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N-Heterocyclic Carbene Modified Palladium Catalysts for the Direct Synthesis of Hydrogen Peroxide

https://doi.org/10.1021/jacs.2c04828
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/anie.200503779openalex-snapshot
Hydrogen Peroxide Synthesis: An Outlook beyond the Anthraquinone Process
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Palladium Complexes of N‐Heterocyclic Carbenes as Catalysts for Cross‐Coupling Reactions—A Synthetic Chemist's Perspective
inferredcites →https://doi.org/10.1002/anie.201002782openalex-snapshot
Asymmetric Nanocatalysis: N‐Heterocyclic Carbenes as Chiral Modifiers of Fe3O4/Pd nanoparticles
inferredcites →https://doi.org/10.1002/anie.201508933openalex-snapshot
Modular Bidentate Hybrid NHC‐Thioether Ligands for the Stabilization of Palladium Nanoparticles in Various Solvents
inferredcites →https://doi.org/10.1002/anie.201610552openalex-snapshot
Hybrid Palladium Nanoparticles for Direct Hydrogen Peroxide Synthesis: The Key Role of the Ligand
inferredcites →https://doi.org/10.1002/anie.202205972openalex-snapshot
Electrochemical Reactors for Continuous Decentralized H 2 O 2 Production
inferredcites →https://doi.org/10.1002/cctc.200900171openalex-snapshot
The Effect of Bromide Pretreatment on the Performance of Supported Au–Pd Catalysts for the Direct Synthesis of Hydrogen Peroxide
inferredcites →https://doi.org/10.1002/chem.201803274openalex-snapshot
N‐Heterocyclic Carbene‐Modified Au–Pd Alloy Nanoparticles and Their Application as Biomimetic and Heterogeneous Catalysts
inferredcites →https://doi.org/10.1007/s10562-021-03632-6openalex-snapshot
The Direct Synthesis of Hydrogen Peroxide over AuPd Nanoparticles: An Investigation into Metal Loading
inferredcites →https://doi.org/10.1016/j.jcat.2005.11.024openalex-snapshot
Role of chloride or bromide anions and protons for promoting the selective oxidation of H2 by O2 to H2O2 over supported Pd catalysts in an aqueous medium
inferredcites →https://doi.org/10.1016/j.jcat.2013.11.008openalex-snapshot
Insight into active sites of Pd–Au/TiO2 catalysts in hydrogen peroxide synthesis directly from H2 and O2
inferredcites →https://doi.org/10.1016/j.jcat.2016.12.004openalex-snapshot
The origin of palladium particle size effects in the direct synthesis of H2O2: Is smaller better?
inferredcites →https://doi.org/10.1016/j.jcat.2021.04.020openalex-snapshot
Effects of bromide adsorption on the direct synthesis of H2O2 on Pd nanoparticles: Formation rates, selectivities, and apparent barriers at steady-state
inferredcites →https://doi.org/10.1016/j.molcata.2006.07.009openalex-snapshot
Factors influencing decomposition of H2O2 over supported Pd catalyst in aqueous medium
inferredcites →https://doi.org/10.1021/acs.chemrev.8b00514openalex-snapshot
N -Heterocyclic Carbenes in Materials Chemistry
inferredcites →https://doi.org/10.1021/acscatal.0c01517openalex-snapshot
Tunable Catalytic Performance of Palladium Nanoparticles for H 2 O 2 Direct Synthesis via Surface-Bound Ligands
inferredcites →https://doi.org/10.1021/acscatal.0c03359openalex-snapshot
Enhanced Photocatalytic H2O2 Production over Carbon Nitride by Doping and Defect Engineering
inferredcites →https://doi.org/10.1021/acscatal.5b01160openalex-snapshot
Negatively Charged N-Heterocyclic Carbene-Stabilized Pd and Au Nanoparticles and Efficient Catalysis in Water
inferredcites →https://doi.org/10.1021/acscatal.6b01275openalex-snapshot
Synergy and Anti-Synergy between Palladium and Gold in Nanoparticles Dispersed on a Reducible Support
inferredcites →https://doi.org/10.1021/acscatal.6b02871openalex-snapshot
Design of High-Performance Pd-Based Alloy Nanocatalysts for Direct Synthesis of H 2 O 2
inferredcites →https://doi.org/10.1021/cr9002424openalex-snapshot
Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts
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Stable Carbenes
inferredcites →https://doi.org/10.1021/ja401965dopenalex-snapshot
Addressable Carbene Anchors for Gold Surfaces
inferredcites →https://doi.org/10.1021/jacs.1c00539openalex-snapshot
