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ortho -Methoxycarbonylethynylphenyl Thioglycosides (MCEPTs): Versatile Glycosyl Donors Enabled by Electron-Withdrawing Substituents and Catalyzed by Gold(I) or Cu(II) Complexes

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/9783527618255openalex-snapshot
Carbohydrates in Chemistry and Biology
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Direct and Stereoselective Synthesis of 2‐Acetamido‐2‐deoxy‐β‐ D ‐glycopyranosides by Using the Phosphite Method
inferredcites →https://doi.org/10.1002/anie.198201553openalex-snapshot
Advances in Selective Chemical Syntheses of Complex Oligosaccharides
inferredcites →https://doi.org/10.1002/anie.198602121openalex-snapshot
New Methods for the Synthesis of Glycosides and Oligosaccharides—Are There Alternatives to the Koenigs‐Knorr Method? [New Synthetic Methods (56)]
inferredcites →https://doi.org/10.1002/anie.200501023openalex-snapshot
Protein Posttranslational Modifications: The Chemistry of Proteome Diversifications
inferredcites →https://doi.org/10.1002/anie.200802036openalex-snapshot
New Principles for Glycoside‐Bond Formation
inferredcites →https://doi.org/10.1002/anie.202204420openalex-snapshot
Chemical Synthesis and Antigenic Evaluation of Inner Core Oligosaccharides from Acinetobacter baumannii Lipopolysaccharide
inferredcites →https://doi.org/10.1002/chem.200902548openalex-snapshot
Gold(I)‐Catalyzed Glycosylation with Glycosyl ortho ‐Alkynylbenzoates as Donors: General Scope and Application in the Synthesis of a Cyclic Triterpene Saponin
inferredcites →https://doi.org/10.1002/ejoc.200700101openalex-snapshot
Uronic Acids in Oligosaccharide Synthesis
inferredcites →https://doi.org/10.1007/bf03215464openalex-snapshot
Medical uses of gold compounds: Past, present and future
inferredcites →https://doi.org/10.1016/j.carres.2006.04.004openalex-snapshot
Aromatic O-glycosylation
inferredcites →https://doi.org/10.1016/j.carres.2014.06.009openalex-snapshot
Thioglycosides in Carbohydrate Research
inferredcites →https://doi.org/10.1016/j.carres.2015.02.007openalex-snapshot
Common side reactions of the glycosyl donor in chemical glycosylation
inferredcites →https://doi.org/10.1016/j.carres.2015.10.001openalex-snapshot
Surface polysaccharides from Acinetobacter baumannii : Structures and syntheses
inferredcites →https://doi.org/10.1016/j.tetlet.2012.07.059openalex-snapshot
ortho-Alkynylphenyl thioglycosides as a new type of glycosylation donors under the catalysis of Au(I) complexes
inferredcites →https://doi.org/10.1016/s0040-4039(00)60004-7openalex-snapshot
“Active” and “latent” thioglycosyl donors in oligosaccharide synthesis. Application to the synthesis of α-sialosides
inferredcites →https://doi.org/10.1016/s0040-4039(03)01647-2openalex-snapshot
Di-tert-butylsilylene (DTBS) group-directed α-selective galactosylation unaffected by C-2 participating functionalities
inferredcites →https://doi.org/10.1016/s0065-2318(09)00005-5openalex-snapshot
Chapter 5 Oligosaccharide Synthesis: From Conventional Methods to Modern Expeditious Strategies
inferredcites →https://doi.org/10.1021/acs.accounts.7b00573openalex-snapshot
Gold(I)-Catalyzed Glycosylation with Glycosyl o -Alkynylbenzoates as Donors
inferredcites →https://doi.org/10.1021/acs.chemrev.7b00234openalex-snapshot
Recent Advances in the Chemical Synthesis of C -Glycosides
inferredcites →https://doi.org/10.1021/acs.chemrev.7b00731openalex-snapshot
