and [Sb@Pd12Sb20]3− cluster ions

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Preparation and electronic states of Na16Ba8Si136 clathrate

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Sur les phases de type clathrate du silicium et des éléments apparentés (C, Ge, Sn) : Une approche historique

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Carbon clathrates as strong lightweight structures

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Synthesis and characterization of framework-substituted Cs8Na16Cu5Ge131

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Synthesis and thermoelectric properties of semiconducting germanium-based type-II clathrate (K,Sr)24(Ga,Ge)136

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Investigation of substitution effects and the phase transition in type-I clathrates Rb Cs8–Sn44□2 (1.3≤x≤2.1) using single-crystal X-ray diffraction, Raman spectroscopy, heat capacity and electrical resistivity measurements

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Synthesis and structural characterization of A3In2Ge4 and A5In3Ge6 (A=Ca, Sr, Eu, Yb)—New intermetallic compounds with complex structures, exhibiting Ge–Ge and In–In bonding

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K2Mg5−xSn3 and K3Mg18Tt11 (Tt=Sn, pb) with two types of Mg–Sn/Pb frameworks

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Synthesis and structures of type-I clathrates: Rb6Na2Ge44.89(1), Cs6Na2Zn4Ge42 and Cs6.40(1)Na1.60(1)Ga8Ge38

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Synthesis and characterization of phase-pure clathrate-II Rb12.9Si136

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Synthesis and structure of type –II clathrates Cs8Na16Ga6Ge130, Cs8Na16Si22.0(3)Ge114.0(3) and Rb8Na16Si13.7(4)Ge122.3(4)

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Rattling “guest” impurities in Si and Ge clathrate semiconductors

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Isolated deltahedral clusters of lead in the solid state: synthesis and characterization of Rb4Pb9 and Cs10K6Pb36 with Pb94−, and A3A′Pb4 (A=Cs, Rb, K; A′=Na, Li) with Pb44−

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A brief overview on low sodium content silicides: are they mainly clathrates, fullerenes, intercalation compounds or Zintl phases?

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Crystal structure and powder diffraction reference pattern of type I clathrate Ba 8 Ni 4 Ge 42

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Formation of Type II Silicon Clathrate with Lithium Guests through Thermal Diffusion

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Synthesis and Structural Characterization of Single-Crystal K7.5Si46 and K17.8Si136 Clathrates

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Simple Approach for Selective Crystal Growth of Intermetallic Clathrates

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New bulk Materials for Thermoelectric Power Generation: Clathrates and Complex Antimonides

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Synthesis and Characterization of A3Na10Sn23 (A = Cs, Rb, K) with a New Clathrate-Like Structure and of the Chiral Clathrate Rb5Na3Sn25

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Rare-Earth Germanium Antimonides RE6Ge5-xSb11+x (RE = La−Nd, Sm, Gd−Dy). I. Syntheses and Structures

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Synthesis and Characterization of the Largest Isolated Clusters of Tin, [Sn12]12-, in (AE)Na10Sn12 (AE = Ca or Sr)

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Structural Principles of Semiconducting Group 14 Clathrate Frameworks

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Synthesis and Structural Characterization of NaxSi136 (0 < x ≤ 24) Single Crystals and Low-Temperature Transport of Polycrystalline Specimens

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Synthesis and Properties of Type-I Clathrate Phases Rb8–x–tKx□tAuyGe46–y

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Li18Na2Ge17—A Compound Demonstrating Cation Effects on Cluster Shapes and Crystal Packing in Ternary Zintl Phases

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Li14.7Mg36.8Cu21.5Ga66: An Intermetallic Representative of a Type IV Clathrate

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Mixed Cations and Structural Complexity in (Eu1−xCax)4In3Ge4 and (Eu1−xCax)3In2Ge3—The First Two Members of the Homologous Series A2[n+m]In2n+mGe2[n+m] (n, m = 1, 2, ...∞; A = Ca, Sr, Ba, Eu, or Yb)

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Clathrate III of Group 14 Exists After All

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Naked Clusters of 56 Tin Atoms in the Solid State

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Intermetallic Compounds with 1D Infinite Tunnels. Syntheses and Structures of AAu4In2 (A = K, Rb)

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Origins of Superstructure Ordering and Incommensurability in Stuffed CoSn-Type Phases

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Inorganic Supramolecular Compounds with 3-D Chiral Frameworks Show Potential as Both Mid-IR Second-Order Nonlinear Optical and Piezoelectric Materials

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Oxidative Coupling of Deltahedral [Ge9]4- Zintl Ions

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Cs[H2NB2(C6F5)6] Featuring an Unequivocal 16-Coordinate Cation

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A guest-free germanium clathrate

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5 Carbon, silicon, germanium, tin and lead

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Nesting of fullerenes and Frank–Kasper polyhedra

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Inorganic clathrate-II materials of group 14: synthetic routes and physical properties

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Framework reconstruction between hR8 and cI16 germaniums: A molecular dynamics study

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Rapid crystal growth of type-II clathrates A 8 Na 16 Si 136 (A = K, Rb, Cs) by spark plasma sintering

inferred← citeshttps://doi.org/10.1039/c5dt02766gopenalex-snapshot

Structure and properties of type-II clathrate Cs 8 Na 16−x Tl x Ge 136

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Type-I clathrates of K 7.69(2) Cu 2.94(6) Ge 43.06(6) and Rb 8 Ag 2.79(4) Ge 43.21(4)