Effect of Pd Coordination and Isolation on the Catalytic Reduction of O2 to H2O2 over PdAu Bimetallic Nanoparticles
inferredcites →https://doi.org/10.1021/jacs.5b10669openalex-snapshot
Mechanism for the Direct Synthesis of H2O2 on Pd Clusters: Heterolytic Reaction Pathways at the Liquid–Solid Interface
inferredcites →https://doi.org/10.1021/jacs.6b03821openalex-snapshot
Tunable Heterogeneous Catalysis: N-Heterocyclic Carbenes as Ligands for Supported Heterogeneous Ru/K-Al2O3 Catalysts To Tune Reactivity and Selectivity
inferredcites →https://doi.org/10.1021/jacs.7b05112openalex-snapshot
Molecular Adsorbates Switch on Heterogeneous Catalysis: Induction of Reactivity by N-Heterocyclic Carbenes
inferredcites →https://doi.org/10.1021/jacs.8b01017openalex-snapshot
Supported Au Nanoparticles with N ‑Heterocyclic Carbene Ligands as Active and Stable Heterogeneous Catalysts for Lactonization
inferredcites →https://doi.org/10.1038/nature13384openalex-snapshot
An overview of N-heterocyclic carbenes
inferredcites →https://doi.org/10.1038/nature20795openalex-snapshot
High-spatial-resolution mapping of catalytic reactions on single particles
inferredcites →https://doi.org/10.1038/nchem.1891openalex-snapshot
Ultra stable self-assembled monolayers of N-heterocyclic carbenes on gold
inferredcites →https://doi.org/10.1038/nchem.2622openalex-snapshot
Ballbot-type motion of N-heterocyclic carbenes on gold surfaces
inferredcites →https://doi.org/10.1038/s41570-021-00321-1openalex-snapshot
Recent advances in the chemistry and applications of N-heterocyclic carbenes
inferredcites →https://doi.org/10.1038/s41929-021-00607-zopenalex-snapshot
N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces
inferredcites →https://doi.org/10.1038/s41929-021-00642-wopenalex-snapshot
A residue-free approach to water disinfection using catalytic in situ generation of reactive oxygen species
inferredcites →https://doi.org/10.1039/b714553popenalex-snapshot
Au–Pd supported nanocrystals as catalysts for the direct synthesis of hydrogen peroxide from H 2 and O 2
inferredcites →https://doi.org/10.1039/c3cy00260hopenalex-snapshot
Sol immobilization technique: a delicate balance between activity, selectivity and stability of gold catalysts
inferredcites →https://doi.org/10.1039/c6cc01130fopenalex-snapshot
Long-chain NHC-stabilized RuNPs as versatile catalysts for one-pot oxidation/hydrogenation reactions
inferredcites →https://doi.org/10.1039/c8sc01924jopenalex-snapshot
An N-heterocyclic carbene ligand promotes highly selective alkyne semihydrogenation with copper nanoparticles supported on passivated silica
inferredcites →https://doi.org/10.1039/d0cy00915fopenalex-snapshot
Gold–palladium colloids as catalysts for hydrogen peroxide synthesis, degradation and methane oxidation: effect of the PVP stabiliser
inferredcites →https://doi.org/10.1039/d0cy01079kopenalex-snapshot
Enhanced catalyst selectivity in the direct synthesis of H 2 O 2 through Pt incorporation into TiO 2 supported AuPd catalysts
inferredcites →https://doi.org/10.1126/science.1168980openalex-snapshot
Switching Off Hydrogen Peroxide Hydrogenation in the Direct Synthesis Process
inferredcites →https://doi.org/10.1126/science.aad5705openalex-snapshot
Palladium-tin catalysts for the direct synthesis of H 2 O 2 with high selectivity
inferredcites →https://doi.org/10.1126/science.abl4822openalex-snapshot
Highly efficient catalytic production of oximes from ketones using in situ–generated H 2 O 2
inferredcites →https://doi.org/10.5260/chara.20.4.46openalex-snapshot
Ullmann’s Encyclopedia of Industrial Chemistry

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Bifunctional Reality of Gd Doping to Boost the Photocatalytic H2o2 Production of Au/Bivo4
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N‐Heterocyclic Carbene Functionalization of 2D Transition Metal Dichalcogenides via a Frustrated Lewis Pair Strategy
inferred← citeshttps://doi.org/10.1002/adma.73621openalex-snapshot
Step‐Edge Functionalization by N‐Heterocyclic Carbenes Enhances Catalytic Activity in Electrochemical CO 2 Reduction