Methods for 2-Deoxyglycoside Synthesis
inferredcites →https://doi.org/10.1021/acs.chemrev.8b00036openalex-snapshot
“One-Pot” Protection, Glycosylation, and Protection–Glycosylation Strategies of Carbohydrates
inferredcites →https://doi.org/10.1021/acs.chemrev.8b00144openalex-snapshot
Catalytic Glycosylations in Oligosaccharide Synthesis
inferredcites →https://doi.org/10.1021/acs.chemrev.8b00238openalex-snapshot
Chemoenzymatic Methods for the Synthesis of Glycoproteins
inferredcites →https://doi.org/10.1021/acs.joc.8b01274openalex-snapshot
Diversity-Oriented Synthesis of Steviol Glycosides
inferredcites →https://doi.org/10.1021/acs.orglett.1c04102openalex-snapshot
8-(Methyltosylaminoethynyl)-1-naphthyl (MTAEN) Glycosides: Potent Donors in Glycosides Synthesis
inferredcites →https://doi.org/10.1021/acs.orglett.2c01146openalex-snapshot
GeCl2·Dioxane–AgBF4 Catalyzed Activation of Glycosyl Fluorides for Glycosylation
inferredcites →https://doi.org/10.1021/acs.orglett.5b00716openalex-snapshot
Gallium(III)-Promoted Halocyclizations of 1,6-Diynes
inferredcites →https://doi.org/10.1021/acs.orglett.6b00216openalex-snapshot
A Highly Efficient Approach To Construct (epi)-Podophyllotoxin-4-O-glycosidic Linkages as well as Its Application in Concise Syntheses of Etoposide and Teniposide
inferredcites →https://doi.org/10.1021/acs.orglett.8b03958openalex-snapshot
MPTGs: Thioglycoside Donors for Acid-Catalyzed O-Glycosylation and Latent-Active Synthetic Strategies
inferredcites →https://doi.org/10.1021/cr00020a006openalex-snapshot
Recent progress in O-glycosylation methods and its application to natural products synthesis
inferredcites →https://doi.org/10.1021/cr9502357openalex-snapshot
Formation and Structure of Self-Assembled Monolayers
inferredcites →https://doi.org/10.1021/cr990297nopenalex-snapshot
Synthesis of Complex Carbohydrates and Glycoconjugates: Enzyme-Based and Programmable One-Pot Strategies
inferredcites →https://doi.org/10.1021/cr9903104openalex-snapshot
Solid-Phase Oligosaccharide Synthesis and Combinatorial Carbohydrate Libraries
inferredcites →https://doi.org/10.1021/cs300670kopenalex-snapshot
Gold-Catalyzed Synthesis of 2-Deoxy Glycosides Using S -But-3-ynyl Thioglycoside Donors
inferredcites →https://doi.org/10.1021/ja0450298openalex-snapshot
Efficient Stereoselective Synthesis of γ- N -Glycosyl Asparagines by N-Glycosylation of Primary Amide Groups
inferredcites →https://doi.org/10.1021/ja4064316openalex-snapshot
Mechanistic Insights into the Gold(I)-Catalyzed Activation of Glycosyl ortho -Alkynylbenzoates for Glycosidation
inferredcites →https://doi.org/10.1021/jacs.7b07020openalex-snapshot
o -( p -Methoxyphenylethynyl)phenyl Glycosides: Versatile New Glycosylation Donors for the Highly Efficient Construction of Glycosidic Linkages
inferredcites →https://doi.org/10.1021/jacs.9b00210openalex-snapshot
Glycosylation with 3,5-Dimethyl-4-(2′-phenylethynylphenyl)phenyl (EPP) Glycosides via a Dearomative Activation Mechanism
inferredcites →https://doi.org/10.1021/ol015555topenalex-snapshot
Palladium-Catalyzed Arylation of Enynes and Electron-Deficient Alkynes Using Diaryliodonium Salts
inferredcites →https://doi.org/10.1021/ol701466uopenalex-snapshot
Revisiting the Armed−Disarmed Concept: The Importance of Anomeric Configuration in the Activation of S-Benzoxazolyl Glycosides
inferredcites →https://doi.org/10.1038/s41557-022-00918-zopenalex-snapshot