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New clathrates of Rb 7.50(1) Tl 0.50(1) Ge 46 and K 7.62(1) Tl 0.38(1) Ge 45.34(3)

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Ferromagnetism in germanium clathrate: Ba8Mn2Ge44

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Temperature dependent structural and transport properties of the type II clathrates A8Na16E136 (A=Cs or Rb and E=Ge or Si)

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Raman scattering study of stoichiometric Si and Ge type II clathrates

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Chemical trends of the rattling phonon modes in alloyed germanium clathrates

inferred← citeshttps://doi.org/10.1063/1.4866143openalex-snapshot

Cross-nucleation between clathrate hydrate polymorphs: Assessing the role of stability, growth rate, and structure matching

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Symbolic notation of clathrates

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Theoretical study of two expanded phases of crystalline germanium: clathrate-I and clathrate-II

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Density-functional investigation of Na16A8Ge136(A = Rb,Cs) clathrates

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Structural and electronic properties of germanium clathrates Ge46 and K8Ge46

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Low-density framework form of crystalline silicon with a wide optical band gap

inferred← citeshttps://doi.org/10.1103/physrevb.63.033102openalex-snapshot

23Na and 29Si NMR Knight shifts in the silicon clathrate Na16Cs8Si136

inferred← citeshttps://doi.org/10.1103/physrevb.63.125403openalex-snapshot

NMR Knight shifts and the electronic properties of Rb8Na16Si136 clathrate

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Thermal and lattice dynamical properties of Na8Si46 clathrate

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Structural and electronic properties of tin clathrate materials

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Vibrational properties of tin clathrate materials

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Calculations of electronic structure of Ge44Mn2Ba8 and Ge42Mn4Ba8 clathrates

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Electron structure and temperature-dependent shifts in Cs133 NMR spectra of the Cs8Ge136 clathrate

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Electronic structure of the Na16Rb8Si136 and K16Rb8Si136 clathrates

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Off-center rattling and thermoelectric properties of type-II clathrate (K, Ba) 24 (Ga, Sn, □ ) 136 single crystals

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Crystal-Liquid Phase Relations in Silicon at Negative Pressure

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K and Ba distribution in the structures of the clathrate compounds KxBa16−x(Ga,Sn)136(x= 0.8, 4.4, and 12.9) and KxBa8−x(Ga,Sn)46(x= 0.3)

inferred← citeshttps://doi.org/10.1107/s0108270113030011openalex-snapshot

On the possibility for Rb- and Eu-cation ordering in type-I clathrates: synthesis and homogeneity range of the novel compounds Rb8–xEux(In,Ge)46(0.6 ≤x≤ 1.8)

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Formation of clathrates

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Synthesis and structural characterization of novel clathrate-II compounds of silicon

inferred← citeshttps://doi.org/10.1117/12.2040056openalex-snapshot

Group IV clathrates: synthesis, optoelectonic properties, and photovoltaic applications

inferred← citeshttps://doi.org/10.1126/science.1082342openalex-snapshot

Interpenetrating As 20 Fullerene and Ni 12 Icosahedra in the Onion-Skin [As@Ni 12 @As 20 ] 3 Ion

inferred← citeshttps://doi.org/10.1134/s1063783412020096openalex-snapshot

Electron energy spectrum in silicon-based Pd-substituted clathrate crystals

inferred← citeshttps://doi.org/10.1201/9781420038903.ch32openalex-snapshot

Formation and Crystal Chemistry of Clathrates

inferred← citeshttps://doi.org/10.1201/9781420038903.ch33openalex-snapshot

Structure, Thermal Conductivity, and Thermoelectric Properties of Clathrate Compounds

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A type-II clathrate with a Li-Ge framework

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Thermal Conductiviy of type I and II Clathrate Compounds

inferred← citeshttps://doi.org/10.1557/proc-626-z13.2openalex-snapshot

Framework Stoichiometry and Electrical Conductivity of Si-Ge Based Structure-I Clathrates

inferred← citeshttps://doi.org/10.1557/proc-626-z13.5openalex-snapshot

Synthesis and Characterization of Large Single Crystals of Silicon and Germanium Clathrate-II Compounds and a New Tin Compound with Clathrate Layers

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133Cs and 23Na NMR Studies of Cs8NaxGe136 Clathrates

inferred← citeshttps://doi.org/10.3390/cryst1030145openalex-snapshot

Ternary Compounds in the Sn-Rich Section of the Ba–Ga–Sn System: Ba8Ga16–xSn30+x (1.1 ≤ x ≤ 2.8) Clathrates of Type-I and Type-VIII, and BaGa2–xSn4+x (x ≈ 0.2) with a Clathrate-like Structure

inferred← citeshttps://doi.org/10.3390/inorganics2010079openalex-snapshot

New Type-I and Type-II Clathrates in the Systems Cs–Na–Ga–Si, Rb–Na–Ga–Si, and Rb–Na–Zn–Si

inferred← citeshttps://doi.org/10.3390/ma9040236openalex-snapshot

Synthesis and Structural Characterization of the New Clathrates K8Cd4Ge42, Rb8Cd4Ge42, and Cs8Cd4Ge42

inferred← citeshttps://doi.org/10.3390/ma9070593openalex-snapshot

Binary Alkali-Metal Silicon Clathrates by Spark Plasma Sintering: Preparation and Characterization

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Mechanical Metastructures of Triple Periodic Carbon Clathrates

inferred← citeshttps://doi.org/10.5772/65600openalex-snapshot

Thermoelectric Power Generation by Clathrates

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