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N‐Heterocyclic Olefins on a Metallic Surface – Adsorption, Orientation, and Electronic Influence
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Synergistic photocatalytic synthesis of H2O2 : Mechanistic insights and sustainable applications
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N‐Heterocyclic Olefins on a Silicon Surface
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Revealing the Mechanism of Combining Best Properties of Homogeneous and Heterogeneous Catalysis in Hybrid Pd/NHC Systems
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Azobenzene‐Bridged Covalent Organic Frameworks Boosting Photocatalytic Hydrogen Peroxide Production from Alkaline Water: One Atom Makes a Significant Improvement
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N‐Heterocyclische Carbene auf einem III‐V‐Halbleiter: Von Kettenbildung zu geordneten Monolagen
inferred← citeshttps://doi.org/10.1002/ange.202518099openalex-snapshot
N‐Heterozyklische Carbenmonolagen auf Nickel, Eisen und Stahl durch eine Radikal‐zu‐Carben‐Strategie
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Direct Synthesis of H 2 O 2 by Spatially Separate Hydrogen and Oxygen Activation Sites on Tailored Pt–Au Catalysts
inferred← citeshttps://doi.org/10.1002/anie.202314663openalex-snapshot
N‐Heterocyclic Olefins on a Silicon Surface
inferred← citeshttps://doi.org/10.1002/anie.202317468openalex-snapshot
Revealing the Mechanism of Combining Best Properties of Homogeneous and Heterogeneous Catalysis in Hybrid Pd/NHC Systems
inferred← citeshttps://doi.org/10.1002/anie.202409250openalex-snapshot
Azobenzene‐Bridged Covalent Organic Frameworks Boosting Photocatalytic Hydrogen Peroxide Production from Alkaline Water: One Atom Makes a Significant Improvement
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N‐Heterocyclic Carbenes on a III‐V Semiconductor: From Chain Formation to Ordered Monolayers
inferred← citeshttps://doi.org/10.1002/anie.202518099openalex-snapshot
N‐Heterocyclic Carbene Monolayers on Nickel, Iron, and Steel by a Radical‐to‐Carbene Strategy
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Direct Synthesis of H 2 O 2 by Spatially Separate Hydrogen and Oxygen Activation Sites on Tailored Pt–Au Catalysts
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Redefining Metal–Ligand Interfaces: N‐Heterocyclic Carbene Functionalization of Metal Nanoparticles
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Metal‐Organic Framework‐type NHC‐X‐Pd Complexes for the Selective Oxidation of 5‐HydroxyMethylFurfural to 2,5‐Furandicarboxylic Acid
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How to Get Them on: N‐Heterocyclic Carbenes (NHCs) on Surfaces
inferred← citeshttps://doi.org/10.1002/smll.74633openalex-snapshot
Electron Injection From B 4 C to Sn Sites Optimizes *OOH Adsorption Enabling Efficient H 2 O 2 Electrosynthesis
inferred← citeshttps://doi.org/10.1007/3418_2024_119openalex-snapshot
N-Heterocyclic Carbene Modified Metal Nanocatalysts
inferred← citeshttps://doi.org/10.1007/3418_2024_122openalex-snapshot
Ligand-Capped Heterogeneous Catalysts from Groups 8 to 10
inferred← citeshttps://doi.org/10.1007/s11244-025-02138-4openalex-snapshot
Palladium Bromide–Palladium Composite for Direct Synthesis of Hydrogen Peroxide
inferred← citeshttps://doi.org/10.1016/j.apcatb.2023.122867openalex-snapshot
Synergistic effects of Bi2O3 and Ta2O5 for efficient electrochemical production of H2O2
inferred← citeshttps://doi.org/10.1016/j.apsusc.2024.159664openalex-snapshot
Bifunctional reality of Gd doping to boost the photocatalytic H2O2 production of Au/BiVO4
inferred← citeshttps://doi.org/10.1016/j.cclet.2023.108446openalex-snapshot
Manipulation of the PdAu‒PdAuOx interface on Pd-Au bimetallic catalysts for the direct synthesis of hydrogen peroxide
inferred← citeshttps://doi.org/10.1016/j.ccr.2024.215897openalex-snapshot
Tailoring metal complexes with N-heterocyclic carbene ligands using Electron-Withdrawing Groups: Impact on catalytic activity and property development