Halogen-bond-assisted radical activation of glycosyl donors enables mild and stereoconvergent 1,2-cis-glycosylation
inferredcites →https://doi.org/10.1038/s44160-022-00171-9openalex-snapshot
Automated solution-phase multiplicative synthesis of complex glycans up to a 1,080-mer
inferredcites →https://doi.org/10.1039/c5cc05651aopenalex-snapshot
ortho-(Methyltosylaminoethynyl)benzyl glycosides as new glycosyl donors for latent-active glycosylation
inferredcites →https://doi.org/10.1039/c5sc04392aopenalex-snapshot
Glycosylation, an effective synthetic strategy to improve the bioavailability of therapeutic peptides
inferredcites →https://doi.org/10.1039/c6ob00025hopenalex-snapshot
Fluorine-directed 1,2-trans glycosylation of rare sugars
inferredcites →https://doi.org/10.1039/d1sc05772copenalex-snapshot
Hydrogen bond activated glycosylation under mild conditions
inferredcites →https://doi.org/10.1055/s-0031-1290096openalex-snapshot
Transesterification of α-Amino Esters Catalyzed by a Tetranuclear Zinc Cluster: Zn4(OCOCF3)6O
inferredcites →https://doi.org/10.1111/2049-632x.12125openalex-snapshot
Acinetobacter baumannii : evolution of a global pathogen
inferredcites →https://doi.org/10.1134/s0006297909110170openalex-snapshot
Glycoscience. Chemistry and chemical biology

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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PIFA‐Mediated C─H Thiolation and Selenylation of Pseudo ‐Anomeric Position of Glycals with Disulfides or Diselenides at Room Temperature
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Stereoselective Synthesis of the O‐antigen of A. baumannii ATCC 17961 Using Long‐Range Levulinoyl Group Participation
inferred← citeshttps://doi.org/10.1002/ange.202409004openalex-snapshot
A Radical Activation Strategy for Versatile and Stereoselective N‐Glycosylation
inferred← citeshttps://doi.org/10.1002/ange.202420355openalex-snapshot
Stereoselective P(III)‐Glycosylation for the Preparation of Phosphinated Sugars
inferred← citeshttps://doi.org/10.1002/anie.202306971openalex-snapshot
Stereoselective Synthesis of the O‐antigen of A. baumannii ATCC 17961 Using Long‐Range Levulinoyl Group Participation
inferred← citeshttps://doi.org/10.1002/anie.202409004openalex-snapshot
A Radical Activation Strategy for Versatile and Stereoselective N‐Glycosylation
inferred← citeshttps://doi.org/10.1002/anie.202420355openalex-snapshot
Stereoselective P(III)‐Glycosylation for the Preparation of Phosphinated Sugars
inferred← citeshttps://doi.org/10.1002/cbic.202400864openalex-snapshot
Radical Strategy Towards N ‐glycosides: Current Advances and Future Prospects
inferred← citeshttps://doi.org/10.1002/chem.202403534openalex-snapshot
1‐(2’‐Hydroxy‐2’‐Methylpropionyl)Glycoside as a Versatile Glycosyl Donor for O ‐/ C ‐Glycosylation
inferred← citeshttps://doi.org/10.1002/cjoc.202400121openalex-snapshot
Stereoselective α‐Glycosylation with GlcN3 Donors Enabled Collective Syntheses of Acinetobacter baumannii Capsular Polysaccharides K43 , K47 and K88 Repeating Units†
inferred← citeshttps://doi.org/10.1002/cjoc.202401198openalex-snapshot
Stereoselective Synthesis of 2‐Deoxy Glycosides via a Novel 2‐O‐Resided (o‐Alkynyl)benzoate‐Initiated 1,2‐Sulfur Migration/Glycosylation and Desulfurization Protocol as well as Mechanism Elucidation
inferred← citeshttps://doi.org/10.1002/ejoc.202500102openalex-snapshot
Recent Advances of Carbohydrate‐Based Vaccines Against Acinetobacter baumannii
inferred← citeshttps://doi.org/10.1002/nadc.20244139258openalex-snapshot
