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Stereoselective Synthesis of 2,3-dihydroxy-4-dimethylamino-5-methoxypentanoic acid, a fragment of calyculins ------- determination of the absolute configuration of calyculins
Convenient access to two enantiomeric oxirane synthons bearing a quaternary gem-dimethyl carbon center: Synthesis of 3S-(+) and 3R-(−)-2,2-dimethyl-3,4-oxo-1-butanol from R-(−)-pantolactone
Acyclic diastereoselective synthesis using tartrate ester-modified crotylboronates. Double asymmetric reactions with .alpha.-methyl chiral aldehydes and synthesis of the C(19)-C(29) segment of rifamycin S
Chiral synthesis via organoboranes. 13. A highly diastereoselective and enantioselective addition of [(Z)-.gamma.-alkoxyallyl]diisopinocampheylboranes to aldehydes
Enantiomeric Z- and E-crotyldiisopinocampheylboranes. Synthesis in high optical purity of all four possible stereoisomers of .beta.-methylhomoallyl alcohols
Chiral synthesis via organoboranes. 7. Diastereoselective and enantioselective synthesis of erythro- and threo-.beta.-methylhomoallyl alcohols via enantiomeric (Z)- and (E)-crotylboranes
Bioactive marine metabolites. 24. Isolation and structure elucidation of calyculins B, C, and D, novel antitumor metabolites, from the marine sponge Discodermia calyx
Electrophilic destannylation: stereospecific introduction of electrophiles at the 21 position of (17.alpha.)-19-norpregna-1,3,5(10),20-tetraene-3,17.beta.-diols
Stereochemistry of epoxidation of rigid methylenecyclohexane systems. Determination of stereochemistry of exocyclic epoxides in rigid cyclohexanes by nuclear magnetic resonance half band widths
Base-assisted Migration of Trimethylsilyl Group from Carbon to Oxygen in g-Trimethylsilyl-g,d-unsaturated Alcohols, g-Trimethylsilyl-g,d-epoxy Alcohols, and b-Trimethylsilyl-b,g-epoxy Alcohols to the Corresponding Silyl Ethers
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A versatile approach to pyrrolidine azasugars and homoazasugars based on a highly diastereoselective reductive benzyloxymethylation of protected tartarimide
Multicomponent Linchpin Couplings. Reaction of Dithiane Anions with Terminal Epoxides, Epichlorohydrin, and Vinyl Epoxides: Efficient, Rapid, and Stereocontrolled Assembly of Advanced Fragments for Complex Molecule Synthesis
Diversity-Oriented Synthesis of Polyketide Natural Products via Iterative Chemo- and Stereoselective Functionalization of Polyenoates: Development of a Unified Approach for the C(1−19) Segments of Lituarines A−C
Synthesis of the bis-spiroacetal C25–C40 moiety of the antimitotic agent spirastrellolide B using a bis-dithiane deprotection/spiroacetalisation sequence
Calyculins and Related Marine Natural Products as Serine- Threonine Protein Phosphatase PP1 and PP2A Inhibitors and Total Syntheses of Calyculin A, B, and C
Le soufre en chimie des sucres : évaluation du potentiel synthétique pour la préparation de spiro-orthoesters et intérêt pour l'obtention d'analogues du C-KRN 7000
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