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Energy Counterbalance to Harness Photoinduced Structural Planarization of Dibenzo[ b,f ]azepines toward Thermal Reversibility

https://doi.org/10.1021/jacs.1c11231
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Precise Design of Phosphorescent Molecular Butterflies with Tunable Photoinduced Structural Change and Dual Emission
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White‐Fluorescent Dual‐Emission Mechanosensitive Membrane Probes that Function by Bending Rather than Twisting
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Tuning the Conformation and Color of Conjugated Polyheterocyclic Skeletons by Installing ortho ‐Methyl Groups
inferredcites →https://doi.org/10.1002/anie.201904882openalex-snapshot
Dibenzoarsepins: Planarization of 8π‐Electron System in the Lowest Singlet Excited State
inferredcites →https://doi.org/10.1002/anie.201906083openalex-snapshot
Phenothiazine Scope: Steric Strain Induced Planarization and Excimer Formation
inferredcites →https://doi.org/10.1002/anie.202005466openalex-snapshot
Diversified Excited‐State Relaxation Pathways of Donor–Linker–Acceptor Dyads Controlled by a Bent‐to‐Planar Motion of the Donor
inferredcites →https://doi.org/10.1002/anie.202015274openalex-snapshot
Broadening the Horizon of the Bell–Evans–Polanyi Principle towards Optically Triggered Structure Planarization
inferredcites →https://doi.org/10.1002/chem.200700362openalex-snapshot
Scope and Limitations of Baird's Theory on Triplet State Aromaticity: Application to the Tuning of Singlet–Triplet Energy Gaps in Fulvenes
inferredcites →https://doi.org/10.1002/chem.201904900openalex-snapshot
Mono‐Heteroatom Substitution for Harnessing Excited‐State Structural Planarization of Dihydrodibenzo[a,c]phenazines
inferredcites →https://doi.org/10.1002/chem.201905429openalex-snapshot
Isomeric Dithienophosphepines: The Impact of Ring Fusion on Electronic and Structural Properties
inferredcites →https://doi.org/10.1002/cplu.201900066openalex-snapshot
Is Excited‐State Aromaticity a Driving Force for Planarization of Dibenzannelated 8π‐Electron Heterocycles?
inferredcites →https://doi.org/10.1002/ejoc.202100352openalex-snapshot
Visualisation of Chemical Shielding Tensors (VIST) to Elucidate Aromaticity and Antiaromaticity**
inferredcites →https://doi.org/10.1002/jcc.22885openalex-snapshot
Multiwfn: A multifunctional wavefunction analyzer
inferredcites →https://doi.org/10.1007/bf01339530openalex-snapshot
Quantentheoretische Beitr�ge zum Benzolproblem
inferredcites →https://doi.org/10.1007/bf01341953openalex-snapshot
Quanstentheoretische Beitr�ge zum Benzolproblem
inferredcites →https://doi.org/10.1016/j.jphotochemrev.2014.09.005openalex-snapshot
Thermodynamic vs. kinetic control of excited-state proton transfer reactions
inferredcites →https://doi.org/10.1016/s0040-4039(01)94175-9openalex-snapshot
Definition of aromaticity basing on the harmonic oscillator model
inferredcites →https://doi.org/10.1021/acs.joc.1c01082openalex-snapshot
Synthesis of Tribenzo[b,d,f]azepines via Palladium-Catalyzed Annulation Reaction of 2-Iodobiphenyls with 2-Halogenoanilines
inferredcites →https://doi.org/10.1021/acs.orglett.0c04192openalex-snapshot
Palladium-Catalyzed Dual Coupling Reaction of 2-Iodobiphenyls with o-Bromoanilines through C–H Activation: An Approach for the Synthesis of Tribenzo[b,d,f]azepines
inferredcites →https://doi.org/10.1021/acschembio.0c00100openalex-snapshot
Fluorescence Probes Exhibit Photoinduced Structural Planarization: Sensing In Vitro and In Vivo Microscopic Dynamics of Viscosity Free from Polarity Interference
inferredcites →https://doi.org/10.1021/cr0300901openalex-snapshot
Anisotropy of the Induced Current Density (ACID), a General Method To Quantify and Visualize Electronic Delocalization
inferredcites →https://doi.org/10.1021/cr300471vopenalex-snapshot
Excited State Aromaticity and Antiaromaticity: Opportunities for Photophysical and Photochemical Rationalizations