Trendbericht Organische Chemie 2024
inferred← citeshttps://doi.org/10.1007/164_2025_747openalex-snapshot
Chemical Synthesis of Complex Carbohydrates
inferred← citeshttps://doi.org/10.1016/j.carres.2025.109437openalex-snapshot
Synthesis of aryl thioglycosides by metal-free arylation of glycosyl thiols with diaryliodonium salts under basic conditions
inferred← citeshttps://doi.org/10.1016/j.carres.2025.109639openalex-snapshot
Synthesis of disaccharide and trisaccharide substructures of an A. baumannii lipooligosaccharide core
inferred← citeshttps://doi.org/10.1016/j.carres.2026.110125openalex-snapshot
Recent Advances in Anomeric C-S Bond Activation: Emerging Opportunities for Stereoselective Glycosides
inferred← citeshttps://doi.org/10.1016/j.cclet.2024.110560openalex-snapshot
Catalytic ring-strain release toward a facial and efficient synthesis of versatile C-glycosides
inferred← citeshttps://doi.org/10.1016/j.gresc.2024.03.004openalex-snapshot
Unraveling chemical glycosylation: DFT insights into factors imparting stereoselectivity
inferred← citeshttps://doi.org/10.1021/acs.joc.3c00776openalex-snapshot
Stereoselective AromaticO-Glycosylation of Glycosyl Chloride with Arylboronic Acid under an Air Atmosphere
inferred← citeshttps://doi.org/10.1021/acs.joc.4c00554openalex-snapshot
Reaction Rate and Stereoselectivity Enhancement in Glycosidations with O-Glycosyl Trihaloacetimidate Donors due to Catalysis by a Lewis Acid–Nitrile Cooperative Effect
inferred← citeshttps://doi.org/10.1021/acs.joc.4c01740openalex-snapshot
Highly Reactive Glycosylation with 1-O-(Methylthio)thiocarbonyl Glycosyl Donors under Acidic to Neutral Reaction Conditions
inferred← citeshttps://doi.org/10.1021/acs.joc.4c02620openalex-snapshot
Insertion of Glycosylidene Carbenes into Phenolic O–H Bonds for the Synthesis of O -Aryl Glycosides
inferred← citeshttps://doi.org/10.1021/acs.joc.5c01438openalex-snapshot
Synthesis of Disarmed (Alkylthio)carbonyl Glycosyl Donors and Comparison of Their Glycosylation Reactions.
inferred← citeshttps://doi.org/10.1021/acs.orglett.3c01050openalex-snapshot
Chemical Glycosylation with p -Methoxyphenyl (PMP) Glycosides via Oxidative Activation
inferred← citeshttps://doi.org/10.1021/acs.orglett.3c01163openalex-snapshot
A Cu(OTf) 2 -Catalyzed Glycosylation with Glycosyl ortho - N -Phthalimidoylpropynyl Benzoates as Donors
inferred← citeshttps://doi.org/10.1021/acs.orglett.3c02072openalex-snapshot
S - o -( p -Methoxyphenylethynyl)benzyl (SMPEB) Glycosides for Catalytic Glycosylation and Their Application in the Synthesis of Polyporus Umbellatus Polysaccharides
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c02019openalex-snapshot
Palladium-Catalyzed O -Glycosylation through π–π Interactions
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c04389openalex-snapshot
N -( para -Methoxyphenylpropargyl) Pyrrole-2-carboxylate (PPPC) Glycosides as Donors for Glycosylation
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c04545openalex-snapshot
Total Synthesis of Kasugamycin
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c00473openalex-snapshot
Copper-Catalyzed Glycosylation Protocol Based on 1,4-Naphthoquinone-Derived Thioglycosides
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c02669openalex-snapshot
Unlocking the Potential of Ynamide as a Promoter in Copper(II)-Catalyzed O -Glycosylation
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c03784openalex-snapshot