inferred← citeshttps://doi.org/10.1016/j.cej.2024.157297openalex-snapshot
Masked second-shell sulfur coordinating atomically dispersed Pd on tin oxide boosts the direct synthesis of hydrogen peroxide
inferred← citeshttps://doi.org/10.1016/j.electacta.2025.146778openalex-snapshot
Design and machine learning-assisted evaluation of NHC-functionalized C2N with transition metals for efficient CO reduction
inferred← citeshttps://doi.org/10.1016/j.jpowsour.2025.236454openalex-snapshot
Boosting hydrogen peroxide electro-generation by adjusting the wetting state of porous Janus electrode during oxygen reduction reaction
inferred← citeshttps://doi.org/10.1016/j.mcat.2024.114479openalex-snapshot
Nest-shaped hollow-encapsulated Pd catalyst enhances the catalytic performance of hydrogen peroxide directly synthesizing from hydrogen and oxygen
inferred← citeshttps://doi.org/10.1016/j.susmat.2026.e01852openalex-snapshot
Carbon quantum dots for hydrogen peroxide production
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c01615openalex-snapshot
Coupling Dimethylglyoxime to Enhance Coordination Bonds of Pd Single-Atom Catalyst for Solving Stability and Activity Conflict
inferred← citeshttps://doi.org/10.1021/acs.langmuir.4c01109openalex-snapshot
N-Heterocyclic Carbene Monolayers on Metal-Oxide Films: Correlations between Adsorption Mode and Surface Functionality
inferred← citeshttps://doi.org/10.1021/acs.langmuir.5c00997openalex-snapshot
l -Arginine-Functionalized Pd–Ni Catalyst Enhances Direct H2O2 Synthesis in Microreactors
inferred← citeshttps://doi.org/10.1021/acs.langmuir.5c03563openalex-snapshot
Nucleation-Controlled Approach to Synthesize Sub-2 nm Water-Soluble Purine-Modified Green-Fluorescent Gold Nanoclusters
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Assisting a Type-II Heterojunction with the LSPR Effect for Realizing Photocatalytic Hydrogen Peroxide Evolution with NIR Apparent Quantum Efficiency Exceeding 0.5%
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Localized Oxygen Enrichment in a Covalent Organic Framework–ZnIn 2 S 4 S-Scheme Heterojunction Enables Spatially Confined Oxygen Reduction and Boosts Photocatalytic H 2 O 2 Selectivity
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Modular Approach toward Protic N-Heterocyclic Carbene Complexes from Tosylated Benzyl Isocyanide Metal Complexes and Imines
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Single-Atom Cobalt Catalysts Coupled with Peroxidase Biocatalysis for C–H Bond Oxidation
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Stability of N-Heterocyclic Carbene Monolayers under Continuous Voltammetric Interrogation
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Enhancing Pd Catalytic Activity by Amine Group Modification for Efficient Direct Synthesis of H2O2
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Gold Nanoparticles Grafted with Molecular N-Heterocyclic Carbenes for CO2 Electroreduction: Combining Electronic and Hydrophobic Effects
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Palladium–Tin Alloy Nanoparticles in Different Crystalline Phases for Direct Hydrogen Peroxide Synthesis
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N-Heterocyclic Carbenes Capped Metal Nanoparticles: An Overview of Their Catalytic Scope
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Well-Defined Catalytic System for Integrating Homogeneous and Heterogeneous Catalysis
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Regio- and Chemoselective Hydrogenation over NHC-Decorated Pd Nanoparticles on Carbon Support
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Density Functional Theory Investigation of Simple N-Heterocyclic Carbenes Adsorbed on the Pd/Cu(111) Single-Atom Alloy Surface
inferred← citeshttps://doi.org/10.1021/acssuschemeng.6c07527openalex-snapshot
Hydrogen-Transfer Bridging at Zeolite-Confined Pd–Ni(OH)2 Interfaces Enables Efficient Direct Synthesis of Hydrogen Peroxide
inferred← citeshttps://doi.org/10.1021/jacs.2c07290openalex-snapshot