inferredcites →https://doi.org/10.1021/ct300326fopenalex-snapshot
TD-DFT Assessment of Functionals for Optical 0–0 Transitions in Solvated Dyes
inferredcites →https://doi.org/10.1021/ct400337eopenalex-snapshot
On the Metric of Charge Transfer Molecular Excitations: A Simple Chemical Descriptor
inferredcites →https://doi.org/10.1021/ja00060a063openalex-snapshot
Evidence for a planar cyclically conjugated 8.pi. system in the excited state: large Stokes shift observed for dibenz[b,f]oxepin fluorescence
inferredcites →https://doi.org/10.1021/ja00092a058openalex-snapshot
Palladium-catalyzed formation of carbon-nitrogen bonds. Reaction intermediates and catalyst improvements in the hetero cross-coupling of aryl halides and tin amides
inferredcites →https://doi.org/10.1021/ja00096a059openalex-snapshot
Palladium-Catalyzed Aromatic Aminations with in situ Generated Aminostannanes
inferredcites →https://doi.org/10.1021/ja00769a025openalex-snapshot
Quantum organic photochemistry. II. Resonance and aromaticity in the lowest 3.pi..pi.* state of cyclic hydrocarbons
inferredcites →https://doi.org/10.1021/ja050817yopenalex-snapshot
Phosphepines: Convenient Access to Phosphinidene Complexes
inferredcites →https://doi.org/10.1021/ja404198hopenalex-snapshot
A π-Conjugated System with Flexibility and Rigidity That Shows Environment-Dependent RGB Luminescence
inferredcites →https://doi.org/10.1021/ja960582dopenalex-snapshot
Nucleus-Independent Chemical Shifts: A Simple and Efficient Aromaticity Probe
inferredcites →https://doi.org/10.1021/jacs.0c05611openalex-snapshot
Controlling the S1 Energy Profile by Tuning Excited-State Aromaticity
inferredcites →https://doi.org/10.1021/jacs.5b03491openalex-snapshot
Excited-State Conformational/Electronic Responses of Saddle-Shaped N , N ′-Disubstituted-Dihydrodibenzo[ a , c ]phenazines: Wide-Tuning Emission from Red to Deep Blue and White Light Combination
inferredcites →https://doi.org/10.1021/jacs.5b06136openalex-snapshot
Transnitrilation from Dimethylmalononitrile to Aryl Grignard and Lithium Reagents: A Practical Method for Aryl Nitrile Synthesis
inferredcites →https://doi.org/10.1021/jacs.6b11789openalex-snapshot
Snapshotting the Excited-State Planarization of Chemically Locked N , N ′-Disubstituted Dihydrodibenzo[ a , c ]phenazines
inferredcites →https://doi.org/10.1021/jacs.9b01368openalex-snapshot
Designed Conformation and Fluorescence Properties of Self-Assembled Phenazine-Cored Platinum(II) Metallacycles
inferredcites →https://doi.org/10.1021/jo00012a023openalex-snapshot
Preparation of 9H-tribenz[b,d,f]azepine and its 1-methoxy derivative
inferredcites →https://doi.org/10.1021/jo9006249openalex-snapshot
Synthesis of Carbazoles by Intramolecular Arylation of Diarylamide Anions
inferredcites →https://doi.org/10.1021/om301012zopenalex-snapshot
Dibenzo[b,f]phosphepines: Novel Phosphane–Olefin Ligands for Transition Metals
inferredcites →https://doi.org/10.1038/nchem.1518openalex-snapshot
Exciting excited-state aromaticity
inferredcites →https://doi.org/10.1038/s41467-017-00382-1openalex-snapshot
Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives
inferredcites →https://doi.org/10.1039/b810189bopenalex-snapshot
Long-range corrected hybrid density functionals with damped atom–atom dispersion corrections
inferredcites →https://doi.org/10.1039/c0cp02821eopenalex-snapshot
Influence of excited state aromaticity in the lowest excited singlet states of fulvene derivatives
inferredcites →https://doi.org/10.1039/c2cs35195aopenalex-snapshot
Excited-state proton coupled charge transfer modulated by molecular structure and media polarization
inferredcites →https://doi.org/10.1039/c9mh01167fopenalex-snapshot
Smart molecular butterfly: an ultra-sensitive and range-tunable ratiometric thermometer based on dihydrophenazines
inferredcites →https://doi.org/10.1039/d0sc01591aopenalex-snapshot
The endeavor of vibration-induced emission (VIE) for dynamic emissions
inferredcites →https://doi.org/10.1063/1.2834918openalex-snapshot