Electrochemical 2-Deoxyglycosylation of N -Containing Molecules with β-Stereoselectivity
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c04703openalex-snapshot
Reactivity Tuning by Ring Size: A Glycosylation Protocol Using Thiophene-Scaffolded Glycosyl Donors
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c04886openalex-snapshot
NiCl 2 /Hdipm-Catalyzed 2-OH-Selective Alkylation of Glycoside trans -Diols
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c02219openalex-snapshot
A Photoacid-Assisted Ag(I)-Catalyzed Glycosylation Based on ortho -Methoxycarbonylethynylphenyl Thioglycosides
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c02221openalex-snapshot
Cellobiose-Derived β-Linked Disaccharide Donor Enables Convergent Syntheses of Acinetobacter baumannii K91 and K25 Capsular Trisaccharides
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c02988openalex-snapshot
Thiourea-Catalyzed, Hypervalent Iodine-Assisted Deoxygenative or Desulfurative Amidation of Alcohols
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c03296openalex-snapshot
2-Alkynyl-1-Naphthoate: A Reactive and Base-Tolerant Leaving Group for Gold(I)-Catalyzed Glycosylation
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c03333openalex-snapshot
Sterically Congested 2,2-Dimethylphenylacetate Glycosyl Donors for Versatile Protecting-Group Manipulations and Orthogonal Glycosylations
inferred← citeshttps://doi.org/10.1021/acscatal.4c05257openalex-snapshot
Iridium Photoredox-Catalyzed Stereoselective C-Glycosylation with Tetrafluoropyridin-4-yl Thioglycosides: A Facile Synthesis of C-α/β-Glucogallins and Their Antioxidant Activity
inferred← citeshttps://doi.org/10.1021/acscatal.5c01306openalex-snapshot
Site-Switchable Alkylation of Carbohydrates Controlled by Inexpensive Metal Ion Catalysts
inferred← citeshttps://doi.org/10.1021/acscatal.6c00469openalex-snapshot
Copper-Catalyzed Photocatalyst-Free Radical N -Glycosylation
inferred← citeshttps://doi.org/10.1021/acsomega.5c00189openalex-snapshot
Phenanthroline-Assisted Stereoselective Synthesis of 2-Deoxy Glycosides
inferred← citeshttps://doi.org/10.1021/bk-2026-1528.ch002openalex-snapshot
Recent Advances in O-Glycosylation
inferred← citeshttps://doi.org/10.1021/bk-2026-1528.ch013openalex-snapshot
An Insight into the Synthesis of Oligosaccharides Related to Acinetobacter sp. and Their Implications toward Human Health
inferred← citeshttps://doi.org/10.1021/jacs.4c15805openalex-snapshot
Gold(I)-Catalyzed 2-Deoxy-β-glycosylation via 1,2-Alkyl/Arylthio Migration: Synthesis of Velutinoside A Pentasaccharide
inferred← citeshttps://doi.org/10.1021/jacs.5c01845openalex-snapshot
Minimally Protected and Stereoselective O -Glycosylation of Carboxylic Acid Allows Rapid Access to α-1- O - and 2- O -Acyl Glycosides
inferred← citeshttps://doi.org/10.1021/jacs.6c00723openalex-snapshot
Partially Protected N -Acetylglycosamine Donors Enable Direct β- O -Glycosylation: Applications and Mechanistic Insights
inferred← citeshttps://doi.org/10.1021/jacs.6c10448openalex-snapshot
AgOTf-Assisted β-Glucuronidation Enables Convergent Synthesis of β-(1 → 4)-Linked Polyglucuronates up to the 32-Mer
inferred← citeshttps://doi.org/10.1021/jacsau.5c00574openalex-snapshot
First Total Synthesis and Bioactivity Study of Dumortierinoside A and Concinnoside D: Two Representative D/E-Ring Simultaneously Functionalized Oleanane-Type Triterpene Saponins