Coordination-Induced Trigger for Activity: N-Heterocyclic Carbene-Decorated Ceria Catalysts Incorporating Cr and Rh with Activity Induction by Surface Adsorption Site Control
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Cooperative Use of N-Heterocyclic Carbenes and Thiols on a Silver Surface: A Synergetic Approach to Surface Modification
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Axial Ligand Engineering of Silver Single-Atom Catalysts with N -Heterocyclic Carbenes Unlocks Efficient Photocatalytic H 2 O 2 Production
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Chiral N-Heterocyclic Carbene On-Surface Induced Electronic Spin Filtration
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Atomically precise Au8Pd1(DPPF)42+ catalyst orchestrates the synthesis and utilization of hydrogen peroxide
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Understanding the role of imidazolium-based ionic liquids in the electrochemical CO2 reduction reaction
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Cyclohexanone ammoximation via in situ H 2 O 2 production using TS-1 supported catalysts
inferred← citeshttps://doi.org/10.1039/d3dt02961aopenalex-snapshot
Molar excess of coordinating N-heterocyclic carbene ligands triggers kinetic digestion of gold nanocrystals
inferred← citeshttps://doi.org/10.1039/d3im00054kopenalex-snapshot
Progress and perspectives of Pd-based catalysts for direct synthesis of hydrogen peroxide
inferred← citeshttps://doi.org/10.1039/d3tc00681fopenalex-snapshot
Influence of the defect density on the ordering of an NHC monolayer on a silicon surface
inferred← citeshttps://doi.org/10.1039/d4cs01299bopenalex-snapshot
Insights into the surface chemistry of N-heterocyclic carbenes
inferred← citeshttps://doi.org/10.1039/d4dt02434fopenalex-snapshot
N-Heterocyclic carbene-functionalized metal nanoparticles and nanoclusters for nanocatalysis
inferred← citeshttps://doi.org/10.1039/d4dt02460eopenalex-snapshot
Recent advances in tailoring the microenvironment of Pd-based catalysts for enhancing the performance in the direct synthesis of hydrogen peroxide
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Trifluoromethylnitrone: a versatile building block for synthesizing trifluoromethyl-containing heterocyclic compounds
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Redox reaction between N-heterocyclic carbenes and sulfonates: insights into unproductive catalytic paths
inferred← citeshttps://doi.org/10.1039/d4sc01560fopenalex-snapshot
Facet-dependent synthesis of H 2 O 2 from H 2 and O 2 over single Pt atom-modified Pd nanocrystal catalysts
inferred← citeshttps://doi.org/10.1039/d5cc05365jopenalex-snapshot
Regulating the substituent of the electron-acceptor in a D–A system for boosting H 2 O 2 photosynthesis from air and water
inferred← citeshttps://doi.org/10.1039/d5qi01170aopenalex-snapshot
Exploring copper β-diketiminate complexes for heterogeneous ammonia oxidation anchored on graphitic surfaces via CH–π and π–π interactions
inferred← citeshttps://doi.org/10.1039/d5ta02845kopenalex-snapshot
Tri-coordinated PdNP architecture for simultaneous capture, activation, and catalytic conversion of dilute CO 2 via multisite synergy
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The First Application of Palladium–Phosphorus Catalysts in the Direct Synthesis of Hydrogen Peroxide: Reasons for the Promoting Action of Phosphorus
inferred← citeshttps://doi.org/10.1134/s0023158423601249openalex-snapshot
Properties of Palladium-Phosphorus Catalysts Supported on HZSM-5 Zeolite in Direct Synthesis of Hydrogen Peroxide
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The First Application of Palladium–Phosphorus Catalysts in the Direct Synthesis of Hydrogen Peroxide: Reasons for the Promoting Action of Phosphorus
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Properties of palladium-phosphorus catalysts supported on HZSM-5 zeolite in the direct synthesis of hydrogen peroxide
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