Systematic optimization of long-range corrected hybrid density functionals
inferredcites →https://doi.org/10.1063/1.3382344openalex-snapshot
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
inferredcites →https://doi.org/10.1063/1.4775591openalex-snapshot
Communication: One third: A new recipe for the PBE0 paradigm
inferredcites →https://doi.org/10.1063/1.5143076openalex-snapshot
TheoDORE: A toolbox for a detailed and automated analysis of electronic excited state computations
inferredcites →https://doi.org/10.3390/chemistry3020038openalex-snapshot
Exploitation of Baird Aromaticity and Clar’s Rule for Tuning the Triplet Energies of Polycyclic Aromatic Hydrocarbons

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Synergetic Carbonyl and Heptagonal Structure for Single‐Molecule White Organic Light‐Emitting Diodes with Dual Thermally Activated Delayed Fluorescence
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Syntheses and Photophysical Properties of Pnictogen‐ and Chalcogen‐Containing Diheteroanthracenes
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Dithienoazepine‐Based Near‐Infrared Dyes: Janus‐Faced Effects of a Thiophene‐Fused Structure on Antiaromatic Azepines
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Reaktion von Blatter‐ und Verdazyl‐Radikalen mit Arinen: Synthese und Untersuchung N‐chiraler, antiaromatischer Triazine und Tetrazinone
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Dithienoazepine‐Based Near‐Infrared Dyes: Janus‐Faced Effects of a Thiophene‐Fused Structure on Antiaromatic Azepines
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Capturing the Progressive Conformational Evolutions of Sterically‐Congested Dihydrophenazines via Crystallization
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Regulating Structures and Properties of Overcrowded‐Ethylene Decorated (Diaza)Phosphinines via Tunable Main‐Group Element Hyperconjugation
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Reaction of Blatter and Verdazyl Radicals with Arynes: Synthesis and Investigation of N‐Chiral, Antiaromatic Triazines, and Tetrazinones
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Central Ring Puckering Enhances the Stokes Shift of Xanthene Dyes
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An Energy‐Tunable Dual Emission Mechanism of the Hybridized Local and Charge Transfer (HLCT) and the Excited State Conjugation Enhancement (ESCE)
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Benzo‐Fused Phosphepines: Synthesis by Gold(I)‐Catalyzed Intramolecular Hydroarylation and Ring Inversion
inferred← citeshttps://doi.org/10.1002/elt2.70044openalex-snapshot
Photoinduced Solution‐Stable Radicals via Intramolecular Charge Separation From anti‐Kasha Emissive BN‐Azepines
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Recent progress in conformation-tunable organic luminescent molecules
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Sequential conformational dynamics in the excited state programmed multicolor emission in a carbon nanohoop
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Seven-membered rings
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Employing N-phenyl-tribenzo[b,d,f]azepine as a new electron-donating group to construct high-emissive AIE molecules for NIR-II fluorescence imaging
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Polarization induced excited isomerization of single molecule white-light emitter derived from phenothiazine
inferred← citeshttps://doi.org/10.1016/j.dyepig.2026.113913openalex-snapshot
Distorted donor decoration on C=O/N multi-resonance TADF dyes toward narrowband green electroluminescence
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Conformational Effect of Catechol-Terephthalonitrile Emitters Leading to Ambient Violet Phosphorescence
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Multi-Stimuli-Responsive Polyamides Containing Benzophenothiazine Being Sensitive to TNP, Acid, Voltage, and Light
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