inferred← citeshttps://doi.org/10.1021/jacsau.5c00948openalex-snapshot
Hexafluoroisopropanol-Promoted Stereospecific Glycosylation Enables Efficient Access to N−O-Linked 1,2- cis -2-Amino Glycosides
inferred← citeshttps://doi.org/10.1038/s41467-023-39619-7openalex-snapshot
Efficient and versatile formation of glycosidic bonds via catalytic strain-release glycosylation with glycosyl ortho−2,2-dimethoxycarbonylcyclopropylbenzoate donors
inferred← citeshttps://doi.org/10.1038/s41467-024-54020-8openalex-snapshot
Catalyst-free and wavelength-tuned glycosylation based on excited-state intramolecular proton transfer
inferred← citeshttps://doi.org/10.1038/s41467-025-56445-1openalex-snapshot
Fe(OTf)3 or Photosensitizer-free blue light activated diazo-thioglycoside donors for Iterative and stereoselective glycosylations
inferred← citeshttps://doi.org/10.1038/s41467-025-63874-5openalex-snapshot
Direct and efficient synthesis of nucleosides through the ortho-(tert-butylethynyl)phenyl thioglycosides (BEPTs) protocol
inferred← citeshttps://doi.org/10.1039/d3sc06619copenalex-snapshot
Efficient O - and S -glycosylation with ortho -2,2-dimethoxycarbonylcyclopropylbenzyl thioglycoside donors by catalytic strain-release
inferred← citeshttps://doi.org/10.1039/d4ob00064aopenalex-snapshot
Thiourea-Cu(OTf) 2 /NIS-synergistically promoted stereoselective glycoside formation with 2-azidoselenoglycosides or thioglycosides as donors
inferred← citeshttps://doi.org/10.1039/d4qo00171kopenalex-snapshot
Electrochemically dehydrogenative C(sp 2 )–H/S–H cross-coupling: efficient synthesis of ortho -aminophenyl thioglycoside derivatives
inferred← citeshttps://doi.org/10.1039/d5qo01342aopenalex-snapshot
Glycosyl thiosulfonate-enabled ortho -thiolation via the Catellani strategy: a modular synthesis of polysubstituted aryl thioglycosides
inferred← citeshttps://doi.org/10.1055/a-2272-8163openalex-snapshot
Fragments Synthesis of A. baumannii ATCC 17961 O-Antigen
inferred← citeshttps://doi.org/10.1080/07328303.2024.2366774openalex-snapshot
Insight into gold-catalyzed glycosylation of glycosyl ynenoates
inferred← citeshttps://doi.org/10.1080/07328303.2025.2552365openalex-snapshot
Scalable synthesis of 8-iodo-1-naphthoate via photoinduced Suárez halodecarboxylation for the preparation of glycosyl donors
inferred← citeshttps://doi.org/10.1126/sciadv.adu7747openalex-snapshot
Nitrene-mediated glycosylation with thioglycoside donors under metal catalysis
inferred← citeshttps://doi.org/10.1126/sciadv.ady4274openalex-snapshot
Para -(3-phenylpropiolamido)phenyl (PPAP) glycosides: Harnessing ipso -cyclization–driven glycosylation for strategic flexibility
inferred← citeshttps://doi.org/10.1126/science.adk1111openalex-snapshot
Palladium catalysis enables cross-coupling–like S N 2-glycosylation of phenols
inferred← citeshttps://doi.org/10.1360/tb-2024-0471openalex-snapshot
Research progress on the chemical synthesis of carbohydrate antigens from three highly drug-resistant bacteria
inferred← citeshttps://doi.org/10.2174/0109298673340376241031041048openalex-snapshot
Recent Advances in Synthetic Strategies of Glycans and their Pharmaceutical Applications
inferred← citeshttps://doi.org/10.3390/molecules29225367openalex-snapshot
Catalytic Thioglycoside Activation with Diazo-Derived Copper Carbenes
inferred← citeshttps://doi.org/10.6023/cjoc202307001openalex-snapshot
Regio- and Stereo-selective Synthesis of 1β-/3R-Aryl Thiosugar
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